Application of Mixed Colloidal Magnetic Fluid of Single Domain Fe3o4 and Nife2o4 Ferrite Nanoparticles in Audio Speaker
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S. D. Kemkar et al. Int. Journal of Engineering Research and Application www.ijera.com ISSN : 2248-9622, Vol. 7, Issue 1, ( Part -3) January 2017, pp.11-18 RESEARCH ARTICLE OPEN ACCESS Application of mixed colloidal magnetic fluid of single domain Fe3O4 and NiFe2O4 ferrite nanoparticles in audio speaker S. D. Kemkar*, Milind Vaidya**, Dipak Pinjari***, Sammit Karekar****, Sanjana Kemkar*****, Siddhesh Nanaware******, Sanjukta Kemkar******* *Department of Physics, Smt. Chandibai Himathmal Mansukhani College, Ulhasnagar, India **Department of Physics, Vedanta College, Vithalwadi, India ***Department of Chemical Engineering, Institute of Chemical Technology, Mumbai, India ****Department of Chemical Engineering, Institute of Chemical Technology, Mumbai, India *****Smolensk State Medical University, Smolensk, Russia ******STES NBN Sinhgad School of Engineering, Pune, India *******Department of Microbiology, Smt. CHM College, Ulhasnagar, India ABSTRACT Ferrofluids are stable suspensions of colloidal ferrimagnetic particles in suitable non – magnetic carrier liquids. They have attracted a lot of attention from scientists and engineers due to their many interesting properties and applications in various branches of engineering. The present work reports the performance of colloidal fluid of single domain nanoparticles of NiFe2O4 and Fe3O4. The thermal properties and its dynamics on magnetization as well as its effect on thermal conductivity on the colloidal fluid are studied here. Advantages of the increased thermal conductivity and optimization of magnetization of mixed colloidal fluid is used to extract the heat from voice coil. Nanoparticles of 21 nm of Fe3O4 and 12 nm of NiFe2O4 are used for mixed colloidal fluid. The suspension of particles is achieved by coating the nanoparticles with mono-corboxylic group on both the types of particles. The higher size (21 nm of Fe3O4 and 12 nm of NiFe2O4) particles are taken for synthesizing colloidal fluid, to have magnetic property of mixed colloidal liquid at elevated temperature of voice coil of speaker (Higher sized particles gives better magnetization). Oil is used as a carrier. Mixed magnetic colloidal fluid is used as a medium for damping so that noise is reduced at higher temperature of voice coil. Keywords: Audio speaker, nanoparticles of NiFe2O4 and Fe3O4, magnetization, mixed colloidal magnetic fluid. I. INTRODUCTION studied [8]. Their work was on increasing the radial Nowadays, nanotechnology is emerging as restoring force on the voice coil and factors one of the prime fields of technology. influencing splash loss of the ferrofluid due to shock. Nanotechnology deals with creation of useful nano- Ferrohydrodynamic analysis was employed for materials and devices through control of these matters modeling. Ferrofluid is a temperature sensitive fluid, on nanometer scale. Such a material has different because they exhibit some properties like high phenomena and many physical properties that have thermal conductivity, small change in temperature, been observed on this scale. The phenomena and large change in magnetization. In case of mixed benefits of this technology are used in making colloidal ferrofluids, small change in temperature and materials in many fields like nano-electronics [18, 20, small change in magnetization occurs. This work 21, 22], optical fiber [1,17,19], computing, medicine deals with the preparation, characterization and and health, space exploration, environment and application of the mixed ferrofluid on audio speaker energy, aeronautics, magnetic recording media, for performance up gradation and optimizing the magnetic fluid, catalysis, medical diagnostics, magnetization of mixed colloidal fluid. We aim at pigment in paint and ceramics [2-4] etc. Nano- designing of colloidal magnetic fluid for consistent science and technology is emerging as a very performance on heat extraction, noise damping and promising field as far as applications are concerned. high fidelity achievement with minimum deviation in Various Devices based on ferrofluids continue to magnetization against temperature. The NiFe2O4 have offer high reliability and low cost solutions to many been used because of its high permeability in higher complicated industrial problems [5]. Many frequency range and low core losses at such applications based on the susceptibility of the frequencies, as well as somewhat flat magnetization ferrofluid are devised [6]. Various studies on the characteristics in the temperature span of interest. magnetization of the magnetic colloidal fluid have The heat generated by the voice coil will be been carried out [7]. Recently, extensive study on partly transferred to speaker components by the way audio speakers containing ferrofluid has also been of convection and conduction under the situation www.ijera.com DOI: 10.9790/9622-0701031118 11 | P a g e S. D. Kemkar et al. Int. Journal of Engineering Research and Application www.ijera.com ISSN : 2248-9622, Vol. 7, Issue 1, ( Part -3) January 2017, pp.11-18 when only air is present in the coil. This process is not so efficient. The pioneering work on application of ferrofluid in speaker was carried out with reference to centering of voice coil and enhancement in performance of voice coil with ferrofluid in the vicinity of the voice coil [9]. II. PREPARATION OF NiFe2O4 AND Fe3O4 NANOPARTICLES AND THEIR FERROFLUIDS The particles are prepared by chemical co- precipitation method and dispersed in the carrier liquid with stabilizer. The nanoparticles are prepared Figure 1(a). TEM image of NiFe2O4 ferrofluid sample. using aqueous solution of FeCl3 and NiCl2 with (2:1) proportion in ammonium hydroxide to achieve X-rays diffraction characterization has also NiFe2O4 magnetic nanoparticles. Ferritization of NiO been performed on the Nickel substituted particles. 0 and Fe2O3 was achieved at 98 C. Oleic acid XRD characterization was carried out by using molecules were adsorbed on particles. Particles were powder X-ray diffractometer (Phillips PW 1800, decanted and washed with acetone as well as warm range is 6-80O 2θ). Fig.1(b) shows that the particles water three times. Collected particles were dried in have inverse spinel structure of calculated size of oven and dispersed in transformer oil as carrier. Dried 12.3 nm. The details of plane d- spacing and 2 theta powder sample was preserved for XRD values are given in table 1. characterization. Ferrofluid was centrifuged at 4500 RPM for one and half hour. Lumps were removed and clean solution was obtained. The volume fraction Фm of 0.08 was prepared for NiFe2O4. Similarly, Fe3O4 magnetic nanoparticles were also prepared with chemical co-precipitation method. Aqueous solution of salts of FeCl2 and FeCl3 with 1:2 proportions in NaOH base solutions were used to achieve Fe3O4 magnetic nanoparticles. The ferritization was readily achieved at room temperature without any difficulty. Surfactant molecules of Oleic acid were adsorbed on particles. Particles were decanted and washed. Magnetite powder was dried in oven for 24Hrs at 80OC. Powder Figure 1(b). XRD pattern of NiFe2O4 powder. was dispersed in transformer oil. Samples were centrifuged at 4500 RPM for one and half hour. Table 1. d-spacing and 2theta values for NiFe2O4 crystal. Lumps were removed and clean ferrofluid was obtained. Dried sample was also preserved for XRD characterization. Ferrofluid with volume concentration of 0.08 was prepared. III. CHARACTERIZATION OF NiFe2O4 AND Fe3O4 NANOPARTICLES TEM of the sample of NiFe2O4 was obtained as in Fig 1(a). The morphology and particle size of this nanoparticle was characterized by transmission electron microscopy (TEM, H-7650 accelerating voltage of 120 KV).TEM shows the particle size of TEM of the sample of Fe3O4 was obtained as in Fig about 12 nm. 2(a). TEM shows the particle size of about 21 nm. www.ijera.com DOI: 10.9790/9622-0701031118 12 | P a g e S. D. Kemkar et al. Int. Journal of Engineering Research and Application www.ijera.com ISSN : 2248-9622, Vol. 7, Issue 1, ( Part -3) January 2017, pp.11-18 m of a particle in the field direction is described by Langevin expression. m = Md [coth ξ – 1/ξ] Where, ξ = (mHo/ kT). The behavior of the ferrofluid depends upon the behavior of individual particle. The Brownian relaxation time τB = 3 Vη / kT, Neel relaxation time σ τN = τO ℮ affects the susceptibility of the particle, where V is the hydrodynamic volume of a particle, η is the dynamic viscosity of the carrier liquid, σ is associated with anisotropy of the crystal K and given with KV / kT and τO, the damping or extinction time Figure 2(a). TEM of Fe3O4 system with 21 nm particle -9 size ferrofluid. is about ~10 seconds. In Neel relaxation, the magnetic moment may change or reverse the direction within the particle without the rotation of the particle. This is achieved by overcoming the energy barrier. The probability of such a transition is approximately equal to ℮σ. It is interesting that when τN = τB, one can determine critical particle radius; above this radius, the Brownian relaxation mechanism occurs and below this, is the relaxation by Neel’s mechanism. The total susceptibility of the ferrofluid depends on number of particles contribution. The Xi can be shown as a function of volumetric fraction Фm. Where Xi = (π/18) (Фm) 2 3 (μ0Md d /kT). The mean particle size was d≈21 nm in this work. The volume concentration Фt of the Figure 2(b). XRD pattern of Fe3O4 powder. particles coated with oleic acid in the carrier has Ф =0.08. The carrier used was transformer oil for its Table 2. d-spacing and 2theta values for Fe O powder t 3 4 stability at higher temperature. IV. MAGNETIZATION OF MAGNETIC NANOPARTICLES Magnetization of nanoparticles of magnetite is studied under applied transient field at various packing fractions [11]. Field induced particle alignment and magnetization of ferrofluid was also studied [12]. Magnetization of particles was deliberated that the shell of the particle affects The structural properties of produced magnetization of the particle [13]. However nanoparticles were analyzed by XRD taken on classically, a mathematical modeling on Philipsmake X’pert PRO model XRD machine as magnetization of particle is carried out and magnetic shown in Fig 2(b).