Neopentyl Glycol Flake 10470 Version / Revision 3.01 Revision Date 15-Dec-2020 Supersedes Version 3.00*** Issuing Date 15-Dec-2020 ______
Total Page:16
File Type:pdf, Size:1020Kb
SAFETY DATA SHEET Neopentyl glycol flake 10470 Version / Revision 3.01 Revision Date 15-Dec-2020 Supersedes Version 3.00*** Issuing date 15-Dec-2020 ___________________________________________________________________________________________ SECTION 1: Identification of the substance / mixture and of the company / undertaking 1.1. Product identifier Identification of the substance/preparation Neopentyl glycol flake Chemical Name 2,2-Dimethylpropane-1,3-diol CAS-No 126-30-7 EC No. 204-781-0 Registration number (REACh) 01-2119480396-30 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Intermediate Formulation Distribution of substance laboratory chemicals Polymerization coatings Road and construction applications Uses advised against None 1.3. Details of the supplier of the safety data sheet Company/Undertaking OQ Chemicals GmbH Identification Rheinpromenade 4A D-40789 Monheim Germany Product Information Product Stewardship FAX: +49 (0)208 693 2053 email: [email protected] 1.4. Emergency telephone number Emergency telephone number +44 (0) 1235 239 671 (UK) available 24/7 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture This substance is classified based on Directive 1272/2008/EC and its amendments (CLP Regulation) Serious eye damage/eye irritation Category 1, H318 Additional information For full text of Hazard- and EU Hazard-statements see SECTION 16. 2.2. Label elements ___________________________________________________________________________________________ 1 / 14 Africa and Asia (IAF) /EN SAFETY DATA SHEET 10470 Revision Date 15-Dec-2020 Neopentyl glycol flake Version / Revision 3.01 ___________________________________________________________________________________________ Labelling according to Regulation 1272/2008/EC and its amendments (CLP Regulation). Hazard pictograms Signal word Danger Hazard statements H318: Causes serious eye damage. Precautionary statements P280: Wear protective gloves/protective clothing/eye protection/face protection. P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310: Immediately call a POISON CENTER/doctor. 2.3. Other hazards Dust can form an explosive mixture in air Components of the product may be absorbed into the body by inhalation and ingestion PBT and vPvB assessment This substance is not considered to be persistent, bioaccumulating nor toxic (PBT), nor very persistent nor very bioaccumulating (vPvB) SECTION 3: Composition / information on ingredients 3.1. Substances Component CAS-No REACh-No 1272/2008/EC Concentration (%) 2,2-Dimethylpropane-1,3-di 126-30-7 01-2119480396-30 Eye Dam. 1; H318 > 99,0 ol For full text of Hazard- and EU Hazard-statements see SECTION 16. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation Keep at rest. Aerate with fresh air. When symptoms persist or in all cases of doubt seek medical advice. Eyes Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Immediate medical attention is required. Skin Wash off immediately with plenty of water. When symptoms persist or in all cases of doubt seek medical advice. Ingestion Call a physician immediately. Do not induce vomiting without medical advice. ___________________________________________________________________________________________ 2 / 14 Africa and Asia (IAF) /EN SAFETY DATA SHEET 10470 Revision Date 15-Dec-2020 Neopentyl glycol flake Version / Revision 3.01 ___________________________________________________________________________________________ 4.2. Most important symptoms and effects, both acute and delayed Main symptoms cough. Special hazard Lung irritation. 4.3. Indication of any immediate medical attention and special treatment needed General advice Remove contaminated, soaked clothing immediately and dispose of safely. First aider needs to protect himself. Treat symptomatically. If ingested, irrigate the stomach using activated charcoal. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media foam, dry chemical, carbon dioxide (CO2), water spray Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire. 5.2. Special hazards arising from the substance or mixture Under conditions giving incomplete combustion, hazardous gases produced may consist of: carbon monoxide (CO) carbon dioxide (CO2) Combustion gases of organic materials must in principle be graded as inhalation poisons Dust can form an explosive mixture in air 5.3. Advice for firefighters Special protective equipment for firefighters Fire fighter protection should include a self-contained breathing apparatus (NIOSH-approved or EN 133) and full fire-fighting turn out gear. Precautions for firefighting Cool containers / tanks with water spray. Dike and collect water used to fight fire. Keep people away from and upwind of fire. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel: For personal protective equipment see section 8. Avoid contact with skin and eyes. Do not breathe dust. Keep people away from and upwind of spill/leak. Ensure adequate ventilation, especially in confined areas. Keep away from heat and sources of ignition. For emergency responders: Personal protection see section 8. 6.2. Environmental precautions ___________________________________________________________________________________________ 3 / 14 Africa and Asia (IAF) /EN SAFETY DATA SHEET 10470 Revision Date 15-Dec-2020 Neopentyl glycol flake Version / Revision 3.01 ___________________________________________________________________________________________ Prevent further leakage or spillage. Do not discharge product into the aquatic environment without pretreatment (biological treatment plant). 6.3. Methods and material for containment and cleaning up Methods for containment Stop the flow of material, if possible without risk. Dike spilled material, where this is possible. Methods for cleaning up Use mechanical handling equipment. Avoid dust formation. Keep in suitable, closed containers for disposal. Dispose of in accordance with local regulations. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). 6.4. Reference to other sections For personal protective equipment see section 8. SECTION 7: Handling and storage 7.1. Precautions for safe handling Advice on safe handling Avoid dust formation. Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. Provide sufficient air exchange and/or exhaust in work rooms. Hygiene measures When using, do not eat, drink or smoke. Take off all contaminated clothing immediately. Wash hands before breaks and immediately after handling the product. Advice on the protection of the environment See Section 8: Environmental exposure controls. Incompatible products strong oxidizing agents 7.2. Conditions for safe storage, including any incompatibilities Advice on protection against fire and explosion Risk of dust explosion in fine crystalline powder form. Dust can form an explosive mixture in air. Keep away from sources of ignition - No smoking. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). In case of fire, emergency cooling with water spray should be available. Ground and bond containers when transferring material. Technical measures/Storage conditions Keep containers tightly closed in a cool, well-ventilated place. Handle and open container with care. Protect from moisture. Temperature class T2 7.3. Specific end use(s) Intermediate Formulation ___________________________________________________________________________________________ 4 / 14 Africa and Asia (IAF) /EN SAFETY DATA SHEET 10470 Revision Date 15-Dec-2020 Neopentyl glycol flake Version / Revision 3.01 ___________________________________________________________________________________________ Distribution of substance laboratory chemicals Polymerization coatings Road and construction applications SECTION 8: Exposure controls / personal protection 8.1. Control parameters Exposure limits Egypt Egypt OELs; Threshold limits of air pollutants in the workplace (Decree No. 338, Annex 8) Component TWA TWA STEL STEL (mg/m³) (ppm) (mg/m³) (ppm) Dust, general threshold limit 10 value (inhalable fraction) CAS: - Dust, general threshold limit 3 value (respirable fraction) CAS: - Exposure limits Israel Israel OELs Component TWA TWA STEL STEL (mg/m³) (ppm) (mg/m³) (ppm) Dust, general threshold limit 10 value (inhalable fraction) CAS: - Dust, general threshold limit 3 value (respirable fraction) CAS: - Exposure limits South Africa South Africa OELs; Recommended exposure limits Component TWA TWA STEL STEL (mg/m³) (ppm) (mg/m³) (ppm) Dust, general threshold limit 10 value (inhalable fraction) CAS: - Dust, general threshold limit 5 value (respirable fraction) CAS: - Exposure limits United Arab Emirates United Arab Emirates OELs Component TWA TWA STEL STEL (mg/m³) (ppm) (mg/m³) (ppm) ___________________________________________________________________________________________ 5 / 14 Africa and Asia (IAF) /EN SAFETY DATA SHEET 10470 Revision Date 15-Dec-2020 Neopentyl glycol flake Version / Revision 3.01 ___________________________________________________________________________________________ Dust, general threshold