Sediment-Hosted Copper Deposits of the World: Deposit Models and Database
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Podiform Chromite Deposits—Database and Grade and Tonnage Models
Podiform Chromite Deposits—Database and Grade and Tonnage Models Scientific Investigations Report 2012–5157 U.S. Department of the Interior U.S. Geological Survey COVER View of the abandoned Chrome Concentrating Company mill, opened in 1917, near the No. 5 chromite mine in Del Puerto Canyon, Stanislaus County, California (USGS photograph by Dan Mosier, 1972). Insets show (upper right) specimen of massive chromite ore from the Pillikin mine, El Dorado County, California, and (lower left) specimen showing disseminated layers of chromite in dunite from the No. 5 mine, Stanislaus County, California (USGS photographs by Dan Mosier, 2012). Podiform Chromite Deposits—Database and Grade and Tonnage Models By Dan L. Mosier, Donald A. Singer, Barry C. Moring, and John P. Galloway Scientific Investigations Report 2012-5157 U.S. Department of the Interior U.S. Geological Survey U.S. Department of the Interior KEN SALAZAR, Secretary U.S. Geological Survey Marcia K. McNutt, Director U.S. Geological Survey, Reston, Virginia: 2012 This report and any updates to it are available online at: http://pubs.usgs.gov/sir/2012/5157/ For more information on the USGS—the Federal source for science about the Earth, its natural and living resources, natural hazards, and the environment—visit http://www.usgs.gov or call 1–888–ASK–USGS For an overview of USGS information products, including maps, imagery, and publications, visit http://www.usgs.gov/pubprod To order this and other USGS information products, visit http://store.usgs.gov Suggested citation: Mosier, D.L., Singer, D.A., Moring, B.C., and Galloway, J.P., 2012, Podiform chromite deposits—database and grade and tonnage models: U.S. -
Abstract in PDF Format
PGM Associations in Copper-Rich Sulphide Ore of the Oktyabr Deposit, Talnakh Deposit Group, Russia Olga A. Yakovleva1, Sergey M. Kozyrev1 and Oleg I. Oleshkevich2 1Institute Gipronickel JS, St. Petersburg, Russia 2Mining and Metallurgical Company “Noril’sk Nickel” JS, Noril’sk, Russia e-mail: [email protected] The PGM assemblages of the Cu-rich 6%; the Ni content ranges 0.8 to 1.3%, and the ratio sulphide ores occurring in the western exocontact Cu/S = 0.1-0.2. zone of the Talnakh intrusion and the Kharaelakh Pyrrhotite-chalcopyrite ore occurs at the massive orebody have been studied. Eleven ore top of ore horizons. The ore-mineral content ranges samples, weighing 20 to 200 kg, were processed 50 to 60%, and pyrrhotite amount is <15%. The ore using gravity and flotation-gravity techniques. As a grades 1.1 to 1.3% Ni, and the ratio Cu/S = 0.35- result, the gravity concentrates were obtained from 0.7. the ores and flotation products. In the gravity Chalcopyrite ore occurs at the top and on concentrates, more than 20,000 PGM grains were the flanks of the orebodies. The concentration of found and identified, using light microscopy and sulphides ranges 50 to 60%, and pyrrhotite amount EPMA. The textural and chemical characteristics of is <1%; the Ni content ranges 1.3 to 3.4%, and the PGM were documented, as well as the PGM ratio Cu/S = 0.8-0.9. distribution in different size fractions. Also, the The ore types are distinctly distinguished balance of Pt, Pd and Au distribution in ores and by the PGE content which directly depends on the process products and the PGM mass portions in chalcopyrite quantity, but not on the total sulphide various ore types were calculated. -
Biofilm Adhesion on the Sulfide Mineral Bornite & Implications for Astrobiology
University of Rhode Island DigitalCommons@URI Open Access Master's Theses 2019 BIOFILM ADHESION ON THE SULFIDE MINERAL BORNITE & IMPLICATIONS FOR ASTROBIOLOGY Margaret M. Wilson University of Rhode Island, [email protected] Follow this and additional works at: https://digitalcommons.uri.edu/theses Recommended Citation Wilson, Margaret M., "BIOFILM ADHESION ON THE SULFIDE MINERAL BORNITE & IMPLICATIONS FOR ASTROBIOLOGY" (2019). Open Access Master's Theses. Paper 1517. https://digitalcommons.uri.edu/theses/1517 This Thesis is brought to you for free and open access by DigitalCommons@URI. It has been accepted for inclusion in Open Access Master's Theses by an authorized administrator of DigitalCommons@URI. For more information, please contact [email protected]. BIOFILM ADHESION ON THE SULFIDE MINERAL BORNITE & IMPLICATIONS FOR ASTROBIOLOGY BY MARGARET M. WILSON A THESIS SUBMITTED IN PARTIAL FULFILLMENT OF THE REQUIREMENTS FOR THE DEGREE OF MASTER OF SCIENCE IN BIOLOGICAL & ENVIRONMENTAL SCIENCE UNIVERSITY OF RHODE ISLAND 2019 MASTER OF SCIENCE IN BIOLOGICAL & ENVIRONMENTAL SCIENCE THESIS OF MARGARET M. WILSON APPROVED: Thesis Committee: Major Professor Dawn Cardace José Amador Roxanne Beinart Nasser H. Zawia DEAN OF THE GRADUATE SCHOOL UNIVERSITY OF RHODE ISLAND 2019 ABSTRACT We present research observing and documenting the model organism, Pseudomonas fluorescens (P. fluorescens), building biofilm on a natural mineral substrate composed largely of bornite (Cu5FeS4), a copper-iron sulfide mineral, with closely intergrown regions of covellite (CuS) and chalcopyrite (CuFeS2). In examining biofilm establishment on sulfide minerals, we investigate a potential habitable niche for microorganisms in extraterrestrial sites. Geochemical microenvironments on Earth and in the lab can also serve as analogs for important extraterrestrial sites, such as sheltered, subsurface microenvironments on Mars. -
LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, and COBALT ARSENIDE and SULFIDE ORE FORMATION Nicholas Allin
Montana Tech Library Digital Commons @ Montana Tech Graduate Theses & Non-Theses Student Scholarship Spring 2019 EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION Nicholas Allin Follow this and additional works at: https://digitalcommons.mtech.edu/grad_rsch Part of the Geotechnical Engineering Commons EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION by Nicholas C. Allin A thesis submitted in partial fulfillment of the requirements for the degree of Masters in Geoscience: Geology Option Montana Technological University 2019 ii Abstract Experiments were conducted to determine the relative rates of reduction of aqueous sulfate and aqueous arsenite (As(OH)3,aq) using foils of copper, nickel, or cobalt as the reductant, at temperatures of 150ºC to 300ºC. At the highest temperature of 300°C, very limited sulfate reduction was observed with cobalt foil, but sulfate was reduced to sulfide by copper foil (precipitation of Cu2S (chalcocite)) and partly reduced by nickel foil (precipitation of NiS2 (vaesite) + NiSO4·xH2O). In the 300ºC arsenite reduction experiments, Cu3As (domeykite), Ni5As2, or CoAs (langisite) formed. In experiments where both sulfate and arsenite were present, some produced minerals were sulfarsenides, which contained both sulfide and arsenide, i.e. cobaltite (CoAsS). These experiments also produced large (~10 µm along longest axis) euhedral crystals of metal-sulfide that were either imbedded or grown upon a matrix of fine-grained metal-arsenides, or, in the case of cobalt, metal-sulfarsenide. Some experimental results did not show clear mineral formation, but instead demonstrated metal-arsenic alloying at the foil edges. -
Washington State Minerals Checklist
Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite -
Key to Rocks & Minerals Collections
STATE OF MICHIGAN MINERALS DEPARTMENT OF NATURAL RESOURCES GEOLOGICAL SURVEY DIVISION A mineral is a rock substance occurring in nature that has a definite chemical composition, crystal form, and KEY TO ROCKS & MINERALS COLLECTIONS other distinct physical properties. A few of the minerals, such as gold and silver, occur as "free" elements, but by most minerals are chemical combinations of two or Harry O. Sorensen several elements just as plants and animals are Reprinted 1968 chemical combinations. Nearly all of the 90 or more Lansing, Michigan known elements are found in the earth's crust, but only 8 are present in proportions greater than one percent. In order of abundance the 8 most important elements Contents are: INTRODUCTION............................................................... 1 Percent composition Element Symbol MINERALS........................................................................ 1 of the earth’s crust ROCKS ............................................................................. 1 Oxygen O 46.46 IGNEOUS ROCKS ........................................................ 2 Silicon Si 27.61 SEDIMENTARY ROCKS............................................... 2 Aluminum Al 8.07 METAMORPHIC ROCKS.............................................. 2 Iron Fe 5.06 IDENTIFICATION ............................................................. 2 Calcium Ca 3.64 COLOR AND STREAK.................................................. 2 Sodium Na 2.75 LUSTER......................................................................... 2 Potassium -
Contrasting Styles of Lead-Zinc-Barium Mineralization in the Lower Benue Trough, Southeastern Nigeria
EARTH SCIENCES RESEARCH JOURNAL Earth Sci. Res. J. Vol. 21, No. 1 (March, 2017): 7 - 16 ORE DEPOSITS Contrasting styles of lead-zinc-barium mineralization in the Lower Benue Trough, Southeastern Nigeria Ifeanyi Andrew Oha*,1, Kalu Mosto Onuoha1, Silas Sunday Dada2 1Department of Geology, University of Nigeria, Nsukka. 2Kwara State University Malete *[email protected] ABSTRACT Keywords: Lead-Zinc-Barium mineralization, In the Lower Benue Trough of Southeastern Nigeria, lead-zinc-barium mineralization occurs as widely distributed Benue Trough, epigenetic, vein deposits. epigenetic fracture-controlled vein deposits which are restricted to Albian – Turonian sediments. Detailed field studies carried out in Ishiagu, Enyigba-Ameki-Ameri, Wanikande-Wanakom, and Gabu-Oshina which together constitute the four main areas of mineralization in the Lower Benue Trough, show that mineralization appears restricted to NW-SE and N-S fractures while the more common NE-SW fractures are barren. Apart from the Enyigba area, igneous bodies are found in the vicinity of the ore deposits while in the Wanikande area, barite veins and veinlets were observed to be closely interwoven with intrusive bodies. The host lithologies are highly varied, ranging from shales to siltstones, sandstones and occasionally igneous bodies. The ore assemblage also varies remarkably, with lead:zinc:barium ratios ranging from approximately 3:1:0 at Ishiagu, to 2:1:0 at Enyigba, 1:0:2 at Wanikande and nearly 100% barite at Gabu-Oshina. Thus, there is a remarkable increase in barite content from the southwest (Ishiagu) to the northeast (Gabu). The characteristics of the ore deposits roughly fit the base metal type mineralization known as clastic dominated lead-zinc-barium deposits. -
PHASE CHANGES in Cu 2 S AS a FUNCTION of TEMPERATURE 1. PREVIOUS WORK
National Bureau of Standards Special Publication 364, Solid State Chemistry, Proceedings of 5th Materials Research Symposium, issued July 1972. PHASE CHANGES IN cu2s AS A FUNCTION OF TEMPERATURE William R. Cook, Jr. Gould Inc., Gould Laboratories Cleveland, Ohio 44108 and Case Western Reserve University Cleveland, Ohio 44106 The high-'copper phase boundary of Cu2s deviates from stoichiometry above 300 °C, first becoming copper deficient, then above - 1075 °C becoming copper rich. The maximum copper content occurs at the monotectic temperature of 1104 °C. The strong effect of oxygen on the hexagonal-cubic transition in Cu2S was confirmed; the transition was also found to be sensi tive to the type of pretreatment of the material. The high temperature tetragonal "Cu1 96s" phase is stable between Cu1.95S and Cu2s, at temperatures of - 90° to - 140 °C. The tr~nsi tion to the tetragonal phase is extremely sluggish. The true composition of djurleite has been shown to be approximately Cu1.93S. The phases near the chalcocite-digenite region of the diagram may be grouped into those with hexagonal close packing of sulfur atoms and those with cubic close packing of sulfurs. This is important in understanding rates of transformation among the various phases that occur in this area of the diagram. Key words: Chalcocite; cu2s; digenite; djurleite; nonstoichiometry; phase relations. 1. PREVIOUS WORK Fairly thorough explorations of the Cu-s phase diagram between cu2s and cu1• ,shave been made by a number of previous workers [1-8] 1 The resulting diagram may be seen in figure 1 taken largely from Roseboom [7] and Riu [8]. -
Ore Geology Reviews 112 (2019) 103037
Ore Geology Reviews 112 (2019) 103037 Contents lists available at ScienceDirect Ore Geology Reviews journal homepage: www.elsevier.com/locate/oregeorev Framboidal chalcopyrite and bornite constrain redox conditions during formation of their host rocks in the copper stratabound mineralization of T Picachos, north-central Chile ⁎ R. Merineroa, , L. Ortegaa, R. Lunara, R. Piñaa, V. Cárdenesb a Mineralogy and Petrology Department, Complutense University of Madrid, Avda. Complutense s/n, 28040 Madrid, Spain b Geology Department, Oviedo University, C/Jesús Arias de Velasco s/n, 33005 Oviedo, Asturias, Spain ARTICLE INFO ABSTRACT Keywords: The Picachos Project is a copper deposit that occurs in manto-type orebodies in north-central Chile and it ex- Framboidal pyrite hibits common features of Chilean stratabound or manto-type copper deposits: (1) an increase of copper contents Framboidal chalcopyrite from the margins to the centre of the orebodies; (2) sodic and potassic hydrothermal alteration of host rocks with Framboidal bornite subsequent chloritization and sericite alteration; and (3) its occurrence in sequences of limestones that are Representative size distributions intercalated with volcanic rocks. The most salient characteristic of the Picachos Project is the presence of per- vasive framboidal pyrite in both the non-mineralized limestones and the host rocks of the copper mineralization. These framboidal pyrites are well preserved, probably due to their close relationship with organic matter, and have no evident textures of overgrowth, recrystallization or dissolution. Moreover, framboidal chalcopyrite and bornite are formed in the external and internal areas, respectively, of the orebodies, sharing common mor- phological characteristics with framboidal pyrite, and are formed by the replacement of the original pyrite framboids, without changing their shape and size distribution. -
Leaching of Pure Chalcocite with Reject Brine and Mno2 from Manganese Nodules
metals Article Leaching of Pure Chalcocite with Reject Brine and MnO2 from Manganese Nodules David Torres 1,2,3, Emilio Trigueros 1, Pedro Robles 4 , Williams H. Leiva 5, Ricardo I. Jeldres 5 , Pedro G. Toledo 6 and Norman Toro 1,2,3,* 1 Department of Mining and Civil Engineering, Universidad Politécnica de Cartagena, 30203 Cartagena, Spain; [email protected] (D.T.); [email protected] (E.T.) 2 Faculty of Engineering and Architecture, Universidad Arturo Prat, Almirante Juan José Latorre 2901, Antofagasta 1244260, Chile 3 Departamento de Ingeniería Metalúrgica y Minas, Universidad Católica del Norte, Antofagasta 1270709, Chile 4 Escuela de Ingeniería Química, Pontificia Universidad Católica de Valparaíso, Valparaíso 2340000, Chile; [email protected] 5 Departamento de Ingeniería Química y Procesos de Minerales, Facultad de Ingeniería, Universidad de Antofagasta, Antofagasta 1270300, Chile; [email protected] (W.H.L.); [email protected] (R.I.J.) 6 Department of Chemical Engineering and Laboratory of Surface Analysis (ASIF), Universidad de Concepción, P.O. Box 160-C, Correo 3, Concepción 4030000, Chile; [email protected] * Correspondence: [email protected]; Tel.: +56-552651021 Received: 21 September 2020; Accepted: 24 October 2020; Published: 27 October 2020 Abstract: Chalcocite (Cu2S) has the fastest kinetics of dissolution of Cu in chlorinated media of all copper sulfide minerals. Chalcocite has been identified as having economic interest due to its abundance, although the water necessary for its dissolution is scarce in many regions. In this work, the replacement of fresh water by sea water or by reject brine with high chloride content from desalination plants is analyzed. -
SAMPLING for COBALT at BORNITE, ALASKA Ry Jeffrey Y
SAMPLING FOR COBALT AT BORNITE, ALASKA Ry Jeffrey Y. Foley %*9 * * * * * * * * * * * * * * * * * * * * * Field Report - January, l9R 11. S. nEPARTMENT OF THE INTERIOR James S. Watt, Secretary BuREAuA OF MINES TARLE OF CONTENTS Page Introduction ................................................ Economic Geoloqy............................................ Work by the Bureau.......................................... Recommendations............................................. References ................................................. SAMDLING FOR cnRALT AT RORNITE, ALASKA By Jeffrey Y. Foley 1 INTRODIICTION Carrollite (CuCo2S4), an ore mineral of cobalt, is known to occur in the Ruby Creek Cu-Zn deposit at Bornite (fig. 1), in northwest Alaska (5, q). 2 The events leading to mineralization of dolomite and argillite units and the distribution of these rocks in the Bornite district are among the topics covered in a PhD discertation by M. W. Hitzman of Stan- ford University (in progress). Hitzman has identified carkollite and cobaltiferous pyrite at numerous intersections in diamond drill core belonging to Rear Creek Mining Corporation, the present operator of the property. A brief visit to collect bulk samples was made by a Bureau geologist in July, 19R1, as part of the Alaska Critical Metals program. ECONOMIC GEOLOGY Hitzman summarizes the distribution of cobalt as occurring: 1) "...as late cobaltiferous pyrite rims on earlier formed pyrite grains in pyritiferous, ferroan dolo- mite with disseminated sphalerite and massive siderite" 2) "...as carrollite in high-grade hornite, chalcocite, chalcopyrite, and sphalerite ore at higher levels in the deposit." 1 Geologist, U.S. Rureau of Mines, Alaska Field Operations Center, Fairbanks. 2 Underlined numbers in parentheses refer to items in the list of references at the end oF this report. ; - > . ; - .>;. -1,; g n/ /- ; > @ ! - xi #."R-: 3 2 vl- t 7:'i "^. -
Copper and Its Electrifying Future 19
SECTOR BRIEFING number DBS Asian Insights DBS Group61 Research • October 2018 Copper And Its Electrifying Future 19 DBS Asian Insights SECTOR BRIEFING 61 02 Copper And Its Electrifying Future Eun Young LEE Equity Analyst [email protected] Yi Seul SHIN Equity Analyst [email protected] Special thanks to Rachel Miu for her contribution to the report Produced by: Asian Insights Office • DBS Group Research go.dbs.com/research @dbsinsights [email protected] Goh Chien Yen Editor-in-Chief Martin Tacchi Art Editor 19 DBS Asian Insights SECTOR BRIEFING 61 03 04 Executive Summary 06 Introduction 12 Bullish on Long Term Copper Prices 18 Copper Demand’s New Growth Path Over the Next Decade 27 Electrifying Society: A Key Driver of Copper Demand 42 Copper Supply Lagging Demand 50 Appendix I Global Copper Sector Value Chain 52 Appendix II China Copper Sector Value Chain 53 Appendix III Top copper mines and refiners DBS Asian Insights SECTOR BRIEFING 61 04 Executive Summary opper is set for an electrifying future. Already the metal of choice wherever electricity is needed, copper is to experience demand at growth rates not seen in previous decades, as the world moves towards the electrification of energy. In particular, the Celectrification of transportation will be a mega-trend. Electric vehicles use copper more intensely than internal combustion engine vehicles (ICEVs) – a battery-powered electric vehicle contains four times as much copper as an ICEV (80kg versus 20kg). Renewable energy also uses significantly more copper per megawatt hour of power generated than for coal or nuclear power. With the electrification of energy, we expect demand for electricity to outstrip the growth in total primary energy demand going forward.