Untangling the Formation and Liberation of Water in the Lunar Regolith
Untangling the formation and liberation of water in the lunar regolith Cheng Zhua,b,1, Parker B. Crandalla,b,1, Jeffrey J. Gillis-Davisc,2, Hope A. Ishiic, John P. Bradleyc, Laura M. Corleyc, and Ralf I. Kaisera,b,2 aDepartment of Chemistry, University of Hawai‘iatManoa, Honolulu, HI 96822; bW. M. Keck Laboratory in Astrochemistry, University of Hawai‘iatManoa, Honolulu, HI 96822; and cHawai‘i Institute of Geophysics and Planetology, University of Hawai‘iatManoa, Honolulu, HI 96822 Edited by Mark H. Thiemens, University of California at San Diego, La Jolla, CA, and approved April 24, 2019 (received for review November 15, 2018) −8 −6 The source of water (H2O) and hydroxyl radicals (OH), identified between 10 and 10 torr observed either an ν(O−H) stretching − − on the lunar surface, represents a fundamental, unsolved puzzle. mode in the 2.70 μm (3,700 cm 1) to 3.33 μm (3,000 cm 1) region The interaction of solar-wind protons with silicates and oxides has exploiting infrared spectroscopy (7, 25, 26) or OH/H2Osignature been proposed as a key mechanism, but laboratory experiments using secondary-ion mass spectrometry (27) and valence electron yield conflicting results that suggest that proton implantation energy loss spectroscopy (VEEL) (28). However, contradictory alone is insufficient to generate and liberate water. Here, we dem- studies yielded no evidence of H2O/OH in proton-bombarded onstrate in laboratory simulation experiments combined with minerals in experiments performed under ultrahigh vacuum − − imaging studies that water can be efficiently generated and re- (UHV) (10 10 to 10 9 torr) (29).
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