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ECONOMIC SOCIAL Cour\JCIL UNITED NATIONS RESTRICTED ECONOMIC E/CH.2/conF.5/11.323/Add.l AND 19 February 1974 ENGLISH ONLY SOCIAL cour\JCIL COM11ITTEE OF EXPERTS ON THE 1RANSPORT OF DANGEROUS GOODS GROUP OF RAPPORTEURS ON' THE Pl'..CKHTG OF DANGEilOUS GOODS Fifteenth session Fe bruary-lfarch 197 4 Geneva LISTING AJTD CLASSIFICATION OF SUBSTANCES AND ARTICLES Additional substances Proposal by the rapporteur of the United Kingdom Addendum 1 1. The rapporteur from the United Kingdom has sent the Secretariat the attached lis-t basecl on that circulated as J::;/CN.2/CO:NF.5/11.323 shoving the formulae, classification and hazard grouping of those substances 1rl1ich the United Kingdom considers should be inserted-in the UN List of Dangerous Goods. 2. In view of the number of substances involved, it may not prove possible for the Rapporteurs to deal with the list in depth at their fifteenth session but it is suggested that they be requested to submit any observations in time for discussion at the follmdng session so that the UN Committee of Experts can have before them a fully collated list consisting of the agreed entries as submitted by the various States and organizations. GE.74-22766 . ~/cif. •2/C0NF.5/R.323/Add.l page 2.: 1 SUGGESTED SUCC;-;?.;~ ~ SureTANCE FOR!fULA CLASSIDCATIGN ,. · GRCu.2:Ir.C- ---., . , ... \• .Acrylic Acid 8 +3 II Allyl glycidyl ether 3,+ 6.1 li! 2-Amino-4-chloro-phenol . ·6.1 _: , II . Anisole 3 III Benzonitrile c6%CN 6.1 II Benzene Sul·phony1: ~hloride · · · -c- :r·,:r.so -c1- ·· - 8 III 6J :;, 2- Benzotrichloride c ~-CG1 8 II 6 3 Bromoohlorodifluoromethane .BrCl.F 2 C 2 Dltanal CH (~) CHO E 3 2 Sec UN 3/1129,Bu Qirl?,l d ehy d lutyl glycol acetate c ~~C~o ccH 3, 4 2 3 III lutyl methacrylate C~ • C(CH )co c ~ II 3 2 4 3 lhtyl phenols (liquid) HOC6H • C ~ 6.1 Ill 4 4 . lhtyl phenols (solid-) HOC6Hf ~ · · · ·· 6.1 4 III Jbtyl toluene· CHf H •· c ~ ·J. ·. 6 4 4 Ill 5-tert-Butyl-l, 3-xylene (<~:u3,· 3. Ill 1htyric acid ethyl ester See· mt" 3/1180, Eth rl J3utyrf':~ c317co2c~cH3 Chlorinated anthraeene oil 6.1 II Ca:bcn dioxide .(compressed) 2 Chloroaoetaldehyde 6.1 II· p-Chloro-o-anisidine 6.1 II Chlorobanzotrifluoride 3 n p-Chlorobenzyl chloride G.l rr 6.1 II ·Chloroni troanilines 6.1 II 3-chl.oroprop-l-ene 3 · II Chlorotoluenes· 3; II ChlorotoluidL~es 6.1 n Chromium trifluoride See UN f}1. 756 ,Chr r) J?iBo-:ria4• Chromosulphuric acid 8 I Cycloheptane 3 n Cyclobeptene 3 II Cyolohexyl acet~te 3 m Cyclopen'b¼n o J. · 3 Ill Cyclopentanona 3 n Cyolopentene 3. ' n: n-Deoane . ) Ill E/ON.2/coNF.5/R.323/Aaa.1 page 3 SUGG:&STED SUGGESTED SumTANCE FOmroLA. CLASSlFIOATICN GROUPJNG 4-Decanol 3 ... nr.. - ~ - . -.. ' C~ 6.1 m . Di bromomethane :ar2 c ~~c~oc ~ 3. nr 1,-2-Di-n-butozj-ethane 4 4 (c ~) NH 3-. II Di-(n-btttyl)amine 4 2 Ootadiene _ C88i6 . 3 II · 8 · III ·11et~yl dichloroacetate ci2CHoo2cH3 CC~ + CJ.. F 2 Dichlorodifluoromethane +) mix;uri 2 c2 2 4 0 dichlorotetratluoroethane) · . cci 2 Dichlorodifluoromethane + ~ mix. t ur,i. CC1 2F2 + 3F trichloromononuoromethane of 6.1 + 3 , I (eym) Dichlorodimethyl ether O(C~Cl )2 ci H 0H 6.1 . · III niohlorophenols 2c6 3 H NCO 6.1 n Dichlorophenyl isocyanate ci2c6 3 · Dicycloheptadiene "14~0 · )'' II 1 . -:::..,- I. 3 II 1,2-Dimetboxyethane CH] OCl!.i C~ OCH3 ) 6.1 III Dimethylacetaaide CHfON(CH3 2 ~N(CH ) 6.1 II N,N-Dimethylaniline c6 3 2 DimethyloarbamOYl · .chloride 6.1 II (cH3)~COCl CH --c:>-CH 3 3 ', II 1,4-Dim.ethylcyolohexane 3 · Dimethylcyclohexylamine (CH3)~ 061,_1 3 II J-:- II N,N-Dimethyl-2-amino-ethanol (~3)2NC~C~OH !f,.N-DimethyUormamide HC-N(CH3)2 , 6 + 3, n . (CH ) B c 3 II Dimethyl-N-propylamine 3 2 a, chloride (cH o) P~ci.1 6.1 II . D~etbyl th1ophosphoryl 3 2 I . oc:_N. c H Cltz c 6.1 III . Diphenylmethane-4-,4,-diieocyanate 6 4 6Hlco 35% H~ (35%)+ 6.1 llI : Diphenyl-p-phenylenediamine (c6~)2Nc6 4 . + phenyl-J3-naphthylamine 65% c10~c6~ ,(65%) ItiNC H imc· H N~ 8 II Dipropylene triamine 3 6 3 6 ·n1thionites n. 0 • s. various salts Ca 4.2 II . ... .... I . l. I -- · -- Etbylaudne 50-70% Sain invr,ater ICH_fHl\112 3· II I -E/ON.2/coNF.5/R.323/Add.l page 4 SUGGESTED SUBSTANCE FORMULA SUC.CESTED CLASSIFICATION GTlODPnm Ethyl amyl ketone 3 III CH3C~C~C~C~C~CHj N-Ethylanil!ne 6.1 II c6~HHC~CH3 2-Ethylaniline 6.1 II ~l'I·· CHf~ • C6Hl~ N-Ethy\benzylaniline . c6~N(Et)C~C6~ 6.1 II 2-Ethylbutanol CH C~CH(Et)C~OH 3: ._ · III 3 Ethylene chlorohydrin C~Cl.C~OH . r. $e&'UN )1135, 2-Chloroethanc 2-Ethylhexyl acrylate m ~ 6.1 C~ CHC02~CH{Et)c4 nt ~ Ethylhexyl amine Cl9CH(Et)C~~ . 3· II 2-Ethylhexyl methacrylate CitzC(CH3)co2c81,,7 6.1 IJI Ethyl metha.crylate C~C(CH )co Et J II 3 2 Ferrous·chloride FeC1 8 III 2 Aluminium a1k¥I halides, 4.2 II- in solution Aluminium allcyl halides · ( pure ) 4.2 I ~ ·: .· n-Heptene C71i,4 __ . 3 · II HexQ.Chlorobutadiene C1C=CC1 6.1- II C~C.=CCl. 2 (solid) 8 HeY..amethylenediamine ~N{C~)6~ n Rexamethylenediiaocyanate OCN(C~)6NC.0 6.1 II Hexamethylenetetramine (~)6N4 . See UN4..1/1328, Hex.rrtiine He;xanols- Ill c6Hi. 30H 3 ·. Isobutyl methacrylate . C~C(CH3)C0 c ~ 3 .... n- 2 4 Isobutyronitrile CH3(C~)2CN 6.1 + 3 I Isocyanatobenzotrifluoride · OCNC H CF 6.1 n 6 4 3 Ieododecane(Pentamethylheptane) C12~6 3 III Isoheptene c i;_ 7 4 3 II Isohexene C68i2 o 3 JI Isophorone H.e A,..." 6.1 -III t-4i . Isophoronediamine -8 III Isophoronediisocyanate 6.1 II Lead residues 6.1 III Lead tetraa.cetate 6.1 III Maleio acid 8.1 II.I llaleic anhydride 6.1 m E/CN.2/coo.5/R.32;/Add.l page 5 SUGG:ESTED SUC-Grel'ED StJmTANCE FORMULA CLASSIFICATION GROUPDiG l -. ~... I 4-Methoxy-4-methyl-pent0:,n-2-one _ 3 Ill caA~~cocu3 l (:H.3 N-Methyl afliline jca3~6~ . 6.1. II 3.2 II 6.1 III Methyl-n-buty\_.methacrylate j C~C(OHJ)co2o5Hi_1 solution Methyl chl.oroacetate ·6.1 :+ 3 n Methyl cyclohexane 3 II Methyl cyclohexanone 3 II Methyl cyclopentane · l II Methyl diphenylamine 6.1 · III Methylene-bie(J,,-phenylieocyanate) "',6.1 · Ill 2-Methyl-5-ethyl p_yrid1ne 6.1 Ill 2-Methylfuran 3 II 5-Methylhexan-2-one } .. II 2-Picoline J II ~ -Methylstyrene 3 II Naphthalene (molteti) ~ 4.1 III Nit:robenzenesulpho~io acid lo c H so H 8 II 2 6 4 3 s·- . •Nitrobenzotrifiuoride II See UN 6/1578, C ~loro-· Nitrochlorobenzene · . _ni tro ben7..enes 3-Nit.ro-4-chlorobenzotrifluoride 8 II~ Nitrosylsulph4ric acid 8 II 3 _:. Pentan-2i4-dione III Phenetid ine 6.1 II I ..i - II.. Phenol (mol te.11) 6.1 Phenylenediamine 42% + ~ !T.ixture 8 II Cumenediamine 581' , of fl 6.1 o{ Hon-hazardous /J III K-Phenyl-naphthylamine (if free /3 ) · ,JGN.2/con.5/R.;23/Add.l page 6' SUGGE3TED SUGC:ESTZD SUBSTANCE FORMULA CLASSIPICATION GROUPING Triieobutylphosphate in propanol (c4~)lo4 .in o3a,oH 3 II - Phosphorus oxychloride POCl. See UN. c/1810, Phosphoryl chloride 3 Phosphorus sulphochloride PSC1 8 'n 3 Polychlorinated biphenyls 6.1 lll Seif-igniting metal powders Al,Mg, 2'n See UN ~~/1383, Pyrophoric rrietal.s Sodium cuprocyanide (solid) Na0u(CN) 6.1 I 2 Sodium cuprocyanide,(sln) NaCu(CN)~ 6.1 I .. ., .---,- --· ·- ' Sodium hydrosulphide INaSH 4.2 II .;.·f Sul.phamic acid Ill ~so3H 8 Aryl sulphonic acids various 8 II Terpene hydrocarbons (C Hg)n 3 llI ' 5 Tetraethylenepentamine 8 ~(C~~NH)3c¾~112~ m -· T.richlorobenzene, mj_xed isomers 6.1 III: Trichloro butene 6.1 II Triethyl phosphite 3 III ·Triisobutylene 3 II. l, 3, 5-Trimethylbenzene 3 II Trimethylcyclohexylamine Ill · 3_, 3! 5-'l'rimethylhe~ethy lenoditine ( C~ ) C ) Cll:! CH( CH 8 III ~ 2 (;;'n3 2 3 )~~ Truethylhe~methylenediisocyanate 6.1 II Trimethyl phosphite . (CH]O)l 3 II Undeoane CHiC~)fH] 3 III Xylenols (CH ) c n oH 6.1 Ill 3 2 6 3 Zino Chloride {anhydrous) 2nCl. 8 III 2· E/mI.2/colU!.5/R.32;/Add.l page 7 SUGG!STED SUGG:&'STED · SU'$TANCE FORMULA CLASSIFICATION GROU?!NG Acetaldehyde oxime CHfHNOR 3 II + 6.1 I Allyl acetate C~CHC~co2cR3 3 Allylrunine C~CH~~ 3~ . + 6.1 I Allyl ethyl ether C~CHC~~CH) 3, + 6.1 I Allyl r ormate HC029~CHC~ 3 + 6.1 I II Benzene thiol ( Thiophenol) c6~sH 3 Benzotrifluoride C61½CF3 3 II I . 3,. n 2-Bromobutane CHfHBr C¾CH3 l-Bromo-2~3-epoxypropane c11i :arct-'c~ 3 .: II 2-Branoethyl ethyl-ether 3- Il BrC~C~OC~CH3 l-Bromo-3-methylbut..l:\ne )cH 3 II BrC~~CH(CH3 3 1-13romo-2-methylpropane :BrC~CH(CH ) 3 II 3 2 2-13romo-2-m.ethylpropane (CH3)fBr 3, .. II 2-'.Bromopentane CHiC~)2CHBrC~ 3. II 1-Bromopropane CHf82C~Br 3. II 2-llromopropane 3 .. II CHfHBrC~3 3-Bromopropyne Hc=cc~Br -3 , II Dltanedione 3 ·_ II CHfOCOCH3 lbtane-1-thiol II c4~SH 3 lbtan-2-ol CH ~CHOHCH 3.
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