Evaluation of Combined Treatments of Natural Fibers: Kenaf, Abaca and Oil Palm Fibers Using Micromechanical and SEM Methods

Total Page：16

File Type：pdf, Size：1020Kb

Evaluation of combined treatments of natural fibers: kenaf, abaca and oil palm fibers using micromechanical and SEM methods ABSTRACT This paper presents the results of three different fibers, Kenaf (hibiscus cannabinus), oil palm (Elaeis guineensis) and abaca (Musa textilis) which were treated using 5 different types of surface treatments namely sodium hydroxide for 24 hours, glycidoxypropyltrimethoxy-silane for 24 hours, NaOH followed by Silane (each 24 hours), NaOH followed by Silane (each 12 hours) and NaOH followed by Silane (each 6 hours). The mechanical strength of the fibers were then studied and compared to the untreated fibers. The highest strength was given by the fibers treated with NaOH followed by the combined treatments and the lowest were the fibers treated with silane. Also the bonding strength between the fibers and unsaturated polyester resin were then evaluated using micro droplet pull out tests. It was proven that all the treatments improved on the bonding strength. The highest was silane followed by NaOH. For the combined treatments it was found that the highest IFSS was given by the lowest treatment duration at 6 hours, due to the alkali nature of NaOH corroding the fibers which were then filled with silane, thus losing the ability to properly bond with the resin. The samples were also then characterized using a SEM to check the surface morphology which revealed that the NaOH reduced the diameter by removing impurities and lignin, thus increasing the aspect ratio. While silane coats the surface, increases the diameter and reduces the aspect ratio. Keyword: Abaca; Bonding strength; Chemical treatment; Droplet test; Kenaf; OPF; SEM .

Copy Link

Recommended publications

Cuba: Informe Nacional Sobre Los Rfaa
CUBA: INFORME NACIONAL SOBRE LOS RFAA La Habana, abril 2007 1 INDICE Página LISTA DE ACRÓNIMOS 4 SECCIÓN I: SUMARIO EJECUTIVO. 5 SECCIÓN II: INTRODUCCIÓN AL PAÍS Y AL SECTOR AGRÍCOLA. 9 II.1. Principales características de la naturaleza y la biodiversidad de Cuba. 9 II. 2. Características socio-económicas de Cuba. El Plan Turquino y su papel en la agricultura cubana. 10 II.3. Principales sistemas de producción, cultivos y productos animales, así como exportaciones. 11 SECCIÓN III. CUERPO PRINCIPAL DEL INFORME DE PAÍS. 15 Capítulo 1: Estado de la Diversidad. 15 1.1. El estado de la diversidad e importancia relativa para la seguridad alimentaria de granos básicos y cereales. 15 1.2. El estado de la diversidad e importancia relativa de raíces, tubérculos y rizomas, plátanos y bananos. 17 1.3. El estado de la diversidad e importancia relativa para la seguridad alimentaria de los frutales. 18 1.4. El estado de la diversidad e importancia relativa para la seguridad alimentaria en hortalizas y oleaginosas. 18 1.5. El estado de la diversidad en los cultivos industriales (caña de azúcar, café, cacao, tabaco y fibras). 20 1.6. El estado de la diversidad de los pastos y forrajes y plantas silvestres útiles. 21 1.7. El estado de la diversidad en los recursos genéticos forestales. 22 1.8. El estado de la diversidad en los cultivos subutilizados. 24 1.9. Consideraciones generales. 24 Capítulo 2: El Estado del Manejo In Situ de los RFAA. 25 2.1. Inventarios de la agrobiodiversidad in situ. 25 2.2. Apoyo para el ordenamiento en y mejoramiento en fincas de los 26 RFAA.
[Show full text]
Complete Sequence of Kenaf (Hibiscus Cannabinus)
www.nature.com/scientificreports OPEN Complete sequence of kenaf (Hibiscus cannabinus) mitochondrial genome and comparative analysis Received: 2 November 2017 Accepted: 27 July 2018 with the mitochondrial genomes of Published: xx xx xxxx other plants Xiaofang Liao1,2,3, Yanhong Zhao3, Xiangjun Kong2, Aziz Khan2, Bujin Zhou 2, Dongmei Liu4, Muhammad Haneef Kashif2, Peng Chen2, Hong Wang5 & Ruiyang Zhou2 Plant mitochondrial (mt) genomes are species specifc due to the vast of foreign DNA migration and frequent recombination of repeated sequences. Sequencing of the mt genome of kenaf (Hibiscus cannabinus) is essential for elucidating its evolutionary characteristics. In the present study, single- molecule real-time sequencing technology (SMRT) was used to sequence the complete mt genome of kenaf. Results showed that the complete kenaf mt genome was 569,915 bp long and consisted of 62 genes, including 36 protein-coding, 3 rRNA and 23 tRNA genes. Twenty-fve introns were found among nine of the 36 protein-coding genes, and fve introns were trans-spliced. A comparative analysis with other plant mt genomes showed that four syntenic gene clusters were conserved in all plant mtDNAs. Fifteen chloroplast-derived fragments were strongly associated with mt genes, including the intact sequences of the chloroplast genes psaA, ndhB and rps7. According to the plant mt genome evolution analysis, some ribosomal protein genes and succinate dehydrogenase genes were frequently lost during the evolution of angiosperms. Our data suggest that the kenaf mt genome retained evolutionarily conserved characteristics. Overall, the complete sequencing of the kenaf mt genome provides additional information and enhances our better understanding of mt genomic evolution across angiosperms.
[Show full text]
Tensile Properties of Bamboo, Jute and Kenaf Mat-Reinforced Composite
Available online at www.sciencedirect.com ScienceDirect Energy Procedia 56 ( 2014 ) 72 – 79 11th Eco-Energy and Materials Science and Engineering (11th EMSES) Tensile Properties of Bamboo, Jute and Kenaf Mat-Reinforced Composite Toshihiko HOJOa,Zhilan XUb, Yuqiu YANGb*, Hiroyuki HAMADAa aKyoto Institute of Technology,Matsugasaki,Sakyo-ku, Kyoto, 6068585,Japan b Donghua University,Songjiang District,Shanghai, 201620,China Abstract Natural fibers, characterized by sustainability, have gained a considerable attention in recent years, due to their advantages of environmental acceptability and commercial viability. In this paper, several kinds of composites with natural fiber mat as reinforcement and unsaturated polyester(UP) as matrix, including jute/UP, kenaf/UP and bamboo/UP, were fabricated by hand lay-up and compression molding methods. Their tensile properties were tested and discussed, as well as the low cycle fatigue(LCF) behavior of three composites, which was compared with glass/UP. After the test, the fracture cross sectional observations were carried out on the selected test specimens using a scanning electron microscope(SEM),with a focus on the fracture morphologies. © 2014 Elsevier The Authors. Ltd. This Published is an open by access Elsevier article Ltd. under the CC BY-NC-ND license Peer-review(http://creativecommons.org/licenses/by-nc-nd/3.0/ under responsibility of COE of Sustainalble). Energy System, Rajamangala University of Technology Thanyaburi (RMUTT).Peer-review under responsibility of COE of Sustainalble Energy System, Rajamangala University of Technology Thanyaburi (RMUTT) Keywords: tensile property ; natural fiber mat; composites 1. Introduction Over the past few decades, there has been a growing interest in the use of natural fibers [1].
[Show full text]
Experimentally and Investigation on Mechanical Properties of Kenaf & Flax with Different Compositions Using Hand Layup Technique
|| Volume 5 || Issue 12 || December 2020 || ISO 3297:2007 Certified ISSN (Online) 2456-3293 EXPERIMENTALLY AND INVESTIGATION ON MECHANICAL PROPERTIES OF KENAF & FLAX WITH DIFFERENT COMPOSITIONS USING HAND LAYUP TECHNIQUE 1PYLA SATYA SAIRAM, 2Mr. K. SIVA RAJU 1M.Tech student, Dept.of Mechanical Engineering, Helapuri Institute of Technology and Science(Vegavaram, Denduluru (M), ELURU, West Godavari District – 534 450)Andhrapradesh. 2Internal Guide, Assistant professor, Head of the department, Dept.of Mechanical Engineering, Helapuri Institute of Technology and Science (Vegavaram, Denduluru (M), ELURU, West Godavari District – 534 450) Andhrapradesh. [email protected],[email protected] ------------------------------------------------------------------------------------------------------------ Abstract: A composite material is made from two or more constituent materials; having better properties compared two both two parent materials. The composite is stronger, lighter, and less expensive compared with the traditional materials. In current years composites have considerable importance as a potential operational material. Less cost, less weight , more specific modulus, biodegradability and renew ability are the most basic and common attractive features of composites that make them useful for industrial applications. With less cost, ,more specific mechanical properties natural fiber signifies a worthy renewable and biodegradable composite. Among those kenaf, flax and its hybrid fibers. The present work has been done with an
[Show full text]
Mechanical Behaviour of Hybrid Composites Prepared Using Sisal-Pineapple-Kenaf Fibre
International Journal of Recent Technology and Engineering (IJRTE) ISSN: 2277-3878, Volume-8 Issue-5, January 2020 Mechanical Behaviour of Hybrid Composites Prepared using Sisal-Pineapple-Kenaf Fibre D Tamilvendan, G Mari Prabu, S Sivaraman, A. R. Ravikumar durability, tensile strength, impact strength, rupture strengths, Abstract: Variety of application use fibre reinforced composites stiffness and fatigue characteristics. Due to these numerous because of their intrinsic properties in mechanical strength, superior properties, they are extensively used in the machine renewability and low production cost compared to conventional parts like drive shafts, tanks, pressure vessels , automotive, materials. Natural fibres are environmentally friendly their use will not break the budget when used as an alternative to the combustion engines, thermal management, railway coaches regular materials. Reinforcement used in polymer is either and aircraft structures and power plant structures. man-made or natural. Man-made synthetic, metallic, Composites are made up of chemically distinct multiphase semi-synthetic, polymer fibres have superior specific strength but materials separated by distinct interface that exhibit better their high cost of production limits its application and feasibility to combination of properties compared to the constituent make composites. Recently there is a rise in use of natural fibres materials. Composite material is a combination of robust from various natural resources which are available abundantly. Composites based on natural fibres have their advantages of cost load-carrying material (known as reinforcement) imbedded in making the fibres from different vegetables, wood, animals and with weaker materials (known as matrix) differing in minerals. In this work a thorough and systematic inquiry composition on a macro scale.
[Show full text]
Raffia Palm Fibre, Composite, Ortho Unsaturated Polyester, Alkali Treatment
American Journal of Polymer Science 2014, 4(4): 117-121 DOI: 10.5923/j.ajps.20140404.03 The Effect of Alkali Treatment on the Tensile Behaviour and Hardness of Raffia Palm Fibre Reinforced Composites D. C. Anike1,*, T. U. Onuegbu1, I. M. Ogbu2, I. O. Alaekwe1 1Department of Pure and Industrial Chemistry, Nnamdi Azikiwe University Awka, Anambra State, Nigeria 2Department of Chemistry Federal University Ndufu-Alike, Ikwo Ebonyi State, Nigeria Abstract The effects of alkali treatment and fibre loads on the properties of raffia palm fibre polyester composite were studied. Some clean raffia palm fibres were treated with 10% NaOH, and ground. The ground treated and untreated fibres were incorporated into the ortho unsaturated polyester resin. The treated and the untreated fibre composites samples were subjected to tensile tests according to ASTM D638 using instron model 3369. The microhardness test was done by forcing a diamond cone indenter into the surface of the hard specimen, to create an indentation. The significant findings of the results showed that alkali treatment improved the microhardness and extension at break at all fibre loads, better than the untreated fibre composites, with the highest values at 20% (14.40 and 3.47mm for microhardness and extension at break respectively). Tensile strength, tensile strain and modulus of elasticity also improved for alkali treated fibre composites, except in 5% and 20% for tensile strength, 15% for tensile strain, and 15% and 20% for modulus of elasticity, compared to the corresponding fibre loads of untreated fibre composites. Keywords Raffia palm fibre, Composite, Ortho unsaturated polyester, Alkali treatment The main drawbacks of such composites are their water 1.
[Show full text]
Natural Fibers and Fiber-Based Materials in Biorefineries
Natural Fibers and Fiber-based Materials in Biorefineries Status Report 2018 This report was issued on behalf of IEA Bioenergy Task 42. It provides an overview of various fiber sources, their properties and their relevance in biorefineries. Their status in the scientific literature and market aspects are discussed. The report provides information for a broader audience about opportunities to sustainably add value to biorefineries by considerin g fiber applications as possible alternatives to other usage paths. IEA Bioenergy Task 42: December 2018 Natural Fibers and Fiber-based Materials in Biorefineries Status Report 2018 Report prepared by Julia Wenger, Tobias Stern, Josef-Peter Schöggl (University of Graz), René van Ree (Wageningen Food and Bio-based Research), Ugo De Corato, Isabella De Bari (ENEA), Geoff Bell (Microbiogen Australia Pty Ltd.), Heinz Stichnothe (Thünen Institute) With input from Jan van Dam, Martien van den Oever (Wageningen Food and Bio-based Research), Julia Graf (University of Graz), Henning Jørgensen (University of Copenhagen), Karin Fackler (Lenzing AG), Nicoletta Ravasio (CNR-ISTM), Michael Mandl (tbw research GesmbH), Borislava Kostova (formerly: U.S. Department of Energy) and many NTLs of IEA Bioenergy Task 42 in various discussions Disclaimer Whilst the information in this publication is derived from reliable sources, and reasonable care has been taken in its compilation, IEA Bioenergy, its Task42 Biorefinery and the authors of the publication cannot make any representation of warranty, expressed or implied, regarding the verity, accuracy, adequacy, or completeness of the information contained herein. IEA Bioenergy, its Task42 Biorefinery and the authors do not accept any liability towards the readers and users of the publication for any inaccuracy, error, or omission, regardless of the cause, or any damages resulting therefrom.
[Show full text]
Jute and Kenaf Chapter 7
7 Jute and Kenaf Roger M. Rowell and Harry P. Stout CONTENTS 7.1 Introduction......................................................................................................................406 7.2 Formation of Fiber .......................................................................................................407 7.3 Separation of Blast Fiber from Core ............................................................................408 7.4 Fiber Structure................................................................................................................ 409 7.5 Chemical Composition..................................................................................................................411 7.6 Acetyl Content ................................................................................................................412 7.7 Changes in Chemical and Fiber Properties during the Growing Season ................. 414 7.8 Fine Structure ...............................................................................................................419 7.9 Physical Properties ..........................................................................................................420 7.10 Grading and Classification............................................................................................421 7.11 Fiber and Yarn Quality..................................................................................................................... 423 7.12 Chemical Modification for Property Improvement.......................................................424
[Show full text]
Thermal Behaviour of Flax Kenaf Hybrid Natural Fiber Composite
ISSN: 2350-0328 International Journal of Advanced Research in Science, Engineering and Technology Vol. 2, Issue 10 , October 2015 Thermal Behaviour of Flax Kenaf Hybrid Natural Fiber Composite V.S. Srinivasan, S. Rajendra Boopathy, B. Vijaya Ramnath Department of Mechanical Engineering, CEGC, Anna University, Chennai-25. Department of Mechanical Engineering, CEGC, Anna University, Chennai-25. Department of Mechanical Engineering, Sri Sairam Engineering College, Chennai-44. ABSTRACT: In this work, natural fibers of flax and kenaf are used. Hybrid materials are given importance as they play very important role in all applications and characterizations. This paper deals with one of such hybrid composite made of natural fibers namely, kenaf and flax fibers. The hybrid built-up is such that one layer of kenaf is sandwiched between two layers of flax fibres by hand layup method with a volume fraction of 40% using Epoxy resin and HY951 hardener. Glass fiber reinforcement polymer (GFRP) is used for lamination on both sides. Thermal properties are investigated for single fiber composites and kenaf - flax with GFRP hybrid composites. The hybrid composites have better thermal stability than single fibre composites. KEYWORDS: Flax, Kenaf, GFRP, Thermal behavior 1. INTRODUCTION The usage of natural fiber- reinforced composite materials is rapidly growing both in industries and in various research activities. The advantages of fibers are cheap, recyclable and biodegradable. Plants such as flax, hemp, cotton sisal, kenaf, banana etc., are the most used reinforcements of composites. They are used widely for manufacturing composites because of their easy availability, renewability, low density, and low price. The natural fiber containing composites are more environmental friendly and are used in transportation (automobiles, railway coaches, aerospace etc.,), military applications, building and construction industries in paneling and partition boards, packaging, consumer products etc.
[Show full text]
Kinetics and Thermodynamics of Dispersed Oil Sorption by Kapok Fiber
DOI: 10.1515/eces-2019-0053 ECOL CHEM ENG S. 2019;26(4):759-772 Check Shyong QUEK 1, Norzita NGADI 1* and Muhammad Abbas Ahmad ZAINI 1,2 KINETICS AND THERMODYNAMICS OF DISPERSED OIL SORPTION BY KAPOK FIBER KINETYKA I TERMODYNAMIKA SORPCJI ZDYSPERGOWANEGO OLEJU PRZEZ WŁÓKNO KAPOKA Abstract: This work was aimed at evaluating the sorption of dispersed oil by kapok fiber. The physicochemical characteristics of kapok fiber were investigated using BET, SEM, FTIR, XRD, contact angle and elemental analysis. The oil droplet size distribution at different temperatures was analysed using a Coulter counter, and its relationship with sorption was investigated. The effects of dosage, hydraulic retention time and temperature, on the sorption performance were studied. The result indicates that the sorption of dispersed oil by kapok fiber is spontaneous, endothermic and agreed with the pseudo-first-order reaction kinetics. The amount of oil that could be removed is about 28.5 %, while that of water is less than 1 % of the original amount (0.5 dm 3). Kapok is a promising natural hydrophobic fiber for dispersed oil removal from oily wastewater. Keywords: dispersed oil, hydrophobic, kapok fiber, kinetics of sorption, thermodynamics of sorption Introduction There has been an increasing concern over the presence of dispersed oil in oily wastewater [1]. Most of the earlier and related works are mainly concerned about the removal of floating oil from the surface of water, and to be more specific, in the remediation of marine oil spills caused by the accidental release of petroleum from tankers and drilling rigs. The usual steps are to employ boomers and skimmers, to contain and collect the oil, and then to apply dispersant on the remaining oil slick to break it up into small droplets that would dilute and travel to deeper parts of the ocean and away from the coastline [2].
[Show full text]
Properties of Raphia Palm Interspersed Fibre Filled High Density Polyethylene
Hindawi Publishing Corporation Advances in Materials Science and Engineering Volume 2013, Article ID 932143, 5 pages http://dx.doi.org/10.1155/2013/932143 Research Article Properties of Raphia Palm Interspersed Fibre Filled High Density Polyethylene Henry C. Obasi Department of Polymer and Textile Engineering, Federal University of Technology, Owerri, P.M.B. 1526, Owerri, Imo State, Nigeria Correspondence should be addressed to Henry C. Obasi; [email protected] Received 29 May 2013; Accepted 1 October 2013 Academic Editor: Wen-Hua Sun Copyright © 2013 Henry C. Obasi. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. Blends of nonbiodegradable and biodegradable polymers can promote a reduction in the volume of plastic waste when they undergo partial degradation. In this study, properties of raphia palm interspersed fibre (RPIF) filled high density polyethylene (HDPE) have been investigated at different levels of filler loadings, 0 to 60 wt.%. Maleic anhydride-graft polyethylene was used as a compatibilizer. Raphia palm interspersed fibre was prepared by grinding and sieved to a particle size of 150 m. HDPE blends were prepared in a corotating twin screw extruder. Results showed that the tensile strength and elongation at break of the blends decreased with increase in RPI loadings and addition of MA-g-PE was found to improve these properties. However, the Young’s modulus increased with increase in the amount of RPI into HDPE and compatibilization further increased the Young’s modulus. The water absorption indices and weight loss for RPI/HDPE composites were found to increase with RPI loadings but were decreased on addition of MA-g-PE.
[Show full text]
Stress Physiology in Cotton
STREss PHYSIOLOGY IN COTTON NRUMBE SEVEN THE COTTON FOUNDATION REFERENCE BOOK SERIES Edited by Derrick M. Oosterhuis STRESS PHYSIOLOGY IN COTTON THE COTTON FOUNDATION Reference Book Series The Cotton Foundation was created in 1955 to foster research and education for the cotton industry. Supported by membership dues and grants from agribusiness firms, the Foundation plays an integral role in focusing attention to high priority research and education needs. Foun- dation members include the world’s finest manufactures and suppliers of cotton machinery, plant health products, transgenic technologies, planting seed, testing instruments, processing materials; and consulting, financial and communications services The alliance of agribusiness and the cotton industry strengthens the ability of both to reach common objectives – enhance markets and profitability. Understanding that sales and service are ultimately linked to the vitality of the cotton industry, corporate suppliers support the Foun- dation with dues and special earmarked grants. The Foundation’s offices are located at the Na- tional Cotton Council’s headquarters in Cordova, Tennessee. We are pleased to publish STRESS PHYSIOLOGY IN COTTON, the seventh in the series of cotton reference books. The first volume, COTTON PHYSIOLOGY was published in 1986; the second, WEEDS OF COTTON: Characterization and Control was published in 1992; the third, COTTON INSECTS AND MITES: Characterizations and Management, was published in 1996; the fourth volume, VEGETABLE OILS AND AGROCHEMICALS became available in 1994; the fifth volume,COTTON HARVEST MANAGEMENT: Use and Influence of Har- vest Aids and the sixth volume, BOLL WEEVIL ERADICATION IN THE UNITED STATES THROUGH 1999 were both published in 2001. Bill M.
[Show full text]