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Noncovalent Bonds Through Sigma and Pi-Hole Located on the Same Molecule. Guiding Principles and Comparisons
molecules Review Noncovalent Bonds through Sigma and Pi-Hole Located on the Same Molecule. Guiding Principles and Comparisons Wiktor Zierkiewicz 1,* , Mariusz Michalczyk 1,* and Steve Scheiner 2 1 Faculty of Chemistry, Wrocław University of Science and Technology, Wybrzeze˙ Wyspia´nskiego27, 50-370 Wrocław, Poland 2 Department of Chemistry and Biochemistry, Utah State University Logan, Logan, UT 84322-0300, USA; [email protected] * Correspondence: [email protected] (W.Z.); [email protected] (M.M.) Abstract: Over the last years, scientific interest in noncovalent interactions based on the presence of electron-depleted regions called σ-holes or π-holes has markedly accelerated. Their high directionality and strength, comparable to hydrogen bonds, has been documented in many fields of modern chemistry. The current review gathers and digests recent results concerning these bonds, with a focus on those systems where both σ and π-holes are present on the same molecule. The underlying principles guiding the bonding in both sorts of interactions are discussed, and the trends that emerge from recent work offer a guide as to how one might design systems that allow multiple noncovalent bonds to occur simultaneously, or that prefer one bond type over another. Keywords: molecular electrostatic potential; halogen bond; pnicogen bond; tetrel bond; chalcogen bond; cooperativity Citation: Zierkiewicz, W.; Michalczyk, M.; Scheiner, S. Noncovalent Bonds through Sigma and Pi-Hole Located on the Same 1. Introduction Molecule. Guiding Principles and The concept of the σ-hole, introduced to a wide audience in 2005 at a conference in Comparisons. Molecules 2021, 26, Prague by Tim Clark [1], influenced a way of thinking about noncovalent interactions 1740. -
PM Curriculum Vitae
Prof. Dr. P. Melchiorre CV Curriculum Vitae Prof. Dr. Paolo Melchiorre (29/05/1973) - Italian ICREA Research Professor & ICIQ Senior Group Leader Institute of Chemical Research of Catalonia (ICIQ) Tarragona – Spain. E-mail: [email protected] Web site: http://www.iciq.org/research/research_group/prof-paolo-melchiorre/ Twitter handle: @MelchiorreGroup Researcher ID: K-9301-2014 [link] – ORCID: 0000-0001-8722-4602 The following list summarises the most important steps of his educational and professional career: MSc in Chemistry University of Bologna (Italy) 1993-1999 PhD in Chemical Sciences University of Bologna 2000-2003 Research Period at Centre for Catalysis University of Århus (DK) 2002 Postdoctoral Fellow in Chemistry University of Bologna 2003-2006 Assistant Professor University of Bologna 2007-2009 Research Professor & Group Leader ICIQ – Tarragona (Spain) Sept.2009-present Main Professional Experience September 2009 PM moved to the Institute of Chemical Research of Catalonia (ICIQ) in Tarragona as an ICREA (Catalan Institution of Research and Advanced Studies) Professor and ICIQ Senior Group Leader. October 2007 Assistant Professor (Ricercatore) at Bologna University – Alma Mater Studiorum (Italy) - Dept. of Organic Chemistry, Industrial Chemistry Faculty Research Record Paolo Melchiorre has authored more than 95 publications in international journals with a high impact factor (e.g. 27 × Angewandte Chemie, 2 × Nature, 1 × PNAS, 1 × Nature Chemistry, 1 × Nature Protocols, 5 × the Journal of American Chemical Society, 2 × Chemical Science, 8 × Organic Letters, 4 × Chemistry European Journal and 5 × Chemical Communication) and four book chapters. His papers have attracted more than 6350 citations (source: ISI-Web of Science as of March 15, 2016) h factor = 46 PM has delivered more than 100 invited lectures and seminars at the national and international level. -
Annual Report: CY2018 Chempubsoc Europe
1 Annual Report: CY2018 ChemPubSoc Europe Growth, change, awards, and sponsorship More scientists, more publications, more competition. As in the past, growth continued unabated worldwide in 2018 and is also reflected in the performance metrics of the ChemPubSoc Europe / Wiley-VCH publishing program, which now consists of 16 titles. The most recent product, ChemSystemsChem, was announced in Fall 2018. In 2018, the journals that are co-owned by ChemPubSoc Europe societies published nearly 9,000 articles (excluding contributions to the online publication ChemViews Magazine). Compared to the previous year, manuscript submissions grew by 12%, and the number of published articles rose by approximately 5%. A record number of full-text downloads, >8.9 million, was witnessed for the ChemPubSoc Europe journals, with increases in usage compared to the same time last year; notable among them ca. +20–30% for ChemCatChem, ChemElectroChem, ChemMedChem, and ChemPlusChem; and ca. +70% for ChemistrySelect and ChemPhotoChem. Approximately 3% of articles published in ChemPubSoc Europe's hybrid journals in 2018 were open access: ca. 10% at ChemBioChem and ca. 5% at ChemCatChem, Chemistry—A European Journal, ChemMedChem, and ChemPhysChem, respectively. ChemPubSoc Europe's gold open access journal, ChemistryOpen, experienced a ca. 47% growth in submissions compared to 2017. Generational change After the retirement of Peter Gölitz in November 2017, additional responsibility was taken on by Guido Herrmann (VP, Co-Managing Director Wiley-VCH, since April 1, 2017), Eva Wille (VP, Executive Director Wiley-VCH), Neville Compton (Editor-in-Chief of Angewandte Chemie and publisher for the GDCh journals), Haymo Ross (Editor-in-Chief of Chemistry—A European Journal and publisher of the ChemPubSoc Europe journals), Theresa Kueckmann (Editor-in-Chief of Chemistry—An Asian Journal and publisher for the Asian Chemical Editorial Society (ACES) journals), and Greta Heydenrych (development of new journals). -
Chemcatchem 11/2016
On these pages, we feature aselection computer,click on any of the items to of the excellent work that has recently read the full article. Otherwise please been published in our sister journals. see the DOIs for easy online access If you are reading these pages on a through Wiley Online Library. Gold Nanorod Analysis B. J. Plowman, N. P. Young, C. Batchelor-McAuley,R.G.Compton* Nanorod Aspect Ratios Determined by the Nano-Impact Technique Shapingup:The electrochemical determination of the aspectratio of gold nanorods on an individual basis through nano-impact ex- periments is demonstrated. The measured dimensions are in excel- lent agreement with electron microscopy results, establishing the use of nanoparticleimpact electrochemistry for the characterization of anisotropic nanomaterials. Angew.Chem. Int. Ed. DOI: 10.1002/anie.201602867 Graphene F. Wan, Y.-H. Li, D.-H. Liu, J.-Z. Guo, H.-Z. Sun, J.-P.Zhang,*X.-L. Wu* Alkali-Metal-Ion-Functionalized Graphene Oxide as aSuperior AnodeMaterial for Sodium-Ion Batteries Superior Na-storage properties of unreduced graphene oxide (GO) by asimple andscalable alkali-metal-ion (Li+,Na+,K+)-functional- ized process has been achieved. Different alkali metal ions play dif- ferent roles on adjusting the structure and Na-storage properties, and the GNa electrode exhibits much improved electrochemical properties in terms of higherrate performance and longer cycle sta- Chem. Eur.J. bility compared to GO, GLi, andGK(see figure). DOI: 10.1002/chem.201600660 Ruthenium Complexes K. Isozaki,* T. Yokoi, R. Yoshida, K. Ogata, D. Hashizume, N. Yasuda, K. Sadakane, H. Takaya,* M. Nakamura* Synthesis and Applicationsof (ONO Pincer)Ruthenium-Complex-BoundNorvalines ONO?OYes! (ONO pincer)ruthenium-complex-bound norvalines were successfully synthesized as anew type of bioorganometallic material. -
Spotlights on Our Sister Journals: Chemcatchem 14/2016
On these pages, we feature aselection computer,click on any of the items to of the excellent work that has recently read the full article. Otherwise please been published in our sister journals. see the DOIs for easy online access If you are reading these pages on a through Wiley Online Library. Redox Chemistry B. Bagh, D. L. J. Broere, M. A. Siegler,J.I.van der Vlugt* Redox-Active-Ligand-MediatedFormation of an Acyclic Trinuclear Ruthenium Complex with Bridging Nitrido Ligands Three strikes aN2dyou’re out! The spontaneousazide decomposi- tion on mononuclear ruthenium complexes bearing aredox-active aminophenol-derived tridentate NNO ligand selectively generates a rare trinuclearcomplex with an unsymmetric Ru=N Ru N=Ru skele- À À ton, proposedly by oxidative nitride coupling. DFTand experimental data support apivotal role for the NNO ligand. The bridging bis- (nitrido) complex is reactive towards H2 and hydrogen-atom donor Angew.Chem. Int. Ed. species. DOI: 10.1002/anie.201603659 ArtificialPhotosynthesis H. Zhou,* R. Yan, D. Zhang,T.Fan* Challenges and Perspectives in Designing Artificial Photosynthetic Systems Let’slearn from nature:The developmentofartificial photosyn- thetic systems for water splitting and CO2 reduction on alarge scale for practical applications is the ultimategoal towards asustainable world. This Concepthighlights the state-of-the-artresearch trends of artificial-photosynthesis concepts and designsfrom some new Chem. Eur.J. perspectives. DOI: 10.1002/chem.201600289 Polymer Solar Cells Q. Wang, S. Zhang, B. Xu,* L. Ye,H.Yao, Y. Cui, H. Zhang,W.Yuan,* J. Hou* Effectively Improving Extinction Coefficient of Benzodithiophene and Benzodithiophenedione-based PhotovoltaicPolymerby GraftingAlkylthio Functional Groups What adifference an Smakes:Alkylthio substitution on the conju- gated thiopheneside chains in benzodithiophene(BDT) and benzo- dithiophenedione (BDD)-based photovoltaic polymer can effectively improvethe extinction coefficient. -
A Review of Battery Materials As CDI Electrodes for Desalination
water Review A Review of Battery Materials as CDI Electrodes for Desalination Yuxin Jiang 1, Sikpaam Issaka Alhassan 1, Dun Wei 1 and Haiying Wang 1,2,3,* 1 Department of Environmental Engineering, School of Metallurgy and Environment, Central South University, Changsha 410083, China; [email protected] (Y.J.); [email protected] (S.I.A.); [email protected] (D.W.) 2 Chinese National Engineering Center for Control and Treatment of Heavy Metals Pollution, Changsha 410083, China 3 Water Pollution Control Technology Key Lab of Hunan Province, Changsha 410083, China * Correspondence: [email protected]; Tel.: +86-0731-8883-0511 Received: 15 September 2020; Accepted: 19 October 2020; Published: 28 October 2020 Abstract: The world is suffering from chronic water shortage due to the increasing population, water pollution and industrialization. Desalinating saline water offers a rational choice to produce fresh water thus resolving the crisis. Among various kinds of desalination technologies, capacitive deionization (CDI) is of significant potential owing to the facile process, low energy consumption, mild working conditions, easy regeneration, low cost and the absence of secondary pollution. The electrode material is an essential component for desalination performance. The most used electrode material is carbon-based material, which suffers from low desalination capacity (under 15 mg g 1). However, · − the desalination of saline water with the CDI method is usually the charging process of a battery or supercapacitor. The electrochemical capacity of battery electrode material is relatively high because of the larger scale of charge transfer due to the redox reaction, thus leading to a larger desalination capacity in the CDI system. -
Journal Impact Factor (JCR 2018)
See discussions, stats, and author profiles for this publication at: https://www.researchgate.net/publication/323571463 2018 Journal Impact Factor (JCR 2018) Technical Report · March 2018 CITATIONS READS 0 36,968 1 author: Chunbiao Zhu Peking University 21 PUBLICATIONS 35 CITATIONS SEE PROFILE Some of the authors of this publication are also working on these related projects: Robust Saliency Detection via Fusing Foreground and Background Priors View project A Multilayer Backpropagation Saliency Detection Algorithm Based on Depth Mining View project All content following this page was uploaded by Chunbiao Zhu on 27 June 2018. The user has requested enhancement of the downloaded file. Journal Data Filtered By: Selected JCR Year: 2017 Selected Editions: SCIE,SSCI Selected Category Scheme: WoS Journal Eigenfactor Rank Full Journal Title Total Cites Impact Score 1 CA-A CANCER JOURNAL FOR CLINICIANS 28,839 244.585 0.066030 2 NEW ENGLAND JOURNAL OF MEDICINE 332,830 79.258 0.702000 3 LANCET 233,269 53.254 0.435740 4 CHEMICAL REVIEWS 174,920 52.613 0.265650 5 Nature Reviews Materials 3,218 51.941 0.015060 6 NATURE REVIEWS DRUG DISCOVERY 31,312 50.167 0.054410 7 JAMA-JOURNAL OF THE AMERICAN MEDICAL ASSOCIATION 148,774 47.661 0.299960 8 Nature Energy 5,072 46.859 0.020430 9 NATURE REVIEWS CANCER 50,407 42.784 0.079730 10 NATURE REVIEWS IMMUNOLOGY 39,215 41.982 0.085360 11 NATURE 710,766 41.577 1.355810 12 NATURE REVIEWS GENETICS 35,680 41.465 0.094300 13 SCIENCE 645,132 41.058 1.127160 14 CHEMICAL SOCIETY REVIEWS 125,900 40.182 0.275690 15 NATURE MATERIALS -
1/10 Institute of Chemistry
1/10 ASS.-PROF. PRIV.-DOZ. DR.RER.NAT. MÉLANIE HALL Institute of Chemistry · University of Graz Heinrichstrasse 28/II · 8010 Graz · Austria Tel.: +43-316-380-5479 · Fax.: +43-316-380-9840 Email: [email protected] English (fluent) | German (fluent) | French (native) MAIN AREAS OF RESEARCH Biocatalysis – Asymmetric Enzymatic Synthesis – Sustainable Bio-Based Technologies EDUCATION 2016 Habilitation (Priv.-Doz.) | Institute of Chemistry, University of Graz, Austria Field: organic chemistry (venia docendi) – related field: molecular biosciences 2007 Ph.D. (Dr.rer.nat.) | Institute of Chemistry, University of Graz, Austria 2004 M.Sc. (diplôme d’ingénieur) | École Nationale Supérieure de Chimie de Rennes (ENSCR), France 2003-2004 Master program ERASMUS | Faculty of Engineering (LTH), Lund University, Sweden 2000-2004 Engineering program | École Nationale Supérieure de Chimie de Rennes (ENSCR), France 1998-2000 French undergraduate studies for enrollment in engineering school (cycle préparatoire) | École Nationale Supérieure de Chimie de Rennes (ENSCR), France ACADEMIC EMPLOYMENT 2021- Assistant Professor of sustainable bioorganic synthetic chemistry | Institute of Chemistry, University of Graz, Austria 2017-2021 Independent group leader | Institute of Chemistry, University of Graz, Austria 2010-2016 University assistant | Institute of Chemistry, University of Graz, Austria 2010 Research scientist | School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, USA 2008-2010 Postdoctoral associate | School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, USA THIRD-PARTY FUNDING & COLLABORATIONS 2020-2023 Stand-Alone Project | Austrian Science Fund (FWF) Scouting Lactamases for Chemically Stable Lactams 2019-2020 Mobility Support | University of Évry Val D'Essonne, France Genome Sequencing for the Identification of Novel Enzymes Project partner: Prof. -
Liste Des Publications Équipe De Chimie Organique Pour Les Matériaux, La Biologie Et L’Optique Période 2013-2018
Liste des publications Équipe de Chimie Organique pour les Matériaux, la Biologie et l’Optique Période 2013-2018 -------------------------------------------------------------------------------------------------------------------------------------- Publications de 2018 Dyes and Pigments 2019, 163, 475–482. Jacquemin, Denis; Khelladi, Mustapha; De Nicola, Antoinette; Ulrich, Gilles Turning ESIPT-Based triazine fluorophores into dual emitters: From theory to experiment European Journal of Organic Chemistry (2018), Ahead of Print. , Ethynyl-Tolyl Extended 2- (2'-Hydroxyphenyl)benzoxazole Dyes: Solution and Solid-state Excited-State Intramolecular Proton Transfer (ESIPT) Emitters Munch, Maxime; Curtil, Mathieu; Verite, Pauline M.; Jacquemin, Denis; Massue, Julien; Ulrich, Gilles. Journal of Organic Chemistry 2018, 83, 14406-14418, Synthesis of Indolo[3,2-b]carbazole- Based Boron Complexes with Tunable Photophysical and Electrochemical Properties Mula, S.; Leclerc, N.; Leveque, P.; Retailleau, P.; Ulrich, G. Chemistry Letters 2018, 47, 1083-1089. Massue, J.; Jacquemin, D.; Ulrich, G. Molecular engineering of excited-state intramolecular proton transfer (ESIPT) dual and triple emitters. Dyes and Pigments 2019, 160, 915–922. Massue, J.; Felouat, A.; Curtil, M.; Vérité, P. M.; Jacquemin, D.; Ulrich, G. Solution and Solid-State Excited-State Intramolecular Proton Transfer (ESIPT) Emitters Incorporating Bis-Triethyl-or Triphenylsilylethynyl Units J. Mater. Chem. C 2018, 6 (37), 9925–9931. Huaulmé, Q.; Sutter, A.; Fall, S.; Jacquemin, D.; Lévêque, P.; Retailleau, P.; Ulrich, G.; Leclerc, N. Versatile Synthesis of α-Fused BODIPY Displaying Intense Absorption in the NIR Region and High Electron Affinity ChemistrySelect 2018, 3, 7674– 7679. Courrier, E.; Maret, C.; Charaoui-Boukerzaza, S.; Lambert, V.; De Nicola, A.; Muzuzu, W.; Ulrich, G. Raberin, H.; Flori, P.; Moine, B.; He, Z., Gain, P., Thuret G. -
Source Publication List for Web of Science
SOURCE PUBLICATION LIST FOR WEB OF SCIENCE SCIENCE CITATION INDEX EXPANDED Updated July 2017 Journal Title Publisher ISSN E-ISSN Country Language 2D Materials IOP PUBLISHING LTD 2053-1583 2053-1583 ENGLAND English 3 Biotech SPRINGER HEIDELBERG 2190-572X 2190-5738 GERMANY English 3D Printing and Additive Manufacturing MARY ANN LIEBERT, INC 2329-7662 2329-7670 UNITED STATES English 4OR-A Quarterly Journal of Operations Research SPRINGER HEIDELBERG 1619-4500 1614-2411 GERMANY English AAPG BULLETIN AMER ASSOC PETROLEUM GEOLOGIST 0149-1423 1558-9153 UNITED STATES English AAPS Journal SPRINGER 1550-7416 1550-7416 UNITED STATES English AAPS PHARMSCITECH SPRINGER 1530-9932 1530-9932 UNITED STATES English AATCC Journal of Research AMER ASSOC TEXTILE CHEMISTS COLORISTS-AATCC 2330-5517 2330-5517 UNITED STATES English AATCC REVIEW AMER ASSOC TEXTILE CHEMISTS COLORISTS-AATCC 1532-8813 1532-8813 UNITED STATES English Abdominal Radiology SPRINGER 2366-004X 2366-0058 UNITED STATES English ABHANDLUNGEN AUS DEM MATHEMATISCHEN SEMINAR DER UNIVERSITAT HAMBURG SPRINGER HEIDELBERG 0025-5858 1865-8784 GERMANY German ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY AMER CHEMICAL SOC 0065-7727 UNITED STATES English Academic Pediatrics ELSEVIER SCIENCE INC 1876-2859 1876-2867 UNITED STATES English Accountability in Research-Policies and Quality Assurance TAYLOR & FRANCIS LTD 0898-9621 1545-5815 UNITED STATES English Acoustics Australia SPRINGER 1839-2571 1839-2571 AUSTRALIA English Acta Bioethica UNIV CHILE, CENTRO INTERDISCIPLINARIO ESTUDIOS BIOETICA 1726-569X -
European Journal of Inorganic Chemistry 19/2013
19/2013 EurJIC 1st July Issue European Journal of Inorganic Chemistry Cover Picture Emmanuel Terazzi, Claude Piguet et al. Single-Stranded Dinuclear Lanthanide Helicates A Journal of www.eurjic.org EJICFK (19) 3271–3440 (2013) · ISSN 1099-0682 · No. 19/2013 CONTENTS Hungary Italy Germany Greece EurJIC is a journal of ChemPubSoc Europe, a union of 16 European chemical societies formed for the pur- pose of publishing high-quality Czech Republic France science. All owners merged their national journals to form two leading chemistry journals, the European Journal of Inorganic Sweden Belgium Chemistry and the European Journal of Organic Chemistry. Austria Portugal Poland Spain Netherlands Other ChemPubSoc Europe journals are Chemistry – A European Journal, ChemBioChem, ChemPhysChem, ChemMedChem, ChemSusChem, ChemCatChem, ChemPlusChem and ChemistryOpen. COVER PICTURE The cover picture shows how single-stranded di- nuclear lanthanide helicates (green) survive immer- sion into a drop of less polar solvent (e.g. CH2Cl2) and their eventual self-organization into a liquid- crystalline material. For alternative triple- stranded lanthanide helicates (red), drastic solvation effects lead to complete dissociation. Details are discussed in the article by E. Terazzi, C. Piguet et al. on p. 3323ff. For more on the story behind the cover research, see the Cover Profile. Eur. J. Inorg. Chem. 2013, 3273 3273 © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim FULL PAPER DOI:10.1002/ejic.201300176 Implementing Liquid-Crystalline Properties in Single- Stranded -
General Information
General Information Dear Author, Thank you for choosing ChemPlusChem for your publication. Please follow this step-by-step guide to help us publish your manuscript as quickly as possible. This document contains the following information: 1 Revising Manuscripts ............................................................................................................................ 2 2 Accepted Article .................................................................................................................................... 3 3 Graphics ................................................................................................................................................ 4 4 Submitting Cover Artwork .................................................................................................................... 5 Visit our homepage or contact the Editorial Office if you have any additional questions: Phone (+49) 6201-606-305 E-mail: [email protected] Homepage: http://www.chempluschem.org We look forward to the publication of your article! With kind regards, ChemPlusChem Editorial Team ChemPlusChem is a ChemPubSoc Europe journal published by Wiley-VCH. You may wish to consider sister journals from the ChemPubSoc Europe program for future papers. Visit http://www.chempubsoc.eu for more information on these journals: Chemistry – A European Journal, European Journal of Organic Chemistry, European Journal of Inorganic Chemistry, Batteries & Supercaps, ChemBioChem, ChemCatChem, ChemElectroChem, ChemMedChem, ChemPhotoChem,