Examples of Inner Transition Metals
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Lanthanides & Actinides Notes
- 1 - LANTHANIDES & ACTINIDES NOTES General Background Mnemonics Lanthanides Lanthanide Chemistry Presents No Problems Since Everyone Goes To Doctor Heyes' Excruciatingly Thorough Yearly Lectures La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Actinides Although Theorists Prefer Unusual New Proofs Able Chemists Believe Careful Experiments Find More New Laws Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr Principal Characteristics of the Rare Earth Elements 1. Occur together in nature, in minerals, e.g. monazite (a mixed rare earth phosphate). 2. Very similar chemical properties. Found combined with non-metals largely in the 3+ oxidation state, with little tendency to variable valence. 3. Small difference in solubility / complex formation etc. of M3+ are due to size effects. Traversing the series r(M3+) steadily decreases – the lanthanide contraction. Difficult to separate and differentiate, e.g. in 1911 James performed 15000 recrystallisations to get pure Tm(BrO3)3! f-Orbitals The Effective Electron Potential: • Large angular momentum for an f-orbital (l = 3). • Large centrifugal potential tends to keep the electron away from the nucleus. o Aufbau order. • Increased Z increases Coulombic attraction to a larger extent for smaller n due to a proportionately greater change in Zeff. o Reasserts Hydrogenic order. This can be viewed empirically as due to differing penetration effects. Radial Wavefunctions Pn,l2 for 4f, 5d, 6s in Ce 4f orbitals (and the atoms in general) steadily contract across the lanthanide series. Effective electron potential for the excited states of Ba {[Xe] 6s 4f} & La {[Xe] 6s 5d 4f} show a sudden change in the broadness & depth of the 4f "inner well". -
Why Do Transition Metals Have Similar Properties
Why Do Transition Metals Have Similar Properties Saturnalian Haydon never reek so round-the-clock or spruik any explanations in-flight. Cerebrovascular Elisha parries his weasands delaminating disproportionably. Dan divulgate her ohm ought, randy and grouchy. Based on the coinage metals do have low electronegativity The similar properties do transition have similar. However, the trends in these values show the usual discontinuity half way along the series. This chapter on contact, why do transition have similar properties, why does it has both of! What is the major use today cadmium also extend across the oxidizing agent in the row of exceptions to accept varying numbers exhibit so that have similar. Oh, sorry I apologize on that. The more highly charged the ion, the more electrons you have to remove and the more ionisation energy you will have to provide. Transition metals in everything from hand is more rapidly when you would you typically, why do transition have similar properties identified in ionisation energy as inner electrons can be reduced, including superconducting magnets. Here is a result, why transition metals are heated, as is still others, can ask that attack dcp molecules. Density and malleable, why do transition metals have similar properties because cobalt atom of energy for you can be determined by consuming concentrated sulfuric acid with pyrolusite. Make sure to remember your password. It has the symbol Rh. We expect to the new york: he devised the needs no difference between two electrons go now what do transition have similar properties. Also, we do not collect or ask for personally identifiable information on any of our sites. -
The Place of Zinc, Cadmium, and Mercury in the Periodic Table
Information • Textbooks • Media • Resources The Place of Zinc, Cadmium, and Mercury in the Periodic Table William B. Jensen Department of Chemistry, University of Cincinnati, Cincinnati, OH 45221-0172; [email protected] One of the few facts that I can remember from my un- a quarter of the more recent introductory inorganic texts. In dergraduate inorganic course was my instructor’s insistence all cases, the Zn group was incorrectly labeled as being a mem- that zinc, cadmium, and mercury should be classified as main- ber of the d block or transition block. Those introductory block elements rather than as transition-block or d-block el- inorganic texts that presented some sort of systematic survey ements. Though I have always assumed that the evidence for of descriptive chemistry usually contradicted this assignment this statement was unambiguous, I have also noticed the ap- in their later discussions of the chemistry of these elements. pearance over the last decade of an increasing number of gen- On the other hand, the surveys of descriptive chemistry found eral chemistry texts, inorganic texts, and advanced inorganic in most of the general chemistry texts were so superficial that monographs that either explicitly or implicitly contradict this the existence of this inconsistency seldom became explicit. assignment. The inorganic textbook by Cotton and In light of these trends, I thought it might be of interest Wilkinson, which has served as the American standard for to summarize the evidence relating to the proper placement nearly 40 years, has always been firm in its treatment of the of the Zn group within the periodic table. -
Largest Mixed Transition Metal/Actinide Cluster: a Bimetallic Mn/Th Complex with A
Inorg. Chem. 2006, 45, 2364−2366 Largest Mixed Transition Metal/Actinide Cluster: A Bimetallic Mn/Th 18+ Complex with a [Mn10Th6O22(OH)2] Core Abhudaya Mishra, Khalil A. Abboud, and George Christou* Department of Chemistry, UniVersity of Florida, GainesVille, Florida 32611-7200 Received December 6, 2005 A high-nuclearity mixed transition metal/actinide complex has been well-characterized transition metal/actinide complexes, among III - - prepared from the reaction of a Mn 4 complex with Th(NO3)4 in which are the dinuclear metal metal bonded M An orga- ) ) 6a MeCN/MeOH. The complex [Th6Mn10O22(OH)2(O2CPh)16(NO3)2- nometallic complexes (M Fe, Ru and An Th, U) and the family of linear trimetallic M IIUIV (M ) Co, Ni, Cu, (H2O)8] is the largest such complex to date and the first Th/Mn 2 6b species. It is rich in oxide groups, which stabilize all of the metals Zn) complexes containing a hexadentate Schiff base. in the high ThIV and MnIV oxidation levels. Magnetic characterization However, only one of these contains Mn, trinuclear [MnU O L (py) ](L- ) 1,7-diphenyl-1,3,5,7-heptanetetro- establishes that the complex has an S ) 3 ground-state spin value. 2 2 2 4 nato).7 Although Th is used in a wide array of products and processes, the cluster chemistry of Th is poorly developed compared to transition metals: Currently, there - 8a We have had a longstanding interest in the development are metal organic frameworks and organically templated 8b of manganese carboxylate cluster chemistry, mainly because Th complexes known, and the largest molecular Th 9 of its relevance to a variety of areas, including bioinorganic complex is Th6. -
Naming Transition Metal Compounds 2015 Filled In.Notebook January 08, 2016
Naming Transition Metal Compounds 2015 Filled In.notebook January 08, 2016 DO NOW Name the following: 1. CaBr2 2. K2CO3 Write formulas for the following: 3. Nickel (I) Oxide 4. Strontium Sulfate Jan 2312:32 PM NAMING COMPOUNDS WITH TRANSITION METALS Aim: To name compounds with multiple oxidation state metals using roman numerals. Jan 2312:44 PM 1 Naming Transition Metal Compounds 2015 Filled In.notebook January 08, 2016 Iron Oxide Iron Oxide Fe+2 O2 Fe+3 O2 Fe+3 O2 O2 FeO Fe2O3 Iron (II) Oxide Iron (III) Oxide Which formula is correct? BOTH. The name needs a roman numeral with the metal in order to determine which cation is present. Compounds containing metals with multiple oxidation states must have a roman numeral to indicate which cation is present. Jan 2312:44 PM Naming Compounds with Multiple oxidation state metals 1. List all parent ions present. AuCl3 Determine the charge and quantity Au+3 Cl of the anion FIRST. Cl Cl 2. Use the anion charges and the (+3) (3) neutrality rule to determine which metal cation is present. Au must have a +3 charge to make the 3. Name the compound and include compound neutral. a roman numeral representing the charge number of the metal Gold (III) Chloride cation. Jan 2312:44 PM 2 Naming Transition Metal Compounds 2015 Filled In.notebook January 08, 2016 List of Roman Numerals 1 – I 2 – II 3 – III 4 – IV 5 – V 6 – VI 7 – VII Jan 2312:44 PM Naming Compounds with Multiple oxidation state metals 1. -
L. Arulmurugan, M. Ilangkumaran " Experimental Study on Graphene/Transition Metal Chalcogenide Based Energy Storage and Conversion
Journal of Ovonic Research Vol. 16, No. 4, July - August 2020, p. 197 - 211 EXPERIMENTAL STUDY ON GRAPHENE/TRANSITION METAL CHALCOGENIDE BASED ENERGY STORAGE AND CONVERSION L. ARULMURUGANa, *, M. ILANGKUMARANb, aDepartment of Electronics and Communication Engineering, Bannari Amman Institute of Technology, Sathyamangalam, Erode, Tamilnadu, India bDepartment of Mechatronics Engineering, K S Rangasamy College of Technology, Tiruchengode, Tamilnadu, India The ever-increasing energy demand and the shortage of fossil fuels force the researchers to do research on utilization and conversion of renewable energy sources. In Recent years, the graphene and Transition Metal Chalcogenide (TMC) based Phase Change material (PCM) have been reviewed towards the future energy storage and energy conversion. This PCM is considered as a promising pathway to alleviate the energy crisis. The TMC material is considered as an emerging material due to their optoelectronic behavior and stability of the material. Moreover, the integration of TMC with graphene, significantly improve the performance of the system. The storage of solar energy in the form of sensible and latent heat has become an important aspect of energy management. To improve the performance of domestic solar water heater system, the vertical spiral and cylindrical heat exchanger is designed. The spiral module and cylindrical modules filled with and without PCM are analyzed and the obtained results are compared with each other. The results show that the spiral and cylindrical heat exchanger filled with PCM store and release the thermal energy efficiently and it performs the desired functions than the without PCM module. (Received April 28, 2020; Accepted July 14, 2020) Keywords: Graphene/transition metal chalcogenide, Phase change material, Thermal management, Heat exchanger, Spiral and cylindrical module 1. -
Aluminum-Vanadium System Donald Joseph Kenney Iowa State College
Iowa State University Capstones, Theses and Retrospective Theses and Dissertations Dissertations 1953 Aluminum-vanadium system Donald Joseph Kenney Iowa State College Follow this and additional works at: https://lib.dr.iastate.edu/rtd Part of the Physical Chemistry Commons Recommended Citation Kenney, Donald Joseph, "Aluminum-vanadium system " (1953). Retrospective Theses and Dissertations. 13302. https://lib.dr.iastate.edu/rtd/13302 This Dissertation is brought to you for free and open access by the Iowa State University Capstones, Theses and Dissertations at Iowa State University Digital Repository. It has been accepted for inclusion in Retrospective Theses and Dissertations by an authorized administrator of Iowa State University Digital Repository. For more information, please contact [email protected]. NOTE TO USERS This reproduction is the best copy available. UMI mmMm-immim STSTEM BmaM S, Ktrmey A Mssertattioa aibaitted to the Sradttate Paeulty in fsKptial Fulfillffleat of the l®cpiir«a®ats tor the Degree of eocfoa or piiLosoFif Sabjecti aysiefil CheBdstry ^proved f Signature was redacted for privacy. In C2iarg®;!6f Ifejor Work Signature was redacted for privacy. Signature was redacted for privacy. Iowa State College 1953 UMI Number: DP12420 INFORMATION TO USERS The quality of this reproduction is dependent upon the quality of the copy submitted. Broken or indistinct print, colored or poor quality illustrations and photographs, print bleed-through, substandard margins, and improper alignment can adversely affect reproduction. In the unlikely event that the author did not send a complete manuscript and there are missing pages, these will be noted. Also, if unauthorized copyright material had to be removed, a note will indicate the deletion. -
Periodic Table 1 Periodic Table
Periodic table 1 Periodic table This article is about the table used in chemistry. For other uses, see Periodic table (disambiguation). The periodic table is a tabular arrangement of the chemical elements, organized on the basis of their atomic numbers (numbers of protons in the nucleus), electron configurations , and recurring chemical properties. Elements are presented in order of increasing atomic number, which is typically listed with the chemical symbol in each box. The standard form of the table consists of a grid of elements laid out in 18 columns and 7 Standard 18-column form of the periodic table. For the color legend, see section Layout, rows, with a double row of elements under the larger table. below that. The table can also be deconstructed into four rectangular blocks: the s-block to the left, the p-block to the right, the d-block in the middle, and the f-block below that. The rows of the table are called periods; the columns are called groups, with some of these having names such as halogens or noble gases. Since, by definition, a periodic table incorporates recurring trends, any such table can be used to derive relationships between the properties of the elements and predict the properties of new, yet to be discovered or synthesized, elements. As a result, a periodic table—whether in the standard form or some other variant—provides a useful framework for analyzing chemical behavior, and such tables are widely used in chemistry and other sciences. Although precursors exist, Dmitri Mendeleev is generally credited with the publication, in 1869, of the first widely recognized periodic table. -
Recent Advances in Transition Metal Sensitizers for Lanthanide NIR Emission
Recent Advances in Transition Metal Sensitizers for Lanthanide NIR Emission Brian Bellott Literature Seminar October 11, 2005 Materials that emit in the near infrared (NIR) are useful in biological applications because tissue is relatively transparent to NIR radiation but relatively opaque in the ultraviolet or visible range. NIR devices could be used to perform deep tissue studies in real time, thus avoiding the delays associated with ex situ analyses.1 Lanthanides have unusually sharp NIR absorption and emission spectra due to the small radial extension of the f-orbitals relative to the filled 5s and 5p orbitals.2 The narrow spectroscopic features enable lanthanides to be used in a variety of applications, such as lasers, flat panel displays, contrast agents, and numerous biological applications.3-11 Due to the Laporte forbidden nature of the f-f transitions, the lanthanides have very small molar absorptivities. As a result, direct photogeneration of the lanthanide emissive states is very inefficient. The use of sensitizers can compensate for the symmetry-forbidden nature of the f-f transitions. Sensitizers act by absorbing light energy to generate a sensitizer-localized excited state; subsequent energy transfer from the sensitizer to the lanthanide generates the emissive lanthanide excited state. The use of sensitizers results in higher quantum yields for the lanthanide emission: effective sensitizers have larger molar absorptivities than the lanthanide elements and serve as antenna chromophores. The antenna effect is demonstrated in Figure 1.11 Ligand Energy Transfer (Ln3+)* hn Emission Antenna (Ln3+) Lanthanide Figure 1: The antenna effect (Adapted from ref 11). Organic based sensitizers have been studied since the early 1990s.12 Recently, researchers have been interested in synthesizing lanthanide compounds connected to transition metal sensitizers.13 Transition metals have many properties that make them good sensitizers. -
Toxicological Profile for Vanadium
VANADIUM 107 4. CHEMICAL AND PHYSICAL INFORMATION 4.1 CHEMICAL IDENTITY Vanadium is a naturally occurring element that appears in group 5(B5) of the periodic table (Lide 2008). Vanadium is widely distributed in the earth’s crust at an average concentration of 100 ppm nd (approximately 100 mg/kg), similar to that of zinc and nickel (Byerrum 1991). Vanadium is the 22 most abundant element in the earth’s crust (Baroch 2006). Vanadium is found in about 65 different minerals; carnotite, roscoelite, vanadinite, and patronite are important sources of this metal along with bravoite and davidite (Baroch 2006, Lide 2008). It is also found in phosphate rock and certain ores and is present in some crude oils as organic complexes (Lide 2008). Table 4-1 lists common synonyms and other pertinent identification information for vanadium and representative vanadium compounds. 4.2 PHYSICAL AND CHEMICAL PROPERTIES Vanadium is a gray metal with a body-centered cubic crystal system. It is a member of the first transition series. Because of its high melting point, it is referred to as a refractory metal (Baroch 2006). When highly pure, it is a bright white metal that is soft and ductile. It has good structural strength and a low- fission neutron cross section. Vanadium has good corrosion resistance to alkalis, sulfuric and hydrochloric acid, and salt water; however, the metal oxidizes readily above 660 °C (Lide 2008). The chemistry of vanadium compounds is related to the oxidation state of the vanadium (Woolery 2005). Vanadium has oxidation states of +2, +3, +4, and +5. When heated in air at different temperatures, it oxidizes to a brownish black trioxide, a blue black tetraoxide, or a reddish orange pentoxide. -
AP TOPIC 10: Transition Metal Basics
© Adrian Dingle’s Chemistry Pages 2004, 2005, 2006, 2007, 2008, 2009, 2010, 2011, 2012. All rights reserved. These materials may NOT be copied or redistributed in any way, except for individual class instruction. Revised August 2011 AP TOPIC 10: Transition Metal Basics • Introduction TOPIC 10 of the AP course is really what I like to describe as a “bonus topic”. Many AP courses will not touch upon transition metal chemistry at all, and it is certainly possible to do extremely well on the AP exam without devoting any time to it. So why bother? Well, there are two reasons. 1. Some information on this topic may well help in the other, more important areas (for example, TOPIC 10 is related to REDOX chemistry). A little extra knowledge cannot hurt, and this constitutes some solid chemistry that can be viewed as reading around the subject, increasing chemical general knowledge and broadening chemical horizons. 2. Study of this topic may help in the equation writing section of the exam. Several equations involving this topic have been examined in the past and students often ignored them (before 2007 you could choose to ignore them since you only had to choose five equations from a total of eight but since 2007 there is no longer any choice in which equations to write). Below is a survey of the appearance of transition metal chemistry in the equation writing section of the exam since 1981. 2+ 2010B b (XS conc. NH3 + Ni ) 2008 a (XS conc. OH- + Al3+) 2006B d (conc. HCl + Ni2+) 2006 b (conc. -
Effect of the Vanadium Addition on the Grain Size and Mechanical Properties of the Copper-Aluminium-Zinc Shape Memory Alloys K
EFFECT OF THE VANADIUM ADDITION ON THE GRAIN SIZE AND MECHANICAL PROPERTIES OF THE COPPER-ALUMINIUM-ZINC SHAPE MEMORY ALLOYS K. Enami, N. Takimoto, S. Nenno To cite this version: K. Enami, N. Takimoto, S. Nenno. EFFECT OF THE VANADIUM ADDITION ON THE GRAIN SIZE AND MECHANICAL PROPERTIES OF THE COPPER-ALUMINIUM-ZINC SHAPE MEMORY ALLOYS. Journal de Physique Colloques, 1982, 43 (C4), pp.C4-773-C4-778. 10.1051/jphyscol:19824126. jpa-00222109 HAL Id: jpa-00222109 https://hal.archives-ouvertes.fr/jpa-00222109 Submitted on 1 Jan 1982 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. JOURNAL DE PHYSIQUE Colloque C4, suppl&nent au no 12, Tome 43, dbcembre 1982 page C4-773 EFFECT OF THE VANADIUM ADDITION ON THE GRAIN SIZE AND MECHANICAL PROPERTIES OF THE COPPER-ALUMINIUM-ZINC SHAPE MEMORY ALLOYS K. Enami, N. Takimoto and S. Nenno Department of Materials Science and Engineering, Osaka University, Suita, Osaka, Japan (Revised text accepted 27 September 1982) Abstract. - The effects of vanadium addition on the 0-grain size, pseudo- elastic and shape memory behaviour and fracture mode of the copper-aluminium- zinc shape memory alloys with different vanadium contents were investigated.