Geochemistry of Coal–Bearing Permo−Triassic Strata in Allan Hills, South Victoria Land, Antarctica: Implications for Palaeoclimate

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Geochemistry of Coal–Bearing Permo−Triassic Strata in Allan Hills, South Victoria Land, Antarctica: Implications for Palaeoclimate The Palaeobotanist 67(2018): 89–97 0031–0174/2018 Geochemistry of coal–bearing Permo−Triassic strata in Allan Hills, South Victoria Land, Antarctica: Implications for palaeoclimate SUNDEEP K. PANDITA1*, N.S. SIDDAIAH2, RAJNI TEWARI3, SANKAR CHATTERJEE4 AND DEEPA AGNIHOTRI5 1Department of Geology, University of Jammu, Jammu 180 006, India. 2Department of Environmental Science, Jawahar Lal Nehru University, New Delhi 110 016, India. 3C–38, Alkapuri, Sector C, Aliganj, Lucknow 226 024, India. 4Texas Tech University, Lubbock, Texas, USA. 5Birbal Sahni Institute of Palaeosciences, 53 University Road, Lucknow 226 007, India. *Corresponding author: [email protected] (Received 09 February, 2018; revised version accepted 03 March, 2018) ABSTRACT Pandita SK, Siddaiah NS, Tewari R, Chatterjee S & Agnihotri D 2018. Geochemistry of coal–bearing Permo–Triassic strata in Allan Hills, South Victoria Land, Antarctica: Implications for palaeoclimate. The Palaeobotanist 67(1): 89–97. Major, trace and rare earth element (REE) geochemistry has been carried out in this paper to characterize source–rock weathering and climatic variability of the late Permian Weller Formation and the late Triassic Lashly Formation of Gondwana sequences which have yielded rich record of plant mega–and micro fossils associated with coal beds in post–glacial conditions in Allan Hills of South Victoria Land, Antarctica. The geochemistry suggests dominantly a felsic provenance with a volcanogenic input and role of weathering and hydrothermal alteration. The palaeoclimatic interpretation derived from geochemical analysis indicates warm, temperate and humid conditions during the late Permian, and warm and humid conditions during the late Triassic. Key–words—Geochemistry, Permian, Triassic, Allan Hills, Antarctica. ,Syu igkfM+;ka] nf{k.k foDVksfj;k Hkwfe] vaVkdZfVdk esa dks;yk&/kkjd ieksZ&Vªk;fld Lrjksa dk Hkw&jlk;ufoKku% iqjktyok;q fufgrkFkZ Laknhi ds- iafMrk] ,u-,l- fln~/kS;k] jtuh frokjh] 'kadj pSVthZ ,oa nhik vfXugks=kh lkjka'k xksaMokuk vuqØeksa ds foyafcr ifeZ;u oSYyj 'kSylewg ,oa foyafcr Vªkb,fld yS'kyh 'kSylewg dk lzksr 'kSy vi{k; ,oa tyok;oh ifjorZuh;rk dks vfHky{kf.kr djus ds fy, bl 'kks/k i=k esa izeq[k rRo] lw{eekf=kd ,oa nqyZHk i`Foh rRoksa ¼REE½ dk Hkw&jlk;ufoKku fd;k x;k gSA ftuls nf{k.k foDVksfj;k Hkwfe] vaVkdZfVdk dh ,Syu igkfM+;ksa esa fge;qxksRrj n'kkvksa esa dks;yk laLrjksa ls la?kfVr ikni LFkwy ,oa lw{e thok'eksa ds izpqj vfHkys[k feys gSaA Hkw&jlk;ufoKku izcyrk ls okWYdsukstsfud vkxr ds lkFk QsfYld mn~xe&LFky rFkk vi{k; o m".ktyh; ifjorZu dh Hkwfedk lq>krk gSA Hkw&jklk;fud fo'ys"k.k ls O;qRiUu iqjktyok;oh foospu foyafcr ifeZ;u ds nkSjku dks".k] 'khrks".k o vknZz fLFkfr;ka rFkk foyafcr Vªkb,fld ds nkSjku dks".k o vknZz fLFkfr;ka bafxr djrk gSA lwpd 'kCnµHkw&jlk;ufoKku] ifeZ;u] Vªkb,fld] ,Syu igkfM+;ka] vaVkdZfVdkA © Birbal Sahni Institute of Palaeosciences, India 90 THE PALAEOBOTANIST INTRODUCTION 1994; Roex et al., 1985; Zhao et al., 1997; Khare et al., 2009; Srivastava et al., 2013), and petrological (Roex et al., 1985; NTARCTICA, presently one of the world’s driest deserts Kumar et al., 2013) aspects. Aand totally inhospitable to plant life, was a part of the The late Permian Weller Formation and the late Triassic Gondwana Supercontinent during Permian and Triassic along Lashly Formation of Gondwana sequences in Allan Hills with other continents such as India, Australia, South America (latitude 76.72ºS, longitude 159.67ºE) of South Victoria Land, and South Africa. The melting of the late Carboniferous–Early Antarctica have yielded rich record of plant mega–and micro Permian ice sheet led to amelioration of climate subsequently fossils associated with coal beds in post–glacial conditions followed by a rapid evolution of the Glossopteris flora in the (Chatterjee et al., 2013; Ram–Awatar et al., 2014: Tewari Gondwana continents. Extensive cold–temperate swamps et al., 2015). The Weller Formation, which lies directly with thriving plant communities of Glossopteris and other over the early Permian glacial strata, records a change from allied plants formed thick coal seams in different Gondwana glacial to postglacial condition with the establishment of basins. The trunks of the trees that bore Glossopteris leaves polar forest (Tewari et al., 2015). Upward in the Gondwana are marked by growth rings, reflecting the effects of strong sequence, thick coal beds occur in swamp and meandering seasonality. At the end of the Permian, when the climate stream facies of Weller and Lashly formations, while they are became increasingly hot and dry with marked seasonality conspicuously absent in the intervening Feather Formation of rainfall, a new flora–the Dicroidium flora appeared in of channel deposits. Sedimentological (Retallack et al., the Gondwana continents. The Permo–Triassic transition 2005) and petrographic (Kumar et al., 2011) studies of these is an important time in the evolution of several groups of fossiliferous horizons exhibit microscopic charcoal remains, Gondwana plants, when Dicroidium flora gradually replaced which suggest ancient forest fire events, possibly caused by the Glossopteris flora. Antarctica, too, fostered dense forests continental volcanism (Kumar et al., 2013). The preservation of Glossopteris and Dicroidium floras during Permian and of carbonaceous material and the deposition of coal during Triassic, respectively. Permian and Triassic were probably related to climatic The vegetation of Antarctica is of evolutionary changes, including increase in temperature and humidity. significance since it encompasses not only early vascular Major, trace and rare earth element (REE) geochemistry land plants like bryophytes but also a number of higher plant has been found to be useful to characterize source–rock orders such as Sphenophyllales, Filicales, Pteridospermales, weathering and climatic variability from the terrestrial detritus Glossopteridales, Cordaitales Corystospermales, Cycadales of a basin (Nesbitt & Young, 1982; Cox et al., 1995; Basu, and Pinales. A plethora of information is available on the 1976; Quasim et al., 2017). Their records are influenced Permian (Plumstead, 1975; Rigby, 1969; Rigby & Schopf, by source rock lithologies, chemical weathering, sorting, 1969; Schopf, 1968, 1976; Kräusel, 1962; Maheshwari, sedimentation and post depositional diagenetic reactions 1972; Chatterjee et al., 1983; Gee, 1989; Pigg & Taylor, (McLennan et al., 1993). The distribution of these elements 1990, 1993; Smoot & Taylor, 1986; Taylor & Taylor, 1987; provides clues of the geological processes, provenance and Taylor et al., 1992; Retallack & Krull, 1999; Retallack et al., tectonic setting (McLennan et al., 1993; Cullers et al., 1988; 2005) and Triassic (Osborne & Taylor, 1989; Osborne et al., McLennan, 1989). The REE geochemistry has an added 2000; Bose et al., 1990 and references cited therein, Perovich advantage over major and trace elements to decipher the & Taylor, 1989; Delevoryas et al., 1992; Webb & Fielding, provenance, since the concentration of these elements is not 1993; Taylor, 1996; Taylor et al., 1994; Cantrill et al., 1995; affected during erosion, sedimentation and diagenesis and McLoughlin et al., 1997; Yao et al., 1995,1997; Phipps et al., thus represents a homogenized average source composition 1998; Axsmith et al., 2000; Rothwell et al., 2002; McManus (McLennan, 1989; Bhatia, 1985; Nance & Taylor, 1976). et al., 2002; Klavins et al., 2002, 2003, 2004; Hermans et al., This paper attempts to investigate the geochemistry 2007; Bomfleur & Kerp, 2010; Bomfleur et al., 2007, 2011; of two rock samples collected from the Permian Weller Escapa et al., 2011) megafloras of east and west, and central and Triassic Lashly formations to understand the source Transantarctic Mountains, Antarctica. Besides, several studies and composition of these rocks and their implication on have been carried out on palynological (Balme & Playford, palaeoclimate of the area. 1967; Kyle, 1977; Kyle & Schopf, 1982; Larson et al., 1990; Farabee et al., 1990; Lindstörm, 1996, 2005; Masood et al., GEOLOGICAL SETTING 1994; Askin, 1995; McLoughlin et al., 1997; Ram–Awatar et al., 2014), faunal (Hammer et al., 2004; Retallack et al., The Beacon Supergroup crops out along the length of 2005 and references cited therein), palaeofire (Kumar et al., the Transantarctic Mountains and was deposited in a retroarc 2011) geochemical and geophysical (Angino & Armitage, foreland basin (Collinson et al., 2006). The exposures of this 1963; Weiss et al., 1979; Saunders et al., 1980; Kurat et al. supergroup in the Allan Hills occur in the shape of a Y (Fig. PANDITA et al.—GEOCHEMISTRY OF COAL–BEARING PERMO−TRIASSIC STRATA IN ANTARCTICA 91 Fig. 1—Geological map of Allan Hills (marked by an arrow), South Victoria Land, central Transantarctic Mountains, Antarctica (modified after Kyle, 1977) showing the sample locations. 92 THE PALAEOBOTANIST 1) and are divided into two units: the lower Victoria Group 4–5 drops of polyvinyl alcohol as binding agent (Stork et al., of mainly fluvial siliciclastics, and the upper Ferrar Group 1987; Saini et al., 2002). The pellets were analyzed for the of volcanic origin (Ballance, 1977; Chatterjee et al., 1983). major and trace elemental abundance by standard Wavelength The stratigraphy of Allan Hills has been discussed by Dispersive X–ray Flourescence Spectrometer (Siemens SRS– Gunn and Warren (1962), Borns and Hall (1969), Barrett et 3000) at Wadia Institute of Himalayan Geology, Dehradun al. (1971), Barrett and Kohn (1975), Ballance (1977),
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