The Journal of Gemmology
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X-Ray Rietveld and 57Fe Mössbauer Study of Babingtonite from Kouragahana, Shimane Peninsula, Japan
Journal of MineralogicalBabingtonite and from Petrological Kouragahana, Sciences, Shimane Volume Peninsula, 108, pageJapan 121─ 130, 2013 121 X-ray Rietveld and 57Fe Mössbauer study of babingtonite from Kouragahana, Shimane Peninsula, Japan * * ** Masahide AKASAKA , Takehiko KIMURA and Mariko NAGASHIMA *Department of Geoscience, Graduate School of Science and Engineering, Shimane University, 1060 Nishikawatsu, Matsue 690-8504, Japan **Department of Earth Science, Graduate School of Science and Engineering, Yamaguchi University, Yamaguchi 753-8512, Japan Babingtonite from Kouragahana, Shimane Peninsula, Japan, was investigated using electron microprobe, X-ray Rietveld, and 57Fe Mössbauer spectral analyses to characterize its chemical compositions, crystal structure, oxi- dation state of Fe, and distribution of Fe between two crystallographically independent octahedral Fe1 and Fe2 sites. _ The_ Kouragahana babingtonite occurs as single parallelohedrons with {100}, {001}, {001}, {111}, {110}, and {101} and sometimes shows penetration twinning. Both normal and sector-zoned crystals occur. Babing- tonite crystals with sector zoning consist of sectors relatively enriched in Fe and of sectors enriched in Mg, Mn, and Al. Babingtonite also shows compositional zoning with higher Fe2+ and Al core and higher Fe3+ and Mn 2+ rim. The average Fe content of the babingtonite without sector zoning is similar to the Fe -rich sector of the sector-zoned babingtonite. The chemical formula based on the average composition of all analytical data (n = 2+ 3+ - 193) is [Na0.01(2)Ca2.01(2)] [Mg0.11(4)Mn0.09(3)Fe0.76(7)Fe_ 0.93(5)Ti0.01(1)Al0.06(5)]Si5.01(4)O14(OH). X ray Rietveld refinement was carried out using a model of space group P1. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Alphab Etical Index
ALPHAB ETICAL INDEX Names of authors are printed in SMALLCAPITALS, subjects in lower-case roman, and localities in italics; book reviews are placed at the end. ABDUL-SAMAD, F. A., THOMAS, J. H., WILLIAMS, P. A., BLASI, A., tetrahedral A1 in alkali feldspar, 465 and SYMES, R. F., lanarkite, 499 BORTNIKOV, N. S., see BRESKOVSKA, V. V., 357 AEGEAN SEA, Santorini I., iron oxide mineralogy, 89 Boulangerite, 360 Aegirine, Scotland, in trachyte, 399 BRAITHWAITE, R. S. W., and COOPER, B. V., childrenite, /~kKERBLOM, G. V., see WILSON, M. R., 233 119 ALDERTON, D. H. M., see RANKIN, A. H., 179 Braunite, mineralogy and genesis, 506 Allanite, Scotland, 445 BRESKOVSKA, V. V., MOZGOVA, N. N., BORTNIKOV, N. S., Aluminosilicate-sodalites, X-ray study, 459 GORSHKOV, A. I., and TSEPIN, A. I., ardaite, 357 Amphibole, microstructures and phase transformations, BROOKS, R. R., see WATTERS, W. A., 510 395; Greenland, 283 BULGARIA, Madjarovo deposit, ardaite, 357 Andradite, in banded iron-formation assemblage, 127 ANGUS, N. S., AND KANARIS-SOTIRIOU, R., autometa- Calcite, atomic arrangement on twin boundaries, 265 somatic gneisses, 411 CANADA, SASKATCHEWAN, uranium occurrences in Cree Anthophyllite, asbestiform, morphology and alteration, Lake Zone, 163 77 CANTERFORD, J. H., see HILL, R. J., 453 Aragonite, atomic arrangements on twin boundaries, Carbonatite, evolution and nomenclature, 13 265 CARPENTER, M. A., amphibole microstructures, 395 Ardaite, Bulgaria, new mineral, 357 Cassiterite, SW England, U content, 211 Arfvedsonite, Scotland, in trachyte, 399 Cebollite, in kimberlite, correction, 274 ARVlN, M., pumpellyite in basic igneous rocks, 427 CHANNEL ISLANDS, Guernsey, meladiorite layers, 301; ASCENSION ISLAND, RE-rich eudialyte, 421 Jersey, wollastonite and epistilbite, 504; mineralization A TKINS, F. -
Sugilite in Manganese Silicate Rocks from the Hoskins Mine and Woods Mine, New South Wales, Australia
Sugilite in manganese silicate rocks from the Hoskins mine and Woods mine, New South Wales, Australia Y. KAWACHI Geology Department, University of Otago, P.O.Box 56, Dunedin, New Zealand P. M. ASHLEY Department of Geology and Geophysics, University of New England, Armidale, NSW 2351, Australia D. VINCE 1A Ramsay Street, Essendon, Victoria 3040, Australia AND M. GOODWIN P.O.Bo• 314, Lightning Ridge, NSW 2834, Australia Abstract Sugilite relatively rich in manganese has been found at two new localities, the Hoskins and Woods mines in New South Wales, Australia. The occurrences are in manganese-rich silicate rocks of middle to upper greenschist facies (Hoskins mine) and hornblende hornfels facies (Woods mine). Coexisting minerals are members of the namansilite-aegirine and pectolite-serandite series, Mn-rich alkali amphiboles, alkali feldspar, braunite, rhodonite, tephroite, albite, microcline, norrishite, witherite, manganoan calcite, quartz, and several unidentified minerals. Woods mine sugilite is colour-zoned with pale mauve cores and colourless rims, whereas Hoskins mine sugilite is only weakly colour-zoned and pink to mauve. Within single samples, the chemical compositions of sugilite from both localities show wide ranges in A1 contents and less variable ranges of Fe and Mn, similar to trends in sugilite from other localities. The refractive indices and cell dimensions tend to show systematic increases progressing from Al-rich to Fe- Mn-rich. The formation of the sugilite is controlled by the high alkali (especially Li) and manganese contents of the country rock, reflected in the occurrences of coexisting high alkali- and manganese- bearing minerals, and by high fo2 conditions. KEYWORDS: sugilite, manganese silicate rocks, milarite group, New South Wales, Australia Introduction Na2K(Fe 3 +,Mn 3 +,Al)2Li3Sit2030. -
38Th RMS Program Notes
E.fu\wsoil 'og PROGRAM Thursday Evening, April 14, 2011 PM 4:00-6:00 Cocktails and Snacks – Hospitality Suite 400 (4th Floor) 6:00-7:45 Dinner – Baxter’s 8:00-9:15 THE GUALTERONI COLLECTION: A TIME CAPSULE FROM A CENTURY AGO – Dr. Renato Pagano In 1950, the honorary curator of the Museum of Natural History in Genoa first introduced Dr. Renato Pagano to mineral collecting as a Boy Scout. He has never looked back. He holds a doctorate in electrical engineering and had a distinguished career as an Italian industrialist. His passion for minerals has produced a collection of more than 13,000 specimens, with both systematic and aesthetic subcollections. His wife Adriana shares his passion for minerals and is his partner in collecting and curating. An excellent profile of Renato, Adriana, and their many collections appeared earlier this year in Mineralogical Record (42:41-52). Tonight Dr. Pagano will talk about an historic mineral collection assembled between 1861 and 1908 and recently acquired intact by the Museum of Natural History of Milan. We most warmly welcome Dr. Renato Pagano back to the speakers’ podium. 9:15 Cocktails and snacks in the Hospitality Suite on the 4th floor will be available throughout the rest of the evening. Dealers’ rooms will be open at this time. All of the dealers are located on the 4th floor. Friday Morning, April 15, 2011 AM 9:00 Announcements 9:15-10:15 CRACKING THE CODE OF PHLOGOPITE DEPOSITS IN QUÉBEC (PARKER MINE), MADAGASCAR (AMPANDANDRAVA) AND RUSSIA (KOVDOR) – Dr. Robert F. Martin Robert François Martin is an emeritus professor of geology at McGill University in Montreal. -
Scandiobabingtonite, a New Mineral from the Baveno Pegmatite
American Mineralogist, Volume 83, pages 1330-1334, 1998 Scandiobabingtonite,a new mineral from the Bavenopegmatite, Piedmont, Italy Ploro ORl.tNnIrr'* Ma,nco PasERorr and GrovlNNa Vn,zzllrNr2 rDipartimento di Scienzedella Terra, Universitd di Pisa, Via S. Maria 53,1-56126 Pisa, Italy '?Dipartimento di Scienzedella Terra, Universitd di Modena, Via S Eufemia 19, I-41 100 Modena, Italy Ansrntcr Scandiobabingtonite,ideally Ca,(Fe,*,Mn)ScSi,O,o(OH) is the scandium analogue of babingtonite; it was found in a pegmatitic cavity of the Baveno granite associatedwith orthoclase, albite, muscovite, stilbite, and fluorite. Its optics are biaxial (+) with 2V : : ^v: 64(2)",ct 1.686(2),P: 1.694(3), 1.709(2).D-"." : 3.24(5)slcm3, D.",.:3.24 sl cm3, and Z : 2. Scandiobabingtoniteis colorless or pale gray-green, transparent,with vitreous luster. It occurs as submillimeter sized, short, tabular crystals, slightly elongated on [001],and characterizedby the associationof forms {010}, {001}, {110}, {110}, and {101}. It occurs also as a thin rim encrustingsmall crystals of babingtonite.The strongest lines in the X-ray powder pauern are at2.969 (S), 2.895 (S), 3.14 (mS), and 2.755 (mS) 4. fn" mineralis triclinic, ipu.. g.oup PT, with a : 7.536(2),b : 1L734(2),c : 6.t48(Z) A, : 91.10(2), : 93.86(2), : lO+.S:(2)'. Scandiobabingtoniteis isostructural " B r with babingtonite, with Sc replacing Fe3* in sixfold coordination, but no substitution of Fer* by Sc takes place. Due to the lack of a suitably large crystal of the new species, such a replacementhas been confirmed by refining the crystal structure of a Sc-rich babingtonite (final R : O.O47)using single-crystal X-ray diffraction (XRD) data. -
Astrology & Gemstones 1
Astrology & Gemstones A birthstone is a gem whose vibrarion harmonizes with a person’s sun sign. Although today we wear gems primarily for decorative purposes, our ances- tors chose gemstones to influence an individual’s astrological characteristics. Gems, they believed, could strengthen weaknesses or tone down ex- cesses in a person’s natal makeup. Don’t choose a birthstone based on the calendar month in which you were born, however––go by the astrological sign instead. Each sign straddles two months. Aquarius, for example, begins on about January 20 and ends around February 18. Astrologers consider the garnet Aquarius’s sign, but jewelers who don’t understand astrology usually link garnets with January and amethysts with February. Amethyst, astrologers argue, belongs to the zodiac sign Pisces. As you can see in the following lists, each planet and each sign relates to more than one gem. The correspondences are based on energetic proper- ties, colors, and other factors. Aries, a sign known for its aggressive and daring nature, is linked with bloodstone, a gem used by Roman soldiers for protection. Moonstone relates to the sign Cancer, which is ruled by the moon. Some stones may possess the qualities of more than one sign and there- fore have affinities with others, as is the case with aquamarine. Stones that come in many colors, such as agates, are usually associated with the planet(s) and signs(s) that govern their colors. Today, as in the past, we can use gemstones to attract things we desire and to repel or prevent things we don’t want to interfere in our lives. -
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New Minerals Approved Bythe Ima Commission on New
NEW MINERALS APPROVED BY THE IMA COMMISSION ON NEW MINERALS AND MINERAL NAMES ALLABOGDANITE, (Fe,Ni)l Allabogdanite, a mineral dimorphous with barringerite, was discovered in the Onello iron meteorite (Ni-rich ataxite) found in 1997 in the alluvium of the Bol'shoy Dolguchan River, a tributary of the Onello River, Aldan River basin, South Yakutia (Republic of Sakha- Yakutia), Russia. The mineral occurs as light straw-yellow, with strong metallic luster, lamellar crystals up to 0.0 I x 0.1 x 0.4 rnrn, typically twinned, in plessite. Associated minerals are nickel phosphide, schreibersite, awaruite and graphite (Britvin e.a., 2002b). Name: in honour of Alia Nikolaevna BOG DAN OVA (1947-2004), Russian crys- tallographer, for her contribution to the study of new minerals; Geological Institute of Kola Science Center of Russian Academy of Sciences, Apatity. fMA No.: 2000-038. TS: PU 1/18632. ALLOCHALCOSELITE, Cu+Cu~+PbOZ(Se03)P5 Allochalcoselite was found in the fumarole products of the Second cinder cone, Northern Breakthrought of the Tolbachik Main Fracture Eruption (1975-1976), Tolbachik Volcano, Kamchatka, Russia. It occurs as transparent dark brown pris- matic crystals up to 0.1 mm long. Associated minerals are cotunnite, sofiite, ilin- skite, georgbokiite and burn site (Vergasova e.a., 2005). Name: for the chemical composition: presence of selenium and different oxidation states of copper, from the Greek aA.Ao~(different) and xaAxo~ (copper). fMA No.: 2004-025. TS: no reliable information. ALSAKHAROVITE-Zn, NaSrKZn(Ti,Nb)JSi401ZJz(0,OH)4·7HzO photo 1 Labuntsovite group Alsakharovite-Zn was discovered in the Pegmatite #45, Lepkhe-Nel'm MI. -
Gem-Quality Chrysoprase from Haneti-Itiso Area, Central Tanzania
GEM-QUALITY CHRYSOPRASE FROM HANETI-ITISO AREA, CENTRAL TANZANIA KARI A. KINNUNEN and ELIAS J. MALISA KINNUNEN, KARI A. and MALISA ELIAS J., 1990: Gem-quality Chrysoprase from Haneti-Itiso area, Central Tanzania. Bull. Geol. Soc. Finland 62, Part 2, 157—166. Gem-quality, apple-green, Ni-bearing chalcedonic quartz occurs as near-surface veins in silicified serpentinite in the Haneti-Itiso area, Central Tanzania. AAS de- terminations revealed a high Ni content, 0.55 wt.%, and low Co and Cr contents of 120 and 1 ppm respectively. NAA determination revealed near chondritic REE contents. X-ray diffraction determinations showed that the Chrysoprase consists main- ly of alpha quartz with some opal-CT. The gemmological properties are: refractive indices from 1.548 to 1.553 (±0.002), mean specific gravity 2.56, hardness about 7 on Moh's scale, inert to ultraviolet radiation, green through Chelsea filter, and absorption in the deep red and violet part of the optical absorption spectrum. The results confirm the identity of the material as Chrysoprase. Microscopically the Tanzanian Chrysoprase consists of spherules which are high- ly disordered, concentric, and composed of bipyramidal quartz, chalcedony, quart- zine, and opal-A. They were classified into four main types according to the shell arrangement. The diameter of the spherules ranged from 40 um to 77 um. Fluid inclusion types in the bipyramidal quartz were monophasic, low-temperature type. The spherules, silica types and REE contents suggest that this Chrysoprase was deposited by evaporation of surface waters connected with the silicification of the serpentinites. Genetically analogous formations, common in Africa, include M-fabric type, weathering profile silcretes. -
Wrapped up Statement Earrings
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Winter 2009 Gems & Gemology
G EMS & G VOLUME XLV WINTER 2009 EMOLOGY W INTER 2009 P AGES 235–312 Ruby-Sapphire Review V Nanocut Plasma-Etched Diamonds OLUME Chrysoprase from Tanzania 45 N Demantoid from Italy O. 4 THE QUARTERLY JOURNAL OF THE GEMOLOGICAL INSTITUTE OF AMERICA EXPERTISE THAT SPREADS CONFIDENCE. Because Public Education AROUND THE WORLD AND AROUND THE CLOCK. Happens at the Counter. ISRAEL 5:00 PM GIA launches Retailer Support Kit and website Cutter checks parameters online with GIA Facetware® Cut Estimator. NEW YORK 10:00 AM GIA Master Color Comparison Diamonds confirm color quality of a fancy yellow. CARLSBAD 7:00 AM MUMBAI 7:30 PM Laboratory technicians calibrate Staff gemologist submits new findings on measurement devices before coated diamonds to GIA global database. the day’s production begins. HONG KONG 10:00 PM Wholesaler views grading results and requests additional services online at My Laboratory. JOHANNESBURG 5:00 PM Diamond graders inscribe a diamond and issue a GIA Diamond Dossier® A $97.00 value, shipping and handling extra. All across the planet, GIA labs and gemological reports are creating a common language for accurate, unbiased gemstone GIA’s Retailer Support Kit has been developed to help evaluation. From convenient locations in major gem centers, to frontline detection of emerging treatments and synthetics, to online services that include ordering, tracking, and report previews — GIA is pioneering the technology, tools and talent sales associates educate the public about diamonds, that not only ensure expert service, but also advance the public trust in gems and jewelry worldwide. the 4Cs, and thoroughly explain a GIA grading report.