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Chapter 2 EXPLOSIVES
Chapter 2 EXPLOSIVES This chapter classifies commercial blasting compounds according to their explosive class and type. Initiating devices are listed and described as well. Military explosives are treated separately. The ingredi- ents and more significant properties of each explosive are tabulated and briefly discussed. Data are sum- marized from various handbooks, textbooks, and manufacturers’ technical data sheets. THEORY OF EXPLOSIVES In general, an explosive has four basic characteristics: (1) It is a chemical compound or mixture ignited by heat, shock, impact, friction, or a combination of these conditions; (2) Upon ignition, it decom- poses rapidly in a detonation; (3) There is a rapid release of heat and large quantities of high-pressure gases that expand rapidly with sufficient force to overcome confining forces; and (4) The energy released by the detonation of explosives produces four basic effects; (a) rock fragmentation; (b) rock displacement; (c) ground vibration; and (d) air blast. A general theory of explosives is that the detonation of the explosives charge causes a high-velocity shock wave and a tremendous release of gas. The shock wave cracks and crushes the rock near the explosives and creates thousands of cracks in the rock. These cracks are then filled with the expanding gases. The gases continue to fill and expand the cracks until the gas pressure is too weak to expand the cracks any further, or are vented from the rock. The ingredients in explosives manufactured are classified as: Explosive bases. An explosive base is a solid or a liquid which, upon application or heat or shock, breaks down very rapidly into gaseous products, with an accompanying release of heat energy. -
Schedule 1 — Authorised Explosives [Cl
Schedule 1 — Authorised explosives [cl. 3] UN number Specified explosives of UN classification 1.1A (0129) Lead Azide (0130) Lead Styphnate (0135) Mercury Fulminate (0114) Tetrazene UN number Specified explosives of UN classification 1.1B (0029) Anoline Delay Detonators (ICI) (0029) Austin Delay Primer Delays (0225) Boosters, with Detonator (0029) Capped (Detonator) safety fuse (0360) Capped Fuse Delay Assembly (ICI) (0360) CXA MS Connectors (TES) (0030) Carrick Short Delay Detonators (ICI) (0030) Coal Mine Delay Detonators (Du Pont) (0360) Cordline Delay Detonators (ICI) (0030) Delay Detonators (0029) Detaline MS in the hole Delays (Du Pont) (0029) Detaline MS Surface Delays (Du Pont) (0029) Detaline Starter (Du Pont) (0029) Detonating Relays (0029) Detonators (0030) Du Pont Acudet Mark V Detonators (0360) Du Pont Detaslide (0030) Du Pont SSS Seismic Detonators (0030) Electric Delay Detonators (ERT) (0030) Electric Detonators (0030) Electric Instantaneous II Detonators (ICI) (0030) Electric Super SP (DWL) (0030) Electric Super Seismicdet (DNAP) (0360) Etinel Non Electric Detonators (ERT) (0360) Exel Bunchdet Detonators (ICI) (0360) Exel Connectadet Detonators (ICI) (0360) Exel Detonators (ICI) (0360) Exel Detonators (MS & LP Series) (ICI) (0360) Exel Enduredet Detonators (ICI) (0360) Exel Goldet Detonators (ICI) (0360) Exel Lead-In Line (ICI) (0360) Exel LLHD Detonators (ICI) (0360) Exel MS Connectors (ICI) (0360) Exel Trunkline Delay (ICI) (0360) Fanel Non Electrical Delay Detonators (TES) (0360) Fuse Delay Assembly (0030) High Pressure -
Guide for the Selection of Commercial Explosives Detection Systems For
2.5.3.8 EXPRAY Field Test Kit EXPRAY is a unique, aerosol-based field test kit for the detection of what the manufacturer refers to as Group A explosives (TNT, DNT, picric acid, etc.), Group B explosives (Semtex H, RDX, PETN, NG, smokeless powder, etc.), and compounds that contain nitrates that are used in improvised explosives. Detection of explosive residue is made by observing a color change of the test paper. EXPRAY can be used in a variety of applications, and although in some aspects it does not perform as well as many of the other trace detectors discussed in this section, it costs only $250. This very low cost, coupled with simplicity and ease of use, may make it of interest to many law enforcement agencies (see the EXPRAY kit in fig. 13). The EXPRAY field kit2 is comprised of the following items: - one can of EXPRAY-1 for Group A explosives, - one can of EXPRAY-2 for Group B explosives, - one can of EXPRAY-3 for nitrate-based explosives (ANFO, black powder, and commercial and improvised explosives based on inorganic nitrates), - special test papers which prevent cross contamination. Figure 13. Photo of the EXPRAY Field Test Kit for explosives Initially, a suspected surface (of a package, a person’s clothing, etc.) is wiped with the special test paper. The paper is then sprayed with EXPRAY-1. The appearance of a dark violet-brown color indicates the presence of TNT, a blue-green color indicates the presence of DNT, and an orange color indicates the presence of other Group A explosives. -
Schedule 1 — Authorised Explosives [Cl
Schedule 1 — Authorised explosives [cl. 3] UN number Specified explosives of UN classification 1.1A (0129) Lead Azide (0130) Lead Styphnate (0135) Mercury Fulminate (0114) Tetrazene UN number Specified explosives of UN classification 1.1B (0029) Anoline Delay Detonators (ICI) (0029) Austin Delay Primer Delays (0225) Boosters, with Detonator (0029) Capped (Detonator) safety fuse (0360) Capped Fuse Delay Assembly (ICI) (0360) CXA MS Connectors (TES) (0030) Carrick Short Delay Detonators (ICI) (0030) Coal Mine Delay Detonators (Du Pont) (0360) Cordline Delay Detonators (ICI) (0030) Delay Detonators (0029) Detaline MS in the hole Delays (Du Pont) (0029) Detaline MS Surface Delays (Du Pont) (0029) Detaline Starter (Du Pont) (0029) Detonating Relays (0029) Detonators (0029) DRC Detonators (Orica) (0030) Du Pont Acudet Mark V Detonators (0360) Du Pont Detaslide (0030) Du Pont SSS Seismic Detonators (0030) Electric Delay Detonators (ERT) (0030) Electric Detonators (0030) Electric Instantaneous II Detonators (ICI) (0030) Electric Super SP (DWL) (0030) Electric Super Seismicdet (DNAP) (0360) Etinel Non Electric Detonators (ERT) (0360) Exel Bunchdet Detonators (ICI) (0360) Exel Connectadet Detonators (ICI) (0360) Exel Detonators (ICI) (0360) Exel Detonators (MS & LP Series) (ICI) (0360) Exel Enduredet Detonators (ICI) (0360) Exel Goldet Detonators (ICI) (0360) Exel Lead-In Line (ICI) (0360) Exel LLHD Detonators (ICI) (0360) Exel MS Connectors (ICI) (0360) Exel Trunkline Delay (ICI) (0360) Fanel Non Electrical Delay Detonators (TES) (0360) Fuse Delay -
Type E High Explosives
G03-01 Type E High Explosives Classification and Authorization General and Detailed Requirements for Type E Explosives March 2015 Explosives Regulatory Division 1 Table of Contents 1. Introduction ........................................................................................................................ 1 1.1 Scope ....................................................................................................................... 1 1.2 Approvals - Authorization of explosives .................................................................... 3 1.3 Regulation of use ...................................................................................................... 3 1.4 Required documentation ........................................................................................... 3 1.5 Continuing authorization ........................................................................................... 3 2. Request for authorization .................................................................................................. 4 2.1 List of articles ............................................................................................................ 4 2.2 Mandatory documentation ........................................................................................ 4 2.2.1 Additional mandatory documentation specific to bulk explosives used for commercial blasting ...................................................................................... 4 2.2.2 Additional mandatory documentation specific to packaged -
Explosives and Blasting Procedures Manual
Information Circular 8925 Explosives and Blasting Procedures Manual By Richard A. Dick, Larry R. Fletcher, and Dennis V. D'Andrea US Department of Interior Office of Surface Mining Reclamation and Enforcement Kenneth K. Eltschlager Mining/Blasting Engineer 3 Parkway Center Pittsburgh, PA 15220 Phone 412.937.2169 Fax 412.937.3012 [email protected] UNITED STATES DEPARTMENT OF THE INTERIOR James G. Watt, Secretary BUREAU OF MINES Robert C. Horton, Director As the Nation's principal conservation agency, the Department of the Interior has responsibility for most of our nationally owned public lands and natural resources. This includes fostering the wisest use of our land and water re• sources, protecting our fish and wildlife, preserving the environmental and cultural values of our national parks and historical places, and providing for the enjoyment of life through outdoor recreation. The Department assesses our energy and mineral resources and works to assure that their development is in the best interests of all our people. The Department also has a major re· sponsibility for American Indian reservation communities and for people who live in Island Territories under U.S. administration. This publication has been cataloged as follows: Dick, Richard A Explosives and blasting procedures manual, (Bureau of Mines Information circular ; 8925) Supt. of Docs. no.: I 28.27:8925. 1. Blasting-Handbooks, manuals, etc, 2. Explosives-Haodbooks, manuals, etc, I. Fletcher, Larry R. II. D'Andrea, Dennis V. Ill, Title, IV. Series: Information circular (United States, Bureau of Mines) ; 8925, TN295,U4 [TN279] 622s [622'.23] 82·600353 For sale by the Superintendent of Documents, U.S. -
FM 5-250: Explosives and Demolitions
FM 5-250 HEADQUARTERS Field Manual DEPARTMENT OF THE ARMY 5-250 Washington, DC, 15 June 1992 i FM 5-250 ii FM 5-250 iii FM 5-250 iv FM 5-250 v FM 5-250 vi FM 5-250 vii FM 5-250 viii FM 5-250 ix FM 5-250 x FM 5-250 xi FM 5-250 xii FM 5-250 xiii FM 5-250 xiv FM 5-250 xv FM 5-250 xvi FM 5-250 xvii FM 5-250 xviii FM 5-250 xix FM 5-250 xx FM 5-250 xxii FM 5-250 xxi FM 5-250 xxiv FM 5-250 xxiii FM 5-250 xxv FM 5-250 xxvi FM 5-250 xxvii FM 5-250 Preface The purpose of this manual is to provide technical information on explosives used by United States military forces and their most frequent applications. This manual does not discuss all applications but presents the most current information on demolition procedures used in most situations. If used properly, explosives serve as a combat multiplier to deny maneuverability to the enemy. Focusing mainly on these countermobility operations, this manual provides a basic theory of explosives, their characteristics and common uses, formulas for calculating various types of charges, and standard methods of priming and placing these charges. When faced with unusual situations, the responsible engineer must either adapt one of the recommended demolition methods or design the demolition from basic principles presented in this and other manuals. The officer in charge must maintain ultimate responsibility for the demolition design, ensuring the safe and efficient application of explosives. -
Chapter 11 SPECIALIZED BLASTING TECHNIQUES
Chapter 11 SPECIALIZED BLASTING TECHNIQUES This chapter includes information about: • Avalanche Blasting • Animal Carcass Removal • 105-M 102 Howitzer • Boulder Blasting • Military Weapons • Air Gapping • Fireline Explosives • Expansion Alternatives • Burnol Backfiring Devices SECTION 11A - AVALANCHE BLASTING SECTION CONTENTS: • Initiating Devices • Explosive Assembly • Use of Hand Charge • Cornice Control • Explosive Safety • Recoilless Weapons - Military Weapons • Avalauncher AVALANCHE BLASTING Slope testing, avalanche release, and snow stabilization are the main objectives for using explosives in avalanche blasting. To achieve these objectives, a standard charge is used that is capable of developing deto- nation pressure equal to 1 kg of TNT. 167 There are several types of explosives that can develop the appropriate detonation pressure. By knowing the detonation velocity and the density of a given explosive, the detonation pressure can be calculated (Chapter 2 - Explosives). INITIATING DEVICES Avalanche blasting is based on a nonelectric detonating system or systems that are not susceptible to initiation from the high static electricity that is prevalent in snowstorms and near ridge crests. Even with non- electric blasting caps, avalanche blasting should not be conducted when there is evidence of a strong static electricity field (cumulonimbus clouds, electric buzzing). Cap-and-Fuse - A cap-and-fuse assembly can detonate explosives that are sensitive to a No. 6 cap (Figure 11- 1). However, in severe winter weather, some primers with low proportions of sensitizers may require a No. 8 cap or larger. Blasting caps are susceptible to accidental ignition from excess heat, friction, or static electricity and should be handled with great care. Where adverse conditions are expected (static electricity), other tech- niques should be used or the blasting operation should be shut down. -
Introduction to Explosives
Introduction to Explosives FOR OFFICIAL USE ONLY Overview Military Explosives – C4 – HMX – PETN – RDX – Semtex Commercial Explosives – ANAL – ANFO – Black Powder – Dynamite – Nitroglycerin – Smokeless Powder – TNT – Urea Nitrate Improvised Explosives* – HMTD – TATP *While many military and commercial explosives can be improvised, HMTD and TATP do not have military or commercial purposes. Introduction to Explosives FOR OFFICIAL USE ONLY Military Explosives Introduction to Explosives FOR OFFICIAL USE ONLY C4: Characteristics, Properties, and Overview American name for the 4th generation of Composition C Explosives, also called Harrisite – Western counterpart to Semtex plastic explosive – Requires a blasting cap for detonation Ingredients: – Approximately 90% RDX; remainder is a plasticizer Appearance: – Smells like motor oil, light brown putty-like substance Uses: – Typically for demolition and metal cutting – Can be specially formed to create targeted explosion – Can be used for underwater operations Sensitivity: – Non-toxic, insensitive to shock, will ignite and burn Introduction to Explosives FOR OFFICIAL USE ONLY C4: Analysis and Trends U.S. manufactured so likely to be found in countries where the U.S. has military connections A preferred terrorist explosive Damaged hull – Used in 2000 U.S.S. Cole and 2002 Bali nightclub of U.S.S. Cole in Yemeni port bombings – Recommended in Al-Qaeda’s traditional curriculum of explosives training – Frequently used in IEDs in Iraq Can only be purchased domestically by legitimate buyers through -
Explosives Glossary
TCM: Improvised Explosive and Incendiary Devices Glossary Ammonium Nitrate – a chemical oxidizer commonly used in the manufacture of explosive products. ANFO – an explosive material consisting of ammonium nitrate and fuel oil. Binary Explosive – a blasting explosive formed by mixing or combining two plosophoric materials (e.g., ammonium nitrate and nitromethane). Black Powder –a low explosive consisting of a mixture of sulfur, charcoal, and an alkali nitrate, usually potassium or sodium nitrate. Blasting Agent –an explosive material which meets prescribed criteria for insensitivity to initiation. For storage, Title 27, Code of Federal Regulations, Section 55.11 defines a blasting agent as any material or mixture, consisting of fuel and oxidizer intended for blasting, not otherwise defined as an explosive: provided, that the finished product, as mixed for use or shipment, cannot be detonated by means of a No. 8 test blasting cap (detonator) when unconfined (Bureau of Alcohol, Tobacco and Firearms Regulation). For transportation, Title 49 CFR, Section 1173.50, defines Class 1, Division 1.5 (blasting agent) as a substance which has mass explosion hazard but is so insensitive that there is very little probability of initiation or of transition from burning to detonation under normal conditions in transport. Camouflaged device - An explosive device disguised to avoid detection. Class A Explosives – a term formerly used by the U.S. Department of Transportation to describe explosives that possess detonating or otherwise maximum hazard. (Currently classified as Division 1.1 or 1.2 materials.) Class B Explosives – a term formerly used by the U.S. Department of Transportation to describe explosives that possess a flammable hazard. -
Exam Study Material – Blaster Part 2
/ ISEE -Journal of Explosives : En o-ineering . • Vof. 13 No.7 July/August 1996 : Back to Basics: : Electric Initiation Part 4 A blaster, using electric initia sense require that whenever an tion, must be aware of certain electrical storm approaches, hazards specific to this type of blasting operations must be sus system. Since electric detonators pended. Not only must opera are designed to fire when electri tions cease, but the blasting crew cal energy is applied to them, any must evacuate the area and clear extraneous source of electric cur the site of personnel and equip rent represents a potential prema ment, just as if detonation were ture initiation source. Therefore, imminent. There are devices such things as lightning, radio available which are capable of transmitters, high voltage power detecting a storm's approach · lines or sources of static electrici before it poses a threat to the ty m~rst be avoided. Additionally, blasting crew, and emitting a any condition which would cause warning signal when a thunder by Larry Schneider a reduction in the applied current storm and lightning comes within may result in insufficient firing a certain range. current and create a misfire haz ard; any condition producing an High Voltage Power excessive current may result in Transmission Lines hangfires. High voltage power lines pre sent two distinct dangers to Lightnin9 blasters using electric initiation Lightning is considered to be systems. First, high voltage alter the greatest danger associated nating current in the power li~e with electric blasting. Nearly eve,ry has the potential to produce a ,blaster has either experienced this secondary current in the blasting personally, or knows of such circuit. -
Construction Safety and Health Standard Part 27. Blasting and Use of Explosives
MIOSHA-STD-1322 (04/15) For further information 14 Pages Ph: 517-284-7740 www.michigan.gov/mioshastandards DEPARTMENT OF LICENSING AND REGULATORY AFFAIRS DIRECTOR'S OFFICE CONSTRUCTION SAFETY STANDARDS Filed with the Secretary of State on January 20, 1982 (as amended January 11, 1988) (as amended June 1, 1994) (as amended April 5, 2013) (as amended April 7, 2015) These rules become effective immediately upon filing with the Secretary of State unless adopted under section 33, 44, or 45a(6) of 1969 PA 306. Rules adopted under these sections become effective 7 days after filing with the Secretary of State. (By authority conferred on the director of the department of licensing and regulatory affairs by sections 19 and 21 of 1974 PA 154, MCL 408.1019 and 408.1021, and Executive Reorganization Order Nos. 1996-2, 2003-1, 2008-4, and 2011-4, MCL 445.2001, 445.2011, 445.2025, and 445.2030) R 408.42701 of the Michigan Administrative Code is amended, R 408.42705 and R 408.442710 are added, and R 408.42724, R 408.42725, R 408.42726, R 408.42727, R 408.42728, R 408.42731, R 408.42732, R 408.42733, R 408.42734, R 408.42735, R 408.42737, R 408.42741, R 408.42742, R 408.42743, R 408.42744, R 408.42751, R 408.42752, R 408.42753, R 408.42754, R 408.42755, R 408.42757, R 408.42758, R 408.42759, R 408.42761, R 408.42762, R 408.42763, R 408.42799 are rescinded, as follows: CONSTRUCTION SAFETY AND HEALTH STANDARD PART 27.