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Surface Engineering: Science and Technology Ii SURFACE ENGINEERING: SCIENCE AND TECHNOLOGY II Edited by: Ashok Kumar Yip-Wah Chung John J. Moore Gary L. Doll Kyoshi Yatsui D.S. Misra SURFACE ENGINEERING: SCIENCE AND TECHNOLOGY II Proceedings of a symposium sponsored by the Surface Engineering Committee of the Materials Processing & Manufacturing Division (MPMD) of TMS (The Minerals, Metals & Materials Society). Held during the TMS 2002 Annual Meeting in Seattle, Washington February 17-21, 2002 Partial funding for this publication was provided for by the Seeley W. Mudd Fund Edited by: Ashok Kumar Yip-Wah Chung John J. Moore Gary L. Doll Kyoshi Yatsui D.S. Misra A Publication of A Publication of The Minerals, Metals & Materials Society 184 Thorn Hill Road Warrendale, Pennsylvania 15086-7528 (724) 776-9000 Visit the TMS web site at http://www.tms.org The Minerals, Metals & Materials Society is not responsible for statements or opinions and is absolved of liability due to misuse of information contained in this publication. Printed in the United States of America ISBN Number 0-87339-521-2 Library of Congress Number:2002100526 Authorization to photocopy items for internal or personal use, or the internal or personal use of specific clients, is granted by The Minerals, Met- als & Materials Society for users registered with the Copyright Clearance Center (CCC) Transac- tional Reporting Service, provided that the base fee of $7.00 per copy is paid directly to Copyright Clearance Center, 27 Congress Street, Salem, Massachusetts 01970. For those organizations that have been granted a photocopy license by Copyright Clearance Center, a separate system of payment has been arranged. © 2002 If you are interested in purchasing a copy of this book, or if you would like to receive the latest TMS publications catalog, please telephone 1-800-759-4867 (U.S. only) or 724-776-9000, EXT. 270. TABLE OF CONTENTS Preface ......................................................................................................................................... ix Nanomaterials Modifying the Surface of Nanoparticles by Coating ................................................................ 3 D.V. Szabó, S. Schlabach, B. Xu and D. Vollath Formation of Photonic Nanocomposites by Surface Engineering Over Inorganic Nanoparticles ............................................................................................................ 15 N. Kambe Micro To Nano-Small Research For Fuels and Combustion ................................................. 25 C.E. Bunker, J.R. Gord, T.R. Meyer, M.S. Brown, V.R. Katta, D.A. Zweifel, B.A. Harruff and Y-P. Sun Formation of Gold Nanowires with MgO Surfaces ................................................................ 35 A. Ueda, R.R. Mu, V.C. Saunders, T.C. Livingston, M.H. Wu and D.O. Henderson Dense Deposition of Nanocomposites By a Compact YAG Laser ......................................... 43 M. Senna and K. Hamada Aqueous Chemical Growth of Advanced Nanostructured Metal Oxides Thin Films .................................................................................................................................. 51 L. Vayssieres Purification of Aluminum Nitride Nanosized Powder Synthesized by Pulsed Wire Discharge .............................................................................................................. 61 C. Cho, Y. Kinemuchi, T. Suzuki, H. Suematsu, W. Jiang and K. Yatsui Engineered Nanomaterial Hard Coatings on Metal and Polymer Substrates ................................................................................................................................... 69 A. Singhal and G. Skandan Synthesis of Nickel Ferrite Nanosized Powders by Pulsed Wire Discharge ......................... 79 K. Ishizaka, Y. Kinemuchi, T. Suzuki, H. Suematsu, W. Jiang and K. Yatsui Reinforced Epoxies Using Carbon Nanotubes ........................................................................ 89 R.A. Bley, D. Beascoechea and R. Niedner v Tunable Self-Assembly of Carbon Nanotubes on Silica Surface........................................... 99 Z.J. Zhang, B.Q. Wei and P.M. Ajayan Issues in Surface Engineering Laser Surface Modification of Electronic Properties in Wide Band Gap Materials ................................................................................................................................... 113 I.A. Salama, N.R. Quick and A. Kar Preparation of TiFe Thin Films of Hydrogen Absorbing Alloy by Intense Pulsed Ion-Beam Evaporation................................................................................................ 125 T. Saikusa, T. Suzuki, H. Suematu, W. Jiang and K. Yatsui Surface Modification of Austenitic Stainless Steels .............................................................. 133 H. Ocken and R. Asay Synthesis of Functional Materials using Pulsed Power Technology ................................... 143 K. Yatsui, W. Jiang, H. Suematsu, T. Suzuki, Y. Kinemuchi and S.C. Yang Surface Modification of P/M TiC Reinforced Iron Matrix Composites ............................. 153 O.N. Dogan, D.E. Alman, J.A. Hawk and P. Danielson Functionally Graded Materials Produced with High Power Lasers................................... 163 J.T. De Hosson and Y. Pei Advances in Coating Technology Nucleation and Growth of Cubic Boron Nitride Under Different Substrate Bias .......................................................................................................................... 179 Q. Li, Y. Lifshitz, L.D. Marks, I. Bello and S.T. Lee Role of Precursors on the Formation of CNX Deposited by PE-HF-CVD .......................... 189 D. Dumitriu and A. Karami Optimization of Thermoelectric Properties in Boron Carbide Thin Films Prepared by Ion-Beam Evaporation ...................................................................................... 199 H. Suematsu, I. Ruiz, K. Kobayashi, M. Takeda, D. Shimbo, T. Suzuki, W. Jiang and K. Yatsui Developing a MoSi2+ SiC Oxidation Resistance Coating for MO, a Prototype Refractory Metal ................................................................................................. 207 E.C. Hixson, G.G.W. Mustoe, J.J. Moore, H.J. Kleebe, D.L. Olson and C. Suryanarayana vi The Influence of Particle Energy Distributions on the Microstructure and Properties of Reactively Sputtered Titanium Oxide and Titanium Nitride Thin Films ................................................................................................................................ 217 C. Muratore, J.J. Moore and J.A. Rees Effects of Bias-Enhanced Nucleation and Growth of Diamond Films on Copper and Transition-Metal Alloy Substrates .................................................................... 227 A. Kumar and A.K. Sikder Epitaxial Nucleation of Diamond Polytypes on Silicon by Direct Ion Beam Deposition ...................................................................................................................... 239 Q. Li, X.F. Duan, Y. Lifshitz, F.Y. Meng, N.G. Shang, I. Bello and S.T. Lee Characterization of Materials Development of Cermet Thin Films Coatings ....................................................................... 369 B. Mishra, J. Zhou and F. Kustas Relative Nanomechanical and Raman Studies of Diamond-Like Carbon Thin Films ................................................................................................................................ 251 J. Goldsmith, E. Sutter, J. Moore, B. Mishra and M. Crowder Fabrication and Characterization of Mechanical Properties of Ultra- Thin Silicon Microcantilevers................................................................................................. 261 P.B. Zantye, A.K. Sikder, R.K. Sharma and A. Kumar Influence of Surface Roughness on Coercivity and Magnetic Interactions in CoCrX (X=Pt,Pd,Ta,B) Thin Film Media.................................................... 273 M. Tarakci and S. Guruswamy Mechanical Properties of Microstructural Evaluation of Chromium Containing Hard Coatings on Fe-Mn-Al Alloy ..................................................................... 283 J-W. Lee and J.-G. Duh Curvature Method as a Tool to Evaluate Shape Memory Effects for TiNiCu Thin Films................................................................................................................... 293 Y. Fu, H. Du and S. Zhang Observation of Surface-Related Phenomena During In-situ Nanoindentation in a Transmission Electron Microscope (TEM) ...................................... 305 A.M. Minor, E.T. Lilleodden, E.A. Stach and J.W. Morris Comparison in Characteristics of Electroless Deposited and Magnetron Sputtered Ni-P-W Coatings .................................................................................................... 315 F-B. Wu, Y.-Y. Tsai and J.-G. Duh vii Oxidation/Corrosion/Nitridation/Diffusion Factors Controlling In-Plane Cracking of Thermal Barrier Coatings ............................... 327 Z. Zhang, J. Kameda, A.H. Swanson, S. Sakurai and M. Sato The Corrosion Behavior of PVD-Grown WC-(Ti1-xAlx) N Films Multilayers in 3.5%NaCl Solution ......................................................................................... 337 S.H. Ahn, J.H. Yoo, Y.S. Choi, J.G. Kim and J.G. Han Ferritic Nitrocarburising in Fludised Bed............................................................................. 347 D.M. Fabijanic, P.D. Hodgson and G.L. Kelly Surface Phenomena in Diffusion Limited Capillary Flow in a Reactive Porous Film .............................................................................................................................
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