Geological Survey, Petrology and Fluid Geochemistry of the Apacheta-Aguilucho Volcanoes (Andean Central Volcanic Zone, Northern Chile) and Their Geothermal System F

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Geological Survey, Petrology and Fluid Geochemistry of the Apacheta-Aguilucho Volcanoes (Andean Central Volcanic Zone, Northern Chile) and Their Geothermal System F GNGTS 2008 SESSIONE 1.2 GEOLOGICAL SURVEY, PETROLOGY AND FLUID GEOCHEMISTRY OF THE APACHETA-AGUILUCHO VOLCANOES (ANDEAN CENTRAL VOLCANIC ZONE, NORTHERN CHILE) AND THEIR GEOTHERMAL SYSTEM F. Aguilera 1, S. Ahumada 2, J.L. Mercado 2, F. Piscaglia 3, A. Renzulli 3, F. Tassi 4 1 Programa de Doctorado en Ciencias mención Geología, Universidad Católica del Norte, Antofagasta, Chile 2 Departamento de Ciencias Geológicas, Universidad Católica del Norte, Antofagasta, Chile 3 Istituto di Scienze della Terra, Università degli Studi “Carlo Bo”, Urbino, Italy 4 Dipartimento di Scienze della Terra, Università degli Studi di Firenze, Italy The Apacheta-Aguilucho Volcanoes (AAV; ca. 21º50’S and 68º10’W; Fig. 1) are located in the northernmost sector of the Altiplano Puna Volcanic Complex (APVC; Fig. 1) which is a large zone of silicic volcanism occupying the 21-24°S segment of the Central Andean Volcanic Zone (ACVZ; de Silva, 1989; de Silva et al., 1994) an area characterized by a continental crust >70 km thick (Schmitz et al., 1999).The APVC is dominated by 1-10 Ma ignimbrite flare up (de Silva et al., 2007) and, although no major ignimbrite-caldera forming eruptions of < 1 Ma are known, relatively young dacite to rhyolite lavas (e.g. Chao; Fig. 1) and domes (tortas; e.g. Chillauita dome; Fig. 1) erupted in the past 100 ka and the presence of famous active geothermal fields (i.e El Tatio and Sol de la Mañana) seem to indicate that the magmatic system of the APVC is currently active (de Silva, 1989). A geothermal system was recently discovered 60 km to the NNW of El Tatio by CODEL- CO, while drilling a shallow water well, in the area of the AAV (Lahsen et at., 2005). MT and TDEM survey detected a low resistivity boundary (< 10 ohm-m) extending over an area of 25 km2 Fig. 1 – Landsat TM image of the northernmost sector of the APVC. 55 GNGTS 2008 SESSIONE 1.2 (Urzua et al, 2002) whereas a temperature >200°C was found at depths >500 m in a 550 m-deep core-hole recently carried out (October 2007) by the Empresa Nacional de Geotermia (Enel-Enap joint venture). The Apacheta-Aguilucho geothermal system is hosted by a 3 to 5 km wide, NW trending Inacaliri graben (Fig. 1) nesting the Pliocene-Pleistocene lavas and pyroclastics of the AAV. The graben is bordered by NW striking normal faults (up to 18 km long) and associated with minor faults affecting the downward block. Although the regional tectonic environment of the ACVZ is dominantly compressive, both N-S and NW–SE fault systems were often reactivated with extensional motions (Froidevaux and Isacks, 1984). The structural pattern of the Inacaliri graben, as well as that of the northernmost centers of the APVC appears to be therefore controlled by a series of NW striking faults (de Silva et al., 1994), possibly related to the well constrained Pastos Grandes-Lipez-Coranzuli fault system to the east. The geological survey of the AAV coupled with petrology, geochronology and fluid geochem- istry investigations were carried out as additional surface exploration of this promising geothermal system. The regional basement of the AAV is constituted by the Miocene to Plio-Pleistocene ign- imbrites of the APVC. The evolution of the AAV was divided into five stages during which high-K calcalkaline pyroclastic flows and lavas of andesite to dacite composition were erupted. On a petro- logic point of view, low Sm/Yb ratios of the AAV andesites and dacites seem to rule out the pres- ence of a “garnet control” during crustal contamination processes of these magmas. Such ratios are similar to those of other silicic centres of the APVC and differ significantly from those of many products of the ACVZ where high Sm/Yb and Sr/Y ratios were controlled by low Y and Yb, due to the presence of garnet in the residue of mafic lower crustal assimilation (e.g. granulites and amphi- bolites), and/or during high-P fractional crystallization after crustal thickening. In addition, low La/Sr ratios of the AAV lavas do not emphasize a fundamental role played by plagioclase during fractional crystallization. Stage I-III represents the main build up of the andesite to dacite Apacheta volcano, now moder- ately eroded and hosting the present fumarolic activity (eastern flank). The old crater is covered by a succession of slightly to strongly welded pyroclastic flows, and is sealed by a single porphyritic dacite lava flow, extending up to 2.5 km and showing ridge flow structures. Stage IV-V corresponds to the development of the Aguilucho volcano and mainly consist of dacite lava flow units and two lava dome systems. These latter (Chac-Inca and Pabellón domes) are located to the north and east of the Aguilucho volcano, respectively, and are characterized by abun- dant fine grained mostly aphyric andesite-basaltic andesite inclusions (from few up to 20 cm) show- ing liquid-liquid interactions (crenulated margins) with the dacite magma. The two dacite dome sys- tems clearly represent the youngest activity of the AAV and were emplaced along the northern fault systems of the NW trending Inacaliri graben. The Pabellón dome was dated at 50 ± 10 ka, (K/Ar; Urzua et al., 2002) and 80-130 ka (Ar-Ar Renzulli et al., 2006). Prominent hydrothermal alteration is present in the north, west, southwest and eastern flanks of the AAV, and is partially related to past and present fumarolic activity. The structural weakening of the AAV by hydrothermal alteration is confirmed by the presence of a Debris Avalanche Deposit (DAD) morphologically emphasized by small hummocks in the eastern flank of AAV and mainly consisting of hydrothermally-altered lava fragments. Extensive moraines deposits are present at the northeastern sectors of Chac-Inca dome and western flanks of the Apacheta volcano. They are relat- ed to the last maximum glacial age (11,000 yr BP). Thermal fluid discharges of the Apacheta fumarolic system have outlet temperatures varying between 83.2 and 84.3 °C. The chemical composition of dry gases is dominated by the presence of CO2 (up to 978597 µmol/mol) and N2 (up to 25876 µmol/mol). Among acid gases, H2S is general- ly present in considerable amounts (up to 7987 µmol/mol) whereas HCl and SO2 contents are lower (up to 607 and 146 µmol/mol, respectively). HF is virtually absent. H2 and O2 show variable con- 56 GNGTS 2008 SESSIONE 1.2 centrations (4097–2170 and 244–76.58 µmol/mol, respectively), while Ar, He and Ne are present only in minor amounts, and CO contents are below the detection limit (0.01 µmol/mol), likely due to its complete dissolution into shallow aquifers. Concerning the organic gas fraction, the composi- tion of light hydrocarbons is marked by a high speciation, a feature that has been commonly observed in fluids of worldwide geothermal areas (e.g. Capaccioni et al., 2004; Tassi et al., 2005). Gas species pertaining to the light alkenes prevail over those of their homologue alkanes. The origin of the thermal fluid discharges of the Apacheta-Aguilucho area is mainly related to the contribution of at least three different component: 1) a low-temperature atmospheric–rich, 2) a medium–temperature hydrothermal, and 3) a high–temperature magmatic–related. The presence of highly acidic gases, coupled with the particularly low contents of hydrocarbons, mainly composed by alkenes, suggest a strong contribution of a high–temperature magmatic fluids (Capaccioni et al., 1995; Giggenbach, 1996). Reservoir temperatures of the AAV geothermal system, calculated on the basis of the H2/Ar geothermometer (Chiodini et al., 2001) and organic gas geothermometers (Capaccioni and Mangani, 2001; Tassi et al., 2005), are particularly high (>330°C), possibly in rela- tion to the presence of a magmatic system still active in the area, as also indicated by the relative- ly high contents of light alkenes, HCl and SO2. Geochemical surveys and related gas thermometers (CO2/Ar and H2/Ar) previously provided by Urzua et al. (2002) indicated lower reservoir tempera- tures (ca 250°C). References Capaccioni B., Martini M. and Mangani F.; 1995: Light hydrocarbons in hydrothermal and magmatic fumaroles: hints of catalytic and thermal reactions. Bull. Volcanol., 56, 593–600. Capaccioni B. and Mangani F.; 2001: Monitoring of active but quiescent volcanoes using light hydrocarbon distribution in volcanic gases: the results of 4 years of discontinuous monitoring in the Campi Flegrei (Italy). Earth Planet. Sci. Lett., 188, 543-555. Capaccioni B., Taran Y., Tassi F., Vaselli O., Mangani F. and Macias J.L.; 2004: Source conditions and degradation processes of light hydrocarbons in volcanic gases: an example from the Chichon Volcano (Chiapas State, Mexico). Chem. Geol., 206, 81-96. Chiodini G., Marini L. and Russo M.; 2001: Geochemical evidence for the existence of high-temperature hydrothermal brines at Vesuvio Volcano, Italy. Geochim. Cosmochim. Acta, 65, 2129-2147. de Silva S.L.; 1989: Altiplano-Puna volcanic complex of the Central Andes. Geology, 17, 1102–1106. de Silva S.L., Self S., Francis P.W., Drake R.E. and Ramirez R.C.; 1994: Effusive silicic volcanism in the Central Andes: the Chao dacite and other young lavas of the Altiplano-Puna volcanic complex. J. Geophys. Res., 99, 17805–17825. de Silva S.L. and Gosnold W.D. ; 2007: Episodic construction of batholiths: insights from the spatiotemporal development of an ignimbrite flare-up. J. Volcanol. Geotherm. Res., 167, 320-335 Froidevaux C. and Isacks B.B.; 1984: The mechanical state of the lithosphere in the Altiplano-Puna segment in the Andes. Earth Planet. Sci. Lett., 71, 305–314. Giggenbach W.; 1996: Chemical composition of volcanic gases. In: Monitoring and mitigation of Volcano Hazards.
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