Herbicide Mode of Action Groups
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(12) United States Patent (10) Patent No.: US 8,586,504 B2 Wright Et Al
USOO85865.04B2 (12) United States Patent (10) Patent No.: US 8,586,504 B2 Wright et al. (45) Date of Patent: Nov. 19, 2013 (54) HERBICIDAL COMPOSITIONS CONTAINING FOREIGN PATENT DOCUMENTS GLYPHOSATE AND A PYRONE ANALOG AU 100.73/92 B 10, 1992 CA 2340240 A1 2, 2000 (75) Inventors: Daniel R. Wright, St. Louis, MO (US); EP O 808 569 A1 11, 1997 Joseph J. Sandbrink, Chesterfield, MO GB 2267 825 A 12/1993 (US); Paul G. Ratliff, Olivette, MO WO 99/00013 1, 1999 WO OO,30452 6, 2000 (US) WO OO,642.57 11, 2000 WO OO/67571 11, 2000 (73) Assignee: Monsanto Technology LLC, St. Louis, WO O1/35740 A2 5, 2001 MO (US) WO 02/21924 A2 3, 2002 (*) Notice: Subject to any disclaimer, the term of this OTHER PUBLICATIONS patent is extended or adjusted under 35 Exhibit PMH-17 Supplemental Labeling regarding Roundup Pro U.S.C. 154(b) by 0 days. Herbicide by Monsanto, EPA Reg. No. 524-475 (Nov. 1995), 11 pageS. (21) Appl. No.: 13/404,861 Exhibit PMH-18 Notice of Pesticide Registration issued on Oct. 5, 2000, 35 pages. Exhibit PMH-19 EPA Application for Pesticide, ID No. 200405 (22) Filed: Feb. 24, 2012 (Sep. 1995), 33 pages. Exhibit PMH-20-Documentation regarding Starmas Racun/ (65) Prior Publication Data Rumpai Herbicide (bears the year 2003), 10 pages. Exhibit PMH-21—Documentation regarding Starmix Racun/ US 2012/O157309 A1 Jun. 21, 2012 Rumpai Herbicide (Date Unknown), 3 pages. Exhibit PMH-22—article entitled Control of Eucalyptus grandis cut stumps by Keith Little et al., ICFR Bulletin Series, No. -
2,4-Dichlorophenoxyacetic Acid
2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators. -
USDA, Forest Service Forest Health Protection GSA Contract No
SERA TR 02-43-13-03b Triclopyr - Revised Human Health and Ecological Risk Assessments Final Report Prepared for: USDA, Forest Service Forest Health Protection GSA Contract No. GS-10F-0082F USDA Forest Service BPA: WO-01-3187-0150 USDA Purchase Order No.: 43-1387-2-0245 Task No. 13 Submitted to: Dave Thomas, COTR Forest Health Protection Staff USDA Forest Service Rosslyn Plaza Building C, Room 7129C 1601 North Kent Street Arlington, VA 22209 Submitted by: Patrick R. Durkin Syracuse Environmental Research Associates, Inc. 5100 Highbridge St., 42C Fayetteville, New York 13066-0950 Telephone: (315) 637-9560 Fax: (315) 637-0445 E-Mail: [email protected] Home Page: www.sera-inc.com March 15, 2003 TABLE OF CONTENTS LIST OF APPENDICES ...................................................... iv LIST OF WORKSHEETS ...................................................... v LIST OF ATTACHMENTS .................................................... v LIST OF TABLES ............................................................ v LIST OF FIGURES ......................................................... viii ACRONYMS, ABBREVIATIONS, AND SYMBOLS .............................. ix COMMON UNIT CONVERSIONS AND ABBREVIATIONS ......................... xi CONVERSION OF SCIENTIFIC NOTATION .................................... xii EXECUTIVE SUMMARY ................................................... xiii 1. INTRODUCTION ........................................................ 1-1 2. PROGRAM DESCRIPTION ................................................ 2-1 2.1. OVERVIEW -
Common and Chemical Names of Herbicides Approved by the WSSA
Weed Science 2010 58:511–518 Common and Chemical Names of Herbicides Approved by the Weed Science Society of America Below is the complete list of all common and chemical of herbicides as approved by the International Organization names of herbicides approved by the Weed Science Society of for Standardization (ISO). A sponsor may submit a proposal America (WSSA) and updated as of September 1, 2010. for a common name directly to the WSSA Terminology Beginning in 1996, it has been published yearly in the last Committee. issue of Weed Science with Directions for Contributors to A herbicide common name is not synonymous with Weed Science. This list is published in lieu of the selections a commercial formulation of the same herbicide, and in printed previously on the back cover of Weed Science. Only many instances, is not synonymous with the active ingredient common and chemical names included in this complete of a commercial formulation as identified on the product list should be used in WSSA publications. In the absence of label. If the herbicide is a salt or simple ester of a parent a WSSA-approved common name, the industry code number compound, the WSSA common name applies to the parent as compiled by the Chemical Abstracts Service (CAS) with compound only. CAS systematic chemical name or the systematic chemical The chemical name used in this list is that preferred by the name alone may be used. The current approved list is also Chemical Abstracts Service (CAS) according to their system of available at our web site (www.wssa.net). -
Herbicide Mode of Action Table High Resistance Risk
Herbicide Mode of Action Table High resistance risk Chemical family Active constituent (first registered trade name) GROUP 1 Inhibition of acetyl co-enzyme A carboxylase (ACC’ase inhibitors) clodinafop (Topik®), cyhalofop (Agixa®*, Barnstorm®), diclofop (Cheetah® Gold* Decision®*, Hoegrass®), Aryloxyphenoxy- fenoxaprop (Cheetah®, Gold*, Wildcat®), fluazifop propionates (FOPs) (Fusilade®), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) Cyclohexanediones (DIMs) butroxydim (Factor®*), clethodim (Select®), profoxydim (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) Phenylpyrazoles (DENs) pinoxaden (Axial®) GROUP 2 Inhibition of acetolactate synthase (ALS inhibitors), acetohydroxyacid synthase (AHAS) Imidazolinones (IMIs) imazamox (Intervix®*, Raptor®), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, Lightning®*, Midas®* OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) Pyrimidinyl–thio- bispyribac (Nominee®), pyrithiobac (Staple®) benzoates Sulfonylureas (SUs) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*, Trimac Plus®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron (Logran®, Logran® B-Power®*), tribenuron (Express®), -
R Graphics Output
Dexamethasone sodium phosphate ( 0.339 ) Melengestrol acetate ( 0.282 ) 17beta−Trenbolone ( 0.252 ) 17alpha−Estradiol ( 0.24 ) 17alpha−Hydroxyprogesterone ( 0.238 ) Triamcinolone ( 0.233 ) Zearalenone ( 0.216 ) CP−634384 ( 0.21 ) 17alpha−Ethinylestradiol ( 0.203 ) Raloxifene hydrochloride ( 0.203 ) Volinanserin ( 0.2 ) Tiratricol ( 0.197 ) trans−Retinoic acid ( 0.192 ) Chlorpromazine hydrochloride ( 0.191 ) PharmaGSID_47315 ( 0.185 ) Apigenin ( 0.183 ) Diethylstilbestrol ( 0.178 ) 4−Dodecylphenol ( 0.161 ) 2,2',6,6'−Tetrachlorobisphenol A ( 0.156 ) o,p'−DDD ( 0.155 ) Progesterone ( 0.152 ) 4−Hydroxytamoxifen ( 0.151 ) SSR150106 ( 0.149 ) Equilin ( 0.3 ) 3,5,3'−Triiodothyronine ( 0.256 ) 17−Methyltestosterone ( 0.242 ) 17beta−Estradiol ( 0.24 ) 5alpha−Dihydrotestosterone ( 0.235 ) Mifepristone ( 0.218 ) Norethindrone ( 0.214 ) Spironolactone ( 0.204 ) Farglitazar ( 0.203 ) Testosterone propionate ( 0.202 ) meso−Hexestrol ( 0.199 ) Mestranol ( 0.196 ) Estriol ( 0.191 ) 2,2',4,4'−Tetrahydroxybenzophenone ( 0.185 ) 3,3,5,5−Tetraiodothyroacetic acid ( 0.183 ) Norgestrel ( 0.181 ) Cyproterone acetate ( 0.164 ) GSK232420A ( 0.161 ) N−Dodecanoyl−N−methylglycine ( 0.155 ) Pentachloroanisole ( 0.154 ) HPTE ( 0.151 ) Biochanin A ( 0.15 ) Dehydroepiandrosterone ( 0.149 ) PharmaCode_333941 ( 0.148 ) Prednisone ( 0.146 ) Nordihydroguaiaretic acid ( 0.145 ) p,p'−DDD ( 0.144 ) Diphenhydramine hydrochloride ( 0.142 ) Forskolin ( 0.141 ) Perfluorooctanoic acid ( 0.14 ) Oleyl sarcosine ( 0.139 ) Cyclohexylphenylketone ( 0.138 ) Pirinixic acid ( 0.137 ) -
Weed Control in Direct-Seeded Field Pea Gregory J
Weed Control in Direct-seeded Field Pea Gregory J. Endres and Blaine G. Schatz Weed control and field pea response to selected soil- and POST-applied herbicides were evaluated in a randomized complete-block design with three replicates. The experiment was conducted on a Heimdahl loam soil with 6.7 pH and 2.9% organic matter at the NDSU Carrington Research Extension Center. Herbicide treatments were applied to 5- by 25-ft plots with a pressurized hand-held plot sprayer at 17 gal/A and 30 psi through 8002 flat-fan nozzles. Fall sulfentrazone treatments were applied October 25, 2004 to a moist soil surface with 47 F, 71% RH, 15% clear sky, and 11 mph wind. On April 28, 2005, inoculated 'Integra' field pea was seeded into standing wheat stubble in 7-inch rows at a rate of 300,000 pure live seeds/A. PRE treatments were applied to a dry soil surface on April 30 with 31 F, 64% RH, 30% clear sky, and 10 mph wind. Rainfall totaled 1.22 inches 8 d following PRE application. The trial area was treated on May 6 with a PRE burn-down application of glyphosate at 0.75 lb ae/A plus ammonium sulfate at 1% v/v. The early POST (EPOST) treatment was applied on May 23 with 73 F, 35% RH, 100% cloudy sky, and 6 mph wind to 2-inch tall field pea, 1- to 2-leaf green and yellow foxtail, 0.5-inch tall common lambsquarters, 0.5-inch tall prostrate and redroot pigweed, and 0.5-inch tall wild buckwheat. -
Ecological Risk Assessment for Saflufenacil
TEXT SEARCHABLE DCOUMENT 2011 UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 OFFICE OF CEMICAL SAFETY AND POLLUTION PREVENTION PC Code: 118203 DP Barcode: 380638 and 381293 Thursday, April 07, 2011 MEMORANDUM SUBJECT: Ecological Risk Assessment for Saflufenacil Section 3 New Chemical Uses as a harvest aid on dry edible beans, dry peas, soybean, oilseeds "sunflower subgroup 20B", oilseeds "cotton subgroup 20C", and oilseeds canola "subgroup 20A". TO: Kathryn Montague, M.S., Product Manager 23 Herbicide Branch Registration Division (RD) (7505P) FROM: ~ Mohammed Ruhman, Ph.D., Agronomist 2 :4- . ""=- ........ 04!tJt! (I neith Sappington, Senior Biologist/Science Adviso~.... Vd- Environmental Risk Branch V O'f/ .../ II Environmental Fate and Effects Division (7507P) THROUGH: Mah Shamim, Ph.D., Branch Chief Environmental Risk Branch VI Environmental Fate and Effects Division (7507P) This ecological risk assessment for saflufenacil new uses is relying on the attached previous assessment (Attachment 1). As shown in the usage summary (Table 1), the single and seasonal rate, for all the crops range from 0.045 to 0.089 lbs a.i/A are within the range application rates used in exposure modeling for the 2009 Section 3 New Chemical Environmental Fate and Ecological Risk Assessment (DP Barcode 349855). Therefore, risk findings determined for the 2009 assessment may be used in the assessment for this submittal. Specifically, the 2009 assessment found no chronic risks to avian and mammalian species at an agricultural use rate 0 0.134 lb a.i.lA. Acute risks were not determined for birds and mammals since saflufenacil was not acutely toxic at the highest doses tested. -
U.S. Geological Survey National Water-Quality Assessment Program
U.S. Geological Survey National Water-Quality Assessment Program Stream water-quality analytes Major ions and trace elementsschedule 998 (20 constituents) Pesticides schedule 2437 (229 compounds) Alkalinity 1H1,2,4Triazole Arsenic 2,3,3Trichloro2propene1sulfonic acid (TCPSA) Boron 2,4D Calcium 2(1Hydroxyethyl)6methylaniline Chloride 2[(2Ethyl6methylphenyl)amino]1propanol Fluoride 2AminoNisopropylbenzamide Iron 2Aminobenzimidazole Lithium 2Chloro2',6'diethylacetanilide 2Chloro4,6diaminostriazine {CAAT} Magnesium (Didealkylatrazine) pH 2Chloro4isopropylamino6aminostriazine Potassium 2Chloro6ethylamino4aminostriazine {CEAT} Total dissolved solids 2ChloroN(2ethyl6methylphenyl)acetamide Selenium 2Hydroxy4isopropylamino6aminostriazine 2Hydroxy4isopropylamino6ethylaminostriazin Silica e {OIET} Sodium 2Hydroxy6ethylamino4aminostriazine Specific conductance 2Isopropyl6methyl4pyrimidinol Strontium 3,4Dichlorophenylurea Sulfate 3Hydroxycarbofuran Turbidity 3Phenoxybenzoic acid Vanadium 4(Hydroxymethyl)pendimethalin 4Chlorobenzylmethyl sulfoxide Suspended sediment 4Hydroxy molinate 4Hydroxychlorothalonil Nutrientsschedule 2430 (18 constituents) 4Hydroxyhexazinone A Inorganic carbon, suspended Acephate Dissolved inorganic carbon Acetochlor ammonia + organic nitrogen (unfilteredKjeldahl) Acetochlor oxanilic acid ammonia + organic nitrogen (filteredKjeldahl) Acetochlor sulfonic acid Ammonia as N, filtered Acetochlor sulfynilacetic acid nitrite, filtered Alachlor -
Efficacy of Imazapic/Imazapyr and Other Herbicides in Mixtures for The
Efficacy of imazapic/imazapyr and other herbicides in mixtures for the control of Digitaria insularis prior to soybean sowing Efectividad de imazapic/imazapyr y otros herbicidas en mezclas para el control de Digitaria insularis en pre-siembra de soya Alfredo Junior Paiola Albrecht1, Leandro Paiola Albrecht1, André Felipe Moreira Silva²*, Romulo Augusto Ramos³, Everson Pedro Zeny³, Juliano Bortoluzzi Lorenzetti4, Maikon Tiago Yamada Danilussi4, and Arthur Arrobas Martins Barroso4 ABSTRACT RESUMEN Herbicide mixtures, use of multiple sites of action, and other Las mezclas entre herbicidas, el uso de múltiples sitios de acción weed management practices are necessary to avoid cases of y otras prácticas de manejo de malezas son necesarias para biotype resistance. The aim of this study was to evaluate the evitar otros casos de resistencia de biotipos. El objetivo de este efficiency of imazapic/imazapyr and other herbicides in mix- estudio fue evaluar la eficiencia de imazapic/imazapyr y otros tures to control Digitaria insularis at burndown before soybean herbicidas en mezclas para controlar Digitaria insularis en la sowing. This field research was conducted in Umuarama, State desecación antes de la siembra de soya. Esta investigación de of Parana (PR), Brazil, in the 2018/19 soybean season. The ex- campo se realizó en Umuarama, Estado de Paraná (PR), Brasil, periment was conducted in a randomized block experimental en la cosecha de soya de 2018/19. El experimento se realizó en design with four replicates and 11 treatments composed of the un diseño experimental de bloques al azar, con cuatro repe- application of glyphosate, clethodim, haloxyfop, imazapic/ ticiones y 11 tratamientos, compuestos por la aplicación de imazapyr, glufosinate, 2,4-dichlorophenoxyacetic acid (2,4-D), glifosato, cletodim, haloxifop, imazapic/imazapir, glufosinato, dicamba, triclopyr, and saflufenacil, in mixtures. -
Post-Emergence Weed Control Options in Tree Nut Orchards
Post-emergence Weed Control Options in Tree Nut Orchards Marcelo L. Moretti1, Rolando Mejorado1, Seth Watkins1, David Doll2, and Bradley D. Hanson1 1University of California, Davis, Dept. of Plant Sciences,2Cooperative Extension Merced County [email protected] Herbicides are the primary means of vegetation management in tree nut orchards in California. Among registered herbicides, post-emergence (POST) materials, like glyphosate, are the most widely used in tree crops because of low cost and broad weed control spectrum. However, herbicide resistance has compromised the efficacy of POST only herbicide programs in many parts of the state. Most cases of resistance in orchards are glyphosate-resistant hairy fleabane, horseweed, ryegrass, and junglerice. To manage resistant weed species, pre-emergence (PRE) herbicides can be applied during winter before weeds emerge; however, PRE herbicide use can be limited by cost and the need for rainfall to incorporate them. Even when PRE herbicides are used, most orchards will need a POST treatment to control weed escapes and to prepare the orchard for harvest operations. One approach to optimize control of late emerging or glyphosate-resistant weeds is to use alternate herbicides, mixtures, rates, or more appropriate application timing. The objective of this project was to evaluate POST control of hairy fleabane and yellow nutsedge with different herbicides combinations. Methods Field experiments were conducted in a three year-old almond orchard infested with hairy fleabane and yellow nutsedge. The orchard was located in a sandy soil area in Merced County, and irrigated with solid set sprinklers. The area is known to be infested with glyphosate-resistant hairy fleabane. -
Safety and Efficacy of Postemergence Herbicides for Container-Grown Landscape Groundcovers
1 17B-Student-Conner-IPPS-2018.doc Safety and Efficacy of Postemergence Herbicides for Container-Grown Landscape Groundcovers© Crystal J. Connera, Chris Marble, and Annette Chandler Mid-Florida Research and Education Center, University of Florida, 2725 S. Binion Road, Apopka, Florida 32703, USA aEmail: [email protected] KeyWords: Landscape nursery, weed management, asiatic jasmine, Trachelospermum asiaticum ‘Minima’, perennial peanut, Arachis glabrata ‘Ecoturf’ SUMMARY Research was conducted to determine crop tolerance of asiatic jasmine (Trachelospermum asiaticum ‘Minima’) and perennial peanut (Arachis glabrata ‘Ecoturf’) to postemergence herbicides including bentazon, sulfentrazone, iron HEDTA, indaziflam (a preemergence herbicide), sulfosulfuron, and clopyralid. Efficacy of these herbicides was evaluated on flowering eclipta (Eclipta prostrata) and hairy beggarticks (Bidens pilosa). All herbicides with the exception of bentazon caused no significant damage to asiatic jasmine; injury resulting from bentazon was minimal. In perennial peanut, the highest injury was noted in plants treated with indaziflam, sulfosulfuron, or clopyralid, but injury was less than 30% and considered acceptable. All herbicides evaluated provided poor control of either weed species with the exception of clopyralid, which provided over 90% control of hairy beggarticks. Results indicate that several postemergence herbicides labeled for use in either nurseries or landscapes could be used to manage weeds in asiatic jasmine or perennial peanut groundcovers but further testing is needed. 1 2 INTRODUCTION Turfgrass is the most widely planted irrigated crop in the United States and occupies the vast majority of most residential and commercial landscapes in Florida (NTRI, 2003). However, the common mantra of landscape design is “right plant right place”. In many neighborhoods, parks, and other areas containing significant tree canopy, turfgrass is not suitable due to limited sunlight.