DOCSLIB.ORG

Amorphous Chalcogenide Semiconductors and Related Materials

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Amorphous Chalcogenide Semiconductors and Related Materials Amorphous Chalcogenide Semiconductors and Related Materials Keiji Tanaka · Koichi Shimakawa Amorphous Chalcogenide Semiconductors and Related Materials 123 Keiji Tanaka Koichi Shimakawa Graduate School of Engineering Faculty of Engineering Department of Applied Physics Gifu University Hokkaido University Yanaido Kita-ku Gifu 501-1193, Japan Sapporo 060-8628, Japan and [email protected] Nagoya Industrial Science Institute Nagoya 460-0008, Japan [email protected] ISBN 978-1-4419-9509-4 e-ISBN 978-1-4419-9510-0 DOI 10.1007/978-1-4419-9510-0 Springer New York Dordrecht Heidelberg London Library of Congress Control Number: 2011926594 © Springer Science+Business Media, LLC 2011 All rights reserved. This work may not be translated or copied in whole or in part without the written permission of the publisher (Springer Science+Business Media, LLC, 233 Spring Street, New York, NY 10013, USA), except for brief excerpts in connection with reviews or scholarly analysis. Use in connection with any form of information storage and retrieval, electronic adaptation, computer software, or by similar or dissimilar methodology now known or hereafter developed is forbidden. The use in this publication of trade names, trademarks, service marks, and similar terms, even if they are not identified as such, is not to be taken as an expression of opinion as to whether or not they are subject to proprietary rights. Printed on acid-free paper Springer is part of Springer Science+Business Media (www.springer.com) Preface Photonic, electronic, and photo-electric applications of non-crystalline1 solids are rapidly growing in recent years. Such growth seems to synchronize with the devel- opment of oxide glass1 fibers and related devices for optical communications, which started near the end of the last century. Otherwise, we can trace its growth back to the use of amorphous1 Se films at around 1950 as xerographic photoreceptors in copy- ing machines. In addition, recent applications of thin films, including Ge–Sb–Te to digital versatile disks (DVDs) and amorphous hydrogenated Si (a-Si:H) to solar cells and thin-film transistors (TFTs), are remarkable. On the other hand, we also know that fundamental studies on amorphous chalcogenide semiconductor have yielded several universal and revolutionary concepts such as “mobility edge” and “magic coordination number,” and some of these concepts have been applied to other mate- rials. The authors therefore believe that, to study fundamentals and applications of non-crystalline insulators and semiconductors, amorphous chalcogenides2 such as Se, As2S3, and Ge–Sb–Te continue to be instructive and valuable substances. The aim of this monograph is to be an introductory textbook in amorphous chalcogenide and related materials. This text will be suitable for graduate students. Actually, KT has used this text (unpublished versions) in seminars for graduate students, who start to study amorphous materials in the departments of applied physics, inorganic chemistry, and electronics. The present text will also be valuable to researchers working on related materials such as oxides, a-Si:H films, and organic semiconductors. This book also serves in comparative understandings of amor- phous and crystalline semiconductors. The readers will see that, for such purposes, chalcogenide could be a good bridging material, since some simple compounds can be obtained in both crystalline and non-crystalline forms. Of course, for materials and topics dealt with in this book, several excellent books, listed at the end of the Preface, are already available. However, those are more or less difficult or detailed for students and research beginners. Zallen’s book (1983) gives a good introduction 1These terminologies are defined in Section 1.1. 2Oxford English Dictionary defines “chalco” as a stem, which is a combining form of Greek χαλκóς (copper and brass), and “gen” as an adjective suffix giving the sense “born in a certain place or condition.” We know that minerals such as Cu2S may be an origin of “chalcogen.” v vi Preface for students and researchers, while the content is focused on some fundamental sub- jects. The authors, therefore, have tried to write a book on glassy semiconductor on the level of the book Introduction to Solid State Physics by Kittel. The present book treats disordered solids, exemplified in Fig. 1, and its related applications in Table 1. To keep the total page into an appropriate length, we will proceed as follows: Experimental methods may be briefly sketched. We then look at fundamental observations, trying to grasp their interpretations from unified standpoints and to draw simple pictures as possible. We will try to bridge atomic structures and physical properties (Fig. 2). In such ways, relationships among dif- ferent macroscopic properties can be understood. The authors have also tried to point out the remaining and controversial problems. We will consider the amorphous chalcogenide material from two standpoints: One is as a kind of glass. At present, we utilize at least three kinds of photonic (highly pure) glasses, which are the oxide, chalcogenide, and halide, all these being treated as (semi-)transparent insulators. In these three kinds of glasses, both Si(Ge) Si(Ge)O2 – As2O3 GeS(Se)2 – As2S(Se,Te)3 – S(Se,Te) Ge-Sb-Te, Ag(Cu)-As-S(Se) Fig. 1 Relationships between materials of interest. Si(Ge) is tetrahedrally coordinated, producing three-dimensional networks. Inserting O to ≡Si−Si≡ bonds produces ≡Si−O−Si≡ connections, giving three-dimensional continuous random SiO2 networks. GeO2 has structures similar to that in SiO2. O can be changed to S, Se, and Te, producing GeS(Se,Te)2. With a change in the cation from Ge to As, the atomic coordination number decreases from 4 to 3, giving As2O(S,Se,Te)3. And, in pure S(Se,Te), the structure is molecular as rings and polymeric chains Table 1 Typical materials and related applications described in this text. For abbreviations, see the text Film Bulk Insulator SiO2 (fiber) Semiconductor Se (vidicon, x-ray imager) Ge2Sb2Te5 (DVD) a-Si:H (solar cell, TFT) Elastic Electrical Optical Density constant conductivity transparency ATOMIC STRUCTURE Fig. 2 A goal of solid-state science, which intends to give universal understandings of macro- scopic properties through simple theories on the basis of known atomic structures Preface vii oxygen (O) and chalcogens (S, Se, and Te) belong to the group VIb (16) atoms in the periodic table. Accordingly, the oxide and chalcogenide glasses possess many common features, which will be understood from a unified point of view. In addi- tion, in these glasses, simple compositions such as SiO2 and As2Se3, which also solidify into crystals, are available. And, for the crystal we have had firmer sci- entific knowledge. Therefore, the group VIb glass can be an interesting target for understanding the glass property through comparisons with that of the correspond- ing crystal. We also mention here that the chalcogenide glass containing group I (1 and 11) atoms such as Li and Ag also exhibits (super)ionic conduction. The other aspect of chalcogenide is as a kind of amorphous semiconductor. As an amorphous semiconductor (or photoconductor), we had utilized a-Se pho- toreceptors in copying machines, although it has now been taken over by organic photoconductors. We have also developed phase-change memories using Ge–Sb–Te films. In fundamentals, a lot of concepts such as the mobility edge, charged defects, and Phillip’s magic number have been proposed. Applications of these concepts to other materials will extend our total understanding of the solid-state science. Nevertheless, amorphous semiconductor physics has remained far behind that of crystalline. Actually, famous texts on solid-state physics, by Kittel for example, deal mostly with single crystals. The reader may notice that the first (glass) and the second (amorphous semi- conductor) standpoints mentioned above have been taken mainly by chemists and physicists, respectively. They also tend to employ different words for pointing nearly the same concepts, e.g., LUMO (lowest unoccupied molecular orbital)–HOMO (highest occupied molecular orbital) in molecular chemistry and conduction– valence bands in physics. However, an important fact here is the interplay between bond and band, developed by Phillips in the famous book, Bonds and Bands in Semiconductors. We will try to take such an approach in the present text. We list several books published in the present and related fields. Written by Physicists J. Tauc, Amorphous and Liquid Semiconductors (Plenum, London, 1974). N.F. Mott and E.A. Davis, Electronic Processes in Non-Crystalline Materials, 2nd Ed. (Clarendon, Oxford, 1979). J.M. Ziman, Models of Disorder (Cambridge University Press, Oxford, 1979). R. Zallen, The Physics of Amorphous Solids (Wiley, New York, NY, 1983). S.R. Elliott, Physics of Amorphous Materials, 2nd Ed. (Longman Scientific & Technical, Essex, 1990). K. Morigaki, Physics of Amorphous Semiconductors (World Scientific, Singapore, 1999). M.A. Popescu, Non-Crystalline Chalcogenides (Kluwer, Dordrecht, 2000). J. Singh and K. Shimakawa, Advances in Amorphous Semiconductors (Taylor & Francis, London, 2003). viii Preface Written by Chemists Z.U. Borisova, Glassy Semiconductors (Plenum, New York, NY, 1981). A. Feltz, Amorphe und Glasartige Anorganische Festkrper (Akademie-Verlag, Berlin, 1983). R.H. Doremus, Glass Science, 2nd Ed. (Wiley, New York, NY, 1994). V.F. Kokorina, Glasses for Infrared Optics (CRC, Boca Raton, FL, 1996). M. Yamane and Y. Asahara, Glasses for Photonics (Cambridge University Press, Cambridge, 2000). Edited Volumes J. Zarzycki (Ed.), Materials Science and Technology Vol. 9, Glasses and Amorphous Materials (VCH, Weinheim, 1991). G. Pacchioni, L. Skuja, and D.L. Griscom (Eds.), Defects in SiO2 and Related Dielectrics: Science and Technology (Kluwer, Dordrecht, 2000). H.S. Nalwa (Ed.), Handbook of Advanced Electronic and Photonic Materials and Devices Vol. 5 (Academic, San Diego, CA, 2001). A.V. Kolobov (Ed.), Photo-Induced Metastability in Amorphous Semiconductors (Wiley-VCH, Weinheim, 2003). G. Lucovsky and M. Popescu (Eds.), Non-Crystalline Materials for Optoelectronics Vol.
Load more

Recommended publications
  • Conductive-Bridging Random Access Memory
    Jana et al. Nanoscale Research Letters (2015) 10:188 DOI 10.1186/s11671-015-0880-9 NANO REVIEW Open Access Conductive-bridging random access memory: challenges and opportunity for 3D architecture Debanjan Jana1, Sourav Roy1, Rajeswar Panja1, Mrinmoy Dutta1, Sheikh Ziaur Rahaman1, Rajat Mahapatra1,2 and Siddheswar Maikap1* Abstract The performances of conductive-bridging random access memory (CBRAM) have been reviewed for different switching materials such as chalcogenides, oxides, and bilayers in different structures. The structure consists of an inert electrode and one oxidized electrode of copper (Cu) or silver (Ag). The switching mechanism is the formation/dissolution of a metallic filament in the switching materials under external bias. However, the growth dynamics of the metallic filament in different switching materials are still debated. All CBRAM devices are switching under an operation current of 0.1 μAto 1mA,andanoperationvoltageof±2Visalsoneeded.Thedevice can reach a low current of 5 pA; however, current compliance-dependent reliability is a challenging issue. Although a chalcogenide-based material has opportunity to have better endurance as compared to an oxide-based material, data retention and integration with the complementary metal-oxide-semiconductor (CMOS) process are also issues. Devices with bilayer switching materials show better resistive switching characteristics as compared to those with a single switching layer, especially a program/erase endurance of >105 cycles with a high speed of few nanoseconds. Multi-level cell operation is possible, but the stability of the high resistance state is also an important reliability concern. These devices show a good data retention of >105 s at >85°C. However, more study is needed to achieve a 10-year guarantee of data retention for non-volatile memory application.
    [Show full text]
  • UCLA Electronic Theses and Dissertations
    UCLA UCLA Electronic Theses and Dissertations Title Electrochemical Performance of Titanium Disulfide and Molybdenum Disulfide Nanoplatelets Permalink https://escholarship.org/uc/item/73h6h1z6 Author Siordia, Andrew F. Publication Date 2016 Peer reviewed|Thesis/dissertation eScholarship.org Powered by the California Digital Library University of California UNIVERSITY OF CALIFORNIA Los Angeles Electrochemical Performance of Titanium Disulfide and Molybdenum Disulfide Nanoplatelets A thesis submitted in partial satisfaction of the requirements of the degree Master of Science in Materials Science and Engineering by Andrew Francisco Siordia 2016 ABSTRACT OF THESIS Electrochemical Performance of Titanium Disulfide and Molybdenum Disulfide Nanoplatelets by Andrew Francisco Siordia Master of Science in Materials Science and Engineering University of California, Los Angeles, 2016 Professor Bruce S. Dunn, Chair Single layer crystalline materials, often termed two-dimension (2D) materials, have quickly become a popular topic of research interest due to their extraordinary properties. The intrinsic electrical, mechanical, and optical properties of graphene were found to be remarkably distinct from graphite, its bulk counterpart. In conjunction with newfound processing techniques, there is renewed interest in elucidating the structure-property relationships of other 2D materials ii like the transition metal dichalcogenides (TMDCs). The energy storage capability of 2D nanoplatelets of TiS2 and MoS2 are studied here providing a contrast with investigations of corresponding bulk materials in the early 1970s. TiS2 was synthesized into nanoplatelets using a hot injection route which provided a capacity of ~143mAhg-1 from thin film electrodes as determined by cyclic voltammetry measurements. Phase identification using X-ray diffraction, scanning electron microscopy, and transmission electron microscopy to complement the electrochemical performance and impurity identification is presented.
    [Show full text]
  • L. Arulmurugan, M. Ilangkumaran " Experimental Study on Graphene/Transition Metal Chalcogenide Based Energy Storage and Conversion
    Journal of Ovonic Research Vol. 16, No. 4, July - August 2020, p. 197 - 211 EXPERIMENTAL STUDY ON GRAPHENE/TRANSITION METAL CHALCOGENIDE BASED ENERGY STORAGE AND CONVERSION L. ARULMURUGANa, *, M. ILANGKUMARANb, aDepartment of Electronics and Communication Engineering, Bannari Amman Institute of Technology, Sathyamangalam, Erode, Tamilnadu, India bDepartment of Mechatronics Engineering, K S Rangasamy College of Technology, Tiruchengode, Tamilnadu, India The ever-increasing energy demand and the shortage of fossil fuels force the researchers to do research on utilization and conversion of renewable energy sources. In Recent years, the graphene and Transition Metal Chalcogenide (TMC) based Phase Change material (PCM) have been reviewed towards the future energy storage and energy conversion. This PCM is considered as a promising pathway to alleviate the energy crisis. The TMC material is considered as an emerging material due to their optoelectronic behavior and stability of the material. Moreover, the integration of TMC with graphene, significantly improve the performance of the system. The storage of solar energy in the form of sensible and latent heat has become an important aspect of energy management. To improve the performance of domestic solar water heater system, the vertical spiral and cylindrical heat exchanger is designed. The spiral module and cylindrical modules filled with and without PCM are analyzed and the obtained results are compared with each other. The results show that the spiral and cylindrical heat exchanger filled with PCM store and release the thermal energy efficiently and it performs the desired functions than the without PCM module. (Received April 28, 2020; Accepted July 14, 2020) Keywords: Graphene/transition metal chalcogenide, Phase change material, Thermal management, Heat exchanger, Spiral and cylindrical module 1.
    [Show full text]
  • Growth of Metal Chalcogenide Nanomaterials and Their Characterizations Yichao Zou Bachelor of Engineering
    Growth of Metal Chalcogenide Nanomaterials and Their Characterizations Yichao Zou Bachelor of Engineering A thesis submitted for the degree of Doctor of Philosophy at The University of Queensland in 2016 School of Mechanical and Mining Engineering Abstract Metal chalcogenides, such as IV-VI and V-VI compounds (SnTe, Bi2Te3, Bi2Se3), are ideal candidates for applications in thermoelectricity and topological (crystalline) insulators. This PhD thesis focuses on the controllable synthesis of metal chalcogenide nanostructures via chemical vapour deposition method (CVD), and on the understanding of the crystal structure, growth mechanism, and structure-property correlation in the as-grown nanomaterials. IV-VI and V-VI compounds have attracted extensive research interest because of their excellent thermoelectric properties and exotic physical properties. Nevertheless, there still exist unresolved issues that prevent the further applications of IV-VI and V-VI nanomaterials by rational design, including (1) it is still difficult to grow these nanomaterials with controllable morphology and (2) crystal structure; (3) limited investigations of their growth mechanisms; (4) limited study on structure-property relationships in the nanostructures. Therefore, in this thesis, the controllable growth technique, growth mechanism and structure-property relation in IV-VI and V-VI based nanostructures are explored. The objective is achieved in the following steps: Realizing the morphological control of the nanostructures. (i) By catalyst engineering in Au-catalysed CVD. For SnTe nanostructures, catalyst composition was found to be a key factor controlling the morphology. AuSn catalysts induce growth of triangular SnTe nanoplates, whereas Au5Sn catalysts result in <010> SnTe NWs. For Bi2Se3 nanostructures, catalyst-nanostructure interface was found to have an impact on their growth directions.
    [Show full text]
  • Crystallization Kinetics of Chalcogenide Glasses
    2 Crystallization Kinetics of Chalcogenide Glasses Abhay Kumar Singh Department of Physics, Banaras Hindu University, Varanasi, India 1. Introduction 1.1 Background of chalcogenides Chalcogenide glasses are disordered non crystalline materials which have pronounced tendency their atoms to link together to form link chain. Chalcogenide glasses can be obtained by mixing the chalcogen elements, viz, S, Se and Te with elements of the periodic table such as Ga, In, Si, Ge, Sn, As, Sb and Bi, Ag, Cd, Zn etc. In these glasses, short-range inter-atomic forces are predominantly covalent: strong in magnitude and highly directional, whereas weak van der Waals' forces contribute significantly to the medium-range order. The atomic bonding structure is, in general more rigid than that of organic polymers and more flexible than that of oxide glasses. Accordingly, the glass-transition temperatures and elastic properties lay in between those of these materials. Some metallic element containing chalcogenide glasses behave as (super) ionic conductors. These glasses also behave as semiconductors or, more strictly, they are a kind of amorphous semi-conductors with band gap energies of 1±3eV (Fritzsche, 1971). Commonly, chalcogenide glasses have much lower mechanical strength and thermal stability as compared to existing oxide glasses, but they have higher thermal expansion, refractive index, larger range of infrared transparency and higher order of optical non-linearity. It is difficult to define with accuracy when mankind first fabricated its own glass but sources demonstrate that it discovered 10,000 years back in time. It is also difficult to point in time, when the field of chalcogenide glasses started.
    [Show full text]
  • United States Patent to 4,009,052 Whittingham 45 Feb
    United States Patent to 4,009,052 Whittingham 45 Feb. 22, 1977 54 CHALCOGENIDE BATTERY the anode-active material a metal selected from the group consisting of Group la metals, Group Ib metals, (75. Inventor: M. Stanley Whittingham, Fanwood, Group IIa metals, Group IIb metals, Group IIIa metals N.J. and Group IVa metals (lithium is preferred), the cath 73) Assignee: Exxon Research and Engineering ode contains as the cathode-active material a chalco Company, Linden, N.J. genide of the formula MZ wherein M is an element selected from the group consisting of titanium, zirco 22 Filed: Apr. 5, 1976 nium, hafnium, niobium, tantalum and vanadium (tita nium is preferred); Z is an element selected from the (21 Appl. No.: 673,696 group consisting of sulfur, selenium and tellurium, and x is a numerical value between about 1.8 and about 2. 1, Related U.S. Application Data and the electrolyte is one which does not chemically 63 Continuation-in-part of Ser. No. 552,599, Feb. 24, react with the anode or the cathode and which will 1975, abandoned, which is a continuation-in-part of permit the migration of ions from said anode-active Ser. No. 396,051, Sept. 10, 1973, abandoned. material to intercalate the cathode-active material. A highly useful battery may be prepared utilizing lithium (52) U.S. Cl. ............................... 429/191; 429/193; as the anode-active material, titanium disulfide as the 429/194; 429/199; 429/218; 429/229 cathode-active material and lithium perchlorate dis (51) Int. Cl’........................................ H01M 35/02 solved in tetrahydrofuran (70%) plus dimethoxyethane.
    [Show full text]
  • Applications of Chalcogenide Glasses: an Overview
    International Journal of ChemTech Research CODEN (USA): IJCRGG ISSN : 0974-4290 Vol.6, No.11, pp 4682-4686, Oct-Nov 2014 Applications of Chalcogenide Glasses: An Overview Suresh Sagadevan*1 and Edison Chandraseelan2 *1Department of Physics, Sree Sastha Institute of Engineering and Technology, Chennai-600 123, India 2 Department of Mechanical Engineering, Sree Sastha Institute of Engineering and Technology, Chennai--600 123, India *Corres.author: [email protected] Abstract: Chalcogenides are compounds formed predominately from one or more of the chalcogen elements; sulphur, selenium and tellurium. Although first studied over fifty years ago, interest in chalcogenide glasses has, over the past few years, increased significantly as glasses, crystals and alloys find new life in a wide range of optoelectronic devices applications. Following the development of the glassy chalcogenide field, new optoelectronic materials based on these materials have been discovered. Several non-oxide glasses have been prepared and investigated in the last several decades, thus widening the groups of chalcogen materials used in various optical, electronic and optoelectronic glasses. This paper reviews the development of chalcogenide glasses, their physical properties and applications in electronics and optoelectronics. The glassy, amorphous and disordered chalcogenide materials, which are important for optoelectronic applications, are discussed. This paper also deals with an overview of representative applications these exciting optoelectronic materials. 1. Introduction The name chalcogenide originates from the Greek word “chalcos” meaning ore and “gen” meaning formation, thus the term chalcogenide is generally considered to mean ore former [1]. The elements of group sixteen of the periodic table is known as the chalcogens. The group consists of oxygen, sulphur, selenium, tellurium and polonium though oxygen is not included in the chalcogenide category.
    [Show full text]
  • WS2: a New Window Layer Material for Solar Cell Application Md
    www.nature.com/scientificreports OPEN WS2: A New Window Layer Material for Solar Cell Application Md. Khan Sobayel Bin Rafq 1, N. Amin2,3*, Hamad F. Alharbi4*, Monis Luqman 4, Afda Ayob2, Yahya S. Alharthi5, Nabeel H. Alharthi5, Badariah Bais2 & Md. Akhtaruzzaman1,2* Radio frequency (RF) magnetron sputtering was used to deposit tungsten disulfde (WS2) thin flms on top of soda lime glass substrates. The deposition power of RF magnetron sputtering varied at 50, 100, 150, 200, and 250 W to investigate the impact on flm characteristics and determine the optimized conditions for suitable application in thin-flm solar cells. Morphological, structural, and opto-electronic properties of as-grown flms were investigated and analyzed for diferent deposition powers. All the WS2 flms exhibited granular morphology and consisted of a rhombohedral phase with a strong preferential orientation toward the (101) crystal plane. Polycrystalline ultra-thin WS2 flms with bandgap of 2.2 eV, carrier concentration of 1.01 × 1019 cm−3, and resistivity of 0.135 Ω-cm were successfully achieved at RF deposition power of 200 W. The optimized WS2 thin flm was successfully incorporated as a window layer for the frst time in CdTe/WS2 solar cell. Initial investigations revealed that the newly incorporated WS2 window layer in CdTe solar cell demonstrated photovoltaic conversion efciency of 1.2% with Voc 2 of 379 mV, Jsc of 11.5 mA/cm , and FF of 27.1%. This study paves the way for WS2 thin flm as a potential window layer to be used in thin-flm solar cells. For many decades, transition metal dichalcogenides (TMDCs) are among the promising materials in a wide range of applications, but their superior performance in complex applications has attracted extensive research atten- tion.
    [Show full text]
  • Mid-Infrared Supercontinuum Generation in Chalcogenide Glass Fibers: a Brief Review Yingying Wang1,2,3 and Shixun Dai1,2,3*
    Wang and Dai PhotoniX (2021) 2:9 https://doi.org/10.1186/s43074-021-00031-3 PhotoniX REVIEW Open Access Mid-infrared supercontinuum generation in chalcogenide glass fibers: a brief review Yingying Wang1,2,3 and Shixun Dai1,2,3* * Correspondence: daishixun@nbu. edu.cn Abstract 1Laboratory of Infrared Material and Devices, The Research Institute of Chalcogenide (ChG) glasses have the characteristics of a wide transparency window 3 Advanced Technologies, Ningbo (over 20 μm) and high optical nonlinearity (up to 10 times greater than that of silica University, Ningbo 315211, China glasses), exhibiting great advantages over silica and other soft glasses in optical 2Key Laboratory of Photoelectric Materials and Devices of Zhejiang property at mid-infrared (MIR) wavelength range. These make them excellent Province, Ningbo 315211, China candidates for MIR supercontinuum (SC) generation. Over the past decades, great Full list of author information is progress has been made in MIR SC generation based on ChG fibers in terms of available at the end of the article spectral extension and output power improvement. In this paper, we introduce briefly the properties of ChG glasses and fibers including transmission, nonlinearity, and dispersion, etc. Recent progress in MIR SC generation based on ChG fibers is reviewed from the perspective of pump schemes. We also present novel ChG fibers such as As-free, Te-based, and chalcohalide fibers, which have been explored and employed as nonlinear fibers to achieve broadband SC generation. Moreover, the potential applications of MIR SC sources based on ChG fibers are discussed. Keywords: Chalcogenide glass fiber, Supercontinuum generation, Mid-infrared, Nonlinear optics Introduction Supercontinuum (SC) generation in nonlinear media originates from the interaction of ultrashort pulses and the dispersion and nonlinear effects, such as self-phase modula- tion (SPM), four wave mixing, stimulated Raman scattering (SRS), soliton self- frequency shift, etc.
    [Show full text]
  • Chalcogenide Glass Materials for Integrated Infrared Photonics
    Chalcogenide Glass Materials for Integrated Infrared Photonics by Vivek Singh B.S. Materials Science and Engineering Columbia University, 2009 Submitted to the Department of Materials Science and Engineering in Partial Fulfillment of the Requirements for the Degree of DOCTOR OF PHILOSOPHY at the MASSACHUSETTS INSTITUTE OF TECHNOLOGY September 2015 © 2015 Massachusetts Institute of Technology. All rights reserved. Signature of Author:_________________________________________ Department of Materials Science and Engineering July 20, 2015 Certified by:_____________________________________________ Lionel C. Kimerling Thomas Lord Professor of Materials Science and Engineering Thesis Supervisor Certified by:_____________________________________________ Anuradha M. Agarwal Principal Research Scientist, Materials Processing Center Thesis Supervisor Accepted by:_____________________________________________ Donald Sadoway Chair, Departmental Committee on Graduate Students 2 Chalcogenide Glass Materials for Integrated Infrared Photonics by Vivek Singh Submitted to the Department of Materials Science and Engineering on July 20, 2015 in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy in Materials Science and Engineering Abstract Chalcogenide glasses (ChGs) are amorphous compounds containing the chalcogen elements (S, Se, Te) and exhibit wide infrared transparency windows. They are easy to synthesize in bulk and thin film forms and their compositional flexibility allows tuning of optical properties such as refractive index making them ideal for infrared photonics. We have studied the material attenuation in ChGs that arises due to the presence of impurities in the raw materials and established UV photolithography-based process flows that enable fabrication of chalcogenide glass waveguides and microresonators for near- and mid-IR wavelength ranges. Waveguides and optical resonators are key microphotonic elements for many on-chip applications such as telecommunications and chemical sensing.
    [Show full text]
  • Do Doubly Charged Monatomicanions Exist in Aqueous Solutions?
    Archives of Organic and Inorganic L UPINE PUBLISHERS Chemical Sciences Open Access DOI: 10.32474/AOICS.2018.02.000134 ISSN: 2637-4609 Opinion Do Doubly Charged Monatomicanions Exist in Aqueous Solutions? *Yizhak Marcus Institute of Chemistry, The Hebrew University of Jerusalem, Israel Received: March 13, 2018; Published: March 21, 2018 *Corresponding author: Yizhak Marcus, Institute of Chemistry, The Hebrew University of Jerusalem, Israel, Email: Introduction K2 = 0. For the The chalcogenide atoms (X = oxygen, sulfur, selenium, tellurium, telluride anion there was the added complication that the anodic 2– 13.9 (1 M NaOH), but no fit was tried with the value polonium) form doubly charged monatomic anions, X , which exist oxidationresulted in the intermediate formation of elemental in crystalline salts. The question arises whether, once such salts 2– tellurium that yields theditelluride anion Te2 , which is then further are dissolved in water, such species persist, or do they hydrolyze oxidized. In fact, the polarography of the ditelluridedianion was completely to form the hydrochalcogenide anion: studied in [3] in aqueous 0.01, 0.1 and 1.0 M NaOH (translated to 2– –– pH = 12, 13, and 14) on the assumption that the disproportionation X++ H2 ODHX OH (1) 2– 2– Te2 DTe+ Te takes place, but, again, the nature of the reduced It is clear that in the case of oxygen this reaction proceeds to the telluride species was not established. What was established was right to completion: O2– + H –. Recently it was shown that 2 that the polarographic electrode reaction corresponded to a two also in the case of sulfur the anion S2– does not exist in aqueous electron change: + – .
    [Show full text]
  • Thin Chalcogenide Films for Photonic Applications
    9 Thin Chalcogenide Films for Photonic Applications Rossen Todorov, Jordanka Tasseva and Tsvetanka Babeva Institute of Optical Materials and Technologies “Acad. J. Malinowski” Bulgarian Academy of Sciences Bulgaria 1. Introduction In nature glass is formed as a result of rapid cooling and solidification of rock melts of volcanic origin. That hints at the existence of glass to have dated back since the dawn of creation. Man has quite soon borrowed the pattern to synthesize glass for their needs: in the production of glass beads and glazes for ceramic pots and vases (3500 BC), hollow glass items (1500 BC) - these developing further through the discovery of glassblowing (between 27 BC and AD 14), leading to fabrication of cast glass windows by Romans (around AD 100) and glass sheets (11th century) (http://glassonline.com/infoserv/history.html). Starting its applications as a non-transparent material for decoration purposes, glass has made a breakthrough to become used in a wide range of fields - from housing construction through optics (for lenses and protective coatings for mirrors), information processing (optical fibres and, in general, waveguides) and storage to photonics. The ingredients of the first accidentally man-synthesized glass were nitrate and sand, the latter being mostly composed of silica (SiO2), usually in the form of quartz. On its part, quartz is the second most abundant mineral in the Earth’s continental crust and is thus justifiable as a basic material in glass- production. Its high glass-transition temperature, however, places some limitations for its applications and other substances, such as sodium carbonate, aluminium, boron, calcium, cerium, magnesium, lead, thorium oxides are added to facilitate the processing and modulate the optical properties, e.g.
    [Show full text]