The Double Cover of the Icosahedral Symmetry Group and Quark Mass
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Symmetry of Fulleroids Stanislav Jendrol’, František Kardoš
Symmetry of Fulleroids Stanislav Jendrol’, František Kardoš To cite this version: Stanislav Jendrol’, František Kardoš. Symmetry of Fulleroids. Klaus D. Sattler. Handbook of Nanophysics: Clusters and Fullerenes, CRC Press, pp.28-1 - 28-13, 2010, 9781420075557. hal- 00966781 HAL Id: hal-00966781 https://hal.archives-ouvertes.fr/hal-00966781 Submitted on 27 Mar 2014 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Symmetry of Fulleroids Stanislav Jendrol’ and Frantiˇsek Kardoˇs Institute of Mathematics, Faculty of Science, P. J. Saf´arikˇ University, Koˇsice Jesenn´a5, 041 54 Koˇsice, Slovakia +421 908 175 621; +421 904 321 185 [email protected]; [email protected] Contents 1 Symmetry of Fulleroids 2 1.1 Convexpolyhedraandplanargraphs . .... 3 1.2 Polyhedral symmetries and graph automorphisms . ........ 4 1.3 Pointsymmetrygroups. 5 1.4 Localrestrictions ............................... .. 10 1.5 Symmetryoffullerenes . .. 11 1.6 Icosahedralfulleroids . .... 12 1.7 Subgroups of Ih ................................. 15 1.8 Fulleroids with multi-pentagonal faces . ......... 16 1.9 Fulleroids with octahedral, prismatic, or pyramidal symmetry ........ 19 1.10 (5, 7)-fulleroids .................................. 20 1 Chapter 1 Symmetry of Fulleroids One of the important features of the structure of molecules is the presence of symmetry elements. -
Arxiv:2006.00374V4 [Math.GT] 28 May 2021
CONTROLLED MATHER-THURSTON THEOREMS MICHAEL FREEDMAN ABSTRACT. Classical results of Milnor, Wood, Mather, and Thurston produce flat connections in surprising places. The Milnor-Wood inequality is for circle bundles over surfaces, whereas the Mather-Thurston Theorem is about cobording general manifold bundles to ones admitting a flat connection. The surprise comes from the close encounter with obstructions from Chern-Weil theory and other smooth obstructions such as the Bott classes and the Godbillion-Vey invariant. Contradic- tion is avoided because the structure groups for the positive results are larger than required for the obstructions, e.g. PSL(2,R) versus U(1) in the former case and C1 versus C2 in the latter. This paper adds two types of control strengthening the positive results: In many cases we are able to (1) refine the Mather-Thurston cobordism to a semi-s-cobordism (ssc) and (2) provide detail about how, and to what extent, transition functions must wander from an initial, small, structure group into a larger one. The motivation is to lay mathematical foundations for a physical program. The philosophy is that living in the IR we cannot expect to know, for a given bundle, if it has curvature or is flat, because we can’t resolve the fine scale topology which may be present in the base, introduced by a ssc, nor minute symmetry violating distortions of the fiber. Small scale, UV, “distortions” of the base topology and structure group allow flat connections to simulate curvature at larger scales. The goal is to find a duality under which curvature terms, such as Maxwell’s F F and Hilbert’s R dvol ∧ ∗ are replaced by an action which measures such “distortions.” In this view, curvature resultsR from renormalizing a discrete, group theoretic, structure. -
The Classification and the Conjugacy Classesof the Finite Subgroups of The
Algebraic & Geometric Topology 8 (2008) 757–785 757 The classification and the conjugacy classes of the finite subgroups of the sphere braid groups DACIBERG LGONÇALVES JOHN GUASCHI Let n 3. We classify the finite groups which are realised as subgroups of the sphere 2 braid group Bn.S /. Such groups must be of cohomological period 2 or 4. Depend- ing on the value of n, we show that the following are the maximal finite subgroups of 2 Bn.S /: Z2.n 1/ ; the dicyclic groups of order 4n and 4.n 2/; the binary tetrahedral group T ; the binary octahedral group O ; and the binary icosahedral group I . We give geometric as well as some explicit algebraic constructions of these groups in 2 Bn.S / and determine the number of conjugacy classes of such finite subgroups. We 2 also reprove Murasugi’s classification of the torsion elements of Bn.S / and explain 2 how the finite subgroups of Bn.S / are related to this classification, as well as to the 2 lower central and derived series of Bn.S /. 20F36; 20F50, 20E45, 57M99 1 Introduction The braid groups Bn of the plane were introduced by E Artin in 1925[2;3]. Braid groups of surfaces were studied by Zariski[41]. They were later generalised by Fox to braid groups of arbitrary topological spaces via the following definition[16]. Let M be a compact, connected surface, and let n N . We denote the set of all ordered 2 n–tuples of distinct points of M , known as the n–th configuration space of M , by: Fn.M / .p1;:::; pn/ pi M and pi pj if i j : D f j 2 ¤ ¤ g Configuration spaces play an important roleˆ in several branches of mathematics and have been extensively studied; see Cohen and Gitler[9] and Fadell and Husseini[14], for example. -
Torsion Homology and Cellular Approximation 11
TORSION HOMOLOGY AND CELLULAR APPROXIMATION RAMON´ FLORES AND FERNANDO MURO Abstract. In this note we describe the role of the Schur multiplier in the structure of the p-torsion of discrete groups. More concretely, we show how the knowledge of H2G allows to approximate many groups by colimits of copies of p-groups. Our examples include interesting families of non-commutative infinite groups, including Burnside groups, certain solvable groups and branch groups. We also provide a counterexample for a conjecture of E. Farjoun. 1. Introduction Since its introduction by Issai Schur in 1904 in the study of projective representations, the Schur multiplier H2(G, Z) has become one of the main invariants in the context of Group Theory. Its importance is apparent from the fact that its elements classify all the central extensions of the group, but also from his relation with other operations in the group (tensor product, exterior square, derived subgroup) or its role as the Baer invariant of the group with respect to the variety of abelian groups. This last property, in particular, gives rise to the well- known Hopf formula, which computes the multiplier using as input a presentation of the group, and hence has allowed to use it in an effective way in the field of computational group theory. A brief and concise account to the general concept can be found in [38], while a thorough treatment is the monograph by Karpilovsky [33]. In the last years, the close relationship between the Schur multiplier and the theory of co-localizations of groups, and more precisely with the cellular covers of a group, has been remarked. -
The Cubic Groups
The Cubic Groups Baccalaureate Thesis in Electrical Engineering Author: Supervisor: Sana Zunic Dr. Wolfgang Herfort 0627758 Vienna University of Technology May 13, 2010 Contents 1 Concepts from Algebra 4 1.1 Groups . 4 1.2 Subgroups . 4 1.3 Actions . 5 2 Concepts from Crystallography 6 2.1 Space Groups and their Classification . 6 2.2 Motions in R3 ............................. 8 2.3 Cubic Lattices . 9 2.4 Space Groups with a Cubic Lattice . 10 3 The Octahedral Symmetry Groups 11 3.1 The Elements of O and Oh ..................... 11 3.2 A Presentation of Oh ......................... 14 3.3 The Subgroups of Oh ......................... 14 2 Abstract After introducing basics from (mathematical) crystallography we turn to the description of the octahedral symmetry groups { the symmetry group(s) of a cube. Preface The intention of this account is to provide a description of the octahedral sym- metry groups { symmetry group(s) of the cube. We first give the basic idea (without proofs) of mathematical crystallography, namely that the 219 space groups correspond to the 7 crystal systems. After this we come to describing cubic lattices { such ones that are built from \cubic cells". Finally, among the cubic lattices, we discuss briefly the ones on which O and Oh act. After this we provide lists of the elements and the subgroups of Oh. A presentation of Oh in terms of generators and relations { using the Dynkin diagram B3 is also given. It is our hope that this account is accessible to both { the mathematician and the engineer. The picture on the title page reflects Ha¨uy'sidea of crystal structure [4]. -
Systematics of Atomic Orbital Hybridization of Coordination Polyhedra: Role of F Orbitals
molecules Article Systematics of Atomic Orbital Hybridization of Coordination Polyhedra: Role of f Orbitals R. Bruce King Department of Chemistry, University of Georgia, Athens, GA 30602, USA; [email protected] Academic Editor: Vito Lippolis Received: 4 June 2020; Accepted: 29 June 2020; Published: 8 July 2020 Abstract: The combination of atomic orbitals to form hybrid orbitals of special symmetries can be related to the individual orbital polynomials. Using this approach, 8-orbital cubic hybridization can be shown to be sp3d3f requiring an f orbital, and 12-orbital hexagonal prismatic hybridization can be shown to be sp3d5f2g requiring a g orbital. The twists to convert a cube to a square antiprism and a hexagonal prism to a hexagonal antiprism eliminate the need for the highest nodality orbitals in the resulting hybrids. A trigonal twist of an Oh octahedron into a D3h trigonal prism can involve a gradual change of the pair of d orbitals in the corresponding sp3d2 hybrids. A similar trigonal twist of an Oh cuboctahedron into a D3h anticuboctahedron can likewise involve a gradual change in the three f orbitals in the corresponding sp3d5f3 hybrids. Keywords: coordination polyhedra; hybridization; atomic orbitals; f-block elements 1. Introduction In a series of papers in the 1990s, the author focused on the most favorable coordination polyhedra for sp3dn hybrids, such as those found in transition metal complexes. Such studies included an investigation of distortions from ideal symmetries in relatively symmetrical systems with molecular orbital degeneracies [1] In the ensuing quarter century, interest in actinide chemistry has generated an increasing interest in the involvement of f orbitals in coordination chemistry [2–7]. -
Chapter 1 – Symmetry of Molecules – P. 1
Chapter 1 – Symmetry of Molecules – p. 1 - 1. Symmetry of Molecules 1.1 Symmetry Elements · Symmetry operation: Operation that transforms a molecule to an equivalent position and orientation, i.e. after the operation every point of the molecule is coincident with an equivalent point. · Symmetry element: Geometrical entity (line, plane or point) which respect to which one or more symmetry operations can be carried out. In molecules there are only four types of symmetry elements or operations: · Mirror planes: reflection with respect to plane; notation: s · Center of inversion: inversion of all atom positions with respect to inversion center, notation i · Proper axis: Rotation by 2p/n with respect to the axis, notation Cn · Improper axis: Rotation by 2p/n with respect to the axis, followed by reflection with respect to plane, perpendicular to axis, notation Sn Formally, this classification can be further simplified by expressing the inversion i as an improper rotation S2 and the reflection s as an improper rotation S1. Thus, the only symmetry elements in molecules are Cn and Sn. Important: Successive execution of two symmetry operation corresponds to another symmetry operation of the molecule. In order to make this statement a general rule, we require one more symmetry operation, the identity E. (1.1: Symmetry elements in CH4, successive execution of symmetry operations) 1.2. Systematic classification by symmetry groups According to their inherent symmetry elements, molecules can be classified systematically in so called symmetry groups. We use the so-called Schönfliess notation to name the groups, Chapter 1 – Symmetry of Molecules – p. 2 - which is the usual notation for molecules. -
A Symplectic Resolution for the Binary Tetrahedral Group
A SYMPLECTIC RESOLUTION FOR THE BINARY TETRAHEDRAL GROUP MANFRED LEHN & CHRISTOPH SORGER Abstract. We describe an explicit symplectic resolution for the quo- tient singularity arising from the four-dimensional symplectic represen- ation of the binary tetrahedral group. Let G be a nite group with a complex symplectic representation V . The symplectic form σ on V descends to a symplectic form σ¯ on the open regular part of V=G. A proper morphism f : Y ! V=G is a symplectic resolution if Y is smooth and if f ∗σ¯ extends to a symplectic form on Y . It turns out that symplectic resolutions of quotient singularities are a rare phenomenon. By a theorem of Verbitsky [9], a necessary condition for the existence of a symplectic resolution is that G be generated by symplectic reections, i.e. by elements whose x locus on V is a linear subspace of codimension 2. Given an arbitrary complex representation V0 of a nite group G, we obtain a symplectic representation on ∗, where ∗ denotes the contragradient V0 ⊕V0 V0 representation of V0. In this case, Verbitsky's theorem specialises to an earlier theorem of Kaledin [7]: For ∗ to admit a symplectic resolution, the V0 ⊕ V0 =G action of G on V0 should be generated by complex reections, in other words, V0=G should be smooth. The complex reection groups have been classied by Shephard and Todd [8], the symplectic reection groups by Cohen [2]. The list of Shephard and Todd contains as a sublist the nite Coxeter groups. The question which of these groups G ⊂ Sp(V ) admits a symplectic res- olution for V=G has been solved for the Coxeter groups by Ginzburg and Kaledin [3] and for arbitrary complex reection groups most recently by Bellamy [1]. -
Can Every Face of a Polyhedron Have Many Sides ?
Can Every Face of a Polyhedron Have Many Sides ? Branko Grünbaum Dedicated to Joe Malkevitch, an old friend and colleague, who was always partial to polyhedra Abstract. The simple question of the title has many different answers, depending on the kinds of faces we are willing to consider, on the types of polyhedra we admit, and on the symmetries we require. Known results and open problems about this topic are presented. The main classes of objects considered here are the following, listed in increasing generality: Faces: convex n-gons, starshaped n-gons, simple n-gons –– for n ≥ 3. Polyhedra (in Euclidean 3-dimensional space): convex polyhedra, starshaped polyhedra, acoptic polyhedra, polyhedra with selfintersections. Symmetry properties of polyhedra P: Isohedron –– all faces of P in one orbit under the group of symmetries of P; monohedron –– all faces of P are mutually congru- ent; ekahedron –– all faces have of P the same number of sides (eka –– Sanskrit for "one"). If the number of sides is k, we shall use (k)-isohedron, (k)-monohedron, and (k)- ekahedron, as appropriate. We shall first describe the results that either can be found in the literature, or ob- tained by slight modifications of these. Then we shall show how two systematic ap- proaches can be used to obtain results that are better –– although in some cases less visu- ally attractive than the old ones. There are many possible combinations of these classes of faces, polyhedra and symmetries, but considerable reductions in their number are possible; we start with one of these, which is well known even if it is hard to give specific references for precisely the assertion of Theorem 1. -
Maximal Subgroups of the Coxeter Group W(H4) and Quaternions
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Elsevier - Publisher Connector Linear Algebra and its Applications 412 (2006) 441–452 www.elsevier.com/locate/laa Maximal subgroups of the Coxeter group W(H4) and quaternions Mehmet Koca a, Ramazan Koç b,∗, Muataz Al-Barwani a, Shadia Al-Farsi a aDepartment of Physics, College of Science, Sultan Qaboos University, P.O. Box 36, Al-Khod 123, Muscat, Oman bDepartment of Physics, Faculty of Engineering, Gaziantep University, 27310 Gaziantep, Turkey Received 9 October 2004; accepted 17 July 2005 Available online 12 September 2005 Submitted by H. Schneider Abstract The largest finite subgroup of O(4) is the non-crystallographic Coxeter group W(H4) of order 14,400. Its derived subgroup is the largest finite subgroup W(H4)/Z2 of SO(4) of order 7200. Moreover, up to conjugacy, it has five non-normal maximal subgroups of orders 144, two 240, 400 and 576. Two groups [W(H2) × W(H2)]Z4 and W(H3) × Z2 possess non- crystallographic structures with orders 400 and 240 respectively. The groups of orders 144, 240 and 576 are the extensions of the Weyl groups of the root systems of SU(3) × SU(3), SU(5) and SO(8) respectively. We represent the maximal subgroups of W(H4) with sets of quaternion pairs acting on the quaternionic root systems. © 2005 Elsevier Inc. All rights reserved. AMS classification: 20G20; 20F05; 20E34 Keywords: Structure of groups; Quaternions; Coxeter groups; Subgroup structure ∗ Corresponding author. Tel.: +90 342 360 1200; fax: +90 342 360 1013. -
Projective Representations of Groups
PROJECTIVE REPRESENTATIONS OF GROUPS EDUARDO MONTEIRO MENDONCA Abstract. We present an introduction to the basic concepts of projective representations of groups and representation groups, and discuss their relations with group cohomology. We conclude the text by discussing the projective representation theory of symmetric groups and its relation to Sergeev and Hecke-Clifford Superalgebras. Contents Introduction1 Acknowledgements2 1. Group cohomology2 1.1. Cohomology groups3 1.2. 2nd-Cohomology group4 2. Projective Representations6 2.1. Projective representation7 2.2. Schur multiplier and cohomology class9 2.3. Equivalent projective representations 10 3. Central Extensions 11 3.1. Central extension of a group 12 3.2. Central extensions and 2nd-cohomology group 13 4. Representation groups 18 4.1. Representation group 18 4.2. Representation groups and projective representations 21 4.3. Perfect groups 27 5. Symmetric group 30 5.1. Representation groups of symmetric groups 30 5.2. Digression on superalgebras 33 5.3. Sergeev and Hecke-Clifford superalgebras 36 References 37 Introduction The theory of group representations emerged as a tool for investigating the structure of a finite group and became one of the central areas of algebra, with important connections to several areas of study such as topology, Lie theory, and mathematical physics. Schur was Date: September 7, 2017. Key words and phrases. projective representation, group, symmetric group, central extension, group cohomology. 2 EDUARDO MONTEIRO MENDONCA the first to realize that, for many of these applications, a new kind of representation had to be introduced, namely, projective representations. The theory of projective representations involves homomorphisms into projective linear groups. Not only do such representations appear naturally in the study of representations of groups, their study showed to be of great importance in the study of quantum mechanics. -
In Boron Chemistry
Bull. Mater. Sci., Vol. 22, No. 5, August 1999, pp. 863-867. © Indian Academy of Sciences. The ubiquitous icosahedral B12 in boron chemistry E D JEMMIS* and M M BALAKRISHNARAJAN School of Chemistry, University of Hyderabad, Hyderabad500 046. India Abstract. Though boranes exhibit a wide variety of polyhedral structures, all the three polymorpbs of elemental boron essentially contain icosahedral Bn units as the predominant building block in their unit cell. Theoretical and experimental studies on boranes show that the icosuhedral arrangement leads to most stable boranes and borane anions. This paper attempts to explain the phenomenal stability associated with the icosahedral Bn structure. Using fragment molecular orbital theory, the remarkable stability of BI2Ht2~ among closo boranes are explained. The preferential selection icosahedral B12 unit by elemental boron is explained by improvising a contrived B84 sub-unit of the ~-rhombohedron, the most stable polymorph. This also leads to a novel covalent way of stuffing fnilerenes with icosahedral symmetry. Keywords. Boron; polyhedral closo borane dianions; icosahedral B12; ~-rhombohedral polymorph; orbital compatibility. 1. Introduction Elemental boron exists in three different polymorphic forms (Wells 1979). The thermodynamically most stable The chemistry of boron formed a vast discipline by itself [t-rhombohedral form has 105 boron atoms in its unit cell. and helped to alter the concept of structure and bonding The next stable ~-rhombohedral form has 12 boron atoms. radically (Lipscomb 1963). Starting from the famous The meta stable ~-tetragonal form has fifty boron atoms three-centre two-electron bond, many of the structural in its unit cell. The icosahedral BI2 unit is the primary features exhibited by boron compounds (most signifi- building block in all of these polymorphic forms.