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Book of Abstrcts ICOSECS 8 University of Belgrade 8th International Conference Faculty of Technology and Metallurgy of the Chemical Societies Belgrade, Serbia, June 27-29, 2013 of the South-East European Countries BOOK OF ABSTRACTS organized by SAC - Society of Albanian Chemists Society of Chemists and Technologists of Macedonia - SCTM UCB - Union of Chemists in Bulgaria Chemical Society of Montenegro - CSM PUC - Pancyprian Union of Chemists Romanian Chemical Society - RCS AGC - Association of Greek Chemists Serbian Chemical Society - SCS CIP - Каталогизација у публикацији Народна библиотека Србије, Београд 54(048)(0.034.2) 577.1(048)(0.034.2) 66(048)(0.034.2) INTERNATIONAL Conference of the Chemical Societies of the South-East European Countries (8 ; 2013 ; Belgrade) Book of abstracts [Elektronski izvor] / 8th International Conference of the Chemical Societies of the South-East European Countries - ICOSECS 8, Belgrade, Serbia, June 27-29, 2013 ; [organized by the Society of Albanian Chemists ... et al. ; editors Sofija Sovilj, Aleksandar Dekanski]. - Belgrade : Serbian Chemical Society, 2013 (Belgrade : Faculty of Technology and Metallurgy). - 1 elektronski optički disk (CD-ROM) ; 12 cm Sistemski zahtevi: Adobe Reader. - Nasl. sa naslovne strane dokumenta. - Tiraž 250. - Bibliografija uz većinu radova. ISBN 978-86-7132-053-5 1. Society of Albanian Chemists a) Хемија - Апстракти b) Биохемија - Апстракти c) Хемијска технологија - Апстракти COBISS.SR-ID 199136780 ICOSECS 8 8th International Conference of the Chemical Societies of the South-East European Countries BOOK OF ABSTACTS Published by Serbian Chemical Society, Karnegijeva 4/III, 11120 Beograd PAK 135804, Srbija www.shd.org.rs, E-mail: [email protected] For Publisher Živoslav Tešić, president of the Society Editors Sofija Sovilj Aleksandar Dekanski Design & Computer Layout Aleksandar Dekanski ISBN 978-86-7132-053-5 Circulation 220 copies Copying Razvojno-istraživački centar grafičkog inženjerstva, Tehnološko-metalurški fakultet, Karnegijeva 4, Beograd, Srbija COUNCIL OF THE CONFERENCE Chairman: Ivanka Popović (SCS) Honorary Chairman: Nikos Katsaros (AGC) Željko Jaćimović (CSM), Svetomir Hadži-Jordanov (SCTM), Epaminondas Leontidis (PUC), Ilirjan Malollari (SAC), Sorin Roşca (RCS), Venko Beshkov (UCB) INTERNATIONAL SCIENTIFIC COMMITTEE Chairman: Sofija Sovilj (SCS) Members: Gheorghiţa Jinescu (RCS), Victor Corneliu Radu (RCS), Željko Jaćimović (CSM), Zoran Zdravkovski (SCTM), Elda Marku (SAC), Chavdar Bonev (UCB), Nikos Katsaros (AGC) INTERNATIONAL ORGANIZING COMMITTEE Chairman: Živoslav Tešić (SCS) Members: Corneliu Radu (RCS), Refik Zejnilović (CSM), Adem Bekteshi (SAC), Marina Stefova (SCTM), Nayden Naydenov (UCB) NATIONAL ORGANIZER Serbian Chemical Society (SCS) EXECUTIVE ORGANIZER CONTENTS Plenary Lectures Chemistry of Cluster Active Sites of Oxidoreductases Drawing a Lesson from the Brilliant Functions of the Enzymes for our Future Sustainable Society Kazuyuki Tatsumi _______________________________________________________________ 2 New bent-core liquid crystals, mesophases and structure-property relationship Katalin Fodor-Csorba ____________________________________________________________ 3 Invited Lectures Anticancer properties of nanostructured materials functionalized with metal complexes or natural products Santiago Gómez-Ruiz, Goran N. Kaluđerović, Damián Pérez-Quintanilla ____________________ 6 Visualization of Biological Processes Using Responsive MRI Contrast Agents Goran Angelovski _______________________________________________________________ 7 Mediterranean diet as a symbol of health and economic development Nikos Katsaros _________________________________________________________________ 8 Contributions 1. Breakthrough Science Synthesis O 01 BS-Sy Double N- and S-arylation for synthesis of azepine and thiepine derivatives Nina S. Božinović, Marija Vranić, Mikloš Tot, Igor Opsenica, Bogdan A. Šolaja ______________ 11 O 02 BS-Sy Development of a sinthetic route to corialstonidine Gordana Tasić, Nikola Vušurović, Milena Simić, Miloš Petković, Predrag Jovanović, Vladimir Savić ________________________________________________________________________ 12 O 03 BS-Sy Is the reduction of gold(III) ''culprit'' for its biological activity? Mirjana D. Đurović, Živadin D. Bugarčić and Rudi van Eldik _____________________________ 13 O 15 BS-Sy New derivatives of hydantoin as potential antiproliferative agents Sleem Hmuda, Nemanja Trišović, Jelena Rogan, Dejan Poleti, Biljana Božić, Gordana Ušćumlić ______________________________________________________________ 14 BS-Sy P01 Complex formation reactions of two sterically hindered Pt(II) complexes with some sulfur and nitrogen bonding ligands Enisa Selimović, Jovana Bogojeski, Biljana Petrović, Živadin D. Bugarčić ___________________ 15 ICOSECS 8 Contents BS-Sy P02 Synthesis of N,N-diethyl-1-ferrocenyl-3-thiabutanamine and its application in Suzuki- Miyaura cross coupling Dragana Stevanović, Anka Pejović, Ivan Damljanović, Mirjana Vukićević, Rastko D. Vukićević _____________________________________________________________ 16 BS-Sy P03 Synthesis and characterization of a gold(III) complex with isoamyl ester of (S,S)- ethylenediamine-N,N’-di-2-propionic acid N. Pantelić, B. B. Zmejkovski, A. Kostić, G. N. Kaluđerović, T. Sabo ________________________ 17 BS-Sy P04 Synthesis and structural characterization of four new Pd complexes with N,N-donor ligands Jelena Poljarević, Sanja Grgurić-Šipka, Tibor Sabo ____________________________________ 18 BS-Sy P05 Synthesis and cytotoxic investigation of new Pt(II) and Pt(IV) complexes with thiacyclopentane- and thiacylohexanespiro-5’-hydantoins Adriana G. Bakalova, Hristo Pl. Varbanov, Rossen Buyukliev, Georgi Zv. Momekov, Darvin S. Ivanov _______________________________________________________________ 19 BS-Sy P06 Design and synthesis of new potential anticancer agent – 4-methoxy-salicylaldehyde isonicotinoylhydrazone Boriana I. Nikolova-Mladenova, Georgi Zv. Momekov, Darvin S. Ivanov ___________________ 20 BS-Sy P07 Reactions of tetrahydro-isoquinolines N-ylides with non-symmetrical dipolarophiles Mino R. Caira, Marcel M. Popa, Denisa Dumitrescu, Florea Dumitrascu, Constantin Draghici ____________________________________________________________ 21 BS-Sy P08 Interaction of Ru(II)-terpyridine complexes with some nitrogen- and sulfur-donor ligands Ana Rilak and Živadin D. Bugarčić _________________________________________________ 22 BS-Sy P09 Synthesis and structure of copper(II) complex with pyridoxal S-methylisothiosemicarbazone Marko V. Rodić, Ljiljana S. Vojinović-Ješić, Sonja A. Ivković, Vukadin M. Leovac _____________ 23 BS-Sy P10 Synthesis of some new oximino-D-modified androstane derivatives Andrea R. Nikolić, Marina P. Savić, Jovana J. Ajduković, Aleksandar M. Oklješa, Evgenija A. Djurendić, Katarina M. Penov-Gaši, Marija N. Sakač _________________________ 24 BS-Sy P11 Microwave assisted reduction of individual naphthenic acids Ksenija J. Pavlović, Ljubica M. Grbović, Bojana R. Prekodravac, Mirjana M. Popsavin, Slavko E. Kevrešan, Vera S. Ćirin-Novta, Branko B. Kordić ______________________________ 25 BS-Sy P12 Microwave-assisted oxidation of bile acids by Oxone/AlCl3 in water Bojana R. Vasiljević, Dušan Đ. Škorić, Marija N. Sakač, Janoš J. Čanadi ____________________ 26 BS-Sy P13 Synthesis and antiproliferative activity of secoandrostane 17-mesilates Aleksandar Oklješa, Suzana Jovanović-Šanta, Dimitar Jakimov, L. Aleksić, Evgenija Djurendić, Marija Sakač, Katarina Penov-Gaši ________________________________ 27 page v ICOSECS 8 Contents BS-Sy P14 Evaluation of passive human skin permeability and human skin retention of newly synthesized 17carboxamide derivatives of methylprednisolone using PAMPA test Vladimir Dobričić, Bojan Marković, Sote Vladimirov, Olivera Čudina ______________________ 28 BS-Sy P15 Synthesis of Warfarin derivatives (Aa A Blood Anticoagulant) Catalyzed under Preyssler Heteropolyacids Ali Gharib, Manouchehr Jahangir, Mina Roshani _____________________________________ 29 BS-Sy P16 Solvent and substituent effects on azo-hydrazone tautomerism of some arylazo pyridone dyes Jelena Mirković, Gordana Ušćumilić, Dušan Mijin _____________________________________ 30 BS-Sy P17 Preparation and spectral characterization of Pt(II) and Pt(IV) dithiocarbamato complexes Danijela Vojta, Milica Kosović, Marijana Đaković, Aleksandar Višnjevac, Zorica Leka ________ 31 BS-Sy P18 Synthesis and structure of copper(II) complex with pyridoxalaminoguanidine and 4-picoline Mirjana M. Radanović, Marko V. Rodić, Ljiljana S. Vojinović-Ješić, Vukadin M. Leovac _______ 32 BS-Sy P19 Antioxidant, antiproliferative and enzyme inhibition activity of new salicyloyloxy androstane derivatives Suzana Jovanović-Šanta, Evgenija A. Đurendić, Marija N. Sakač, Imre Ignáth, Mihály Szécsi, Andrea R. Nikolić, Jovana J. Ajduković, Olivera Klisurić, Katarina M. Penov-Gaši ____________ 33 BS-Sy P20 Solvent-free amidation of naphthenic acids under microwave irradiation Bojana R. Vasiljević, Ljubica M. Grbović, Ksenija J. Pavlović, Mirjana M. Popsavin, Slavko E. Kevrešan, Vera S. Ćirin-Novta _____________________________________________ 34 BS-Sy P21 Reactivity of some oxo bile acids oxazolines in Wittig reaction Srđan Bjedov, Dušan Škorić, Janoš Čanadi, Marija Sakač _______________________________ 35 BS-Sy P22 Synthesis and anti-proliferative activity of new heterocyclic androstane compounds Aleksandar Oklješa, Jovana Ajduković, Dimitar Jakimov, Marina Savić, Andrea Nikolić, Katarina Penov-Gaši, Evgenija Đurendić, Marija
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