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SAFETY DATA SHEET Chlorine

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SAFETY DATA SHEET Chlorine SAFETY DATA SHEET Page : 1/12 Revised edition no : 1 Compilation date : 26 / 10 / 2018 Supersedes : 10 / 10 / 2017 Chlorine NOAL_0022 Country : SE / Language : EN SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name : Chlorine, Chlorine N25, Chlorine N28 SDS no : NOAL_0022 Chemical description : Chlorine CAS-No. : 7782-50-5 EC-No. : 231-959-5 EC Index-No. : 017-001-00-7 Registration-No. : 01-2119486560-35 Chemical formula : Cl2 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses : Industrial and professional. Perform risk assessment prior to use. See the list of identified uses and exposure scenarios in the annex of the safety data sheet. Contact supplier for more information on uses. Uses advised against : Consumer use. 1.3. Details of the supplier of the safety data sheet Company identification AIR LIQUIDE GAS AB Lundavägen 151 21209 Malmö - SWEDEN T +46 40 38 10 00 [email protected] E-Mail address (competent person) : [email protected] 1.4. Emergency telephone number Emergency telephone number : 112 Availability ( 24 / 7 ) SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Physical hazards Oxidising Gases, Category 1 H270 Gases under pressure : Liquefied gas H280 Health hazards Acute toxicity (inhalation:gas) Category 2 H330 Skin corrosion/irritation, Category 2 H315 Serious eye damage/eye irritation, Category 2 H319 Specific target organ toxicity — Single exposure, H335 Category 3, Respiratory tract irritation SAFETY DATA SHEET Page : 2/12 Revised edition no : 1 Compilation date : 26 / 10 / 2018 Supersedes : 10 / 10 / 2017 Chlorine NOAL_0022 Country : SE / Language : EN Environmental hazards Hazardous to the aquatic environment — Acute Hazard, H400 (M=100) Category 1 Hazardous to the aquatic environment — Chronic H410 Hazard, Category 1 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : GHS03 GHS04 GHS06 GHS09 Signal word (CLP) : Danger Hazard statements (CLP) : H270 - May cause or intensify fire; oxidiser.. H280 - Contains gas under pressure; may explode if heated.. H315 - Causes skin irritation.. H319 - Causes serious eye irritation.. H330 - Fatal if inhaled.. H410 - Very toxic to aquatic life with long lasting effects.. EUH071 - Corrosive to the respiratory tract.. Precautionary statements (CLP) - Prevention : P220 - Keep away from clothing and other combustible materials.. P260 - Do not breathe gas, vapours. P273 - Avoid release to the environment.. P280 - Wear protective gloves, protective clothing, eye protection, face protection.. P244 - Keep valves and fittings free from oil and grease.. - Response : P370+P376 - In case of fire: stop leak if safe to do so.. P332+P313 - If skin irritation occurs: Get medical advice/attention.. P304+P340+P315 - IF INHALED : Remove person to fresh air and keep comfortable for breathing. Get immediate medical advice / attention. P305+P351+P338+P315 - IF IN EYES : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice / attention. P302+P352 - IF ON SKIN: Wash with plenty of soap and water.. - Storage : P403 - Store in a well-ventilated place.. P405 - Store locked up.. 2.3. Other hazards : None. SECTION 3: Composition/information on ingredients 3.1. Substances Name Product identifier Composition Classification according to [V-%]: Regulation (EC) No. 1272/2008 [CLP] SAFETY DATA SHEET Page : 3/12 Revised edition no : 1 Compilation date : 26 / 10 / 2018 Supersedes : 10 / 10 / 2017 Chlorine NOAL_0022 Country : SE / Language : EN Chlorine (CAS-No.) 7782-50-5 100 Ox. Gas 1, H270 ​ ​ Press. Gas (Liq.), H280 Acute Tox. 2 (Inhalation:gas), H330 (EC-No.) 231-959-5 ​ ​ Skin Irrit. 2, H315 Eye Irrit. 2, H319 (EC Index-No.) 017-001-00-7 STOT SE 3, H335 ​ ​ Aquatic Acute 1, H400 (M=100) (Registration-No.) 01-2119486560-35 Aquatic Chronic 1, H410 ​ ​ Contains no other components or impurities which will influence the classification of the product. 3.2. Mixtures : Not established. SECTION 4: First aid measures 4.1. Description of first aid measures - Inhalation : Remove victim to uncontaminated area wearing self contained breathing apparatus. Keep victim warm and rested. Call a doctor. Perform cardiopulmonary resuscitation if breathing stopped. - Skin contact : Remove contaminated clothing. Drench affected area with water for at least 15 minutes. In case of frostbite spray with water for at least 15 minutes. Apply a sterile dressing. Obtain medical assistance. - Eye contact : Immediately flush eyes thoroughly with water for at least 15 minutes. - Ingestion : Ingestion is not considered a potential route of exposure. 4.2. Most important symptoms and effects, both acute and delayed : May cause irritation to cornea (with temporary disturbance to vision). May cause irritation to skin. Material is destructive to tissue of the mucuous membranes and upper respiratory tract. Cough, shortness of breath, headache, nausea. Refer to section 11. 4.3. Indication of any immediate medical attention and special treatment needed : Obtain medical assistance. Treat with corticosteroid spray as soon as possible after inhalation. SECTION 5: Firefighting measures 5.1. Extinguishing media - Suitable extinguishing media : Water spray or fog. Foam. - Unsuitable extinguishing media : Do not use water jet to extinguish. 5.2. Special hazards arising from the substance or mixture Specific hazards : Supports combustion. Exposure to fire may cause containers to rupture/explode. Hazardous combustion products : None that are more hazardous than the product itself. 5.3. Advice for firefighters SAFETY DATA SHEET Page : 4/12 Revised edition no : 1 Compilation date : 26 / 10 / 2018 Supersedes : 10 / 10 / 2017 Chlorine NOAL_0022 Country : SE / Language : EN Specific methods : Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat radiation may cause gas receptacles to rupture. Cool endangered receptacles with water spray jet from a protected position. Prevent water used in emergency cases from entering sewers and drainage systems. If possible, stop flow of product. Use water spray or fog to knock down fire fumes if possible. Move containers away from the fire area if this can be done without risk. Special protective equipment for fire fighters : Wear gas tight chemically protective clothing in combination with self contained breathing apparatus. Standard EN 943-2: Protective clothing against liquid and gaseous chemicals, aerosols and solid particles. Gas-tight chemical protective suits for emergency teams. Standard EN 137 - Self-contained open-circuit compressed air breathing apparatus with full face mask. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures : Try to stop release. Evacuate area. Monitor concentration of released product. Wear self-contained breathing apparatus when entering area unless atmosphere is proved to be safe. Eliminate ignition sources. Ensure adequate air ventilation. Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous. Act in accordance with local emergency plan. Stay upwind. 6.2. Environmental precautions : Try to stop release. Reduce vapour with fog or fine water spray. 6.3. Methods and material for containment and cleaning up : Hose down area with water. Keep area evacuated and free from ignition sources until any spilled liquid has evaporated (ground free from frost). Wash contaminated equipment or sites of leaks with copious quantities of water. 6.4. Reference to other sections : See also sections 8 and 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Safe use of the product : The product must be handled in accordance with good industrial hygiene and safety procedures. Only experienced and properly instructed persons should handle gases under pressure. Consider pressure relief device(s) in gas installations. SAFETY DATA SHEET Page : 5/12 Revised edition no : 1 Compilation date : 26 / 10 / 2018 Supersedes : 10 / 10 / 2017 Chlorine NOAL_0022 Country : SE / Language : EN Ensure the complete gas system was (or is regularily) checked for leaks before use. Do not smoke while handling product. Avoid exposure, obtain special instructions before use. Avoid contact with aluminium. Keep equipment free from oil and grease. Use no oil or grease. Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Contact your gas supplier if in doubt. Installation of a cross purge assembly between the cylinder and the regulator is recommended. Purge system with dry inert gas (e.g. helium or nitrogen) before gas is introduced and when system is placed out of service. Avoid suck back of water, acid and alkalis. Do not breathe gas. Avoid release of product into atmosphere. Safe handling of the gas receptacle : Refer to supplier's container handling instructions. Do not allow backfeed into the container. Protect cylinders from physical damage; do not drag, roll, slide or drop. When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport cylinders. Leave valve protection caps in place until the container has been secured against either a wall or bench or placed in a container stand and is
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