UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460

OFFICE OF CHEMICAL SAFETY AND POLLUTION PREVENTION

Dr. Khalid H. Akkari BASF Corporation, Agricultural Products JUN 0 4 2012 26 Davis Drive P.O. Box 13528 Research Triangle Park, NC 27709

Subject: Pristine Fungicide EPA Reg. No. 7969-199 Your letter dated April 13, 2012 EPA Decision Number: 464483

Dear Dr. Akkari:

The master labeling and supplemental labeling referred to above, submitted in connection with registration under the Federal Insecticide, Fungicide, and Rodenticide Act, as amended, to add a restriction for use on blueberries in California, is acceptable.

Stamped copies of the master and supplemental label "Accepted" are enclosed for your records. These labels supersede all other previously accepted labels. Please submit one copy of the final printed labels before the product is released for shipment. If you have any questions please contact Heather Garvie by phone at: 703-308-0034 or via email at: [email protected] .

Sincerely,

Marcel Howard Acting Product Manager (20) Fungicide Branch (7504P) Registration Division BASF I Group Fungicide The Chemical Company ACCEPTED JUN 0 4 2012 Under the Federal insecticide, Fungicide, and Rodenticide Act, as amended, for the pesticide registered under EFA Reg No

PristinFUNGICIDeE

For use in disease control and plant health in the following crops: berries, bulb vegetables, carrots, celery, cotton, cucurbit vegetables, dry beans, grapes, hops, leafy greens, leafy petioles, peanuts, pistachios, pome fruits, soybeans, spinach, stone fruits, strawberries, tree nuts, and tropical fruits

Active Ingredients: pyraclostrobin: (carbamic acid, [2-[[[1-(4-chlorophenyl)- 1H-pyrazol-3-yl]oxy]methyl]phenyl]methoxy-, methyl ester) 12.8% boscalid: 3-pyridinecarboxamide,2-chloro-N-(4'-chloro(1,1'-biphenyl)-2-yl)- .... 25.2% Other Ingredients: 62.0% Total: 100.0% 0.128 oz (0.008 Ib) of pyraclostrobin in 1 oz of Pristine 0.252 oz (0.0158 Ib) of boscalid in 1 oz of Pristine

EPA Reg No. 7969-199 EPA Est. No. KEEP OUT OF REACH OF CHILDREN CAUTION/PRECAUCION Si usted no entiende la etiqueta, busque a alguien para que se la explique a usted en detalle. (If you do not understand the label, find someone to explain it to you in detail.)

See inside for complete First Aid, Precautionary Statements, Directions For Use, Conditions of Sale and Warranty, and state-specific crop and/or use site restric- tions.

In case of an emergency endangering life or property involving this product, call day or night, 1-800-832-HELP (4357).

Net Contents:

BASF Corporation 26 Davis Drive, Research Triangle Park, NC 27709 X

FIRST AID • Take off contaminated clothing. If on skin or clothing • Rinse skin immediately with plenty of water for 15 to 20 minutes. • Call a poison control center or doctor for treatment advice. • Call a poison control center or doctor immediately for treatment advice. • Have person sip a glass of water if able to swallow. If swallowed • DO NOT induce vomiting unless told to do so by a poison control center or doctor. • DO NOT give anything by mouth to an unconscious person. • Hold eyes open and rinse slowly and gently with water for 15 to 20 minutes. If in eyes • Remove contact lenses, if present, after first 5 minutes; then continue rinsing eyes. • Call a poison control center or doctor for treatment advice. • Move person to fresh air. • If person is not breathing, call 91 1 or an ambulance; then give artificial respiration, preferably If inhaled by mouth to mouth, if possible. • Call a poison control center or doctor for further treatment advice. HOTLINE NUMBER Have the product container or label with you when calling a poison control center or doctor or going for treatment. You may also contact BASF Corporation for emergency medical treatment information: 1-800-832-HELP (4357).

Precautionary Statements USER SAFETY RECOMMENDATIONS Hazards to Humans and Domestic Animals Users should: • Wash hands before eating, drinking, chewing gum, CAUTION. Harmful if swallowed or absorbed through using tobacco, or using the toilet. skin. Causes moderate eye irritation. Avoid contact with • Remove clothing/PPE immediately if pesticide gets skin, eyes or clothing. inside. Then wash thoroughly and put on clean cloth- ing. Personal Protective Equipment (PPE) • Remove PPE immediately after handling this product. Some materials that are chemically resistant to this prod- Wash the outside of gloves before removing. As soon uct are listed below. For more options, refer to Category as possible, wash thoroughly and change intc cban A on an EPA chemical-resistance category selection chart. clothing. Prolonged or frequently repeated skin contact may cause allergic reaction in some individuals. Environmental Hazards Applicators and other handlers must wear: DO NOT apply directly to water, areas where surface • Long-sleeved shirt and long pants water is present, or intertidal areas below thfe mean high • Chemical-resistant gloves made of any waterproof water mark. DO NOT contaminate water when < lisoosing material (such as nitrile, butyl, neoprene, and/or of equipment washwaters or rinsate. barrier laminate) Surface Water Advisory • Shoes plus socks This product may contaminate water through drift of spray Follow the manufacturer's instructions for cleaning and in wind. This product has a potential for runcft for several maintaining PPE. If no such instructions for washables months or more after application. Poorly draining soils and exist, use detergent and hot water. Keep and wash PPE soils with shallow water tables are more prone to produce separately from other laundry. runoff that contains this product. A level, well-maintained vegetative buffer strip between areas to which this product Engineering Controls Statement is applied and surface water features such as ponds, When handlers use closed systems, enclosed cabs, or air- streams and springs will reduce the potential for contami- craft in a manner that meets the requirements listed in the nation of water from rainfall runoff. Runoff of this product Worker Protection Standard (WPS) for agricultural pesti- will be reduced by avoiding applications when rainfall is cides [40 CFR 170.240(d)(4-6)], the handler PPE require- forecast to occur within 48 hours. Sound erosion control ments may be reduced or modified as specified in the practices will reduce this product's contribution to surface WPS. water contamination. This pesticide is toxic to fish and aquatic invertebrates. Drift and runoff may be hazardous to aquatic organisms in water adjacent to treated areas. Directions For Use STORAGE AND DISPOSAL (continued) It is a violation of federal law to use this product in a man- Container Handling ner inconsistent with its labeling. DO NOT apply this prod- Nonrefillable Container. DO NOT reuse or refill this uct in a way that will contact workers or other persons, container. Triple rinse or pressure rinse container either directly or through drift. Only protected handlers (or equivalent) promptly after emptying; then offer for may be in the area during application. For any require- recycling, if available, or reconditioning, if appropriate, or ments specific to your state or tribe, consult the agency puncture and dispose of in a sanitary landfill, or by incin- responsible for pesticide regulation. eration, or by other procedures approved by state and local authorities. AGRICULTURAL USE REQUIREMENTS Triple rinse containers small enough to shake Use this product only in accordance with its labeling and (capacity ^ 50 pounds) as follows. Empty the remain- with the Worker Protection Standard, 40 CFR part 170. ing contents into application equipment or a mix tank. Fill This standard contains requirements for the protection the container 1/4 full with water and recap. Shake for of agricultural workers on farms, forests, nurseries, and 10 seconds. Pour rinsate into application equipment or a greenhouses, and handlers of agricultural pesticides. It mix tank, or store rinsate for later use or disposal. Drain contains requirements for training, decontamination, for 10 seconds after the flow begins to drip. Repeat this notification, and emergency assistance. It also contains procedure two more times. specific instructions and exceptions pertaining to the Triple rinse containers too large to shake statements on this label about personal protective (capacity > 50 pounds) as follows. Empty the remain- equipment (PPE), notification to workers and restricted- ing contents into application equipment or a mix tank. Fill entry interval. The requirements in this box only apply to the container 1/4 full with water. Replace and tighten uses of this product that are covered by the Worker closures. Tip container on its side and roil it back and Protection Standard. forth, ensuring at least one complete revolution, for DO NOT enter or allow worker entry into treated areas 30 seconds. Stand the container on its end and tip it during the restricted-entry interval (REI) of 12 hours for back and forth several times. Turn the container over all crop uses except when performing cane tying, cane onto its other end and tip it back and forth several times. turning or cane girdling on grapes. The REI is 5 days for Empty the rinsate into application equipment or a mix treated grapes when conducting cane tying, cane turn- tank, or store rinsate for later use or disposal. Repeat this ing or cane girdling. procedure two more times. PPE required for early entry to treated areas that is per- Pressure rinse as follows: Empty the rema:r.:r.g mitted under the Worker Protection Standard and that contents into application equipment or mix tan';. Hold involves contact with anything that has been treated, ontainer upside down over application equipment or mix such as plants, soil, or water, is: tank, or collect rinsate for later use or disposal, insert • Coveralls oressure rinsing nozzle in the side of the container and • Chemical-resistant gloves, made of any waterproof inse at about 40 PSI for at least 30 seconds. r>£in for material (such as nitrile, butyl, neoprene, and/or 10 seconds after the flow begins to drip. barrier laminate) • Shoes plus socks In Case of Spill In case of large-scale spillage regarding this product, call: STORAGE AND DISPOSAL CHEMTREC 1-800-424-9300 BASF Corporation 1 -800-832-HELP (4357) DO NOT contaminate water, food, or feed by storage or disposal. Steps to be taken in case material is Pesticide Storage released or spilled: Store in original containers only. Keep container closed In case of spill on floor or paved surfaces, mop and when not in use. DO NOT store near food or feed. remove to chemical waste storage area until proper dis- posal can be made if product cannot be used according Pesticide Disposal to label. Wastes resulting from using this product may be dis- Dike and contain the spill with inert material (sand, earth, posed of on-site or at an approved waste disposal facility. etc.) and transfer liquid and solid diking material to sepa- If these wastes cannot be disposed of according to label rate containers for disposal. instructions, contact your state pesticide agency or envi- ronmental control agency, or the Hazardous Waste Remove contaminated clothing, and wash affected skin representatives at the nearest EPA Regional Office for areas with soap and water. guidance. Wash clothing before reuse. (continued) Keep the spill out of all sewers and open bodies of water. 5

Product Information instructions regarding the consecutive use of Pristine or other target site of action Group 7 and 11 fungicides that This package contains Pristine® fungicide, a water dis- have a similar site of action on the same pathogens. persible granule (WG). The active ingredients in Pristine The following recommendations may be considered to belong to two classes of fungicides, the strobilurins and delay the development of fungicide resistance: anilides. Preventive applications optimize disease control resulting in improved plant health. Pristine is effective 1. Tank mixtures. Pristine provides more effective resist- against pathogens resistant to other fungicides. Pristine® ance management of most of its target pathogens, fungicide has a protective effect because it inhibits spore because it is a premix of two fungicides with different germination. It also has a curative effect because it inhibits modes of action. If Pristine is used in tank mixtures mycelial growth and sporulation of the fungus on the leaf with fungicides from different target site of action surface. However, optimum disease control is achieved groups that are registered/permitted for the same use when Pristine is applied in a regularly scheduled protective and that are effective against the pathogens of concern, spray program and is used in a rotation program with other use at least the minimum labeled rates of each fungi- fungicides. Because of its high specific activity and rainfast- cide in the tank mix. ness, Pristine has good residual activity against target fungi. 2. IPM. Pristine should be integrated into an overall dis- Pristine is not for use in greenhouse or transplant ease and pest management program. Cultural practices production. known to reduce disease development should be fol- lowed. Consult your local extension specialist, certified Sensitive Crop Precaution crop advisor and/or BASF representative for additional Pristine may cause injury to foliage of Concord or related IPM strategies established for your area. Pristine may grape varieties such as Worden, Fredonia and Niagara. be used in agricultural extension advisory (disease fore- DO NOT use Pristine on these varieties and use special casting) programs, which recommend application timing care when applying Pristine to prevent contact with these based on environmental factors favorable for disease sensitive varieties. Consult a BASF representative for more development. information concerning these sensitive grape varieties. 3. Monitoring. Monitor efficacy of all fungicides used in Thoroughly rinse spray equipment, including the inside of the disease management program against the targeted the tank, hoses and nozzles after and before using the pathogen and record other factors that may influence same equipment on grape varieties sensitive to Pristine. fungicide performance and/or disease development. Modes of Action 4. Reporting. If a Group 7 or 11 target site fungicide Pyraclostrobin and boscalid, the active ingredients of appears to be less or no longer effective against a Pristine, belong to the groups of respiration inhibitors pathogen that it previously controlled or suppressed, classified by the U.S. EPA and Canada PMRA as target contact a BASF representative, local extension special- site of action Group 11 and Group 7 fungicides, ist, or certified crop advisor to assist in determining the respectively. cause of reduced performance. Resistance Management Cleaning Spray Equipment Pristine contains pyraclostrobin and boscalid, a premix of Spraying equipment must be cleaned thoroughly before a Group 11 and a Group 7 fungicide, and is effective and after applying this product, particularly if a product against pathogens resistant to fungicides with modes of with the potential to injure crops was used prior io action different from those of target site Groups 7 and 11, Pristine. such as dicarboximides, sterol inhibitors, benzimidazoles, or phenylamides. Pristine is also effective against certain Application Instructions pathogens with resistance to Group 11 fungicides, such as pyraclostrobin, azoxystrobin, trifloxystrobin, or Apply directed rates of Pristine as instructed by Table 2. Crop-specific Use Directions. Ground application is kresoxim-methyl. However, fungal isolates resistant to recommended for thorough coverage. Aerial application Group 7 or 11 fungicides may eventually dominate the fun- can be made for those crops or in conditions where appli- gal population if Group 7 or Group 11 fungicides are used predominantly and repeatedly in the same field in succes- cations are not possible using ground equipment. Pristine can be applied through sprinkler irrigation equipment. sive years as the primary method of control for the targeted Equipment should be checked frequently for calibration. pathogen species, especially if resistance to either Group 7 or 11 fungicides is already present in the pathogen popula- Under low-level disease conditions, use the minimum application rates; use maximum application rates and tion. This may result in reduction of disease control by Pristine or other Group 7 or 11 fungicides. To maintain shortened spray schedules for severe or threatening dis- ease conditions. the performance of Pristine in the field, DO NOT exceed the specified number of applications of Pristine and the Ground Application total number of applications of Pristine per season stated Apply Pristine in sufficient water to ensure thorough cov- in Restrictions and Limitations - All Crops and erage of foliage, bloom, and fruit. Thorough coverage is Crop-specific Use Directions. Adhere to the label required for optimum disease control. 438 r Directed or Banded Sprays Application Instructions. Apply Pristine at rates and The application rates on the Pristine® fungicide label timings as described in this label. reflect the amount of product to be applied uniformly over Use Precautions for Sprinkler Irrigation Applications an acre of ground on a broadcast basis. • This product can be applied through sprinkler irrigation In some crops, Pristine may be used as a directed or systems including center pivot, lateral move, end tow, banded spray over the rows or plant beds with the alleys side (wheel) roll, traveler, big gun, solid set, or hand or row middles left unsprayed. For such uses, reduce the move irrigation systems. DO NOT apply this product labeled Pristine rates in proportion to the area actually through any other type of irrigation system. sprayed. This adjustment is necessary to avoid applying • Add this product to the pesticide supply tank containing the product at use rates higher than permitted according sufficient water to maintain a continuous flow by the to label directions. injection equipment. In continuous moving systems, inject this product-water mixture continuously, applying The following formula may be used to determine the the labeled rate per acre for that crop. DO NOT exceed broadcast equivalent rate for doing directed or banded 1/2 inch (13,577 gallons) per acre. In stationary or non- sprays: continuous moving systems, inject the product-water unsprayed row mixture in the last 15 to 30 minutes of each set allowing sprayed bed = total row width width middles width sufficient time for all of the required pesticide to be applied by all the sprinkler heads and applying the sprayed bed labeled rate per acre for that crop. DO NOT apply when width in inches broadcast rate band rate wind speed favors drift beyond the area intended for total row treated acre field acre treatment. Crop injury, lack of effectiveness, or illegal width in inches pesticide residues in the crop can result from nonuniform distribution of treated water. Thorough coverage of Example: A directed spray application will be made to foliage is required for good control. Maintain good agita- 45-inch plant beds that are separated by 15-inch un- tion during the entire application period. sprayed row middles. 15 inches • If you have questions about calibration, you should con- 45 inches 60 inches sprayed unsprayed total row width tact a state extension service specialist, equipment man- bed width row middles ufacturers or other experts. The calculation to determine the appropriate equivalent • The system must contain a functional check valve, vacu- rate of product to use for this situation based on a label um relief valve, and low pressure drain appropriately broadcast rate recommendation of 12 ozs/acre follows: located on the irrigation pipeline to prevent v,kt3,-source 45 inches contamination from backflow. sprayed 12 ozs 9 ozs bed width Pristine Pristine • The pesticide injection pipeline must contain ? functional, 60 inches treated acre field acre automatic, quick-closing check valve to prevent the flow total row width of fluid back toward the injection pump. • The pesticide injection pipeline must also contain a func- Aerial Application tional, normally closed, solenoid-operated valve located For aerial application in New York State, DO NOT on the intake side of the injection pump and connected apply within 100 feet of aquatic habitats (such as, to the system interlock to prevent fluid from being with- but not limited to lakes, reservoirs, rivers, streams, drawn from the supply tank when the irrigation system is marshes, ponds, estuaries, and commercial fish either automatically or manually shut down. ponds). • The system must contain functional interlocking controls Aerial application can be made and thorough coverage is to automatically shut off the pesticide injection pump required to obtain optimum disease control. Avoid applica- when the water pump motor stops. tions under conditions when uniform coverage cannot be • The irrigation line or water pump must include a func- obtained or when spray drift may occur. Use no less than tional pressure switch, which will stop the water pump 5 gallons of spray solution per acre. For aerial applications motor when the water pressure decreases to the point to hops, tree and vine crops, use no less than 10 gallons where pesticide distribution is adversely affected. of spray solution per acre. For all crops, thorough cover- age is required for optimum disease control. • Systems must use a metering pump, such as a positive displacement injection pump (e.g., diaphragm pump), Directions for Use Through Sprinkler effectively designed and constructed of materials that Irrigation Systems are compatible with pesticides and capable of being fit- ted with a system interlock. Sprayer Preparation. Clean chemical tank and injector system thoroughly. Flush system with clean water. • Allow sufficient time for pesticide to be flushed through all lines and all nozzles before turning off irrigation water. r 7 38 A person knowledgeable of the chemigation system and nutrients, or any other additives. Mix Pristine with responsible for its operation, or under the supervision of only water for applications to crops listed in the the responsible person, shall shut the system down and Berries Group. See Berries Group in Table 2. Crop- make necessary adjustments should the need arise. specific Use Directions. • DO NOT connect an irrigation system (including green- Under some conditions, the use of additives or adjuvants house systems) used for pesticide application to a public may improve the performance of Pristine. However, all water system unless the pesticide label-prescribed safe- varieties and cultivars have not been tested with possible ty devices for public water systems are in place. tank mix combinations. Local conditions can also influence crop tolerance and may not match those under which Specific Instructions for Public Water Systems BASF has conducted testing. Physical incompatibility, 1. Public water system means a system for the provision reduced disease control, or crop injury may result from to the public of piped water for human consumption if mixing Pristine with other products. Therefore, before such system has at least 15 service connections or reg- using any tank mix (fungicides, insecticides, herbicides, ularly serves an average of at least 25 individuals daily liquid fertilizers, biological control products, adjuvants, and at least 60 days out of the year. additives), test the combination on a small portion of the 2. Chemigation systems connected to public water sys- crop to be treated to ensure that a phytotoxic response tems must contain a functional, reduced-pressure zone, will not occur as a result of application. backflow preventer (RPZ) or the functional equivalent in the water supply line upstream from the point of pesti- Consult a BASF representative or local agricultural authori- cide introduction. As an option to the RPZ, the water ties for more information concerning additives. from the public water system should be discharged into a reservoir tank prior to pesticide introduction. There shall Compatibility Test and Mixing Order be a complete physical break (air gap) between the out- If tank mixtures are used, adhere to restrictions due to let end of the fill pipe and the top or overflow rim of the rates, label recommendations and precautions on all reservoir tank of at least twice the inside diameter of the labels. fill pipe. 3. The pesticide injection pipeline must contain a function- Compatibility Test for Tank Mix Components al, automatic, quick-closing check valve to prevent the Add components in the following sequence using 2 tea- flow of fluid back toward the injection pump. spoons for each pound or 1 teaspoon for each pint of 4. The pesticide injection pipeline must contain a function- label rate per acre: al, normally closed, solenoid-operated valve located on the intake side of the injection pump and connected to 1. Water. For 100 gallons per acre spray volume, use 16 the system interlock to prevent fluid from being with- cups (1 gallon) of water. For other spray volume's,- adjust drawn from the supply tank when the irrigation system rates accordingly. Use only water from the ihterided is either automatically or manually shut down. source at the source temperature. 5. The system must contain functional interlocking controls 2. Water-dispersible products (dry flowables, wettable to automatically shut off the pesticide injection pump powders, suspension concentrates, or suspo- when the water pump motor stops, or in cases where emulsions). Cap the jar and invert 10 cycles. there is no water pump, when the water pressure 3. Water-soluble products. Cap the jar and invert 10 decreases to the point where pesticide distribution is cycles. adversely affected. 4. Emulsifiable concentrates (oil concentrate or methy- r 6. Systems must use a metering pump, such as a positive lated seed oil when applicable). Cap the ja and- invert displacement injection pump (e.g., diaphragm pump), 10 cycles. effectively designed and constructed of materials that 5. Water-soluble additives. Cap the jar and :nye;110 are compatible with pesticides and capable of being fit- cycles. ted with a system interlock. 6. Let the solution stand for 15 minutes. 7. DO NOT apply when wind speed favors drift beyond 7. Evaluate the solution for uniformity and stability. The the area intended for treatment. spray solution should not have free oil on the surface, nor fine particles that precipitate to the bottom, nor Additives and thick (clabbered) texture. DO NOT use any spray solu- General Tank Mixing Information tion that could clog spray nozzles. Pristine® fungicide can be tank mixed with most recom- Mixing Order mended fungicides, insecticides, herbicides, liquid fertiliz- 1. Water. Begin by agitating a thoroughly clean sprayer ers, biological control products, adjuvants, and additives tank 3/4 full of clean water. as specified in Table 2. Crop-specific Use Directions. 2. Agitation. Maintain constant agitation throughout mix- For the Berries Group, including blueberries (high- ing and application. bush and lowbush), DO NOT tank mix Pristine with any other pesticide products (including fungicides, 3. Inductor. If an inductor is used, rinse it thoroughly after each component has been added. insecticides, herbicides), adjuvants, liquid fertilizers,

6 4. Products in PVA bags. Place any product contained Directions. in water-soluble PVA bags into the mixing tank. Wait • DO NOT make more than the total number of applica- until all water-soluble PVA bags have fully dissolved and tions of Pristine per season as listed in Table 1. Crop- the product is evenly mixed in the spray tank before Specific Restrictions and Limitations and Table 2. continuing. Crop-specific Use Directions. 5. Water-dispersible products (such as Pristine® fun- • DO NOT apply more than the maximum season use gicide, dry flowables, wettable powders, suspension rate of ai/acre or ozs of product/acre for each specific concentrates, or suspo-emulsions). crop from any combination of products (e.g. Pristine, 6. Water-soluble products. Endura® fungicide, Cabrio® EG fungicide, Headline® 7. Emulsifiable concentrates (such as oil concentrates fungicide). when applicable). • Preharvest Interval (PHI): See Table 1. Crop-specific 8. Water-soluble additives (such as AMS or DAN when Restrictions and Limitations and Table 2. Crop- applicable). specific Use Directions. 9. Remaining quantity of water. • Pristine is not for use in greenhouse or transplant production. Make sure that each component is thoroughly mixed and • For aerial application in New York State, DO NOT suspended before adding tank mix partners. Maintain con- apply within 100 feet of aquatic habitats (such as, stant agitation during application. See Table 1. Crop- but not limited to lakes, reservoirs, rivers, streams, specific Restrictions and Limitations for more details. marshes, ponds, estuaries, and commercial fish Restrictions and Limitations - All Crops ponds). • Maximum seasonal use rate. DO NOT apply more Crop Rotation Restriction than the maximum rate per acre per season as listed in Crops listed on the Pristine, Cabrio EG, Endura and Table 1. Crop-specific Restrictions and Limitations Headline labels may be planted immediately following the and Table 2. Crop-specific Use Directions. last application. • Maximum rate per application. DO NOT apply more All other crops can be planted 14 days after the last than the maximum rate per acre per application as listed application. in Table 1. Crop-specific Restrictions and DO NOT use on cowpeas, field peas, grain lupine, Limitations and Table 2. Crop-specific Use sugar beets, garden beets, turnip or radishes. Table 1. Crop-specific Restrictions and Limitations

Minimum Time Maximum Rate Maximum Maximum R^te from Application to per Acre Number per Acrp Crop1 Harvest (PHI) per Application of Applications3 per Son -,011 (days) (ozs product) per Season (ozs product) Berries Group1'' Bushberry 0 23 4 22 Caneberry Bulb Vegetables Group1 Garlic 7 18.5 6 1*1 Leeks Onion

Carrots 0 10.5 6 63

Celery 0 25 2 50

Cotton 30 25 2 50 Cucurbit Vegetables Group1 Cantaloupe Cucumber 0 18.5 4 74 Melon Pumpkin Squash Watermelon

Dry Beans1 21 25 2 50

Grapes2 14 23 3 69 1/58

Table 1. Crop-specific Restrictions and Limitations (continued)

Minimum Time Maximum Rate Maximum Maximum Rate from Application to per Acre Number of per Acre Crop1 Harvest (PHI) per Application Applications3 per Season (days) (ozs product) per Season (ozs product)

Hops 14 28 3" 845 (ground application)

Hops 14 14 14 -1 45 (aerial application)

Leafy Greens (except Brassica and 14 25 2 50 head lettuce and leaf lettuce) Leafy Petioles 0 25 2 50 (except Brassica) Peanut 14 28 3 84

Pistachio 14 14.5 4 58

Pome Fruits Group1 0 18.5 4 74

Soybeans 21 16 2 32

Spinach 14 25 2 50

Stone Fruits Group1 Apricot Cherry (sweet and sour) 0 14.5 5 72.5 Nectarine Peach Plum Prune

Strawberries 0 23 5 115

Tree Nuts Group1 14 14.5 4 58 except Almond

Almond 25 14.5 4 58

Tropical Fruits Avocado Black Sapote Canistel Mamey Sapote 0 18.5 2 37 Mango Papaya Sapodilla Star Apple

1 For a complete list of crops within a crop group, see Table 2. Crop-specific Use Directions. 2 DO NOT use on Concord or Noiret (NY73.0136.17) due to foliar injury. Possible foliar injury could occur to Worden, Fredonia, Niagara, Steuben, Rougeon or related varieties. Not all varieties have been thoroughly tested. 3 At maximum use rate per application. 4 The maximum number of applications per season is 3 ground applications only or 2 ground applications and one aerial application. 5 The maximum product rate per acre per season is 84 ounces if 3 ground applications are made and 70 ounces per season if 2 ground and one aerial application are used. * For the Berries Group, includ ng blueberries (highbush and lowbush), DO NOT tank mix Pristine* fungicide with any other pesticide products (including fungicides, insecticides, herbicides), adjuvants, I quid fertilizers, nutrients, or any other additives. The use in blueberries is not registered in California. Aerial application is permitted for all labeled crop uses. For aerial application in New York State, DO NOT apply within 100 feet of aquatic habitats (such as, but not limited to lakes, reservoirs, rivers, streams, marshes, ponds, estuaries, and commercial fish ponds). to 18

Crop-specific Use Directions

Table 2. Crop-specific Use Directions

Minimum Maxim urn Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Berries Group Alternaria leaf spot and fruit rot 18.5 to 23ozs 4 92 ozs 0 days 04/ternaria spp.) per acre per acre Bushberry Blueberry* Anthracnose (highbush and (Colletotrichum spp., lowbush) Elsinoe spp.) Currant Elderberry Botrytis gray mold Gooseberry (Botrytis cinema) Huckleberry Leaf spot and blotch Caneberry (Mycosphaerel/a spp., Blackberry Septoria spp.) (all varieties) Monilinia blight and mummy berry Loganberry (Monilinia spp.) Raspberry (black and red) Phomopsis leaf spot, twig blight, and fruit rot (Phomopsis spp.)

Powdery mildew (Sphaerotheca spp., Microsphaera spp., O/dium spp.)

Spur blight (Didymella spp., Phoma spp.) Suppression Only Rust [Puccianiastrum spp., Arthuriomyces spp., Phragmidium spp., Kuehneola spp.) Application Directions. Begin applications of Pristine® fungicide prior to onset of disease development and continue on a 7- to 14-day interval. DO NOT apply Pristine to any crops in the Berries Group, including blueberries (highbush and lowbush), as a tank mix with any other pesticide products (including fungicides, insecticides, herbicides), adjuvants, liquid fertilizers, nutrients, or any other additives. * Not registered for use in California. Mix Pristine with only water for applications to crops listed in the Berries Group. Use the shorter interval and/or the higher rate when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than four (4) applications of Pristine or other Group 7 or 11 fungicides per season. DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action. ti 58

Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Bulb Vegetables Botrytis leaf blight 14.5to18.5ozs 6 111 ozs 7 days Group (Botrytis spp.) per acre per acre Garlic Leek Botrytis neck rot* Onions (all varieties) (Botrytis spp.) Shallot Purple blotch and leaf blight 10.5 to 18.5 ozs (fllternaria porri) per acre

Stemphylium leaf blight and stalk rot (Stemphylium vesicarium)

Suppression Only 18.5 ozs Downy mildew per acre (Peronospora destructor)

Application Directions. For control of neck rot, purple blotch and leaf blight, begin applications of Pristine® fungicide prior to onset of disease development and continue on a 14-day interval. If application intervals shorter than 14 days are needed, rotate to another fungicide with a different mode of action. Use the higher rate when disease pressure is high. Applications made to control purple blotch, leaf blight and stalk rot will also suppress downy mildew. If downy mildew occurs during a Pristine appli- ;ation for these diseases, immediately follow the Pristine application with a downy mildew fungicide with a different mode of action.

*Not registered for use in California. For downy mildew, rotate each application of Pristine with an application of a labeled fungicide with a different mode of action. No restriction on livestock grazing or feeding. Resistance Management. To limit the potential for development of resistance, DO NOT make more than six (6) applications of Pristine or other Group 7 or 11 fungicides per season. DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action.

10 \t\ll

Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Carrots Alternaria leaf spot 8 to 10.5 ozs 63 ozs 0 days Ifllternaria spp.) per acre per acre Cercospora leaf spot (Cercospora spp.) Powdery mildew (Erysiphe spp.) Suppression Only Southern root rot (Sclerotium rolfsii)

Application Directions. Begin applications of Pristine® fungicide prior to onset of disease development and continue on a 7- to 14-day interval.

Use the higher rate and the shorter interval when disease pressure is high.

No restriction on livestock grazing or feeding for carrot culls.

Resistance Management. To limit the potential for development of resistance, DO NOT make more than six (6) applications of Pristine or other Group 7 or 11 fungicides per crop growing season.

DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action.

11 Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Celery Alternaria leaf spot 1 0 to 1 5 ozs 2 50 ozs 0 days l/\lternaria spp.) per acre Celery (Chinese) per acre Anthracnose (Colletotrichum spp.) Ascochyta leaf spot lAscochyta spp.) Cercospora leaf spot (Cercospora spp.) Downy mildew (Peronospora spp., Bremia spp.) Phoma (Phoma spp.) Rust (Pucc/nia spp.) Powdery mildew (Erys/phe spp.) Septoria leaf spot (Septoria spp.) White rust (Albugo spp.) Botrytis rot 25 ozs (Botrytis spp.) per acre Sclerotinia rot and blight (Sclerotinia spp.) Application Directions. Begin applications of Pristine® fungicide prior to the onset of disease development and continue on a 7-day interval. Use the higher rate and the shorter interval when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application.

12 (

Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Cotton Alternaria leaf spot 12.5to25ozs 2 50 ozs 30 days (Altemaria spp.) per acre per acre

Anthracnose, boll rot (G/omerella spp.)

Ascochyta blight, boll rot (fiscochyta spp.)

Cercospora leaf spot (Cercospora spp.)

Diplodia boll rot (Dip/odia spp.)

Hard lock, boll rot (Fusarium spp.)

Application Directions. Begin applications of Pristine® fungicide prior to the onset of disease development and continue on a 7- to 14-day interval. Use shorter interval when disease pressure is high. Feed containing commodities from cotton production and processing can be fed to livestock. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application.

13 Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Cucurbit Downy mildew 12.5 to 18.5ozs 4 74 ozs 0 days Vegetables Group (Pseudoperonospora cubensis) per acre per acre

Includes all types Alternaria blight and hybrids of: (Altemaria cucumerina) Chayote Cercospora leaf spot Chinese waxgourd (Cercospora citru/ina) Citron melon Cucumber Gummy stem blight Gherkin (Didymella bryoniae) Pumpkin Watermelon Powdery mildew (Sphaerotheca fuliginea, Edible Gourd Erysiphe cichoracearum ) Chinese okra Cucuzza Hyotan Momordica spp. Balsam apple Balsam pear Bitter melon Chinese cucumber Muskmelon Cantaloupe Anthracnose 18.5 ozs Casaba (Colletotrichum orbicu/are) per acre Crenshaw melon Golden pershaw melon Honeydew melon Honey balls Mango melon Persian melon Pineapple melon Santa Glaus melon Snake melon

Summer Squash Crookneck squash Scallop squash Straightneck squash Vegetable marrow Zucchini

Winter Squash Acorn squash Butternut squash • Calabaza Hubbard squash Spaghetti squash See Cucurbit Vegetables Group Information following, (continued)

14 c Table 2. Crop-specific Use Directions (continued) Cucurbit Vegetables Group Information

Application Directions. Begin applications of Pristine® fungicide prior to onset of disease development and continue on a 7- to 14-day interval.

Use the higher rate and the shorter interval when disease pressure is high.

Use the highest labeled rate for anthracnose.

Tank Mixes with Adjuvants and Other Products. BASF evaluations indicate that tank mixes of additives, adjuvants, and/or other products with Pristine may result in injury. This is particularly true for muskmelon crops such as cantaloupe and honeydew. Users need to be aware of this, proceed with caution, and test for crop safety when tank mixing, as stated below.

Applications of additives, adjuvants, and/or other products that increase penetration may cause injury when mixed with Pristine. Injury potential from these kinds of tank mixes may decrease with lower rates of the tank mix partner. Users are advised to test for crop safety, as stated below.

BASF has not tested all varieties and cultivars with all possible tank mix combinations and rates of additives, adjuvants, and/or other products. Local environmental conditions also influence crop tolerance and may not match those under which BASF has con- ducted testing. Physical incompatibility, reduced disease control, or crop injury may result from mixing Pristine with other products.

To minimize the likelihood of crop injury, BASF recommends testing Pristine in combination with additives, adjuvants, and/or other products for crop safety on a small portion of the crop. However, environmental variability precludes direct and consistent projection of small area test results to future use.

Consult a BASF representative for more information concerning additives or adjuvants.

DO NOT tank mix Pristine with malathion, Kelthane® agricultural miticide, Thiodan® insecticide, Phaser* insecticide, Lannate® insecticide, Lorsban® insecticide, M-Pede® insecticide/fungicide, or Botran® fungicide as crop injury may result.

Resistance Management. To limit the potential of development of resistance, DO NOT make more than four (4) applications of Pristine per season.

DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application.

15 Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Dry Beans Alternaria leaf and pod spot 10 to 15 ozs 2 50 ozs 21 days (except soybeans) (Alternaria spp.) per acre per acre Lupinus spp. Lupine Ascochyta blight Sweet lupine (Phoma exigua, Ascochyta spp.) Phaseolus spp. Field bean Cercospora leaf spot Kidney bean (Cercospora spp.) Lima bean (dry) Downy mildew Navy bean (Phytophthora nicotianae) Pink bean Pinto bean Mycosphaerella blight Tepary bean (Mycosphaerella spp.)

Vigna spp. Powdery mildew Adjuki bean (Erysiphe polygon!) Blackeyed pea Catjang Rust Crowder pea (Uromyces appendicu/atus) Moth bean Septoria leaf spot Mung bean (Septoria spp.) Rice bean Southern pea Anthracnose 1 5 to 25 ozs Urd bean (Colletotrichum spp.) per acre

Botrytis gray mold (Botrytis cinerea)

White mold (Sclerotinia sclerotiorum)

Application Directions. For optimal disease control, begin applications of Pristine® fungicide prior to onset of disease development or at the beginning of flowering and repeat on a 5- to 14-day interval if condtions are conducive for disease development.

Use the higher rate and shorter interval when disease pressure is high. Resistance Management. DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application. Restrictions. DO NOT use on soybean, cowpeas, field pea and grain lupine. DO NOT feed treated pea commodities to livestock.

16 f Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Grapes Angular leaf spot 8 to 12.5ozs 69 ozs 14 days (except Concord, (Mycosphaerella angulata) per acre per acre Worden, Fredonia, Niagara and Anthracnose related varieties) (Elsinoe ampelina) Black rot (Guignardia bidwel/ii)

Downy mildew (Plasmopara viticola)

Leaf blight (Pseudocercospora vitis)

Phomopsis cane and leaf spot (Phomopsis viticola)

Powdery mildew (Uncinu/a necator)

Ripe rot (Colletotrichum gloeosporioides)

Aids in Control Only Summer bunch rot (Sour rot) (Cladosporium spp. and Aspergil/us spp.)

Suppression Only Botrytis gray mold (Botrytis cinerea) Botrytis gray mold 18.5 to 23 ozs (Botrytis cinerea) per acre

Application Directions. For powdery mildew control, begin applications of Pristine® fungicide as of bud break prior to onset of disease, using 8 ozs per acre on a 10- to 14-day interval, or 8 to 12.5 ozs per acre on a 14- to 21-day interval. For black rot and downy mildew control, begin applications of Pristine as of pre-bloom prior to onset of disease and continue applications on a 10- to 14-day interval. For all other diseases listed except for Botrytis gray mold, begin applications of Pristine prior to onset of disease and continue applications on a 10- to 14-day interval. Pristine applied at rates of 8 to 12.5 ozs per acre for control of the listed diseases will also suppress Botrytis gray mold. For control of Botrytis gray mold, apply 18.5 to 23 ozs per acre of Pristine prior to onset of disease development when conditions favor disease development during early bloom, bunch pre-closure and veraison up to 14 days before harvest. Use the higher rate and the shorter interval when disease pressure is high. DO NOT enter or allow worker entry into treated areas during the restricted-entry interval (REI) of 12 hours except when performing cane tying, cane turning or cane girdling. The REI is 5 days for treated grapes when conducting cane tying, cane turning or cane girdling. DO NOT use on Concord or Noiret (NY73.0136.17) due to foliar injury. Possible foliar injury could occur to Worden, Fredonia, Niagara, Steuben, Rougeon or related varieties. Not all varieties have been thoroughly tested. Resistance Management. To limit the potential for development of resistance, DO NOT make more than five (5) applications of Pristine or other Group 7 or 11 fungicides per season. DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action.

17 Table 2. Crop-specific Use Directions (continued)

Pristine® fungicide Hops Ground Application Use Directions

Maximum Minimum Product Number of Maximum Time from Crop Target Disease Use Rate Ground Product Rate Application to per Application Applications per Season Harvest per Season (PHI) Hops Powdery mildew 14 ozs 3 84 ozs 1 4 days (Ground (Erysiphe cichoracearum, per 100 gallons of per acre (2 if one Application) Sphaerotheca spp.) dilute spray aerial application (70 ozs per acre Downy mildew DO NOT use more is made.) if one aerial (Pseudoperonospora humuli} than 28 ozs per application is acre. made.) Application Directions. Begin applications of Pristine prior to disease development and continue on a 10- to 21 -day interval.

Use the shorter interval when disease pressure is high. Application rates are based on 1 00 gallons of dilute spray applied to runoff. Adjust water volume to maintain thorough coverage. Use 25 to 50 gal- lons of dilute spray per acre prior to trellising and 100 to 200 gallons of dilute spray per acre thereafter. DO NOT use more than 200 gallons per acre of this mixture. If additional spray volume is needed for thorough coverage, use 28 ozs of Pristine per acre in the required spray volume. Resistance Management. To limit the potential for development of resistance, DO NOT make more than three (3) applications of Pristine per season (counting both ground and aerial applications). DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action. Restrictions. DO NOT use more than 200 gallons per acre of this mixture. If additional spray volume is needed for thorough coverage, use 28 ozs of Pristine per acre in the required spray volume.

Pristine Hops Aerial Application Use Directions

Maximum Minimum Aerial Aerial Product Number of Time from Aerial Application Crop Target Disease Use Rate Aerial Application to TiminQ per Application Applications Harvest Growth Stage per Season (PHI) Hops Powdery mildew 1 4 ozs per acre as a 1 Wire to 1 4 days 1 4 days (Aerial (Erysiphe cichoracearum, tank mix with a preharvest Application) Sphaerotheca humuli, myclobutanil Sphaerotheca macularis, fungicide product Sphaerotheca spp.) (see myclobutanil rate following)

Application Directions. Aerial application may result in reduced control due to lack of canopy penetration and coverage. Aerial application should only be used in situations when ground application is not possible.

Apply a preventive spray of Pristine at 14 ozs as a tank mix with a myclobutanil fungicide product at rates equivalent to 0.15 Ib per acre of active ingredient (including but not limited to: Rally* 40W fungicide at 6 ozs product per acre or Sonoma™ 40WSP fungicide at 6 ozs product per acre) for resistance management.

Avoid applications under conditions when uniform coverage cannot be obtained or when spray drift may occur. Use a minimum of 10 gallons of water per acre when applying by air. Thorough coverage is essential.

Because complete coverage is important for effective disease control, aerial application at low volumes may result in reduced control due to lack of canopy penetration and coverage.

Mixing Pristine with surfactants or foliar fertilizers is not recommended when applying by air. Similarly, adjuvants that enhance pesticide penetration may cause phytotoxicity when used with Pristine applied by air.

Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) aerial application of Pristine per season and include a myclobutanil product as a tank mix as described.

18 Table 2. Crop-specific Use Directions (continued)

Minimum Maxim urn Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Leafy Greens Alternaria leaf spot 1 0 to 1 5 ozs 2 50 ozs 1 4 days (except Brassica lAlternarla spp.) per acre per acre and head lettuce and leaf lettuce) Anthracnose Amaranth (Co/letotrichum spp.) Arugula Ascochyta leaf spot Chervil lAscochyta spp.) Chrysanthemum (edible-leaved and Cercospora leaf spot garland) (Cercospora spp.) Corn salad Cress Downy mildew (garden and (Peronospora spp.) upland) Phoma Dandelion (Phoma spp.) Dock Endive Powdery mildew Orach (Erysiphe spp., Phyllactinia spp., Parsley Sphaerotheca spp.) Purslane (garden and Rust winter) (Puccinia spp.) Radicchio Septoria leaf spot (red chicory) (Septoria spp.) White rust (Albugo spp.) Botrytis rot 1 5 to 25 ozs (Botrytis spp.) per acre Sclerotinia rot and blight (Sclerotinia spp.)

Application Directions. Begin applications of Pristine8 fungicide prior to the onset, of disease development and continue on a 7-day interval.

Use the higher rate when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application.

19 Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI/DLJ l)\ Leafy Petioles Alternaria leaf spot 1 0 to 1 5 ozs 2 50 ozs 0 days (except Brassica) (Alternaria spp.) per acre per acre Cardoon Celtuce Anthracnose Fennel (Florence) (Co/letotrichum spp.) Rhubarb Ascochyta leaf spot Swiss chard (Ascochyta spp.)

Cercospora leaf spot (Cercospora spp.)

Downy mildew (Peronospora spp., Bremia spp.)

Phoma (Phoma spp.)

Powdery mildew (Erys/phe spp.)

Rust (Puccinia spp.)

Septoria leaf spot (Septoria spp.)

White rust 'Albugo spp.) Botrytis rot 1 5 to 25 ozs (Botrytis spp.) per acre

Sclerotinia rot and blight [Sclerotinia spp.)

Application Directions. Begin applications of Pristine® fungicide prior to the onset of disease development and continue on a 7-day interval.

Use the higher rate when disease pressure is high.

Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application.

20 Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Peanut Early leaf spot 12.5to18.5ozs 84 ozs 14 days (Cercospora arachidicola) per acre per acre

Late leaf spot (Cercosporidium personatum)

Pepperspot (Leptosphaerulina crassiasca)

Rust (Puccinia arachidis)

Web blotch (Phoma arachidico/a)

Rhizoctonia limb rot, peg rot, 18.5 to 28 ozs and pod rot per acre (Rhizoctonia solani)

Sclerotium rot, Southern stem rot, Southern blight, and white mold (Sclerotium raffs//)

Sclerotinia blight (Sc/erotinia minor)

Application Directions. For control of pepperspot, rust, web blotch, early and late leaf spot, begin applications of Pristine® fungicide prior to onset of disease development and continue on a 14-day interval. For control of Rhizoctonia and Sclerotium rot, begin applications of Pristine prior to onset of disease development and continue on a 14-day interval. For control of Sclerotinia blight, begin applications of Pristine prior to onset of disease development or 45 to 60 days after planting. Make a second application 14 to 21 days later. Use the higher rate and/or shorter spray interval when disease pressure is high or in fields with a history of disease. Resistance Management. To limit the potential for development of resistance, DO NOT make more than three (3) applications of Pristine per season. DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application. Restrictions: Use of Pristine with silicone-based adjuvants may cause crop injury. DO NOT feed treated peanut hay to livestock. DO NOT graze livestock or harvest for forage use.

21 MSf

Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Pistachio Alternaria late blight 10.5 to 14.5ozs 58 ozs 14 days (Altemaria spp.) per acre per acre Botrytis blossom and shoot blight (Botrytis cinerea)

Panicle and shoot blight (Botryosphaeria dothidea)

Application Directions. Apply Pristine® fungicide prior to onset of disease development and continue on a 10- to 30-day interval.

Use the higher rate and shorter intervals when disease pressure is high.

Resistance Management. To limit the potential for development of resistance, DO NOT make more than four (4) applications of Pristine or other Group 7 or 11 fungicides per season.

DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action.

For aerial application to pistachio trees, use no less than 10 gallons of spray solution per acre.

22 ( Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Pome Fruits Group Alternaria blotch 14.5to18.5ozs 4 74 ozs 0 days Apple Alternaria mail) per acre per acre Crabapple Loquat Apple scab May haw (Venturis inaequalis) Oriental pear Bitter rot Pear (Colletotrichum spp.) Quince Black rot/Frogeye leaf spot (Botryosphaeria obtusa)

Blue mold* (Penicillium spp.)

Brooks spot (Mycosphaerella pom/1)

Flyspeck (Zygophiala jamaicensis)

Gray mold* (Botrytis spp.)

Pear scab 'Venturia pinna]

Dowdery mildew Podosphaera leucotricha)

Sooty blotch (disease complex)

White rot Botryosphaeria dothidea)

Suppression Only Cedar apple rust Gymnosporangium juniperi- virginianae)

Quince rust Gymnosporangium clavipes)

Application Directions for scab, powdery mildew, frogeye leaf spot and rust. Begin applications of Pristine® fungicide prior to disease development and continue on a 7- to 10-day interval.

Use the higher rate and shorter interval when disease pressure is high. Application Directions for blue mold, gray mold, sooty blotch, flyspeck, white rot, black rot, bitter rot and Alternaria blotch. Begin appli- cations of Pristine prior to disease development and continue on a 7- to 14-day interval.

*Not registered for use in California. Use the higher rate and shorter interval when disease pressure is high. No restriction on livestock grazing or feeding for pome fruits feed items. Resistance Management. To limit the potential for development of resistance, DO NOT make more than four (4) applications of Pristine per sea- son. DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action.

23 tsltf Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Soybeans Alternaria leaf spot 8 to 1 6 ozs 2 32 ozs 21 days Ifllternaria spp.) per acre per acre Anthracnose (Colletotrichum truncatum) Brown spot (Septoria glycines) Cercospora blight (Cercospora kikuchii) Frogeye leaf spot (Cercospora soj'ina) Pod and stem blight (Diaporthe phaseolorum ) Rhizoctonia aerial blight (Rhizoctonia so/ani) Asian soybean rust* 12.5 to 16 ozs (Phakopsora pachyrhizi) per acre Southern blight 16 ozs (Sclerotium ro/fsii) per acre White mold (Sc/erotinia sclerotiorum)

Application Directions. For optimal disease control, apply Pristine® fungicide at early flowering (R1 to R3 growth stage) or prior to disease development, whichever is earlier. Make a second application 7 to 21 days later if monitoring shows disease development or if conditions are conducive for disease infection.

Use the higher labeled rate and shorter interval when disease pressure is high.

Pristine may be applied with adjuvants.

*See Management of Asian Soybean Rust section for specific instructions on use of Pristine to control Asian soybean rust.

Soybean forage may be fed no sooner than 1 4 days after last appl cation. Soybean hay may be fed no sooner than 21 days after last application.

Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application.

24 Management of Asian Soybean Rust Pristine Directions for the Management of Asian Soybean Rust If Asian soybean rust spores are present in the area, soy- beans may be infected, even if symptoms are not present. Preventive + Curative Treatment 1 Once Asian soybean rust is established (infection level Existing Infections and/or if Asian Soybean Rust greater than 3% to 5%) on the soybean plant, control is Spores are Present or Predicted to be in the Area difficult to achieve with a curative approach. Optimum dis- A tank mixture with an EPA-approved fungicide (non-Qol ease control is achieved by utilizing the combination of a mode of action) with known curative activity2 against Asian preventive fungicide like Pristine® fungicide plus an EPA- soybean rust is required for control of existing Asian soy- approved fungicide (non-Qol mode of action) with known bean rust infections, even if symptoms are not present. If 2 curative activity against Asian soybean rust. symptoms or soybean rust lesions and/or pustules are A comprehensive monitoring and scouting program present on soybean plants, some yield loss may have must be continued after initial fungicide applica- already occurred. tions. Fungicide treatments that include Pristine will pro- The Pristine program described in Table 2A must be tect soybeans against Asian soybean rust for up to used for Asian soybean rust if one or more of the follow- 21 days, but subsequent disease infection of treated ing conditions exists: leaves can occur earlier if conditions are favorable for dis- 1. Asian soybean rust is present in the soybean field ease development. New leaves emerging after treatment based on field scouting. will not be protected from new infection pressure. 2. Asian soybean rust is present in the local area. Monitoring for Asian Soybean Rust Presence 3. Predictive models based on weather/wind have predict- ed that spores have reached or will soon reach your Information on the geographic distribution of Asian soy- area. bean rust can be gathered from multiple sources including or local retailers, university extension, USDA, the internet and BASF. These sources must be evaluated frequently during 4. USDA and/or university extension report that Asian soy- the growing season to determine the risk and local pres- bean rust (including spores) has been identified in your ence of rust spores in your geography. Rust spores can geographical area. move hundreds of miles in only a few days based on wind direction and speed. If soybean rust is present in the area Fungicide treatments that include Pristine plus an EPA- or if conditions exist where spore movement from infected approved fungicide (non-Qol mode of action) with known 2 areas is expected or predicted, soybean fields should be curative activity against Asian soybean rust will protect treated utilizing the Pristine program described in soybeans for up to 21 days, but subsequent infection of Table 2A. treated leaves can occur earlier if conditions are favorable for disease development. New leaves emerging after treat- Field Scouting ment will not be protected from new infection pressure. Scout soybean fields for presence of Asian soybean rust frequently. Soybean rust establishment is favored by high IMPORTANT: Because a Second fungicide application humidity, free moisture present on soybean leaves and may be required, a comprehensive monitoring and scout- moderate air temperatures. Asian soybean rust, in most ing program must be continued after the initial fungicide cases, becomes especially aggressive and visible when application. Base the need for a second application on soybean plants reach the reproductive stage of growth soybean growth stage, yield potential and conditions (flowering). Check higher risk areas of soybean field for favorable for continued Asian soybean rust infection. signs of the disease first. These include: earlier planted or Additional fungicide applications may be needed if Asian maturing soybeans; high moisture areas near lakes, rivers soybean rust pressure is extremely high and conditions or other water sources that keep humidity high; areas in are favorable for disease development later in the growing the field that remain shaded longer resulting in higher free season. Continue the monitoring and scouting program leaf moisture; low areas of fields where humidity (dew) can and apply an EPA-approved fungicide (non-Qol mode of settle and persist longer. Look for any signs or symptoms action) with known curative activity2 if a third application is of soybean rust presence. If Asian soybean rust is present needed. in your field immediately implement Pristine program described in Table 2A. 1 Infection level = number of leaves with symptoms/signs of Asian soybean rust per 100 leaves. Scouting tip: Collect leaves from suspected plants, place 2 Contact your local, state or federal agricultural authorities or suspect leaves in a clear plastic bag, inflate bag with local retailer for a list of fungicides approved in your state with breath (adds humidity to bag) and seal, place in warm known curative properties against Asian soybean rust. (75° F to 90° F) environment and incubate in humid plastic bags for 24 hours. Leaves in the bags should display accelerated disease development and show spore pustule development within 24 hours. Spore development should occur approximately two times faster than under normal field conditions. 25 Preventive Treatment Asian Soybean Rust (including spores) Not Present or Predicted to be Present in the Field or Area The preventive Pristine® fungicide program described in Table 2B should only be used if none of the conditions described in one through four of the section immediately preceding exist. Growers must continue to monitor and scout soybean fields as described in sections Monitoring for Asian Soybean Rust Presence and Field Scouting. A second fungicide application may be needed if Asian soybean rust (including spores) is detected or identified in the treated field or geographical area. Continue a compre- hensive monitoring and scouting program after the initial application of Pristine. Infection of treated soybean leaves can occur and new leaves emerging after treatment will not be protected from Asian soybean rust. The need for a second application should be based on soybean growth stage, yield potential and environmental conditions. If a second application is necessary, apply Pristine plus an effective, EPA-approved fungicide (non-Qol mode of action) with known curative activity1 against Asian soybean rust. IMPORTANT: Additional fungicide applications may be needed if Asian soybean rust pressure is extremely high and conditions are favorable for disease development later in the growing season. Continue the monitoring and scouting program and apply an EPA-approved fungicide (non-Qol mode of action) with known curative activity1 if a third application is needed. Need for Season-long Monitoring, Regardless of Pristine Program Selected The key to adequate season-long control of Asian soy- bean rust is careful monitoring and scouting of soybean fields all season, especially from initiation of flowering through pod fill. After the first application, maintain a thor- ough monitoring and scouting program. Apply follow-up fungicide treatments as needed based on crop stage of growth, yield potential, and as the residual protection of the first application begins to wane. Thorough spray coverage of soybean plants is essential for optimum control. Utilize spray application techniques including sufficient water carrier per acre, pressure and proper nozzle selection that ensure thorough coverage. See the Pristine main label and your local retailer for recommendations.

1 Contact your local, state or federal agricultural authorities or local retailer for a list of fungicides approved in your state with known curative properties against Asian soybean rust.

26 Table 2A. Pristine® fungicide application instructions when Asian soybean rust has been identified in the soybean field to be treated, is present in the local geographical area, or spores have been predicted to be in the local geographical area

Pristine (12. 5 to 16 ozs/acre)1 + adjuvant + EPA-approved fungicide (non-Qol Treatment mode of action) with known curative activity against Asian soybean rust2

Application 1 This application must be made soon after first rust infection, preventively, or at blooming start (growth stage R1 to R3), even if symptoms have not appeared. Timing Refer to Pristine Directions for the Management of Asian Soybean Rust section and repeat application as necessary, depending on disease evolution.

Pristine (12.5 to16 ozs/acre)1 + adjuvant + EPA-approved fungicide (non-Qol Treatment mode of action) with known curative activity against Asian soybean rust2 Application 23 21 days after Application 1 Timing or Earlier (no sooner than 7 days) if monitoring shows active disease

1 Higher labeled rates of Pristine provide longer residual control of Asian soybean rust. 2 Contact your local, state or federal agricultural authorities or local retailer for a list of approved fungicides in your state approved for this purpose. 3Continue to carefully monitor and scout soybean fields as described in the Management of Asian Soybean Rust section. Base need for second application on results of monitoring and scouting for disease, crop growth stage and yield potential. Consult with your local retailer or university exten- sion representative for guidance, as needed. Additional fungicide applications may be needed if Asian soybean rust pressure is extremely high and conditions are favorable for disease development later in the growing season. Continue the monitoring and scouting program and apply an EPA- approved fungicide (non-Qol mode of action) with known curative activity if the third application is needed.

Table 2B. Pristine application instructions when Asian soybean rust has not been identified in the soybean field to be treated, is not present in the local geographical area, and spores are not present or predicted to be present in the local geographical area

Treatment Pristine (12.5 to 16 ozs/acre)1 + adjuvant Application 1 Timing R1 to R3 leaf stage (1s1 flower to beginning pod)

Pristine (12.5 to 16 ozs/acre)1 + adjuvant Treatment + EPA-approved fungicide (non-Qol mode of action) with known curative activity against Asian soybean rust2 Application 2 ' 21 days after Application 1 Timing or Earlier (no sooner than 7 days) if monitoring shows active disease

1 Higher labeled rates of Pristine provide longer residual control of Asian soybean rust. 2 Contact your local, state or federal agricultural authorities or local retailer for a list of approved fungicides in your state approved for this purpose. 3 Continue to carefully monitor and scout soybean fields as described in the Management of Asian Soybean Rust section. If Asian soybean rust, including spores, is detected in your fields or local geography, the treatment described in Application 2 may be needed. Base the need for this treat- ment on crop stage of growth, environmental conditions and yield potential. Consult with your local retailer or university extension representative for guidance, as needed. Refer to application information preceding. Additional fungicide applications may be needed if Asian soybean rust pressure is extremely high and conditions are favorable for disease development later in the growing season. Continue the monitoring and scouting program and apply an EPA-approved fungicide (non-Qol mode of action) with known curative activity if the third application is needed.

27 Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Spinach Alternaria leaf spot 1 0 to 1 5 ozs 2 50 ozs 1 4 days lAlternaria spp.) per acre per acre Spinach (New Zealand Anthracnose and vine) (Colletotrichum spp.)

Ascochyta leaf spot (Ascochyta spp.)

Cercospora leaf spot (Cercospora spp.)

Downy mildew (Peronospora spp.)

Phoma (Phoma spp.)

Powdery mildew (Erysiphe spp., Phyllactinia spp., Sphaerotheca spp.)

Rust (Puccinia spp.)

Septoria leaf spot (Septoria spp.)

White rust (Albugo spp.) Botrytis rot 25 ozs (Botrytis spp.) per acre

Sclerotinia rot and blight (Sc/erotinia spp.)

Application Directions. Begin applications of Pristine9 fungicide prior to the onset of disease development and continue on a 7-day interval.

Use the higher rate when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than one (1 ) application of Pristine before alternating to a labeled fungicide with a different mode of action for at least one (1) application.

28 Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Stone Fruits Group Alternaria leaf spot 10.5 to 14.5ozs 5 72.5 ozs 0 days Apricot (4/ternar/a spp.) per acre per acre Cherry (sweet and tart) Anthracnose Nectarine (Colletotrichum spp.) Blossom blight Plum (Monilinia spp.) (all varieties) Plumcot Brown rot Prune (Monilinia spp.)

Leaf spot (Blumeriella jaapii)

Powdery mildew (Sphaerotheca spp., Podosphaera spp.)

Ripe fruit rot (Monilinia fructicola, Monilinia laxa, Botrytis cinerea, Rhizopus spp.)

Rust (Tranzschel/a discolor)

Scab (Cladosporium carpophilum )

Shothole (Wi/sonomyces carpophi/us) Nectarine Suppression Only Peach Leaf curl (Taphrina deformans)

Application Directions. Begin application of Pristine® fungicide at pink bud or prior to onset of disease development and continue on a 7- to 1 4-day interval. Use the shorter interval and/or the higher rate when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than five (5) applications of Pristine or other Group 7 or 11 fungicides per season. DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action. For aerial application to stone fruit trees, use no less than 10 gallons of spray solution per acre,

29 Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI)

Strawberries Anthracnose 18.5 to 23 ozs 115 ozs 0 days (Col/etotrichum spp.) per acre per acre

Botrytis gray mold (Botrytis cinerea)

Leaf spot (Mycosphaerel/a fragariae)

Powdery mildew (Sphaerotheca macularis)

Application Directions. Begin applications of Pristine® fungicide no later than 10% bloom, or prior to disease development, and continue on a 7- to 14-day interval.

Use the higher rate and the shorter interval when disease pressure is high.

The restricted-entry interval (REI) for treated strawberries is 12 hours. Refer to the Agricultural Use Requirements box for PPE required for early entry to treated areas as permitted under the Worker Protection Standard.

Resistance Management. To limit the potential for development of resistance, DO NOT make more than five (5) applications of Pristine or other Group 7 or 11 fungicides per season.

DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action.

30 f

Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI) Tree Nuts Group Alternaria leaf spot 10.5 to 14.5 ozs 58 ozs 14 days Almond (Altemaria spp.) per acre per acre (25 days Beech nut Anthracnose for almond) Brazil nut (Co/letotrichum spp.) Butternut Cashew Blossom blight Chestnut (Monilinia spp.) Chinquapin Filbert Eastern filbert blight Hickory nut (Anisogramma anomala) Macadamia nut Leaf rust Pecan (Tranzsche/ia discolor) Walnut (black and Scab English) (Cladosporium carpophilum, C. caryigenum)

Green fruit rot (Botrytis cinerea)

Shothole (Wi/sonomyces carpophilus)

Application Directions. In almond, begin applications of Pristine* fungicide at pink bud and continue on a 7- to 14-day interval up to 25 days before harvest. In filbert, begin applications at budswell to budbreak, prior to infection and onset of disease development. Continue on a 7- to 14-day interval to cover and protect new growth. In pecan, begin applications of Pristine prior to onset of disease development and continue on a 7- to 21-day interval for the control of scab. For all other crops listed above, apply Pristine prior to disease development and continue on a 7- to 28-day interval. In all cases, use the shorter interval when shoot growth is very rapid.

Use the shorter interval and/or the higher rate when disease pressure is high.

For aerial application to tree nuts, use no less than 10 gallons of spray solution per acre.

No restriction on livestock feeding for almond hulls.

Resistance Management. To limit the potential for development of resistance, DO NOT make more than four (4) applications of Pristine or other Group 7 or 11 fungicides per season.

DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action.

31 Table 2. Crop-specific Use Directions (continued)

Minimum Maximum Product Maximum Time from Number of Crop Target Disease Use Rate Product Rate Application to Applications per Application per Season Harvest per Season (PHI/DLJ 11) Tropical Fruits Anthracnose 18.5 ozs 2 37 ozs 0 days Avocado (Colletotrichum gloeosporioides) per acre per acre Black sapote Canistel Black spot Mamey sapote (Asperisporium caricae, Mango A/ternaria alternata, Papaya Cercospora papaya e) Sapodilla Dry rot Star apple (Mycosphaerel/a spp.) Powdery mildew (Oidium spp., Erysiphe spp.) Pseudocercospora spot/blotch (Pseudocercospora purpurea, Cercospora spp.) Scab (Elsinoe mangiferae)

Application Directions. Begin application of Pristine" fungicide prior to the onset of disease development and repeat applicat on 7 days later, as needed, or alternate with another labeled fungicide having a different mode of action. Resistance Management. To limit the potential for development of resistance, DO NOT make more than two (2) applications of Pristine per season.

32 Conditions of Sale and Warranty The Directions For Use of this product reflect the opinion of experts based on field use and tests. The directions are believed to be reliable and must be followed carefully. However, it is impossible to eliminate all risks inherently associated with the use of this product. Crop injury, ineffectiveness or other unintended consequences may result because of such factors as weather conditions, presence of other materials, or use of the product in a manner inconsistent with its labeling, all of which are beyond the control of BASF CORPORATION ("BASF") or the Seller. To the extent consistent with applicable law, all such risks shall be assumed by the Buyer. BASF warrants that this product conforms to the chemical description on the label and is reasonably fit for the purposes referred to in the Directions For Use, subject to the inherent risks, referred to above. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BASF MAKES NO OTHER EXPRESS OR IMPLIED WARRANTY OF FITNESS OR MERCHANTABILITY OR ANY OTHER EXPRESS OR IMPLIED WARRANTY. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BUYER'S EXCLUSIVE REMEDY AND BASF'S Cabrio, Endura, Headline and Pristine are registered EXCLUSIVE LIABILITY, WHETHER IN CONTRACT, trademarks of BASF. TORT, NEGLIGENCE, STRICT LIABILITY, OR Botran is a registered trademark of Gowan Company. OTHERWISE, SHALL BE LIMITED TO REPAYMENT Kelthane, Lorsban and M-Pede are registered OF THE PURCHASE PRICE OF THE PRODUCT. trademarks and Rally is a trademark of Dow TO THE EXTENT CONSISTENT WITH APPLICABLE AgroSciences LLC. LAW, BASF AND THE SELLER DISCLAIM ANY Lannate is a registered trademark of E.I. duPont de LIABILITY FOR CONSEQUENTIAL, EXEMPLARY, Nemours and Company. SPECIAL OR INDIRECT DAMAGES RESULTING Phaser is a registered trademark of Bayer CropScience. FROM THE USE OR HANDLING OF THIS PRODUCT. Sonoma is a trademark ofAlbaugh, Inc. Thiodan is a registered trademark of Canadian Hoechst, BASF and the Seller offer this product, and the Buyer Ltd. and User accept it, subject to the foregoing Conditions of Sale and Warranty which may be varied only by agreement in writing signed by a duly authorized representative of BASF. nos

© 2012 BASF Corporation All rights reserved.

007969-00199.20120315.NVA 2012-04-156-0057 Supersedes: NVA 2012-04-156-0001

BASF Corporation 26 Davis Drive Research Triangle Park, NC 27709

The Chemical Company

33 Group Fungicide

Supplemental Label ristine FUNGICIDE

Mixing instructions and restrictions for use on crops in the Berries Group - bushberry and caneberry

This supplemental label expires December 31, 2015 and must not be used or distributed after this date.

Active Ingredients: pyraclostrobin: (carbamic acid, [2-[[[1-(4-chlorophenyl)-1H-pyrazol-3- yl]oxy]methyl]phenyl]methoxy-, methyl ester) 12.8% boscalid: (3-pyridinecarboxamide, 2-chloro-N-(4'-chloro(1,1'-biphenyl)-2-yl)) 25.2% Other Ingredients: 62.0% Total: 100.0% EPA Reg. No. 7969-199

Directions For Use crops listed in the Berries Group. See Berries Group in Table 2. Crop-specific Use Directions on • It is a violation of federal law to use this product in a this supplemental label. manner inconsistent with its labeling. • The supplemental labeling and the entire Crop-specific Use Directions Pristine container label, EPA Reg. No. 7969-199, must be in possession of the user at the time of Pristine may be applied on blueberries (highbush and application. lowbush) when used according to the instructions on this supplemental label. • Read the label affixed to the container for Pristine before applying. DO NOT apply Pristine to any crops in the Berries Group, including blueberries (highbush and lowbush), • Use of Pristine according to this labeling is subject to as a tank mix with any other pesticide products the use precautions and limitations imposed by the (including fungicides, insecticides, herbicides), label affixed to the container for Pristine. adjuvants, liquid fertilizers, nutrients, or any other additives. Additives and General Tank The restrictions on this supplemental label regarding Mixing Information tank mixes and/or adjuvant combinations for crops in For the Berries Group, including blueberries the Berries Group, including blueberries (highbush and (highbush and lowbush), DO NOT tank mix Pristine lowbush), supersede those on the Pristine container label. with any other pesticide products (including fungicides, insecticides, herbicides), adjuvants, liquid fertilizers, nutrients, or any other additives. Mix Pristine with only water for applications to ACCEPTED

JUN 0 4 2012 Under the Federal Insecticide, -BASF BASF Corporation Fungicide, and Rodenticide Act, 26 Davis Drive, Research Triangle Park, NC 27709 as amended, for the pesticide The Chemical Company registered under EPA Reg No. Table 1. Crop-specific Restrictions and Limitations Minimum Time Maximum Rate Maximum Maximum Rate from Application per Acre Number per Acre Crop to Harvest per Application of Applications per Season (PHI) (days) (ozs product) per Season (ozs product)

Berries Group* 0 23 4 92 Bushberry Caneberry

*DO NOT tank mix Pristine® fungicide with any other pesticide products (including fungicides, insecticides, herbicides), adjuvants, liquid fertilizers, nutrients, or any other additives. The use in blueberries is not registered for use in California.

Table 2. Crop-specific Use Directions Minimum Product Use Maximum Maximum Time from Rate per Number of Product Rate Crop Target Disease Application to Application Applications per Season Harvest (ozs/A) per Season (ozs/A) (PHI)(days) Berries Group Alternaria leaf spot 18.5 to 23 4 92 0 and fruit rot Bushberry (Alternaria spp.) Blueberry* (highbush and Anthracnose lowbush) (Colletotrichum spp., Currant Elsinoe spp.) Elderberry Botrytis gray mold Gooseberry (Botrytis cinerea) Huckleberry Leaf spot and blotch Caneberry (Mycosphaerella spp., Blackberry Septoria spp.) (all varieties) Loganberry Monilinia blight and Raspberry mummy berry (black and red) (Monilinia spp.) Phomopsis leaf spot, twig blight, and fruit rot (Phomopsis spp.) Powdery mildew (Sphaerotheca spp., Microsphaera spp., Oidium spp.) Spur blight (Didymella spp., Phoma spp.) Suppression Only Rust (Puccianiastrum spp., Arthuriomyces spp., Phragmidiumspp., Kuehneola spp.)

(continued) ( 3?

Table 2. Crop-specific Use Directions (continued) Application Directions. Begin applications of Pristine fungicide prior to onset of disease development and continue on a 7- to 14-day interval. DO NOT apply Pristine to any crops in the Berries Group, including blueberries (highbush and lowbush), as a tank mix with any other pesticide products (including fungicides, insecticides, herbicides), adjuvants, liquid fertilizers, nutrients, or any other additives. * Not registered for use in California. Mix Pristine with only water for applications to crops listed in the Berries Group. Use the shorter interval and/or the higher rate when disease pressure is high. Resistance Management. To limit the potential for development of resistance, DO NOT make more than four (4) applications of Pristine or other Group 7 or 11 fungicides per season. DO NOT make more than two (2) sequential applications of Pristine before alternating to a labeled fungicide with a different mode of action. Conditions of Sale and Warranty

The Directions For Use of this product reflect the opinion of experts based on field use and tests. The directions are believed to be reliable and must be followed carefully. However, it is impossible to eliminate all risks inherently associated with the use of this product. Crop injury, ineffectiveness or other unintended consequences may result because of such factors as weather conditions, presence of other materials, or use of the product in a manner inconsistent with its labeling, all of which are beyond the control of BASF CORPORATION ("BASF") or the Seller. To the extent consistent with applicable law, all such risks shall be assumed by the Buyer. BASF warrants that this product conforms to the chemical description on the label and is reasonably fit for the purposes referred to in the Directions For Use, subject to the inherent risks, referred to above. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BASF MAKES NO OTHER EXPRESS OR IMPLIED WARRANTY OF FITNESS OR MERCHANTABILITY OR ANY OTHER EXPRESS OR IMPLIED WARRANTY. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BUYER'S EXCLUSIVE REMEDY AND BASF'S EXCLUSIVE LIABILITY, WHETHER IN CONTRACT, TORT, NEGLIGENCE, STRICT LIABILITY, OR OTHERWISE, SHALL BE LIMITED TO REPAYMENT OF THE PURCHASE PRICE OF THE PRODUCT. TO THE EXTENT CONSISTENT WITH APPLICABLE LAW, BASF AND THE SELLER DISCLAIM ANY LIABILITY FOR CONSEQUENTIAL, EXEMPLARY, SPECIAL OR INDIRECT DAMAGES RESULTING FROM THE USE OR HANDLING OF THIS PRODUCT. Pristine is a registered trademark of BASF. BASF and the Seller offer this product, and the Buyer and User accept it, subject to the foregoing ©2012 BASF Corporation Conditions of Sale and Warranty which may be All rights reserved. varied only by agreement in writing signed by a duly authorized representative of BASF. nos 007969-00199.20120412b.NVA 2012-04-156-0080 Based on: NVA 2012-04-156-0057 Supersedes: NVA 2012-04-156-0002

BASF Corporation 26 Davis Drive Research Triangle Park, NC 27709

-BASF The Chemical Company