WEED CONTROL in TURF Reviewed by KR Green, Department Of
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2,4-Dichlorophenoxyacetic Acid
2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators. -
U.S. EPA, Pesticide Product Label, DICAMBAZINE, 09/25/2003
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON. D.C. 20460 OFFICE OF PREVENTION, PESTICIDES AND TOXIC SUBSTANCES SEP 2 5 2003 Albaugh, Inc. clo Pyxis Regulatory Consulting, Inc. ATTN: Michael Kellogg 11324 1']'1' Ave. Ct. NW Gig Harbor, W A 98332 Dear Mr. Kellogg: Subject: Fast Track Amendment for Atrazine Product Product: Dicambaiine EPA Registration Number: 42750-41 Submission Date: 04/24/03 The labeling referred to above, submitted in connection with registration under the Federal Insecticide, Fungicide and Rodenticide Act, as amended is acceptable, provided you make the followmg changes before you release the product for shipment. 1. Change the PPE section to the following: • "Some materials that are chemical-resistant to this product are barrier laminate> 14 mils, neoprene rubber> 14 mils, polyvinyl chloride (PVC) > 14 mils, butyl rubber> 14 mils, orviton >14 mils. Ifyou want more options, follow the instructions for category A on an EPA chemical-resistance category selection chart. " • "Mixers, loaders, applicators and other handlers not using Engineering Controls must wear: Coveralls over long sleeved ~hirt and long pants Chemical resistant gloves Chemical resistant footwear plus socks Chemical resistant headgear (if overhead exposure) A NlOSH approved dust mist filtering respirator with any N, R, P or HE filter A chemical resistant apron (if exposed to undiluted product)" • "Mixers, loaders, applicators and other handlers using Engineering Controls must wear: Long-sleeved shirt and long pants Chemical resistant gloves and apron for mixers and loaders Shoes plus socks See Engineering Controls for additional requirements" Note to registrant: You must drop the N type filter from the respirator statement if the product contains or is used with oil. -
Exposure to Herbicides in House Dust and Risk of Childhood Acute Lymphoblastic Leukemia
Journal of Exposure Science and Environmental Epidemiology (2013) 23, 363–370 & 2013 Nature America, Inc. All rights reserved 1559-0631/13 www.nature.com/jes ORIGINAL ARTICLE Exposure to herbicides in house dust and risk of childhood acute lymphoblastic leukemia Catherine Metayer1, Joanne S. Colt2, Patricia A. Buffler1, Helen D. Reed3, Steve Selvin1, Vonda Crouse4 and Mary H. Ward2 We examine the association between exposure to herbicides and childhood acute lymphoblastic leukemia (ALL). Dust samples were collected from homes of 269 ALL cases and 333 healthy controls (o8 years of age at diagnosis/reference date and residing in same home since diagnosis/reference date) in California, using a high-volume surface sampler or household vacuum bags. Amounts of agricultural or professional herbicides (alachlor, metolachlor, bromoxynil, bromoxynil octanoate, pebulate, butylate, prometryn, simazine, ethalfluralin, and pendimethalin) and residential herbicides (cyanazine, trifluralin, 2-methyl-4- chlorophenoxyacetic acid (MCPA), mecoprop, 2,4-dichlorophenoxyacetic acid (2,4-D), chlorthal, and dicamba) were measured. Odds ratios (OR) and 95% confidence intervals (CI) were estimated by logistic regression. Models included the herbicide of interest, age, sex, race/ethnicity, household income, year and season of dust sampling, neighborhood type, and residence type. The risk of childhood ALL was associated with dust levels of chlorthal; compared to homes with no detections, ORs for the first, second, and third tertiles were 1.49 (95% CI: 0.82–2.72), 1.49 (95% CI: 0.83–2.67), and 1.57 (95% CI: 0.90–2.73), respectively (P-value for linear trend ¼ 0.05). The magnitude of this association appeared to be higher in the presence of alachlor. -
INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES
US Environmental Protection Agency Office of Pesticide Programs INDEX to PESTICIDE TYPES and FAMILIES and PART 180 TOLERANCE INFORMATION of PESTICIDE CHEMICALS in FOOD and FEED COMMODITIES Note: Pesticide tolerance information is updated in the Code of Federal Regulations on a weekly basis. EPA plans to update these indexes biannually. These indexes are current as of the date indicated in the pdf file. For the latest information on pesticide tolerances, please check the electronic Code of Federal Regulations (eCFR) at http://www.access.gpo.gov/nara/cfr/waisidx_07/40cfrv23_07.html 1 40 CFR Type Family Common name CAS Number PC code 180.163 Acaricide bridged diphenyl Dicofol (1,1-Bis(chlorophenyl)-2,2,2-trichloroethanol) 115-32-2 10501 180.198 Acaricide phosphonate Trichlorfon 52-68-6 57901 180.259 Acaricide sulfite ester Propargite 2312-35-8 97601 180.446 Acaricide tetrazine Clofentezine 74115-24-5 125501 180.448 Acaricide thiazolidine Hexythiazox 78587-05-0 128849 180.517 Acaricide phenylpyrazole Fipronil 120068-37-3 129121 180.566 Acaricide pyrazole Fenpyroximate 134098-61-6 129131 180.572 Acaricide carbazate Bifenazate 149877-41-8 586 180.593 Acaricide unclassified Etoxazole 153233-91-1 107091 180.599 Acaricide unclassified Acequinocyl 57960-19-7 6329 180.341 Acaricide, fungicide dinitrophenol Dinocap (2, 4-Dinitro-6-octylphenyl crotonate and 2,6-dinitro-4- 39300-45-3 36001 octylphenyl crotonate} 180.111 Acaricide, insecticide organophosphorus Malathion 121-75-5 57701 180.182 Acaricide, insecticide cyclodiene Endosulfan 115-29-7 79401 -
Sorption of Atrazine, Alachlor and Trifluralin from Water Onto Different Geosorbents
RSC Advances Sorption of atrazine, alachlor and trifluralin from water onto different geosorbents Journal: RSC Advances Manuscript ID: RA-ART-04-2014-003886.R1 Article Type: Paper Date Submitted by the Author: 04-Dec-2014 Complete List of Authors: Leovac, Anita; University of Novi Sad Faculty of Sciences, Department for Chemistry, Biochemistry and Environmental Protection Vasyukova, Ekaterina; Technische Universität Dresden, Faculty of Environmental Sciences, Institute of Urban Water Management Ivančev-Tumbas, Ivana; University of Novi Sad Faculty of Sciences, Department for Chemistry, Biochemistry and Environmental Protection Uhl, Wolfgang; Technische Universität Dresden, Faculty of Environmental Sciences, Institute of Urban Water Management Kragulj, Marijana; University of Novi Sad Faculty of Sciences, Department for Chemistry, Biochemistry and Environmental Protection Trickovic, Jelena; University of Novi Sad Faculty of Sciences, Department for Chemistry, Biochemistry and Environmental Protection Kerkez, Đurña; University of Novi Sad Faculty of Sciences, Department for Chemistry, Biochemistry and Environmental Protection Dalmacija, Bozo; University of Novi Sad Faculty of Sciences, Department for Chemistry, Biochemistry and Environmental Protection Page 1 of 21 RSC Advances 1 Sorption of atrazine, alachlor and trifluralin from water onto different geosorbents 2 Anita S. Leovac 1, Ekaterina Vasyukova 2, Ivana I. Ivan čev-Tumbas 1, Wolfgang Uhl 2, 3 Marijana M. Kragulj 1, Jelena S. Tri čkovi ć1, Đur đa V. Kerkez 1, Božo D. Dalmacija 1 -
Trifluralin Human Health and Ecological Risk Assessment FINAL REPORT
SERA TR-052-26-03a Trifluralin Human Health and Ecological Risk Assessment FINAL REPORT Submitted to: Paul Mistretta, COR USDA/Forest Service, Southern Region 1720 Peachtree RD, NW Atlanta, Georgia 30309 USDA Forest Service Contract: AG-3187-C-06-0010 USDA Forest Order Number: AG-43ZP-D-10-0010 SERA Internal Task No. 52-26 Submitted by: Patrick R. Durkin Syracuse Environmental Research Associates, Inc. 8125 Solomon Seal Manlius, New York 13104 E-Mail: [email protected] Home Page: www.sera-inc.com September 20, 2011 Table of Contents LIST OF FIGURES ...................................................................................................................... vii LIST OF TABLES ........................................................................................................................ vii LIST OF APPENDICES .............................................................................................................. viii LIST OF ATTACHEMENTS ...................................................................................................... viii ACRONYMS, ABBREVIATIONS, AND SYMBOLS ................................................................ ix COMMON UNIT CONVERSIONS AND ABBREVIATIONS .................................................. xii CONVERSION OF SCIENTIFIC NOTATION ......................................................................... xiii EXECUTIVE SUMMARY ......................................................................................................... xiv 1. INTRODUCTION ..................................................................................................................... -
Corn Herbicides to Control Glyphsoate-Resistant Canola Volunteers
AGRONOMY SCIENCES RESEARCHRESEARCH UPDAUPDATETE Corn Herbicides to Control Glyphosate-Resistant Canola Volunteers 2013 Background Table 1. Herbicide treatments. • With the rapid adoption of glyphosate-resistant corn in Western Treatment Application Rate/Acre Canada, glyphosate-resistant canola volunteers have become a major weed concern to corn producers in the region. 1 Gly Only (Check) 1 L/acre (360g ae) • The Pest Management Regulatory Agency now allows 2 Gly + Dicamba 1 L/acre + 0.243 L/acre herbicides to be tank-mixed if they have individual registrations 3 Gly + 2,4-D 1 L/acre + 0.4 L/acre (600g/L) on the crop and have a common application timing. 4 Gly + MCPA Amine 1 L/acre + 0.45L/acre • Several herbicide options are available to control glyphosate 5 Gly + Bromoxynil 1 L/acre + 0.48 L/acre tolerant canola volunteers in corn; however, some herbicides may have undesirable effects on corn. Gly / Bromoxynil 6 1 L/acre + 0.48 L/acre (Split Application*) Objectives * Glyphosate and bromoxynil applied separately at V3 stage. • Assess crop injury and yield effects of various herbicides tank- mixed with glyphosate to control glyphosate-resistant canola • Herbicide injury scores were recorded at: volunteers in glyphosate-resistant corn. • 3-5 days after treatment • 7-10 days after treatment • Identify the most suitable post-emergence strategy for • 21-24 days after treatment managing glyphosate-resistant canola volunteers in glyphosate-resistant corn. • Other recorded observations include: • Brittle snap counts Study Description • Yield (bu/acre) & moisture (%) • Test weight (lbs/bu) • The study compared the crop response of four industry leading hybrids (Pioneer® brand and competitive) with five different Results herbicide treatments (Table 1). -
AP-42, CH 9.2.2: Pesticide Application
9.2.2PesticideApplication 9.2.2.1General1-2 Pesticidesaresubstancesormixturesusedtocontrolplantandanimallifeforthepurposesof increasingandimprovingagriculturalproduction,protectingpublichealthfrompest-bornediseaseand discomfort,reducingpropertydamagecausedbypests,andimprovingtheaestheticqualityofoutdoor orindoorsurroundings.Pesticidesareusedwidelyinagriculture,byhomeowners,byindustry,andby governmentagencies.Thelargestusageofchemicalswithpesticidalactivity,byweightof"active ingredient"(AI),isinagriculture.Agriculturalpesticidesareusedforcost-effectivecontrolofweeds, insects,mites,fungi,nematodes,andotherthreatstotheyield,quality,orsafetyoffood.Theannual U.S.usageofpesticideAIs(i.e.,insecticides,herbicides,andfungicides)isover800millionpounds. AiremissionsfrompesticideusearisebecauseofthevolatilenatureofmanyAIs,solvents, andotheradditivesusedinformulations,andofthedustynatureofsomeformulations.Mostmodern pesticidesareorganiccompounds.EmissionscanresultdirectlyduringapplicationorastheAIor solventvolatilizesovertimefromsoilandvegetation.Thisdiscussionwillfocusonemissionfactors forvolatilization.Thereareinsufficientdataavailableonparticulateemissionstopermitemission factordevelopment. 9.2.2.2ProcessDescription3-6 ApplicationMethods- Pesticideapplicationmethodsvaryaccordingtothetargetpestandtothecroporothervalue tobeprotected.Insomecases,thepesticideisapplieddirectlytothepest,andinotherstothehost plant.Instillothers,itisusedonthesoilorinanenclosedairspace.Pesticidemanufacturershave developedvariousformulationsofAIstomeetboththepestcontrolneedsandthepreferred -
List of Herbicide Groups
List of herbicides Group Scientific name Trade name clodinafop (Topik®), cyhalofop (Barnstorm®), diclofop (Cheetah® Gold*, Decision®*, Hoegrass®), fenoxaprop (Cheetah® Gold* , Wildcat®), A Aryloxyphenoxypropionates fluazifop (Fusilade®, Fusion®*), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) butroxydim (Falcon®, Fusion®*), clethodim (Select®), profoxydim A Cyclohexanediones (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) A Phenylpyrazoles pinoxaden (Axial®) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, B Sulfonylureas Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron, (Logran®, Logran® B Power®*), tribenuron (Express®), trifloxysulfuron (Envoke®, Krismat®*) florasulam (Paradigm®*, Vortex®*, X-Pand®*), flumetsulam B Triazolopyrimidines (Broadstrike®), metosulam (Eclipse®), pyroxsulam (Crusader®Rexade®*) imazamox (Intervix®*, Raptor®,), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, B Imidazolinones Lightning®*, Midas®*, OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) B Pyrimidinylthiobenzoates bispyribac (Nominee®), pyrithiobac (Staple®) C Amides: propanil (Stam®) C Benzothiadiazinones: bentazone (Basagran®, -
Chemical Brush Control: Assessing the Hazard
Reprinted from the JOURNAL OF FORESTRY, Vol. 69, No. 10, October 1971 Reproduced by USDA Forest Service for official use. PLEASE DO NOT REMOVE FROM FILES CHEMICAL BRUSH CONTROL: ASSESSING THE HAZARD hazard from the use of any chemical requires consider- ABSTRACT—An adequate evaluation of the hazard asso- ation of both the likelihood of exposure and the toxicity ciated with the use of any chemical agent requires consid- of the chemical (15). eration of both the toxicity of the material and the poten- tial for exposure of nontarget organisms. The hazard can be high only if both the toxicity of the chemical and the Likelihood of Exposure to Herbicides potential for exposure to a significant dose are high. The The likelihood that a nontarget organism will be relatively large doses of 2,4-D, amitrole, 2,4,5-T, and exposed to a significant dose is determined by the picloram required to produce acutely toxic responses in behavior of the chemical. Behavior is the initial dis- most nontarget organisms are not likely to occur from nor- tribution, subsequent movement, persistence, and fate mal chemical brush control operations on forest lands. The short persistence, lack of biomagnification in food chains, of chemicals in the environment. Chemical behavior and the rapid excretion of these herbicides by animals dictates the magnitude and duration of exposure and preclude chronic exposure and, therefore, chronic toxicity. thus the nature of a toxic response. A long history of field use and research shows our com- Herbicides applied aerially are distributed initially mon brush control chemicals can be used with minimum among four components of the forest environment—air, hazard to the quality of our environment. -
Chem Service Pesticide Catalogue 2019 Update GH.Pdf
Pesticide and Metabolite Standards Catalog Table of Contents GENERAL INFORMATION ........................................................................................................ 2 Ordering Information Fax Order Form Making Dilutions Miscibility Table How To Read a Chem Service Label PESTICIDE AND METABOLITE STANDARDS - ALPHABETICAL LISTING .......................7 PESTICIDE STANDARDS LISTING BY CAS NUMBER WITH STRUCTURES .....................28 METABOLITE STANDARDS LISTING BY PARENT COMPOUND WITH STRUCTURES .. 161 GOVERNMENT/STATE/INTERNATIONAL AGENCY STANDARDS .................................... 178 EPA 500 .................................................................................................................................180 EPA 600 .................................................................................................................................190 EPA 1600 ...............................................................................................................................197 EPA 8000 ...............................................................................................................................199 EPA 8100 ...............................................................................................................................200 EPA 8200 ...............................................................................................................................203 EPA 8300 ...............................................................................................................................204 -
Pesticide Simazine and Breast Cancer Risk
Pesticide Simazine and Breast Cancer Risk http://envirocancer.cornell.edu/Bibliography/pesticide/bib.simazine.cfm Skip to main content New Program Learning Resources Events Maps & Stats Research Resources BCERF Research Pesticide Simazine and Breast Cancer Risk Bibliography This bibliography is provided as a service to our readers. It is compiled from the entries in the BCERF Environmental Risk Factors Bibliographic Database. This bibliography is arranged topically. The topics include: Chemical Names and Trade Names Transformation Products and Metabolites History of Use and Usage Regulatory Status and Regulations Human Studies-Evidence of Carcinogenicity Animal Experimental Studies-Evidence of Carcinogencity Evidence of Estrogenicity Effect on Reproduction Formation of Co-Carcinogens Mutagenicity Environmental Fate Persistency in Soil Water Contamination Chemical Names and Trade Names Meister, R. T. (1997). Pesticide Dictionary; Simazine. In 1997 Farm Chemicals Handbook, R. T. Meister, ed. (Willoughby, OH: Meister Publishing Company), pp. C 334. Montgomery, J. H. (1993). Simazine. In Agrochemicals Desk Reference (Boca Raton: Lewis Publishers), pp. 371-377. WSSA. (1994). Simazine. In Herbicide Handbook, 7th, W. H. Ahrens, ed. (Champaign, IL: Weed Science Society of America), pp. 270-272. Transformation Products and Metabolites Adams, N. H., Levi, P., and Hodgson, E. (1990). In vitro studies of the metabolism of atrazine, simazine, and terbutryn in several vertebrate species. Journal of Agricultural and Food Chemistry 38, 1411-1417. WSSA. (1994). Simazine. In Herbicide Handbook, 7th, W. H. Ahrens, ed. (Champaign, IL: Weed Science Society of America), pp. 270-272. History of Use and Usage Bartowiak, D., Newhart, K., Pepple, M., Troiano, J., and Weaver, D. (1995). Sampling for Pesticide Residues in California Well Water; 1995 Update of the Well Inventory Data Base (Sacremento, CA: California Environmental Protection Agency, Dept.