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Safety Data Sheet SAFETY DATA SHEET Revision Date 15-Jan-2021 Revision Number 2 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product Description: Aluminum ethoxide Cat No. : 41336 Synonyms Aluminium ethoxide CAS-No 555-75-9 Molecular Formula C6 H15 Al O3 Reach Registration Number - 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended Use Laboratory chemicals. Uses advised against No Information available 1.3. Details of the supplier of the safety data sheet Company Alfa Aesar . Avocado Research Chemicals, Ltd. Shore Road Port of Heysham Industrial Park Heysham, Lancashire LA3 2XY United Kingdom Office Tel: +44 (0) 1524 850506 Office Fax: +44 (0) 1524 850608 E-mail address [email protected] www.alfa.com Product Safety Department 1.4. Emergency telephone number Call Carechem 24 at +44 (0) 1865 407333 (English only); +44 (0) 1235 239670 (Multi-language) SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture CLP Classification - Regulation (EC) No 1272/2008 Physical hazards Flammable solids Category 2 (H228) Substances/mixtures which, in contact with water, emit flammable gases Category 2 (H261) Health hazards ______________________________________________________________________________________________ ALFAA41336 Page 1 / 11 SAFETY DATA SHEET Aluminum ethoxide Revision Date 15-Jan-2021 ______________________________________________________________________________________________ Skin Corrosion/Irritation Category 1 B (H314) Environmental hazards Based on available data, the classification criteria are not met Full text of Hazard Statements: see section 16 2.2. Label elements Signal Word Danger Hazard Statements H261 - In contact with water releases flammable gases H228 - Flammable solid H314 - Causes severe skin burns and eye damage EUH014 - Reacts violently with water Precautionary Statements P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P280 - Wear eye protection/ face protection P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking P302 + P335 + P334 - IF ON SKIN:Brush off loose particles from skin. Immerse in cool water P402 + P404 - Store in a dry place. Store in a closed container 2.3. Other hazards No information available SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.1. Substances Component CAS-No EC-No. Weight % CLP Classification - Regulation (EC) No 1272/2008 Ethanol, aluminum salt 555-75-9 EEC No. 209-105-8 99 Flam Sol. 2 (H228) Wat. React. 2 (H261) Skin Corr. 1B (H314) (EUH014) ______________________________________________________________________________________________ ALFAA41336 Page 2 / 11 SAFETY DATA SHEET Aluminum ethoxide Revision Date 15-Jan-2021 ______________________________________________________________________________________________ Reach Registration Number - Full text of Hazard Statements: see section 16 SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures Eye Contact Immediate medical attention is required. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Immediate medical attention is required. Ingestion Do NOT induce vomiting. Call a physician immediately. Inhalation Remove from exposure, lie down. Remove to fresh air. If not breathing, give artificial respiration. Immediate medical attention is required. Self-Protection of the First Aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. 4.2. Most important symptoms and effects, both acute and delayed Causes burns by all exposure routes. Difficulty in breathing. Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated: Ingestion causes severe swelling, severe damage to the delicate tissue and danger of perforation: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting 4.3. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. Symptoms may be delayed. SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Suitable Extinguishing Media CO 2, dry chemical, dry sand, alcohol-resistant foam. Extinguishing media which must not be used for safety reasons No information available. 5.2. Special hazards arising from the substance or mixture Flammable. Corrosive material. Reacts violently with water. Contact with water liberates extremely flammable gases. Thermal decomposition can lead to release of irritating gases and vapors. Keep product and empty container away from heat and sources of ignition. Hazardous Combustion Products Carbon monoxide (CO), Carbon dioxide (CO2), Burning produces obnoxious and toxic fumes. 5.3. Advice for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. ______________________________________________________________________________________________ ALFAA41336 Page 3 / 11 SAFETY DATA SHEET Aluminum ethoxide Revision Date 15-Jan-2021 ______________________________________________________________________________________________ SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation. 6.2. Environmental precautions See Section 12 for additional Ecological Information. 6.3. Methods and material for containment and cleaning up Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Sweep up and shovel into suitable containers for disposal. Do not expose spill to water. 6.4. Reference to other sections Refer to protective measures listed in Sections 8 and 13. SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Do not breathe dust. Do not get in eyes, on skin, or on clothing. Handle product only in closed system or provide appropriate exhaust ventilation. Use spark-proof tools and explosion-proof equipment. Use only non-sparking tools. Do not allow contact with water. Do not allow contact with water because of violent reaction. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not eat, drink or smoke when using this product. Remove and wash contaminated clothing and gloves, including the inside, before re-use. Wash hands before breaks and after work. 7.2. Conditions for safe storage, including any incompatibilities Keep in a dry, cool and well-ventilated place. Keep container tightly closed. Keep away from heat, sparks and flame. Keep from any possible contact with water. Corrosives area. Flammables area. Keep under nitrogen. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep away from water or moist air. Keep containers tightly closed in a dry, cool and well-ventilated place. Technical Rules for Hazardous Substances (TRGS) 510 Storage Class (LGK) Class 4.3 (Germany) 7.3. Specific end use(s) Use in laboratories SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Exposure limits This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies Biological limit values This product, as supplied, does not contain any hazardous materials with biological limits established by the region specific ______________________________________________________________________________________________ ALFAA41336 Page 4 / 11 SAFETY DATA SHEET Aluminum ethoxide Revision Date 15-Jan-2021 ______________________________________________________________________________________________ regulatory bodies Monitoring methods BS EN 14042:2003 Title Identifier: Workplace atmospheres. Guide for the application and use of procedures for the assessment of exposure to chemical and biological agents. MDHS14/3 General methods for sampling and gravimetric analysis of respirable and inhalable dust Derived No Effect Level (DNEL) No information available Route of exposure Acute effects (local) Acute effects Chronic effects Chronic effects (systemic) (local) (systemic) Oral Dermal Inhalation Predicted No Effect Concentration No information available. (PNEC) 8.2. Exposure controls Engineering Measures Use explosion-proof electrical/ventilating/lighting/equipment. Ensure that eyewash stations and safety showers are close to the workstation location. Wherever possible, engineering control measures such as the isolation or enclosure of the process, the introduction of process or equipment changes to minimise release or contact, and the use of properly designed ventilation systems, should be adopted to control hazardous materials at source Personal protective equipment Eye Protection Goggles (European standard - EN 166) Hand Protection Protective gloves Glove material Breakthrough time Glove thickness EU standard Glove comments Nitrile rubber See manufacturers - EN 374 (minimum requirement) Viton (R) recommendations Skin and body protection Wear appropriate protective gloves and clothing to prevent
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