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Gasoline (All Grades)

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Gasoline (All Grades) SAFETY DATA SHEET Gasoline (All Grades) Section 1. Identification Product name : Gasoline (All Grades) Product code : Not available. Synonyms : Gasoline, Unleaded Gasoline, Regular Gasoline, Premium Gasoline, Oxyfuel, Reformulated Gasoline Relevant identified uses of the substance or mixture and uses advised against Product use : Use in fuel - Industrial use Area of application : Industrial applications. Manufacturer : HollyFrontier Refining & Marketing LLC 2828 North Harwood Suite 1300 Dallas, Texas 75201 USA Customer Service: (888) 286-8836 Emergency telephone : CHEMTREC® (800) 424-9300 number CCN 201319 Section 2. Hazards identification OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Classification of the : H224 FLAMMABLE LIQUIDS - Category 1 substance or mixture H315 SKIN IRRITATION - Category 2 H319 EYE IRRITATION - Category 2A H340 GERM CELL MUTAGENICITY - Category 1 H350 CARCINOGENICITY - Category 1B H361 TOXIC TO REPRODUCTION (Fertility) - Category 2 H361 TOXIC TO REPRODUCTION (Unborn child) - Category 2 H336 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 H373 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (liver) - Category 2 H304 ASPIRATION HAZARD - Category 1 Percentage of the mixture consisting of ingredient(s) of unknown dermal toxicity: 9% Percentage of the mixture consisting of ingredient(s) of unknown inhalation toxicity: 4% GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : H224 - Extremely flammable liquid and vapor. H319 - Causes serious eye irritation. H315 - Causes skin irritation. H340 - May cause genetic defects. H350 - May cause cancer. H361 - Suspected of damaging fertility or the unborn child. H304 - May be fatal if swallowed and enters airways. H336 - May cause drowsiness or dizziness. H373 - May cause damage to organs through prolonged or repeated exposure. (liver) Precautionary statements Date of issue/Date of revision : 11/08/2017 Date of previous issue : 03/18/2014 Version : 2 1/13 Gasoline (All Grades) HollyFrontier Refining & Marketing LLC Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves. Wear eye or face protection. Wear protective clothing. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating, lighting and all material-handling equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash hands thoroughly after handling. Response : Get medical attention if you feel unwell. IF exposed or concerned: Get medical attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or physician if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower. IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Storage : Store in a well-ventilated place. Keep cool. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise : None known. classified Section 3. Composition/information on ingredients Substance/mixture : Mixture Ingredient name Other names % CAS number Gasoline - 88 - 100 86290-81-5 ethanol - 0 - 10 64-17-5 toluene - 0 - 10 108-88-3 1,2,4-trimethylbenzene - 0 - 5 95-63-6 benzene - 0 - 5 71-43-2 n-hexane - 0 - 3 110-54-3 Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Section 4. First aid measures Description of necessary first aid measures Eye contact : Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention. Continue to rinse for at least 15 minutes. Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Skin contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 15 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Date of issue/Date of revision : 11/08/2017 Date of previous issue : 03/18/2014 Version : 2 2/13 Gasoline (All Grades) HollyFrontier Refining & Marketing LLC Ingestion : Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Most important symptoms/effects, acute and delayed Potential acute health effects Eye contact : Causes serious eye irritation. Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Skin contact : Causes skin irritation. Ingestion : Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. Over-exposure signs/symptoms Eye contact : pain or irritation; watering; redness Inhalation : respiratory tract irritation; coughing; nausea or vomiting; headache; drowsiness/ fatigue; dizziness/vertigo; unconsciousness Skin contact : irritation; redness; dryness; cracking Ingestion : nausea or vomiting Indication of immediate medical attention and special treatment needed, if necessary Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Epinephrine and other sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to high concentrations of hydrocarbon solvents. Specific treatments : No specific treatment. Protection of medical : No action shall be taken involving any personal risk or without suitable training. If it is responders suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. See toxicological information (Section 11) Section 5. Fire-fighting measures Extinguishing media Suitable extinguishing : Use dry chemical, CO₂, water spray (fog) or foam. media Unsuitable extinguishing : Do not use water jet. media Specific hazards arising : Extremely flammable liquid and vapor. Runoff to sewer may create fire or explosion from the chemical hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Hazardous thermal : Decomposition products may include the following materials: decomposition products carbon dioxide carbon monoxide Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode. Date of issue/Date of revision : 11/08/2017 Date of previous issue : 03/18/2014 Version : 2 3/13 Gasoline (All Grades) HollyFrontier Refining & Marketing LLC Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures For non-emergency : No action shall be taken involving any personal risk or without suitable training. personnel Evacuate
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