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Subject Index SUBJECT INDEX Vol. 1: 1–698, Vol. 2: 699–1395, Vol. 3: 1397–2111, Vol. 4: 2113–2798, Vol. 5: 2799–3440, Vol. 6: 3475–4191. Page numbers suffixed by t and f refer to Tables and Figures respectively. AAS. See Atomic absorption spectrometry ions, 1113–1117, 1116t Ab initio model potentials (AIMP) plutonium (IV), 849 for actinyl spectroscopic study, 1930 polymerization, 1151, 1151f for electronic structure calculation, 1908 tetrachloride, 1093–1094, 1094f Absorption cross section, neutron scattering tribromide, 1099t, 1100 and, 2233 trichloride, 1099, 1099t Absorption edge spectrometry, 3942–3944, of plutonyl ion, aqueous solution, 2080, 3944f 2081f for plutonium analysis, 3945–3948, of protactinium 3945f–3947f protactinium (V), 212, 212f Absorption fluorescence measurements, 4082 protactinium (V) sulfates, 216, 218f Absorption spectra in solution, 1604–1605, 1604f of actinides, cyclopentadienyl complexes, of uranium 1955 bromide complexes, 496–497 of americium, 1364–1368 halides, 442, 443f, 529, 557 americium (III), 1364–1365, 1365f hexachloride, 567 americium (IV), 1365 hexafluoride, 561 americium (V), 1366, 1367f iodide complexes, 499 americium (VI), 1366, 1367f oxochloride, 526 americium (VII), 1367–1368, 1368f pentavalent and complex halides, 501 of berkelium, 1455 pentavalent oxide fluorides and berkelium (III), 1444–1445, 1455, 1456f complexes, 521 berkelium (IV), 1455 tetrabromide, 495 of californium, 1515–1516 tetrafluoride, 2068, 2069f californium (III), 2091, 2092f trichloride, 447 compounds, 1542–1545, 1544f trichloride hydrates, 449–450 halides, 1545 trifluoride, 445 organometallic, 1541 uranium (III), 2057–2058, 2057f, 2091, in solution, 1557–1559, 1557t, 1558f, 2092f 1559t uranium oxobromo complexes, 573 of curium uranium pentachloride, 523, 523f curium (III), 1402–1404, 1404f of uranium dioxide, 2276–2278, 2277f curium (IV), 1402–1404, 1405f of uranium tetravalent halides, 482–483, of einsteinium, 1600–1602, 1601f 483f in borosilicate glass, 1601–1602, Absorption spectroscopy, resonance effects 1602f–1603f in, 2236 intensity of, 2089–2093 Absorption spectrum, of uranium of liquid plutonium, 963 hexafluoride, 4105 of neptunium, 763–766, 763f, 786–787 Accelerator mass spectrometry (AMS) neptunium (VII) ternary oxides, 729 applications of, 3318–3319 tetrafluoride, 2068, 2070f components of, 3316, 3317f of neptunyl ion, aqueous solution, 2080, development of, 3317–3318 2081f for environmental actinides, 3059t, of plutonium 3062–3063 hexafluoride, 1088, 1089f, 2084–2085, fundamentals of, 3316–3318, 3317f 2086f historical development of, 3316 I-1 Subject Index I-2 Vol. 1: 1–698, Vol. 2: 699–1395, Vol. 3: 1397–2111, Vol. 4: 2113–2798, Vol. 5: 2799–3440, Vol. 6: 3475–4191 for mass spectrometry, 3310 neptunyl (V), 3111t–3112t, 3121–3122 of neptunium, 790 neptunyl (VI), 3111t–3112t, 3122–3123 overview of, 3315–3316 of plutonium for plutonium analysis, 3954–3955 of plutonium (III), 3113t, 3117–3118 problems of, 3329 of plutonium (IV), 3108–3109, 3113t requirements for, 3317 plutonyl (VI/V), 3113t, 3123–3124 sensitivity of, 3316 of thorium (IV), 3103–3105, 3103t TIMS v., 3329 of uranium, 3100–3103, 3101t–3102t for trace analysis, 3315–3319 uranium (III), 3101t–3102t, 3116 Accelerator transmutation, of SNF, 1812 uranium (IV), 3105–3106 Accelerator transmutation of waste (ATW), uranyl (VI), 3101t–3102t, 3118–3121 overview of, 2693–2694 Acids Acetates for acid decomposition, 3280 of actinide elements, 1796 for Purex process, 711 of americium, 1322, 1323t for solvent extraction, 839 complexation with, 3528–3529 uranium metal reactions with, 328 coordination with, glycolate v., 590 Actinide cations of plutonium, 1177, 1180 complexes of, 2577–2591 structural chemistry of, 2439t–2440t, with inorganic ligands, 2578–2580, 2440–2445, 2444f 2579t, 2581t of thorium, 114 with inorganic oxo ligands, 2580–2584, properties of, 114 2582t of uranium, 603–605, 604t with organic ligands, 2584–2591, Acetone 2585t–2586t, 2588f, 2589t derived compounds, of americium, 1322, correlations in, 2567–2577 1323t, 1324 Gibbs energy, 2568–2570, 2568f–2569f protactinium extraction with, 185 ligand basicity, 2567–2568 Acetonitrile, with uranium trichloride, 452 hydration of, 2528–2544 Acetylacetones in concentrated solution, 2536–2538, actinide complexes with, 1783 2537f californium extraction with, 1513 hexavalent, 2531–2532 SFE separation with, 2680 in non-aqueous media, 2532–2533 of thorium, 115 overview, 2528 Acid-base reactions, mathematical modeling pentavalent, 2531–2532 of, 3643–3644 tetravalent, 2530–2531 Acid decomposition, 3279–3281 thermodynamic properties, 2538–2544, acids for, 3280 2540t–2541t, 2542f, 2543t, 2544f description of, 3279–3280 trivalent, 2528–2530, 2529f, 2529t systems for, 3280–3281 TRLF technique, 2534–2536, 2535f, Acidic extractants, for solvent extraction, 2535t–2536t 2650–2652, 2651f hydrolysis of, 2545–2556, 2545f Acid leaching, for uranium ore, 305 hexavalent, 2553–2556, 2554f–2555f, limitations of, 306–307 2554t–2555t Acid pugging, of uranium ore, 306 pentavalent, 2552–2553 Acid redox speciation tetravalent, 2547–2552, 2549t–2550t, of americium (III), 3114t, 3115 2551f–2552f of berkelium (IV/III), 3109–3110 trivalent, 2546, 2547f, 2547t–2548t of californium (III), 3110, 3114t, 3115 inner v. outer sphere complexations, of curium (III), 3110, 3114t 2563–2566, 2566f, 2567t of environmental samples, 3100–3124 oxidation states of, 2525–2527, 2525f EXAFS, 3100–3103 stability constants of, 2558–2559 monatomic spherical An (III) and correlations, 2567–2577 An (IV) ions, 3100–3118 trivalent, 2562, 2563t triatomic spherical An (V) and Actinide chemistry An (VI) ions, 3118–3124 actinide element properties, 1753–1830 of neptunium biological behavior, 1813–1818 neptunium (III), 3111t–3112t, 3116–3117 electronic structure, 1770–1773 neptunium (IV), 3106–3108, 3111t–3112t environmental aspects, 1803–1813 I-3 Subject Index Vol. 1: 1–698, Vol. 2: 699–1395, Vol. 3: 1397–2111, Vol. 4: 2113–2798, Vol. 5: 2799–3440, Vol. 6: 3475–4191 experimental techniques, 1764–1769 electronic properties and structure, introduction, 1753–1755 1513–1517 metallic state, 1784–1790 gas-phase studies, 1559–1561 oxidation states, 1774–1784 introduction, 1499–1502 practical applications, 1825–1829 metallic state, 1517–1527 solid compounds, 1790–1803 preparation and nuclear properties, sources of, 1755–1763 1502–1504 toxicology, 1818–1825 separation and purification, 1507–1513 actinium, 18–44 solution chemistry, 1545–1559 applications of, 42–44 complexation and kinetics in solution, atomic properties of, 33–34 2524–2607 compounds of, 35–36 bonding, 2556–2563 introduction to, 18–20 cation-cation complexes, 2593–2596 metallic state of, 34–35 cation hydration, 2528–2544 nuclear properties of, 20–26 cation hydrolysis, 2545–2556 occurrence in nature of, 26–27 complexation reaction kinetics, preparation and purification of, 27–33 2602–2606 solution and analytical chemistry of, complexes, 2577–2591 37–42 correlations, 2566–2577 americium inner v. outer sphere, 2563–2566 analytical chemistry and spectroscopy, introduction, 2524–2527 1364–1370 redox reaction kinetics, 2597–2602 aqueous solution chemistry, 1324–1356 summary, 2606–2607 atomic properties, 1295–1297 ternary complexes, 2591–2593 compounds, 1302–1324 curium, 1397–1434 coordination chemistry and complexes, analytical chemistry of, 1432–1434 1356–1364 aqueous chemistry of, 1424–1432 history of, 1265 atomic properties of, 1402–1406 isotope production, 1267–1268 compounds of, 1412–1424 metal and alloys, 1297–1302 history of, 1397–1398 nuclear properties of, 1265–1267 metallic state of, 1410–1412 separation and purification of, 1268–1295 nuclear properties of, 1398–1400 in animals and man, 3339–3424 production of, 1400–1402 binding in bone, 3406–3412 separation and purification of, 1407–1410 in bone, 3400–3406 einsteinium, 1577–1613 clearance from circulation, 3367–3387 atomic and ionic radii, and promotion initial distribution, 3340–3356 energies, 1612–1613 introduction, 3339–3340 compounds, 1594–1612 in vivo chelation, 3412–3423 electronic properties and structure, in liver, 3395–3400 1586–1588 tissue deposition kinetics, 3387–3395 introduction, 1577–1579 transport in body fluids, 3356–3367 metallic state, 1588–1594 berkelium nuclear properties, 1579–1583 analytical chemistry, 1483–1484 production, 1579–1583 compounds, 1462–1472 purification and isolation, 1583–1585 concluding remarks, 1484–1485 electronic structures of compounds of, free atom and ion properties, 1451–1457 1893–1998 history of, 1444–1445 actinyl ions and oxo complexes, ions in solution, 1472–1483 1914–1933 metallic state, 1457–1462 concluding comments, 1995–1996 nuclear properties, availability, and halide complexes, 1933–1942 applications, 1445–1447 introduction, 1893–1901 production, 1448 matrix-isolated, 1967–1991 separation and purification, 1448–1451 organometallics, 1942–1967 californium, 1499–1563 relativistic approaches, 1902–1914 applications, 1505–1507 speciated ions, 1991–1992 compounds, 1527–1545 unsupported metal-metal bonds, concluding remarks, 1561–1563 1993–1994 Subject Index I-4 Vol. 1: 1–698, Vol. 2: 699–1395, Vol. 3: 1397–2111, Vol. 4: 2113–2798, Vol. 5: 2799–3440, Vol. 6: 3475–4191 environmental identification and speciation, 5f9 compounds, 2269–2271 3013–3073 5f10 compounds, 2271 background, 3013–3021 5f11 compounds, 2271–2272 combining and comparing analytical actinide dioxides, 2272–2294 techniques, 3065–3071 introduction, 2225–2239 concluding remarks, 3072–3073 mendelevium, 1630–1636 sampling, handling, treatment, and atomic properties,
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