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Polyurethanes Technical Conference 2016

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Polyurethanes Technical Conference 2016 Polyurethanes Technical Conference 2016 Baltimore, Maryland, USA 26 - 28 September 2016 ISBN: 978-1-5108-3172-8 Printed from e-media with permission by: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 Some format issues inherent in the e-media version may also appear in this print version. Copyright© (2016) by American Chemistry Council All rights reserved. Printed by Curran Associates, Inc. (2016) For permission requests, please contact American Chemistry Council at the address below. American Chemistry Council 700 Second St., NE Washington, DC 20002 USA Phone: (202) 249-7000 Fax: (202) 249-6100 www.americanchemistry.com Additional copies of this publication are available from: Curran Associates, Inc. 57 Morehouse Lane Red Hook, NY 12571 USA Phone: 845-758-0400 Fax: 845-758-2633 Email: [email protected] Web: www.proceedings.com TABLE OF CONTENTS PAPERS AUTOMOTIVE I Vehicle Interior Air Quality - VDA 278 and Beyond..........................................................................................................1 Caroline Widdowson, Ilaria Ferrante, Massimo Santoro Aldehyde Emissions from Flexible Molded Foam...............................................................................................................5 Jennifer Al-Rashid, Torsten Panitzsch, Jackson Su, Gauri Sankar Lal, Allen Arnold L-Shaped Air Flush Spray Mixing Heads for the Production of Lightweight Automotive Components..................... 16 Andrea Bartolini, Alessandro Colella AUTOMOTIVE II Enabling Automotive Light Weighting by Reducing Foam Thickness in Instrument Panels ....................................... 34 Kelly Kiszka, Joe McCormick, Kevin Murphy Evaluation of Cast PVC Processing Conditions for Improved Adhesion to Polyurethane Foam ................................. 47 Robert Bondar, Brent Cassata Dynamic Comfort and Vibration Damping with Polyurethane Foams........................................................................... 60 Mark Brennan, Maarten Moesen, Martino Dossi, Jan Vandenbroeck Latest Developments on Stabilization Systems for Polyurethanes in Automotive Applications ................................... 74 Cinzia Tartarini, Gregor Huber, Jason Yuan BLOWING AGENTS Recent Appliance Development of Opteon™ 1100 - a Zero ODP and Low GWP Foam Expansion Agent..................................................................................................................................................................................... 90 Gary Loh, Saadat Ata, Margaret (Peg) Van Slyke Methylal: A Solution to Recent Regulations on Blowing Agents ................................................................................... 107 Michel Beaujean, Laurent Godefroid The Impact of Amine Catalyst in Hydrohaloolefin Blown Rigid Polyurethane Foam Systems .................................. 121 Yusuke Sesoko, Katsumi Tokumoto B-Side Flammability and Its Implications in Spray Foam Applications....................................................................... 131 Mark Robin, Michael Fraser, Margaret Van Slyke, Saadat Ata, Bruce Hitchens, Gary Loh HFO-1234ze(E) .................................................................................................................................................................. 145 Mojee Cline, Andrew Shinko CASE: COATINGS & ADHESIVES One-component Polyurethane Roofing Adhesive Formulation with the Hydrofluoroolefin, HFO- 1234ze ................................................................................................................................................................................. 157 Megan Thomas, Michelle Hudack, Steven Erio, Herb Reffert, Steven Moskowitz Adhesive Technologies Using Recycled/Renewable Based Polyester Polyols................................................................ 170 Woo-Sung Bae, Mike Christy, Brian Reid High-Performance Polyurethane Coatings and Elastomers from C18-Based Polyols ................................................. 185 Allyson Beuhler, Paul Bertin, Jonathan Brekin, Zhe Wang, Debra Tindall Research on Film Properties of IPDI Based PUDs in Different Kind of Catalyst Systems ......................................... 193 Hao Tian Zhang CASE: TPU & ELASTOMERS Conventional and Reduced-Free Prepolymers Based on trans-1,4-H6XDI: Elastomer Physical/Mechanical Properties, Dynamic Performance and Chemical/Solvent Resistance....................................... 199 Steve Seneker, Robert Czeiszperger, Jordan Duckett, Elizabeth June Formulating of Industrial Elastomer with Exclusive Acid/Alkali Resistance............................................................... 211 Jayant Khadilkar, Kiseok Yu, Sudhir Kamble, Dongyul Jeon CHEMISTRY AND FUNDAMENTALS Impact of Mass Transfer Limitation of Polyurethane Reactions................................................................................... 228 Harith Al-Moameri, Galen Suppes Insights from a Half-Decade of Urethane Reaction Simulation Development.............................................................. 239 Galen Suppes, Harith Al-Moameri Modified Lignin as a Main Composition for a New Generation of Polyurethane Rigid Foams.................................. 245 Abdelkader Benhalima, Damien Maillard, Minh-Tan Ton-That, Karen Stoeffler CONSTRUCTION I The Benefits and Advantages of Using CO2 Based Polyols in Rigid Insulation Foam Applications .......................... 255 Michael Nagridge, Christopher Fordice, Kimberly Jaskula, Simon Waddington Improved Thermal Insulation Performance of Polyisocyanurate Foam Using Isocyanate Prepolymers................... 271 Kshitish Patankar, Steven Crain, Mark Sonnenschein, Tina Rhoton, Todd Pangburn Advances in Aromatic Polyester Polyols for Polyisocyanurate Thermal Insulation Board ........................................ 283 Sachchida Singh, David Shieh, Jason Eubank, Richard Donald, Paul Coleman, Jerry Pilgrim Water Soluble Bismuth Based Curatives with Remarkable Activity and Shelf Life.................................................... 302 Nathan Eckert, Robert Hart CONSTRUCTION II Novel Cardanol-Based Polyols and Their Use in Rigid Polyurethane Foams............................................................... 312 Anbu Natesh, Pietro Campaner Renewable and Engineered EMEROX® Polyols for Spray Polyurethane Foam Applications .................................. 321 Jeff Sowder, Bryan King, Joe Lynch Rigid Polyurethane Foams Used in Artificial Wood Roofing Materials ....................................................................... 334 Daniel Heberer, Michael Anderson, David Bareis, Paul Mallorey GreenSuite® Risk Assessments of Three Spray Polyurethane Systems........................................................................ 340 George Thompson ENVIRONMENT, HEALTH AND SAFETY CPI Spray Polyurethane Foam Product Stewardship Update....................................................................................... 353 William Robert, Heather Palfrey Lessons Learned From Spray Polyurethane Foam Emission Testing Using Micro-Chambers .................................. 357 Dustin Poppendieck, Mengyan Gong, Lauren Lawson Research Activities to Support the Development of ASTM Standards to Measure Emissions from Spray Polyurethane Foam (SPF)...................................................................................................................................... 368 John Sebroski, Jason Miller, Diana Kelley Industrial Hygiene Monitoring During Residential Atticís and Crawl Space Insulation Upgrade with Open Cell and Closed Cell Spray Polyurethane Foam................................................................................................... 395 William Robert, Jim Andersen, Richard Wood, James Tocyloski FLAME RETARDANTS Review of the Scientific Basis for the Report "Healthy Environments: Strategies for Avoiding Flame Retardants in the Built Environment"............................................................................................................................. 429 Thomas Osimitz, Wiebke Droege New Flame Retardants Developments for the Flexible Foam Market .......................................................................... 454 Zhihao Chen, Jeffrey Stowell, Munjal Patel FLEXIBLE FOAMS: RENEWABLE POLYOLS Final Steps on the Route to Commercialization of CO2-Based Polyols for Flexible Foam ......................................... 464 Karsten Malsch, Lutz Brassat, John Hayes, Susan Mcvey Bio-Based Ester Polyol for Flexible Foam Applications................................................................................................. 478 Michael Brooks, Bryan King, Greg Hunt Next Generation Agrol® Polyols ...................................................................................................................................... 491 Carlotta Paulsen, Rick Speas, Neil Nodelman Bio Renewable, High Performance Polyols ..................................................................................................................... 499 Matt Terwillegar FLEXIBLE FOAMS New Cell Structure Control Technology for Ultra-High Air Flow Viscoelastic Polyurethane Foam ......................... 510 Kaoru Aou, Harper Meng, Christopher Thiede, Dale Hunter, Van Delk Jr., Michelle Thomas The Adjustment of Physical Properties of Viscoelastic Foam - the Role of Different Raw Materials ........................ 518 Michael Krebs, Roland Hubel SPRAY POLYURETHANE FOAM A Characterization of the Susceptibility of Various Types of Spray Foam Insulation to the Growth of Mold in Wall Cavities.......................................................................................................................................................
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