Compilation of Crystal Growers and Crystal Growth Projects Research Materials Information Center
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' iW it( 1 ' ; cfrv-'V-'T-'X;^ » I V' 1l1 II V/ f ,! T-'* «( V'^/ l "3 ' lyJ I »t ; I« H1 V't fl"j I» I r^fS' ^SllMS^W'/r V '^Wl/ '/-D I'ril £! ^ - ' lU.S„AT(yMIC-ENERGY COMMISSION , : * W ! . 1 I i ! / " n \ V •i" "4! ) U vl'i < > •^ni,' 4 Uo I 1 \ , J* > ' . , ' ^ * >- ' y. V * / 1 \ ' ' i S •>« \ % 3"*V A, 'M . •. X * ^ «W \ 4 N / . I < - Vl * b >, 4 f » ' ->" ' , \ .. _../.. ~... / -" ' - • «.'_ " . Ife .. -' < p / Jd <2- ORNL-RMIC-12 THIS DOCUMENT CONFIRMED AS UNCLASSIFIED DIVISION OF CLASSIFICATION COMPILATION OF CRYSTAL GROWERS AND CRYSTAL GROWTH PROJECTS RESEARCH MATERIALS INFORMATION CENTER \i J>*\,skJ if Printed in the United States of America. Available from National Technical Information Service U.S. Department of Commerce 5285 Port Royal Road, Springfield, Virginia 22t51 Price: Printed Copy $3.00; Microfiche $0.95 This report was prepared as an account of work sponsored by the United States Government. Neither the United States nor the United States Atomic Energy Commission, nor any of their employees, nor any of their contractors, subcontractors, or their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness or usefulness of any information, apparatus, product or process disclosed, or represents that its use would not infringe privately owned rights. ORNL-RMIC-12 UC-25 - Metals, Ceramics, and Materials Contract No. W-7405-eng-26 COMPILATION OF CRYSTAL GROWERS AND CRYSTAL GROWTH PROJECTS T. F. Connolly Research Materials Information Center Solid State Division NOTICE This report was prepared as an account of work sponsored by the Unitsd States Government. Neither the United States nor the United States Atomic Energy Commission, nor any of their employees, nor any of their contractors, subcontractors, or their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, com- pleteness or usefulness jf any information, apparatus, product or process disclosed, or represents that its use would not infringe privately owned rights. JUNE 1972 OAK RIDGE NATIONAL LABORATORY Oak Ridge, Tennessee 37830 operated by UNION CARBIDE CORPORATION for the U.S. ATOMIC ENERGY COMMISSION DISTRIBUTION OF THIS DOCtiMEHT IS WUJMTTEp The Research Materials Information Center was established in 1963, as part of the Research Materials Program of the ORNL Solid State Division, to provide information on the availability, preparation, and properties of ultrapure inorganic research materials. The ability of RMIC to answer inquiries depends completely on the flow of current information to the Center. Reprints (or preprints, preferabfy) and completed data sheets should be sent to the Center by all working in materials science and particularly by those producing specimens they are willing to sell, lend, or donate to other researchers. Further information and blank data sheets (which should be used both to announce and inquire about materials) are available from the Center on request by mail or telephone. ALL INQUIRIES, PREPRINTS, AND REPRINTS SHOULD BE ADDRESSED TO: T. F. Connolly Research Materials Information Center Oak Ridge National Laboratory P. O. Box X Oak Ridge, Tennessee 37830 Telephone: (615) 483-8611, Ext. 3-1287 COMPILATION OF CRYSTAL GROWERS AND CRYSTAL GROWTH PROJECTS This compilation lists all those who returned questionnaires distributed Internationally by the Research Materials Information Center (most of them in the last half of 1971). Addresses were taken from the RMIC mailing list, and questionnaires were also sent to those — not on the mailing list — making inquiries to the Center during this period. The compilation includes, in addition to those growing crystals, preparers of starting materials for crystal growth and some preparing ultrapure noncrystalline inorganic research specimens. Commercial suppliers — not always producers — are also included and are indicated by an asterisk after the entry number. The format of the entries is self-explanatory except perhaps for the sections introduced by Roman numerals. These represent the answers to the following questions: I. What is your major interest in research materials [preparation of starting materials, crystal growth, characterization, physical properties research (if the last is included, what properties are examined?)] II. What specific techniques and apparatus are used in your program (Czochralski, mass spectrometry, optical)? III. What specific crystals or other materials are prepared or grown? IV. What is the purpose of the crystal growth or intended use of the crystals (e.g., ferroelectric or electro:optic materials, structure or magnetic studies, study of crystal growth methods)? The listing is followed by separate indexes on: specific materials (alphabetical by chemical formula); general classes, such as ferrites, garnets, group III-V; and the intended use of the material (semiconductor, ferroelectric, electro-optic, etc.). Indexes by growth methods and methods of characterization were considered but rejected (after review of the listings) as simply repetitive. * * * * I am very grateful to Betty Edwards who is responsible for the painstaking magnetic-tape typewriter composition and for the copy-editing and correction of often semi-legible material. * * * * Because a publication of this sort will lead to many inquiries to those listed, it seems an appropriate vehicle for the transmission of some ideas on the subject of requests for information or research specimens. For several years now the Research Materials Information Center has been referring inquiries for single crystals to commercial sources and to individuals w^o have produced crystals in the course of their own research and who have been kind enough to inform the Center that they are willing to lend or donate their crystals to others. Comments by many of the latter group indicate that, all too often, there is unnecessary correspondence and delay in such transactions caused by simple carelessness on the part of the requester. In addition, the subsequent fate of the donated crystal and the results of studies made with it frequently remain a mystery to the supplier, particularly in the cases where it is passed on to others by the original recipient. This last is frequently mentioned and was emphasized strongly in a recent survey on the status of crystal growth in the U.S.1 1 Status of Crystal Growth in the United States, D. S. Billington and G. C. Danielson, GRNL-RMIC-10 (December 1968), p. 4. "One indictment of the rest of the solid state community by the crystal growers is that the average scientist is too little concerned with the quality of the crystal he uses in his research and, as a consequence, much of the research reported is of little ox no value. Another serious objection is that more research is often involved in the preparation of the crystal than in the physical measurements. Yet the crystal grower may receive no more than a 'thank you' in the 'Acknowledgements' of the paper. This matter is so serious that some crystal growers will soon refuse to furnish crystals unless they are direct participants in the research." iii Such comments range from suggestions to complaints on the part of the crystal grower; and they are remarks that many are, understandably, reluctant tc make to their colleagues. In the hope, therefore, that the path of both the user and the grower of crystals may be somewhat eased and that the suggestions be taken in the spirit offered, a summary follows: 1. In requesting a crystal, be as specific as possible. List size, purity, orientation, desired dopant and amount, and any other required properties. There is no point in receiving a crystal that might be worthless to you but adequate for other purposes. 2. Specify the nature and the purpose of the work to be done on the crystal. The crystal grower is a fellow scientist and has an interest in studies complementary to (and not competitive with) his own. His crystal supply is very limited, and it should be assumed that he must be selective in distributing it. 3. Be sure to provide the original supplier personally with any data taken from the sample. (Publication is a slow process, and he might never see the paper.) Each separate study can be a further characterization of the crystal and, if recorded, add to its value as a research specimen. 4. Above all, give full acknowledgement to the supplier of the crystal, specifying (if applicable) his methods of characterization and the nature of his studies of the material. This is not only courteous but could be useful correlative information to the readers of your paper. CONTENTS Preface iii Compilation 1 United States 1 Argentina 74 Australia 74 Belgium 77 Brazil 78 Bulgaria 79 Canada 79 Chile 84 Czechoslovakia 85 Denmark 85 England 85 Finland 96 France 97 Germany 102 Hungary 108 India i08 Israel 110 Italy 112 Japan 113 Mexico 122 Netherlands 123 New Zealand ...124 Norway 125 Poland 125 Scotland 126 South Africa 128 Sweden 128 Switzerland 129 U.A.R 130 U.S.S.R 131 Wales 131 Materials and Applications Indexes 133 Index I — Materials by Chemical Formula 134 Index II — Materials by Classes, Generic Names, or Chemical Groups 140 Index III — Applications - Intended Use - Properties Studied 142 v UNITED STATES 1.* LAMBDA/AIRTRON Division of Litton Industries 200 East Hanover Avenue Morris Plains, New Jersey 07950 Project Title: Crystal Growth Division or Department: Advanced Materials Laboratory Project or Dept. Head: Donald A. Lepore Person to Contact: Roger F. Belt Telephone:. (201) 539-5500 1. Single crystal production and characterization; physical properties (laser and x-ray topographic, electro-optical) II. Czochralski, hydrothermal, flux growth (x-ray and optical interferometry, active and passive laser test) III. Y3AlsOa2, Y3Fe5012,ZrSi04,CaC03,Gd3GasOi2, A1203, YA103, LiNb03,PbMo04, spinel ferrites, garnets IV. Laser, ferromagnetic, electro-optic, acousto-optic, soft ferrites, substrates, memory devices 2. UNIVERSITY OF ALABAMA IN HUNTSVILLE P.