Mathcad Modules for Supercritical Fluid Extraction Based on Mixing Rules

Mathcad Modules for Supercritical Fluid Extraction Based on Mixing Rules Appendix C-Progams

Wei-Yin Chen Jiangping Liu

Department of Chemical Engineering University of Mississippi 134 Anderson Hall University, MS 38677

November 13, 2007

Corresponding author. Tel. (662) 915-5651; Fax. (662) 915-7023 E-mail address: [email protected] LIST OF Mathcad Programs

Ideal gas equation: Solubilities of naphthalene in supercritical carbon dioxide based on ideal gas law at three temperatures

Second virial coefficient: Solubilities of naphthalene in supercritical carbon dioxide based on second virial coefficient at three temperatures

Cubic EOS at 308.15K for k12 and Prediction of Dissolution at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on PRSV equation of state and experimental data; recovery of k12 based on data at 308.15K followed by prediction of solubility at 308.15 K

PSRK model at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on PSRK equation of state at 308.15 K

HV - PRSV at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on HV / UNIFAC at 308.15 K

HVOS - PRSV at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on HVOS / UNIFAC at 308.15 K

1 HVOS - PRSV at 328.15K: Solubilities of naphthalene in supercritical carbon dioxide based on HVOS / UNIFAC at 328.15 K

HVOS - PRSV at 333.55K: Solubilities of naphthalene in supercritical carbon dioxide based on HVOS / UNIFAC at 333.55 K

LCVM - PRSV at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on LCVM / UNIFAC at 308.15 K

MHV2 - PRSV at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on MHV2 / UNIFAC at 308.15 K

WS - PRSV at 308.15K for k12 and prediction at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on WS / UNIFAC and experimental data; recovery of k12 based on data at 308.15K followed by prediction of solubility at 308.15 K

HV - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 308.15K : Solubilities of naphthalene in supercritical carbon dioxide based on HV / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 308.15 K

HV - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 328.15K : Solubilities of naphthalene in supercritical carbon dioxide based on HV / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 328.15 K

2 HV - UNIQUAC at 308.15K for Paramenters Recovery and Prediction at 333.55K : Solubilities of naphthalene in supercritical carbon dioxide based on HV / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 333.55 K

HVOS - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on HVOS / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 308.15 K

LCVM - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on LCVM / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 308.15 K

MHV2 - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on MHV2 / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 308.15 K

MHV2 - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 328.15K: Solubilities of naphthalene in supercritical carbon dioxide based on MHV2 / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 328.15 K

3 MHV2 - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 333.55K: Solubilities of naphthalene in supercritical carbon dioxide based on MHV2 / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 333.55 K

WS - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on WS / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 308.15 K