<p> Mathcad Modules for Supercritical Fluid Extraction Based on Mixing Rules Appendix C-Progams</p><p>Wei-Yin Chen Jiangping Liu</p><p>Department of Chemical Engineering University of Mississippi 134 Anderson Hall University, MS 38677</p><p>Copyright©</p><p>November 13, 2007</p><p>Corresponding author. Tel. (662) 915-5651; Fax. (662) 915-7023 E-mail address: [email protected] LIST OF Mathcad Programs</p><p>Ideal gas equation: Solubilities of naphthalene in supercritical carbon dioxide based on ideal gas law at three temperatures</p><p>Second virial coefficient: Solubilities of naphthalene in supercritical carbon dioxide based on second virial coefficient at three temperatures</p><p>Cubic EOS at 308.15K for k12 and Prediction of Dissolution at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on PRSV equation of state and experimental data; recovery of k12 based on data at 308.15K followed by prediction of solubility at 308.15 K</p><p>Cubic EOS at 308.15K for k12 and Prediction of Dissolution at 328.15K: Solubilities of naphthalene in supercritical carbon dioxide based on PRSV equation of state and experimental data; recovery of k12 based on data at 308.15K followed by prediction of solubility at 328.15 K</p><p>Cubic EOS at 308.15K for k12 and Prediction of Dissolution at 333.55K: Solubilities of naphthalene in supercritical carbon dioxide based on PRSV equation of state and experimental data; recovery of k12 based on data at 308.15K followed by prediction of solubility at 333.55 K</p><p>PSRK model at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on PSRK equation of state at 308.15 K</p><p>PSRK model at 328.15K: Solubilities of naphthalene in supercritical carbon dioxide based on PSRK equation of state at 328.15 K</p><p>PSRK model at 333.55K: Solubilities of naphthalene in supercritical carbon dioxide based on PSRK equation of state at 333.55 K</p><p>HV - PRSV at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on HV / UNIFAC at 308.15 K</p><p>HV - PRSV at 328.15K: Solubilities of naphthalene in supercritical carbon dioxide based on HV / UNIFAC at 328.15 K</p><p>HV - PRSV at 333.55K: Solubilities of naphthalene in supercritical carbon dioxide based on HV / UNIFAC at 333.55 K</p><p>HVOS - PRSV at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on HVOS / UNIFAC at 308.15 K</p><p>1 HVOS - PRSV at 328.15K: Solubilities of naphthalene in supercritical carbon dioxide based on HVOS / UNIFAC at 328.15 K</p><p>HVOS - PRSV at 333.55K: Solubilities of naphthalene in supercritical carbon dioxide based on HVOS / UNIFAC at 333.55 K</p><p>LCVM - PRSV at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on LCVM / UNIFAC at 308.15 K</p><p>LCVM - PRSV at 328.15K: Solubilities of naphthalene in supercritical carbon dioxide based on LCVM / UNIFAC at 328.15 K</p><p>LCVM - PRSV at 333.55K: Solubilities of naphthalene in supercritical carbon dioxide based on LCVM / UNIFAC at 333.55 K</p><p>MHV2 - PRSV at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on MHV2 / UNIFAC at 308.15 K</p><p>MHV2 - PRSV at 328.15K: Solubilities of naphthalene in supercritical carbon dioxide based on MHV2 / UNIFAC at 328.15 K</p><p>MHV2 - PRSV at 333.55K: Solubilities of naphthalene in supercritical carbon dioxide based on MHV2 / UNIFAC at 333.55 K</p><p>WS - PRSV at 308.15K for k12 and prediction at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on WS / UNIFAC and experimental data; recovery of k12 based on data at 308.15K followed by prediction of solubility at 308.15 K</p><p>WS - PRSV at 308.15K for k12 and prediction at 328.15K: Solubilities of naphthalene in supercritical carbon dioxide based on WS / UNIFAC and experimental data; recovery of k12 based on data at 308.15K followed by prediction of solubility at 328.15 K</p><p>WS - PRSV at 308.15K for k12 and prediction at 333.55K: Solubilities of naphthalene in supercritical carbon dioxide based on WS / UNIFAC and experimental data; recovery of k12 based on data at 308.15K followed by prediction of solubility at 333.55 K</p><p>HV - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 308.15K : Solubilities of naphthalene in supercritical carbon dioxide based on HV / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 308.15 K</p><p>HV - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 328.15K : Solubilities of naphthalene in supercritical carbon dioxide based on HV / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 328.15 K</p><p>2 HV - UNIQUAC at 308.15K for Paramenters Recovery and Prediction at 333.55K : Solubilities of naphthalene in supercritical carbon dioxide based on HV / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 333.55 K</p><p>HVOS - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on HVOS / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 308.15 K</p><p>HVOS - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 328.15K: Solubilities of naphthalene in supercritical carbon dioxide based on HVOS / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 328.15 K</p><p>HVOS - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 333.55K: Solubilities of naphthalene in supercritical carbon dioxide based on HVOS / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 333.55 K</p><p>LCVM - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on LCVM / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 308.15 K</p><p>LCVM - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 328.15K: Solubilities of naphthalene in supercritical carbon dioxide based on LCVM / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 328.15 K</p><p>LCVM - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 333.55K: Solubilities of naphthalene in supercritical carbon dioxide based on LCVM / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 333.55 K</p><p>MHV2 - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on MHV2 / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 308.15 K</p><p>MHV2 - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 328.15K: Solubilities of naphthalene in supercritical carbon dioxide based on MHV2 / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 328.15 K</p><p>3 MHV2 - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 333.55K: Solubilities of naphthalene in supercritical carbon dioxide based on MHV2 / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 333.55 K</p><p>WS - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 308.15K: Solubilities of naphthalene in supercritical carbon dioxide based on WS / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 308.15 K</p><p>WS - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 328.15K: Solubilities of naphthalene in supercritical carbon dioxide based on WS / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 328.15 K</p><p>WS - UNIQUAC at 308.15K for Parameters Recovery and Prediction at 333.55K: Solubilities of naphthalene in supercritical carbon dioxide based on WS / UNIQUAC and experimental data; recovery interaction parameters based on data at 308.15K followed by prediction of solubility at 333.55 K</p><p>4</p>