Geochronology and Geochemistry of the Nantianwan Mafic–Ultramafic

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Geochronology and Geochemistry of the Nantianwan Mafic–Ultramafic This article was downloaded by: [China University of Geosciences], [Mr Zhaochong Zhang] On: 15 October 2012, At: 20:59 Publisher: Taylor & Francis Informa Ltd Registered in England and Wales Registered Number: 1072954 Registered office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH, UK International Geology Review Publication details, including instructions for authors and subscription information: http://www.tandfonline.com/loi/tigr20 Geochronology and geochemistry of the Nantianwan mafic–ultramafic complex, Emeishan large igneous province: metallogenesis of magmatic Ni–Cu sulphide deposits and geodynamic setting Meng Wang a , Zhaochong Zhang a , John Encarnacion b , Tong Hou a & Wenjuan Luo a a State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing, 100083, China b Department of Earth and Atmospheric Sciences, Saint Louis University, 3642 Lindell Boulevard, St. Louis, MO, 63108, USA Version of record first published: 08 Mar 2012. To cite this article: Meng Wang, Zhaochong Zhang, John Encarnacion, Tong Hou & Wenjuan Luo (2012): Geochronology and geochemistry of the Nantianwan mafic–ultramafic complex, Emeishan large igneous province: metallogenesis of magmatic Ni–Cu sulphide deposits and geodynamic setting, International Geology Review, 54:15, 1746-1764 To link to this article: http://dx.doi.org/10.1080/00206814.2012.668766 PLEASE SCROLL DOWN FOR ARTICLE Full terms and conditions of use: http://www.tandfonline.com/page/terms-and-conditions This article may be used for research, teaching, and private study purposes. Any substantial or systematic reproduction, redistribution, reselling, loan, sub-licensing, systematic supply, or distribution in any form to anyone is expressly forbidden. The publisher does not give any warranty express or implied or make any representation that the contents will be complete or accurate or up to date. The accuracy of any instructions, formulae, and drug doses should be independently verified with primary sources. The publisher shall not be liable for any loss, actions, claims, proceedings, demand, or costs or damages whatsoever or howsoever caused arising directly or indirectly in connection with or arising out of the use of this material. International Geology Review Vol. 54, No. 15, November 2012, 1746–1764 Geochronology and geochemistry of the Nantianwan mafic–ultramafic complex, Emeishan large igneous province: metallogenesis of magmatic Ni–Cu sulphide deposits and geodynamic setting Meng Wanga , Zhaochong Zhanga*, John Encarnacionb , Tong Houa and Wenjuan Luoa aState Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing 100083, China; bDepartment of Earth and Atmospheric Sciences, Saint Louis University, 3642 Lindell Boulevard, St. Louis, MO 63108, USA (Accepted 17 February 2012) The Nantianwan mafic–ultramafic complex is situated in the northwest part of the Panxi district, southwest China. It consists predominantly of gabbros, gabbronorites, and lherzolites. LA–ICP–MS U–Pb zircon dating of the gabbronorites yields an age of 259.7 ± 0.6 million years, consistent with the ages of other mafic–ultramafic intrusions in the Emeishan large igneous province (ELIP). Gabbronorites and lherzolites host Cu–Ni sulphide ores. Cumulus texture is pronounced in these rocks, containing magnesium-rich olivine (up to 81.4% forsterite). SiO2 contents of the lherzolites range from 42.93 to 44.18 wt.%, whereas those of the gabbronorites vary between 44.89 and 52.76 wt.%. Analysed samples have low rare earth element (REE) contents (23.22–30.16 ppm for lherzolites and 25.21–61.05 ppm for gabbronorites). Both lherzolites and gabbronorites have similar chondrite-normalized REE patterns, suggesting that they are comagmatic. All samples are slightly enriched in large ion lithophile elements (LILEs, e.g. Rb, Ba, and Sr) relative to high field strength elements (HFSEs, e.g. Nb, Ta, and Ti), very similar to those of ocean island basalts (OIBs). The presence of cumulus textures and geochemical signatures indicates that 87 86 fractional crystallization played an important role in the petrogenesis of these rocks. Initial ( Sr/ Sr)t (t = 260 Ma) ratios and εNd(t) values of the mafic–ultramafic suite vary from 0.70542 to 0.70763, and −0.4 to 1.7, respectively. Compared to the Cu–Ni-bearing Baimazhai and Limahe intrusions in the ELIP, which were considerably contaminated by variable crustal 87 86 materials, the Nantianwan complex exhibits much lower ( Sr/ Sr)t.TheirεNd(t) versus (Th/Nb)PM ratios also indicate that the ore-bearing magmas did not undergo significant crustal contamination. In combination with (Tb/Yb)PM versus (Yb/Sm)PM modelling, we infer that the magmas originated from an incompatible elements-enriched spinel-facies lherzolite that itself formed by interaction between the Emeishan plume and the lithospheric mantle. Most plots of NiO versus Fo contents of olivine suggest that sulphides are separated from the parental magma by liquid immiscibility, which is also supported by bulk-rock Cu/Zr ratios of the lherzolites (7.04–102.67) and gabbronorites (0.88–5.56). We suggest that the gabbronorites and lherzolites experienced undersaturation to oversaturation of sulphur; the latter may be due to fractional crystallization in a high-level magma chamber, accounting for the sulphide segregation. Keywords: Nantianwan complex; geochemistry; metallogenesis; Cu–Ni sulphide; Panxi region Introduction (platinum group element) sulphide deposits (e.g. Hou et al. The Emeishan igneous complex is a unique large igneous 2011). Particularly, it is well known for the presence of province (LIP) in China, widely recognized by the inter- the world’s largest Fe–Ti–V oxide ore cluster in the Panxi national geoscientific community. It is one of the three region (e.g. Zhang et al. 2009), where the scale of Cu–Ni– LIPs on Earth that formed near the end of the Permian in (PGE) mineralization is relatively small. In contrast, the widely separated locations, the others being the Siberian Siberian LIP is characterized by the world-class Noril’sk Traps (Sharma 1997; Dobretsov 2005) and the Panjal Cu–Ni–(PGE) sulphide deposits. The difference in miner- Traps of northwestern India (e.g. Bhat et al. 1981). The alization between these two Permian LIPs raises an impor- Emeishan large igneous province (ELIP) is thought to be tant question: what caused the different features of the ∼ Downloaded by [China University of Geosciences], [Mr Zhaochong Zhang] at 20:59 15 October 2012 genetically related to a major 260 Ma plume event (e.g. ore deposits: geologic settings, source composition, depth Thompson et al. 2001; Xu et al. 2004; Ali et al. 2010). of melting, lithospheric/crustal contamination, or magma Although the Permian ELIP is not as large as other LIPs chamber processes? (e.g. Zhang et al. 2006), it is one of the richest in min- Recently, small-scale Cu–Ni–(PGE) sulphide miner- eral resources and the only province in the world that hosts alization has been recognized in the Nantianwan mafic– both magmatic Fe–Ti–V oxide ores and Cu–Ni–(PGE) ultramafic complex in the Pingchuan area, Yanyuan *Corresponding author. Email: [email protected] ISSN 0020-6814 print/ISSN 1938-2839 online © 2012 Taylor & Francis http://dx.doi.org/10.1080/00206814.2012.668766 http://www.tandfonline.com International Geology Review 1747 county of Sichuan province, in the western part of the of clastic, carbonate, and metavolcanic rocks (SBGMR ELIP. Current exploration drilling is in progress by the 1991). The early Sinian consists of clastic rocks and 604 Geological Team, Geological and Mineral Resources felsic volcanic rocks, while the late Sinian Dengying Bureau, Sichuan, China. Sparsely disseminated Cu–Ni Formations consist of clastic rocks in the lower part and sulphide ores with a thickness of ∼350 m were recog- phosphorous-bearing carbonate rocks in the upper part. nized in one borehole. Unlike other Cu–Ni–(PGE) sulphide The Early Cambrian strata are characterized by clastic and deposits in the ELIP, such as the Limahe, Zhubu, and carbonate rocks, whereas the Middle–Late Cambrian strata Baimazhai, which are hosted by small sills, the volume are characterized by limestones (Zhulinping Formation) of the Nantianwan mafic–ultramafic intrusion is relatively and dolomitic limestones (Gaojiaping Formation). The large (39 km2). The prospect for large-scale Cu–Ni–(PGE) Early Silurian strata mainly consist of argillaceous rocks sulphide mineralization resembling those large Cu–Ni– and sandstones (Zhongcao Formation). The Ordovician (PGE) sulphide deposits such as Noril’sk and Sudbury strata consist of carbonate (Hongshiya Formation) and (Naldrett 1997, 1999) has aroused extensive interest. argillaceous rocks, whereas the Carboniferous strata con- However, except for a limited geological survey conducted sist of silicalites (Daopingzi Formation) and limestones at the scale of 1:50,000 and 1:200,000 in the Pingchuan (Maping Formation). The Permian Emeishan basaltic suc- area, no other detailed information has been documented cession unconformably overlies the limestones of the Early to date. Permian Maokou Formation (YBGMR 1990). In the Panxi In this article, we present the first geochronology, min- region, extensive erosion and thinning of the Middle eral chemical, bulk-rock major + trace element, and Sr–Nd Permian limestone in the central part of the ELIP indi- isotopic compositions, aimed at constraining the nature of cate kilometre-scale regional uplift linked to the rising the sources of the intrusions and the petrogenesis, which plume (He et al. 2003; Xu et al. 2004). Numerous in turn provide some key constraints on the metalloge- mafic–ultramafic intrusions are exposed along several nesis of Cu–Ni sulphide mineralization. These new data N–S-trending faults. These intrusions host major world- not only shed new light on the petrogenesis of the ELIP class Fe–Ti oxide deposits (Zhou et al. 2005, 2008). that we can apply to other provinces, but may also allow refinement of previously proposed exploration models for the same type of deposits in the region and around the Geology of the Nantianwan complex and associated world.
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