Brazil Biofuels Annual 2019
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Nanocellulose: from Fundamentals to Advanced Applications
Nanocellulose: From Fundamentals to Advanced Applications Djalal Trache, Ahmed Fouzi Tarchoun, Mehdi Derradji, Tuan Sherwyn Hamidon, Nanang Masruchin, Nicolas Brosse, M. Hazwan Hussin To cite this version: Djalal Trache, Ahmed Fouzi Tarchoun, Mehdi Derradji, Tuan Sherwyn Hamidon, Nanang Masruchin, et al.. Nanocellulose: From Fundamentals to Advanced Applications. Frontiers in Chemistry, Frontiers Media, 2020, 8, pp.392. 10.3389/fchem.2020.00392. hal-02649346 HAL Id: hal-02649346 https://hal.univ-lorraine.fr/hal-02649346 Submitted on 29 May 2020 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. REVIEW published: 06 May 2020 doi: 10.3389/fchem.2020.00392 Nanocellulose: From Fundamentals to Advanced Applications Djalal Trache 1*†, Ahmed Fouzi Tarchoun 1, Mehdi Derradji 1, Tuan Sherwyn Hamidon 2, Nanang Masruchin 3, Nicolas Brosse 4 and M. Hazwan Hussin 2*† 1 UER Procédés Energétiques, Ecole Militaire Polytechnique, Bordj El-Bahri, Algeria, 2 Materials Technology Research Group, School of Chemical Sciences, Universiti Sains Malaysia, Penang, Malaysia, 3 Research Center for Biomaterials, Indonesian Institute of Sciences (LIPI), Jakarta, Indonesia, 4 Laboratoire d’Etude et de Recherche sur le MAtériau Bois (LERMAB), Faculté des Sciences et Techniques, Université de Lorraine, Vandœuvre-lès-Nancy, France Over the past few years, nanocellulose (NC), cellulose in the form of nanostructures, has been proved to be one of the most prominent green materials of modern times. -
Assessment of Bio- Ethanol and Biogas Initiatives for Transport in Sweden
Assessment of bio- ethanol and biogas initiatives for transport in Sweden Background information for the EU-project PREMIA EU Contract N° TREN/04/FP6EN/S07.31083/503081 May 2005 2 Abstract This report is the result of an assignment on assessment of bio-ethanol and biogas initiatives for transport in Sweden, granted by VTT Processes, Energy and Environment, Engines and Vehicles, Finland to Atrax Energi AB, Sweden. The report of the assignment is intended to append the literature and other information used in the “PREMIA” project The work has been carried out by Björn Rehnlund, Atrax Energi AB, Sweden, with support from Martijn van Walwijk, France. The report describes the development of the production and use of biobio-ethanol and biogas (biomass based methane) as vehicle fuels in Sweden and gives an overview of today’s situation. Besides data and information about numbers of vehicles and filling stations, the report also gives an overview of: • Stakeholders • The legal framework, including standards, specifications, type approval, taxation etc. • Financial support programs. Public acceptance, side effects and the effect off the introduction of bio-ethanol and biogas as vehicle fuels on climate gases are to some extent also discussed in this report. It can be concluded that since the early 1990’s Sweden has had a perhaps slow but steadily increasing use of bio-ethanol and biogas. Today having the EC directive on promotion of bio bio-fuels and other renewable fuels in place the development and introduction of filling stations and vehicles has started to increase rapidly. From 1994 to 2004 the number of filling stations for bio-ethanol grew from 1 to 100 and during the year 2004 until today to 160 stations. -
Jamaican Domestic Ethanol Fuel Feasibility and Benefits Analysis
Jamaican Domestic Ethanol Fuel Feasibility and Benefits Analysis Caley Johnson, Anelia Milbrandt, Yimin Zhang, Rob Hardison, and Austen Sharpe National Renewable Energy Laboratory NREL is a national laboratory of the U.S. Department of Energy Technical Report Office of Energy Efficiency & Renewable Energy NREL/TP-5400-76011 Operated by the Alliance for Sustainable Energy, LLC May 2020 This report is available at no cost from the National Renewable Energy Laboratory (NREL) at www.nrel.gov/publications. Contract No. DE-AC36-08GO28308 Jamaican Domestic Ethanol Fuel Feasibility and Benefits Analysis Caley Johnson, Anelia Milbrandt, Yimin Zhang, Rob Hardison, and Austen Sharpe National Renewable Energy Laboratory Suggested Citation Johnson, Caley, Anelia Milbrandt, and Yimin Zhang, Rob Hardison, and Austen Sharpe. 2020. Jamaican Domestic Ethanol Fuel Feasibility and Benefits Analysis. Golden, CO: National Renewable Energy Laboratory. NREL/TP-5400-76011. https://www.nrel.gov/docs/fy20osti/76011.pdf NREL is a national laboratory of the U.S. Department of Energy Technical Report Office of Energy Efficiency & Renewable Energy NREL/TP-5400-76011 Operated by the Alliance for Sustainable Energy, LLC May 2020 This report is available at no cost from the National Renewable Energy National Renewable Energy Laboratory Laboratory (NREL) at www.nrel.gov/publications. 15013 Denver West Parkway Contract No. DE-AC36-08GO28308 Golden, CO 80401 303-275-3000 • www.nrel.gov NOTICE This work was authored by the National Renewable Energy Laboratory, operated by Alliance for Sustainable Energy, LLC, for the U.S. Department of Energy (DOE) under Contract No. DE-AC36- 08GO28308. Funding provided by the U.S. Department of State. -
Challenges and Opportunities in Manufacturing Panel
Challenges and Opportunities in Manufacturing Panel Kim Nelson, PhD American Process Inc. Cellulose Nanomaterials –A Path Towards Commercialization A Workshop Co‐Sponsored by USDA Forest Service National Nanotechnology Initiative Sugar is the New Crude® American Process Inc. • Currently installing a 1 ton per day (dry basis) nanocellulose pilot line at our existing AVAP Biorefinery in Thomaston, Georgia to produce cellulose nanocrystals (CNC), cellulose nanofibrils (CNF), and hydrophobic, lignin‐coated varieties directly from biomass CNF Biomass lignin coated product SO2, ethanol, CNC water CNF + CNC Fractionation and Cellulose Separation / Mechanical Mix Bleaching Washing / Lignin Coating treatment L‐CNF Liquor (hemicelluloses , L‐CNC Chemical solvent, SO2, lignin) 1% 10% Regenerated Regeneration L‐CNF + L‐CNC ethanol/ SO2 Mix AVAP CNC Hemicelluloses Hydrolysis Lignin for energy Hemicelluloses sugars to biofuels/biochemicals 1% 10% AVAP L‐CNC 2 Manufacturing Opportunities • Low Production Cost for CNC and CNF with estimates of <$1 lb (wet basis). • Low cost feedstock utilization with omnivorous processes. • Low tonnage “side line” production in existing pulp mills for coproduction with pulp, lignin, and biofuels or biochemicals • High tonnage “stand alone” production in repurposed pulp mills using existing infrastructure including wood delivery and handling, utilities, waste water treatment, bleach lines etc. • Large demand potential with a near term global market size estimate for nanocellulose of 34 million tons per year (recent USDA funded study)1. 1. Cowie, J., Bilek, E.M., Wegner, T.H., et al.(2014) 3 Possible Global Production Curve 500 Plastics Timeline USDA’s near Nanocellulose Timeline term global 2002 market size 400 PLA estimate for nanocellulose tonnes of 34 million 300 tons per year. -
A Review of Nanocellulose As a Novel Vehicle for Drug Delivery David V
Special Issue: NANOCELLULOSE Nordic Pulp & Paper Research Journal Vol 29 no (1) 2014 A review of nanocellulose as a novel vehicle for drug delivery David V. Plackett, Kevin Letchford. John K. Jackson, and Helen M. Burt KEYWORDS: Cellulose nanocrystals, Cellulose has generally been viewed positively by the European nanofibrils, Bacterial cellulose, Antimicrobial, Antibiotic, and North American forest industries because of the Anti-cancer, Drug delivery potential for new value-added products to complement the existing portfolio of pulp and paper commodities and SUMMARY: The current state of research into specialty paper products. The possible applications cited nanocellulose in drug delivery is reviewed in this article. There are three types of nanocellulose: cellulose for the various forms of nanocellulose are quite diverse nanocrystals (CNC), cellulose nanofibrils (CNF) and and have included polymer composites, packaging materials, cosmetics, rheology modifiers in foods, and bacterial cellulose (BC), all of which may be produced in additives for oil-drilling muds, as well as a range of suitable amounts at reasonable cost. All three have been biomedical uses such as tissue culture scaffolds, implants, investigated as drug delivery vehicles with CNC and wound dressings and vehicles for drug delivery. CNF reported to bind and release some water-soluble drugs via ionic interactions whereas BC has been used to The interest in application of nanocelluloses in medicine release drugs from flexible membranes. The rationale for has been stimulated by their perceived non-toxicity, biocompatibility, good mechanical properties, high using nanocellulose is the high surface area-to-volume surface area-to-volume ratio and potential versatility in ratio of the material that may enable high levels of drug terms of chemical modification. -
Bringing Biofuels on the Market
Bringing biofuels on the market Options to increase EU biofuels volumes beyond the current blending limits Report Delft, July 2013 Author(s): Bettina Kampman (CE Delft) Ruud Verbeek (TNO) Anouk van Grinsven (CE Delft) Pim van Mensch (TNO) Harry Croezen (CE Delft) Artur Patuleia (TNO) Publication Data Bibliographical data: Bettina Kampman (CE Delft), Ruud Verbeek (TNO), Anouk van Grinsven (CE Delft), Pim van Mensch (TNO), Harry Croezen (CE Delft), Artur Patuleia (TNO) Bringing biofuels on the market Options to increase EU biofuels volumes beyond the current blending limits Delft, CE Delft, July 2013 Fuels / Renewable / Blends / Increase / Market / Scenarios / Policy / Technical / Measures / Standards FT: Biofuels Publication code: 13.4567.46 CE Delft publications are available from www.cedelft.eu Commissioned by: The European Commission, DG Energy. Further information on this study can be obtained from the contact person, Bettina Kampman. Disclaimer: This study Bringing biofuels on the market. Options to increase EU biofuels volumes beyond the current blending limits was produced for the European Commission by the consortium of CE Delft and TNO. The views represented in the report are those of its authors and do not represent the views or official position of the European Commission. The European Commission does not guarantee the accuracy of the data included in this report, nor does it accept responsibility for any use made thereof. © copyright, CE Delft, Delft CE Delft Committed to the Environment CE Delft is an independent research and consultancy organisation specialised in developing structural and innovative solutions to environmental problems. CE Delft’s solutions are characterised in being politically feasible, technologically sound, economically prudent and socially equitable. -
Micro-Fibrillated Cellulose in Adhesive Systems for the Production of Wood-Based Panels
molecules Article Micro-Fibrillated Cellulose in Adhesive Systems for the Production of Wood-Based Panels Emmanouil Karagiannidis *, Charles Markessini and Eleftheria Athanassiadou CHIMAR HELLAS S.A.,15 km National Road, Thessaloniki–Polygyros, 57001 Thessaloniki, Greece; [email protected] (C.M.); [email protected] (E.A.) * Correspondence: [email protected]; Tel.: +30-2310-424167 Academic Editors: Alejandro Rodríguez, Eduardo Espinosa and Fabrizio Sarasini Received: 31 July 2020; Accepted: 18 October 2020; Published: 21 October 2020 Abstract: Micro-Fibrillated Cellulose (MFC) is a new type of bio-based additive, coming from wood cellulose. It can compete and substitute oil derived chemicals in several application fields. In the present work, the use of micro-fibrillated cellulose, in waterborne adhesive systems applied in the manufacture of composite wood-based panels was evaluated. Research was conducted to test the potential of improving the performance of wood-based panel types such as particleboard, waferboard or randomly-oriented strand board and plywood, by the application of MFC and the substitution of conventional and non-renewable chemical compounds. The approaches followed to introduce MFC into the adhesive systems were three, i.e., MFC 2% suspension added during the adhesive resin synthesis, MFC 10% paste admixed with the already prepared adhesive resin and MFC 2% suspension admixed with the already prepared resin. It was found that MFC improves not only the performance of the final wood panel products but also the behaviour of the applied adhesive polymer colloids (e.g., rheology improvement), especially when admixed with the already prepared resins. Moreover, it was proven that when MFC is introduced into the adhesive resin system, there is a possibility of decreasing the resin consumption, by maintaining the board performance. -
Ethanol Flexible Fuel Vehicle Conversion Kits: Alternative Fuels
Alternative Fuels Data Center: Technology Bulletin - Ethanol Flexible Fuel Vehicle Conversion Kits August 2007 Ethanol Flexible Fuel Vehicle Conversion Kits Rising gasoline prices and concerns about climate change have greatly increased public interest in ethanol use. Vehicle manufacturers currently offer ethanol flex-fuel vehicles (FFVs) in a wide variety of makes and models at little or no extra cost. In spite of the availability of new and used FFVs, many consumers are curious about the prospects for converting their existing gasoline vehicles to operate on ethanol. ● Background ● Regulatory Requirements ● Certification Process Overview ● Status of Ethanol Conversion Certifications ● On-board Diagnostics (OBD) Approval Letter ● Resources Background The Environmental Protection Agency (EPA) implements regulations under the Clean Air Act that require certification of new vehicles as being compliant with emissions requirements (see the Code of Federal Regulations, Title 40, Parts 85 and 86). Certification is granted to the manufacturer for specific vehicle configurations operating on specific fuels according to an established test protocol. Installing or modifying a fuel system to allow a vehicle to operate on a fuel other than that for which it was originally certified is considered tampering—a violation of federal regulations that carries a significant fine. There are currently no certified aftermarket conversion systems that would allow a conventional gasoline vehicle to operate on E85. EPA does have a process by which manufacturers of conversion systems or "kits" can obtain a Certificate of Conformity for converted vehicles. In recent years, manufacturers of natural gas and propane conversions have used this process to certify several vehicles for operation on these fuels. -
CNC) from Eucalyptus Published: Xx Xx Xxxx Hardwood Renli Zhang & Yun Liu
www.nature.com/scientificreports OPEN High energy oxidation and organosolv solubilization for high yield isolation of cellulose Received: 23 April 2018 Accepted: 18 October 2018 nanocrystals (CNC) from Eucalyptus Published: xx xx xxxx hardwood Renli Zhang & Yun Liu Cellulose nanocrystals (CNC) have been widely used as responsive materials, chiral templates, and tough nano-composites due to its unparalleled properties. Acid and enzyme hydrolyses are extensively employed to prepare CNC. These traditional approaches exhibit inherent limitations of corrosion hazards, time-consuming process, and/or low yield. Herein, irradiation oxidation and organosolv solubilization are conducted to cause rapid degradation with simultaneous crystallization of cellulose to achieve approx. 87% yield of CNC. The morphology, spectroscopic, and stability properties of the as-prepared CNC are characterized through UV-vis spectroscopy, zetal potential, XRD, TEM, DLS, GPC, FT-IR and TGA techniques. The resultant CNC suspension presents unique property with high stability after 9 months storage at 4 °C. Moreover, CNC liquid crystal phase is successfully generated by addition of anions or cations solution to the CNC aqueous dispersion without stirring. The innovative approach in this work opens an avenue to obtain CNC directly from lignocellulosic biomass through irradiation oxidation and organosolv solubilization without acid hydrolysis and washing procedure. Cellulose, lignin and hemicellulose are the three principal structural components of lignocellulosic biomass. -
The Impact of Ethanol and Iso-Butanol Blends on Gaseous and Particulate
Energy 82 (2015) 168e179 Contents lists available at ScienceDirect Energy journal homepage: www.elsevier.com/locate/energy The impact of ethanol and iso-butanol blends on gaseous and particulate emissions from two passenger cars equipped with spray-guided and wall-guided direct injection SI (spark ignition) engines * Georgios Karavalakis a, b, , Daniel Short a, b, Diep Vu a, b, Robert L. Russell a, Akua Asa-Awuku a, b, Heejung Jung a, c, Kent C. Johnson a, b, Thomas D. Durbin a, b a University of California, Bourns College of Engineering, Center for Environmental Research and Technology (CE-CERT), 1084 Columbia Avenue, Riverside, CA 92507, USA b Department of Chemical and Environmental Engineering, Bourns College of Engineering, University of California, Riverside, CA 92521, USA c Department of Mechanical Engineering, Bourns College of Engineering, University of California, Riverside, CA 92521, USA article info abstract Article history: We examined the effects of different ethanol and iso-butanol blends on the gaseous and particulate Received 2 August 2014 emissions from two passenger cars equipped with spark ignition direct injection engines and with one Received in revised form spray-guided and one wall-guided configuration. Both vehicles were tested over triplicate FTP (Federal 3 December 2014 Test Procedure) and UC (Unified Cycles) using a chassis dynamometer. Emissions of THC (total hydro- Accepted 8 January 2015 carbons), NMHC (non-methane hydrocarbons), and CO (carbon monoxide) reduced with increasing Available online 7 February 2015 oxygen content in the blend for some of the vehicle/fuel combinations, whereas NOx (nitrogen oxide) emissions did not show strong fuel effects. -
Ethanol-Blended Gasoline • Module 27 Page 1 Ethanol-Blended Gasoline
…Introduction: TankSmart Operator Training • Class A/B Operators • Training Class C Operators • Annual UST System Inspections • Record Keeping • Spills: Cleanup & Reporting • Safety • Tanks: Double-Walled w/ Continuous Electronic Monitoring • Tanks: Double-Walled w/ Manual Monitoring • Tanks: Single-Walled • Daily Inventory & Statistical Inventory Analysis • Automatic Tank Gauges (ATGs) • Piping: Double-Walled Systems • Piping: Single-Walled Systems • Piping: Pressurized Pumping Systems • Piping: Suction Pumping Systems • Overfill Prevention: Ball Floats • Overfill Prevention: Electronic Alarms • Overfill Prevention: Drop-Tube Shutoff Valves • Spill Buckets • Cathodic Protection for Tanks & Piping • Stage I Vapor Recovery • Dispensers • Out-of-Service Tanks • Aboveground Storage Tanks (ASTs) • Heating Oil/Generator Tanks • Ethanol-Blended Gasoline • Module 27 Page 1 ETHANOL-BLENDED GASOLINE Now that ethanol is routinely blended with gasoline in Maine (typically Now that ethanol 10% ethanol with 90% gasoline, known as E10), UST owners and operators is routinely blended must pay attention to several new fuel-storage and fuel-quality-related issues. with gasoline in These issues may cause leaks in tanks, piping, and/or dispensers, and so have an environmental aspect to them as well. Maine (typically 10% ethanol with The potential issues you should be aware of regarding storing, distributing, and 90% gasoline, dispensing ethanol blended fuels are: known as E10), Compatibility with system components UST owners and operators must pay Phase -
A Review on the Application of Nanocellulose in Cementitious Materials
nanomaterials Review A Review on the Application of Nanocellulose in Cementitious Materials Aofei Guo 1, Zhihui Sun 1, Noppadon Sathitsuksanoh 2 and Hu Feng 3,* 1 Civil and Environmental Engineering Department, University of Louisville, Louisville, KY 40292, USA; [email protected] (A.G.); [email protected] (Z.S.) 2 Chemical Engineering Department, University of Louisville, Louisville, KY 40292, USA; [email protected] 3 School of Civil Engineering, Zhengzhou University, Kexue Avenue 100#, Zhengzhou 450001, China * Correspondence: [email protected] Received: 25 November 2020; Accepted: 8 December 2020; Published: 10 December 2020 Abstract: The development of the concrete industry is always accompanied by some environmental issues such as global warming and energy consumption. Under this circumstance, the application of nanocellulose in cementitious materials is attracting more and more attention in recent years not only because of its renewability and sustainability but also because of its unique properties. To trace the research progress and provide some guidance for future research, the application of nanocellulose to cementitious materials is reviewed. Specifically, the effects of cellulose nanocrystal (CNC), cellulose nanofibril (CNF), bacterial cellulose (BC), and cellulose filament (CF) on the physical and fresh properties, hydration, mechanical properties, microstructure, rheology, shrinkage, and durability of cementitious materials are summarized. It can be seen that the type, dosage, and dispersion of nanocellulose, and even the cementitious matrix type can lead to different results. Moreover, in this review, some unexplored topics are highlighted and remain to be further studied. Lastly, the major challenge of nanocellulose dispersion, related to the effectiveness of nanocellulose in cementitious materials, is examined in detail.