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International Workshop on Sensors and Molecular Recognition, 2016

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International Workshop on Sensors and Molecular Recognition, 2016 XIV International Workshop on Sensors and Molecular Recognition th July, 8 and 9 2021 BOOK OF ABSTRACTS ORGANIZING COMMITTEE CHAIR: Pablo Gaviña Costero Salvador Gil Grau Silvia Rodriguez Nuévalos María Manconi Daniel Ferri Angulo Carmen Ferriol Eva Mª Brun Sánchez SCIENTIFIC COMITTEE Ana Mª Costero Ramón Martínez-Mañez Angel Maquieira Catalá Miguel Alcañiz Fillol Rurack Knut Gustavo Fernandez Carla Caddeo Matilde Merino Sanjuan INDEX Page Scientific Program 7 Full Lectures 11 Oral Communications 21 Poster Communications 47 List of participants 147 SCIENTIFIC PROGRAM Thursday, July 8, 2021 MORNING SESSION 9.00 – 9.15h Opening ceremony Chaired by Vicerrector de Investigación de la Universitat de Valencia, Carlos Hermenegildo Caudevilla 9.15 – 10.15h Full Lecture Interfacing Self-Assembly and External Stimuli: from responsive to adaptive behaviour Gustavo Fernández 10.15 – 11.00h First Session of Oral Communications: Chairman: Ana María Costero Nieto O-01 Gold nanoclusters for ratiometric sensing of pH in extremely acidic media Irene Pérez-Herráez, Adele Bonanno, Elena Zaballos-García, Julia Pérez- Prieto O-02 Non-invasive and renal clearable cy7gal probe for the fluorescence senescence detection by direct urine measurement Juan F. Blandez, Beatriz Lozano-Torres, Alba García-Fernández, Félix Sancenón and Ramón Martínez-Máñez O-03 Host-guest chemistry of fullerene derivatives with polyamide macrocycle-based metal-organic frameworks Adrian Saura-Sanmartin, Alberto Martinez-Cuezva, Marta Marin-Luna, Jose Berna 11.00 – 11.30h Coffee break 11.30 – 12.30h Second Session of Oral Communications: Chairman: Salvador Gil Grau O-04 Molecular encapsulagion using molecular cages Vicente Martí-Centelles, Giovanni Montà González, Félix Sancenón, Ramón Martínez-Máñez O-05 An off-on fluorescent probe for the sensitive detection of Alanine Aminopeptidase (APN) in real urine samples Marcia Domínguez, Juan F. Blandeza, Félix Sancenóna, Ramón Martínez-Máñez O-06 Bodipy's derivatives for cathinone detection Jordi H. Contreras, P. Rodrigo Martínez, Ana M. Costero, Salvador Gil O-07 Chromogenic chemodosimeter based on capped silica particles to detect spermine and spermidine Mariana Barros, Alejandro López-Carrasco, Pedro Amorós, Salvador Gil, Pablo Gaviña, Margarita Parra, Jamal El Haskouri, M. Carmen Terencio, Ana M. Costero 12.30 – 13.30h Full Lecture Consequences of the mechanical bond of amide-based rotaxanes in organocatalysis José Berná 13.30 – 15.30h Lunch AFTERNOON SESSION 15.30 – 17.15h Third Session of Oral Communications Chairman: Miguel Alcañiz Fillol O-08 Sensor for food analysis applying impedance spectroscopy and artificial neural networks Josef Peter Gessler, Laura Contat Rodrigo, Nicolás Laguarda Miró, Miguel Alcañiz Fillol y Rafael Masot Peris O-09 The development of photothermal therapy devices in the idm José Manuel Terrés-Haro, Javier Ibañez, Rafael Masot-Peris, Eduardo García-Breijo O-10 System for monitoring deformation in reinforced concrete structures with wireless connection Luis Chapa Chordá, Vicente Beltrán Morte, Cristina Bastida Molina, Roberto Vengut Tro, José Manuel Gandía Romero, Miguel Alcañiz Fillol O-11 Development and perspectives of optochemogenetic devices at idm Javier Monreal-Trigo, José Manuel Terrés-Haro, Esther Giraldo, Victoria Moreno-Manzano O-12 Low cost measurement system for biosensors based on organic electrochemical transistors (oefts) and field effect transistors (fets) Vicente Beltrán Morte, Javier Monreal Trigo, Jakob Sabbe, Flor Boydens, Miguel Alcañiz Fillol, Liv K. Heidenreich O-13 Wirelessly powered reinforced concrete corrosion monitoring system based on potential step voltammetry Cristina Bastida-Molina, Roberto Vengut-Tro, Vicente Beltrán Morte, Josep Ramon Lliso-Ferrando, Ana Martínez-Ibernón, Ignasi Cairó O-14 Wirelessly powered reinforced concrete chloride penetration measurement system based on cyclic voltammetry Roberto Vengut-Tro, Cristina Bastida-Molina, Vicente Beltrán-Morte, Ana Martínez-Ibernón, Josep Ramon Lliso-Ferrando, Román Bataller- Prats 17.15 – 18.30h Poster Session: Everyone who presents a poster must be available by email for any consultation. Friday, July 9, 2021 MORNING SESSION 9.00 – 10.00h Full Lecture Stimuli-Responsive Porphyrin Receptors for Controlled Molecular Recognition Valerié Heitz 10.00 – 11.00h Fourth Session of Oral Communications: Chairman: Pablo Gaviña Costero O-15 Asymptotic modeling of signaling in biomedical analysis Antonio Doménech-Carbó, José Luís Pontones, Clara Doménech- Casasús, David Ramos O-16 New interferometric in-vitro food allergy diagnostic system based on molecular allergens and nanoparticles Rocio L. Espinosa, María Garrido-Arandia, Alejandro Romero-Sahagun, Pedro Herreros, Luca Tramarin, Mª Fe Laguna, Araceli Díaz-Perales , Miguel Holgado O-17 Towards a competitive immunoassay with gold nanoparticles for mmp9 inflamatory biomarker detection in tear sample Beatriz Santamaría, Yolanda Ramírez, Ana María M. Murillo, Luis Vallez, Miguel Holgado O-18 Nanosystem based on mesoporous silica nanoparticles for dual delivery of doxorubicin and mir-99a-5p to treat breast cáncer Iris Garrido-Cano, Anna Adam-Artigues, Ana Catarina Trigo Lameirinhas, Juan F. Blandez, Ana Llucha, Juan Miguel Cejalvo, Pilar Eroles, Ramón Martínez-Máñez 11.00 – 11.30h Coffee break 11.30 – 12.30h Fifth Session of Oral Communications: Chairman: Angel Maquieira Catalá O-19 Exploring the synergy of paper-based electrophoresis and lateral flow assay: towards improved point-of-care biosensing Amadeo Sena-Torralba, Sergi Morais and Ángel Maquieira O-20 Gratings of responsive hydrogels for label free-biosensing María Isabel Lucío, Andy Hernández Montoto, Estrella Fernández, Kheloud Berramdane, Manuel G. Ramírez, Inmaculada Pascual, María- José Bañuls, Ángel Maquieira O-21 Bio bragg gratings: diffractive molecular networks for on-fiber label-free biosensing Augusto Juste-Dolz, Martina Delgado-Pinar, Miquel Avella-Oliver, Estrella Fernández, Daniel Pastor, Miguel V. Andrés, Ángel Maquieira O-22 Nanoscale pillar arrays for vapor detection Sergio Quintero, Rafel Casquel, Maria Fe Laguna, Miguel Holgado 12.30 – 13.30h Full Lecture Tailoring bodipys for (bio)photonic applications Beatriz Lora Maroto 13.30 – 13.45h Closing ceremony POSTER SESSION The posters will be on the website: http://www.iwosmor.com/ from July 5th BOOK OF ARTICLES The deadline for submitting the articles of the communications for the edition of the book will end on September 17, all those that are not received on date we will assume that they are not interested. The format should be like the abstracts but with an extension of 4 or 5 sheets. FULL LECTURES Interfacing Self-Assembly and External Stimuli: from responsive to adaptive behaviour Gustavo Fernández Organisch-Chemisches Institut, Universität Münster, Corrensstraße 36, 48151 Münster, Germany. E-mail: [email protected] Understanding the relationship between external stimuli and self-assembly is key to achieve adaptive behaviour, one of the core elements of intelligent matter.1 However, given that the energy landscape of supramolecular assemblies is extremely sensitive to minor changes in the environment,2 controlling and predicting the influence of external stimuli on self-assembly phenomena remains a major challenge. In this presentation, different strategies to control the self-assembly behaviour of stimuli-responsive - conjugated systems will be discussed. For instance, the hierarchical self-assembly of pyridine-based ligand L1 as well as its responsiveness towards light, trifluoacetic acid II II (TFA) addition (L1:TFA) and complexation of metal ions (Pd and Pt ) will be discussed. Target ligand L1 undergoes complex time-, temperature- and concentration- dependent self-assembly pathways driven by H-bonding leading to fiber-like associates.3 Irradiation with UV light (365 nm) leads to a reversible transition from long to short fibers. On other hand, addition of TFA causes the transformation of the anti- parallel H-bonded fibrillar assembly of L1 in MCH into superhelical fibers stabilized by H-bonding of parallel-stacks of L1:TFA.4 Light irradiation causes a strain-driven disassembly and subsequent aggregate reconstruction that ultimately leads to short II II fibers. In contrast, complexation of Pd and Pt ions (complexes C1 and C3) leads to a slight attenuation of the supramolecular growth into short thin fibers.5 Ultimately, the rational choice of “good” vs. “poor” solvents allows precise control over the photochemical behaviour of light-responsive systems (E/Z isomerization vs. [2 + 2] photocycloaddition).6 Detailed mechanistic insights into the self-assembly and photo responsive behavior of all species have been provided using a combination of spectroscopic and microscopic techniques. Scheme 1. Summary of stimuli-responsive systems described in this presentation 1 Zeng, H.; Wasylczyk, P.; Wiersma, D. S.; Priimagi, A. Adv. Mater., 2018, 30, e1703554. 2 Matern, J.; Dorca, Y.; Sanchez, L; Fernández, G. Angew. Chem. Int. Ed. 2019, 58, 16730. 3 Kartha, K. K.; Allampally, N. K.; Politi, A. T.; Prabhu, D. D.; Ouchi, H.; Albuquerque, R. Q.; Yagai, S.; Fernández, G. Chem. Sci. 2019, 10, 752. 4 Kartha, K. K.; Allampally, N. K.; Yagai, S.; Albuquerque, R. Q.; Fernández, G., Chem. Eur. J. 2019, 25, 9230. 5 Bäumer, N.; Kartha, K. K.; Allampally, N. K.; Yagai, S.; Albuquerque, R. Q.; Fernández, G. Angew. Chem. Int. Ed. 2019, 58, 15626. 6 Dünnebacke, T.; Kartha, K. K.; Wiest, J. M.; Albuquerque, R. Q.; Fernández, G. Chem. Sci. 2020, 11, 10405. CONSEQUENCES
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