50th Lunar and Planetary Science Conference 2019 (LPI Contrib. No. 2132) 1396.pdf STANDARDS FOR GEOCHEMICAL ANALYSIS OF MAJOR, MINOR, AND TRACE ELEMENTS IN ROCK POWDERS. M. Darby Dyar1, Cai R. Ytsma1, and Kate Lepore1, 1Dept. of Astronomy, Mount Holyoke Col- lege, 50 College St., South Hadley, MA 01075,
[email protected]. Introduction: Analytical geochemistry has long group, Massachusetts; depended on availability of robust suites of rock stand- 2. rhyolitic volcanic glass from Mexico; locality un- ards with well-characterized compositions. Standard known, but likely from Tequila Volcano; rock powders were initially characterized and supplied 3. Hawaiian basalt collected from Kīlauea by Tim Orr to the community by the U.S. Geological Survey, (USGS, HVO); which continues to distribute a few dozen standards. 4. washed SiO2 sea sand (Fisher Scientific); Many other rock standards have subsequently been 5. Columbia River continental flood basalt collected developed by organizations such as the Centre de Re- in Moscow, Idaho by Mickey Gunter; cherches Pétrographiques et Géochimiques (CRPG) 6. rhyolite from Newberry Volcano in Oregon; and Brammer Standard Company, Inc. 7. a 50:50 by weight mixture of diopside and forsterit- Existing standards from terrestrial rocks contain ic olivine to simulate an ultramafic rock; and concentration ranges that may not cover what is present 8. granite from the Vinalhaven intrusive complex, on other bodies. Notably, Ni is a primary constituent of Maine collected by Sheila Seaman. meteorites, and thus may be abundant on ancient sur- For dopants, we used reagent-grade chemicals in the faces with impact craters [1,2]. Yet no commercial form of BN, CBaO3, C, CeO2, CoO, Cr2O3, Cs2TiO3, terrestrial rock standards come close to covering the CuO, Ga2O3, La2O3, LiCl, MnO2, MoS2, Nb2O5, NiO, possible extremes of Ni concentration that could result OPb, RbCl, CaSO4, Sc2O3, SeO2, SnO2, SrO, Y2O3, from impact contamination.