MISSOURI

Download the Pipeline Awareness Viewer™ (PAV) app to learn about pipelines, including:

Apply for PIMMA access

Visit the API training center website

COORDINATED RESPONSE EXERCISE Register for a pipeline safety meeting near you

® Download the NENA call intake checklist COORDINATED RESPONSE EXERCISE

Download the PHMSA Emergency Response Guidebook Pipeline Safety Training For First Responders

View a video about the pipeline industry

How to use PAV: • Launch the app on your device. • Review the brief instructions. • Tap the SCAN button and aim your camera at this page.* • When the buttons appear, tap the lock icon to view the available content. • Tap the buttons to view important pipeline safety information.

*For best results, enable Wi-Fi on your device prior to using the PAV app.

EMERGENCY RESPONSE MANUAL PROGRAM GUIDE Overview Operator Profiles Emergency Response NENA Pipeline Emergency Operations Signs of a Pipeline Release High Consequence Area Identification VIEW INTERACTIVE Pipeline Industry ER Initiatives CONTENT* Pipeline Damage Reporting Law

*Instructions on back 2021 showmepipeline.com Foreword Public safety and environmental protection are top priorities in any pipeline incident response. While serious pipeline incidents are rare, pipeline operators appreciate the hard work and effort of those emergency officials who are involved in helping return a community affected by an incident to normal. Because pipeline operators care about the safety of the community, they developed this resource covering the critical tasks that need to be considered when responding to a pipeline incident. General information about pipelines and damage prevention is also included to help The Missouri Underground Facility Safety and Damage Prevention statute (RSMo Chapter 319) provides for a notification center to be used by participating utilities to support your National Incident Management receive locate requests. Missouri One Call System, Inc. (MOCS), operating as a non- System (NIMS), National Association of State profit Missouri corporation, is such a notification center providing a single-point of contact Fire Marshals (NASFM) and agency training, for notification to its members through a state wide toll-free telephone number operating knowledge and other best practices. 24 hours a day, seven days a week. MOCS was established in 1986 and currently is providing statewide services to utilities and excavators to comply with the law. This law Please become familiar with the information in applies to any person excavating in the state of Missouri. this resource and be prepared to work together with the operator in the unlikely event of a MOCS was established as a means to protect underground facilities and assist pipeline incident in your community. excavators and utilities in complying with Missouri’s statute and OSHA Rules 1926.651. By using the service that MOCS provides, the general public’s safety and the environment also are protected.

Using the MOCS system correctly is easy, if you know how.

When you call or use the internet to contact MOCS, you will be asked for specifics about the planned excavation. Once this information is processed by the computer, you will be given a list of member utilities that will be notified of your excavation.The computer then sends this locate request to all member utilities with facilities in your dig site area. After the utility has been notified of the planned excavation, they will mark the “approximate location” of their underground lines or advise you there are no facilities in your area. Table of Contents After it is determined that markings are required, the locate request will be dispatched to a field locator who will locate and mark the excavation site with paint, stakes, or flags. Understanding Pipelines...... 1 Members mark their facilities according to specific guidelines and color codes. Locating Pipelines...... 2 Recognizing a Pipeline Incident...... 3 Upon agreement of the excavator and the facility owner, location may be provided by Responding to a Pipeline Incident...... 4 alternative means such as an on-site meeting or other conference. Preventing Pipeline Damage...... 6 Underground Storage...... 8 Either party may request an on-site meeting to clarify markings, which must occur within Regional Matrix...... 9 2 working days of the request for this meeting. PAM Member Listings...... 19 Emergency Response Guidebook...... 59 Additional information can be found by visiting us at mo1call.com. Safety Data Sheets...... 60 Emergency Response...... 79 Overview...... 81 Training Presentation...... 83 Additional Information...... 90 Emergency Contact List...... 92

©2021 Paradigm Liaison Services, LLC. All Rights Reserved. Understanding Pipelines

The Pipeline System America’s energy transportation network consists of more than 2 million miles of pipelines operated by more than 3,000 companies, large and small. Although these pipelines exist in all 50 states, most people are unaware that the vast network even exists. This is due to the strong safety record of pipeline operators and the fact that most of the pipelines are located underground. The U.S. Department of Transportation’s (DOT) Pipeline and Hazardous Materials Safety Administration (PHMSA), which administers the nation’s pipeline safety program through the Office of Pipeline Safety (OPS) What is a Pipeline? along with state regulatory agencies, is responsible The term pipeline as referenced in this guide, for the oversight of natural gas and hazardous liquid includes transmission, local distribution and pipelines. Their mission is to ensure the safe and gathering systems. Transmission pipelines for reliable operation of the nation’s pipeline transportation natural gas, liquid petroleum (diesel, gasoline, system, all the while protecting the people, property and or crude oil), and liquid natural gas (propane, environments located around the pipelines. Pipeline butane, or anhydrous ammonia) move products operators are equally committed to public safety and from the production area or refinery to outlets environmental responsibility. As a result, pipelines are such as bulk storage terminals or loading facilities. considered the safest, cleanest, and most economical Local distribution systems may also transport way to transport large quantities of natural gas, oil, and liquid petroleum and natural gas. Liquid petroleum other chemicals to businesses and homes across the distribution systems transport product from the United States. bulk storage facility by rail car or tank trucks. Local natural gas distribution companies (LDCs) use In an ongoing effort to improve public safety, pipelines to move natural gas from a city gate or environmental health, and damage prevention, nearly town border station to distribution systems. Local all pipeline operators in Missouri have joined together distribution systems transport natural gas through to sponsor training and educational programs that raise mains that are usually located along or under city community awareness about pipelines. The operators’ streets to service lines that connect to homes goal is to work with local emergency officials, public and businesses. Gathering pipelines link the officials, and excavators to improve the effectiveness of production areas to central collection points. pipeline safety and incident response efforts.

1 PAM21 Locating Pipelines

Markers are placed near pipelines, but not necessarily on top of them. The signs do not provide information on the exact location, depth or diameter. In addition, a pipeline may not follow a straight line between adjacent markers. For these reasons, you need to look around for a pipeline marker when responding to any incident you suspect may involve a pipeline, then contact the operator identified on the pipeline marker.

It is a federal crime to damage or remove a pipeline marker; however vandals, construction crews and others who do not recognize their significance sometimes remove, knock down or obstruct the markers. Suspect a pipeline is nearby if you see the following: • A pipeline marker sign • A buried pipeline that’s exposed and visible • A pipeline facility and equipment, i.e. wellhead or Pipeline marker signs are located at road, railroad, and pump/compressor station navigable waterway crossings. These markers identify • A regulator or meter setting the approximate location of a pipeline at numerous points • A refinery, processing plant, distribution station along the pipeline right-of-way. Each operator’s marker may look different, but the purpose and information on the marker is the same. Markers tell you the: • Approximate location of a pipeline • Material transported • Emergency phone number • Pipeline operator

• Painted metal or plastic posts • Signs located near roads, railroads & along pipeline right-of-ways • Pipeline casing vent • Marker for pipeline patrol airplane

2 PAM21 Recognizing a Pipeline Incident

A pipeline incident exists when there is a pipeline leak, shutdowns, starting and stopping pumps, and opening fire, explosion, natural disaster, accidental release and closing valves. or operational failure that disrupts normal operating Despite the industry’s best efforts to monitor and conditions. protect pipelines, incidents can happen. Pipelines Pipeline control center personnel keep a watchful that were built years ago in rural areas may now lie eye over potential incidents by constantly monitoring beneath populated areas. A minor scrape or dent the daily operation of pipelines. As a result, pipeline from construction and excavation activities can operators are able to minimize the impact of leaks and cause a break or leak in these pipelines. prevent incidents by remotely initiating emergency

Look for Signs of a Pipeline Release As an emergency official, you can recognize a pipeline incident by using your senses of sight, sound Sight and smell, or through the use of electronic detection equipment.

Petroleum on the ground

Smell Strange and unusual gaseous or chemical odors

Mist or cloud of vapor Dying vegetation on green corridor

Sound A hissing, whistling or roaring noise

CO2 vapor cloud Sheen or film on water

Fire or explosion Water bubbling or standing in unusual areas

3 PAM21 Responding to a Pipeline Incident

If a pipeline incident occurs, the emergency response team needs to immediately: • Confirm the presence and identity of the pipeline product. • Initiate protective actions. • Secure the area. • Request the assistance of qualified personnel. Meanwhile, the pipeline operator will focus on the pipeline damage and on bringing the incident to a conclusion as quickly and safely as possible.Their personnel are trained to recognize dangers and respond appropriately to minimize and control pipeline-incident Consult product information documents and the hazards. Emergency Response Guidebook published by 911 Dispatch personnel play a critical role in effective PHMSA/DOT to learn about the specific hazards response to pipeline incidents. For correct and prompt associated with and emergency responses to the response in the event of a pipeline incident, it is important products transported through pipelines in your to know who the companies are in your respective community. jurisdictions, their contact information and the products being transported. Actions taken by dispatchers can save lives, direct the appropriate emergency responders to • Incident potential the scene and protect our nations’ infrastructure from Identify the potential for the incident to escalate into a additional issues that can be caused by an improper more serious event. response. Follow these simple guidelines in the case of a pipeline incident: Establish site control – Gather the proper information (if possible) Site management and incident control involve managing – Company, product, phone numbers on markers/signs and securing the physical layout of the incident area. You and characteristics of any product being released want to employ the Incident Command System (ICS). – Know the appropriate response to each product From a command post, the emergency response team – Know the wind direction at the time can assess the situation, evaluate the hazards and risks, and determine whether or not officials should intervene. – Warn of ignition sources if possible Continually reassess the situation and modify the – Dispatch appropriate emergency responders response accordingly. – Contact the pipeline company Respond to protect people, property and the Approach cautiously from upwind environment from hazards • Do not drive or enter into a leak or vapor cloud area. • Employ public protective actions. • Do not park over a manhole or storm drain. – Evacuate or protect-in-place. Identify the problem – Provide medical assistance. – Refer to product information documents to identify • Pipeline type, product, and nature of incident – health and fire hazards and personal safety Determine the identity of the product via pipeline precautions. Use monitoring equipment to evaluate marker, facility documents, monitoring and detection atmospheric conditions and determine whether it equipment, and your senses of sight, sound and smell. is safe to enter the area. Do not attempt to enter • Exposures the area without appropriate personal protective Identify structures and occupancies in the area and any equipment. special needs for people located there. • Secure the area. • Environmental conditions – Set up barricades to control crowds and traffic. Identify weather conditions that may affect the incident. – Eliminate ignition sources. Do not light a match, start Determine whether the pipeline product may release an engine, use a cell phone or a telephone, switch into a water system or other environmentally sensitive area and take action to prevent contamination. lights on/off, or do anything that may cause a spark. • Safety considerations • Do not operate pipeline equipment. Identify any unique safety hazards or considerations • Notify the railroad authority of any vapor cloud associated with the incident. over or near a railway. • Pipeline isolation Determine whether the pipeline can be isolated.

4 PAM21 Responding to a Pipeline Incident

Use the information in this resource to make initial decisions upon arrival at the scene of a pipeline incident. It should not be considered a substitute for emergency response training, knowledge, or sound judgment. Contact the pipeline operator or the National Association of State Fire Marshals to learn more about pipeline incident prevention and response. And, for emergency response to pipeline hazards, please consult the Emergency Response Guidebook. Employ the National Incident Management System (NIMS), a consistent, nationwide approach for federal, state, tribal, and local governments to work effectively and efficiently together to prepare for and respond to all hazards, including acts of terrorism. Visit www.fema. gov/emergency/nims/index.shtm for more information.

• Control spills (confinement). Contact the pipeline operator – Prevent the entry of liquid products into waterways, Communication provides for timely and effective sewers, basements, or confined areas. Divert the management, coordination, and dissemination of all spill to an open area, if possible. pertinent information to all the stakeholders. Call the – If flammable liquids are involved, use Class B pipeline operator as soon as possible! firefighting foams for vapor suppression. Be prepared to provide your contact information, location, – Conduct air monitoring. and information about the incident, such as the size, – Cover storm drains and sewers ahead of the characteristics and behavior of a leak. Also, notify the release. operator of any change in the incident conditions, such – Do not touch, breathe, or make contact with leaking as a vapor cloud moving or enlarging. liquids! *Per federal requirements, pipeline companies are required to communicate important information to all agencies and departments • Control leaks (containment). that may respond to a pipeline emergency. In addition to educating – Do not operate pipeline equipment. Attempting emergency responders when to notify operators they are required to isolate or operate pipeline valves unless under to “identify the types of gas pipeline emergencies of which the the direction of the pipeline operator may create operator notifies the officials”. Emergency Responders need to additional problems that are worse than the original know that “pipeline operators will contact emergency officials in the event of an emergency”. Some examples of when an operator event. may notify responders include, but are not limited too: Leak, fire, – Do not touch natural gas plastic piping. It may explosion, natural disaster, bodily injury, accidental release or generate a static spark that could act as an ignition operational failure that disrupts normal operating conditions. source. – Do not ignite a vapor cloud. Coordinate response efforts with the pipeline operator • Control fires. – Flammable liquids and gases give off a tremendous Work together to ensure the incident priorities are amount of radiant heat. Protect exposures as accomplished in a safe, timely and effective manner. appropriate. When the pipeline operator’s area representatives arrive, – Never extinguish a flammable gas fire. Always they will identify themselves, establish contact with control or isolate the source of the leak. the incident commander, and may request continued – Permit the fire to self-extinguish and consume any assistance with incident control. Operator representatives residual fuel that may remain inside or around the are trained to minimize hazards and determine when pipeline. the incident is over. The pipeline operator will take the following steps to ensure public safety and environmental – Eliminate ignition sources, such as engines, electric protection: motors, pilot lights, burn barrels, cell phones, cigarettes, ungrounded tools, and emergency radios. • Shut down the pipeline environment. When responding to a pipeline incident, you can help • Close valves to isolate • Excavate and repair the protect your community by understanding the hazards the problem. damaged pipeline. associated with the products transported through • Identify hazardous areas. • Work with emergency pipelines. Refer to product information provided with this • Dispatch personnel to the officials and the public in resource or from the operator, and use the Emergency scene. the affected area. Response Guidebook. • Take steps to protect the

5 PAM21 Preventing Pipeline Damage

Pipeline Operator Efforts In response to federal regulations and in accordance with corporate commitments to protect our communities, pipeline operators use several damage prevention measures to monitor and ensure safe pipeline operation. These include: • Regular internal maintenance inspections • Ongoing pipeline maintenance programs • Routine patrol and visual inspection of pipeline right- of-ways • Satellite and other remote communication. technologies • Constant pipeline monitoring • Participation in state one-call underground damage prevention program • Pipeline marker program • Pipeline Integrity Management Plan (IMP) • Emergency response plans

Though operational disruptions are infrequent, pipeline operators go to great efforts to be prepared for any type of incident. Pipeline operators: • Develop emergency response and crisis management plans • Accumulate manpower and equipment necessary to respond to incidents quickly • Develop extensive training and drill programs • Work closely with federal, state and local agencies to prepare for and respond effectively to an incident Federal codes regulate the planning, design, operation, maintenance, inspection and testing of pipelines. As a result of regular damage prevention activities and response planning, pipeline operators are able to ensure pipeline integrity, achieve safety goals, and comply with applicable laws and regulations. Integrity Management Operators use Integrity Management Plans (IMPs) to prevent pipeline leaks and spills, respond to emergency incidents, determine which pipelines could affect High Consequence Areas (HCAs), and identify opportunities to lower the operating risks of a pipeline. HCAs are segments along transmission pipelines that require supplemental hazard assessment and prevention programs because, in the event of a release, they could result in greater consequences to health and safety or the environment. Contact your local pipeline operators to determine if HCAs are located in your area of responsibility.

Smart Pig: An internal inspection tool

6 PAM21 Preventing Pipeline Damage

Emergency Official Efforts It’s always better to prevent an accident than to respond to an incident. You can help prevent damage in your community by being aware of pipeline locations, promoting pipeline awareness and damage prevention, and watching for suspicious activities near pipelines: • Be aware of pipelines in your area. – Search the Pipeline Integrity Management Mapping Application (PIMMA) on the National Pipeline Mapping System (NPMS) website: www.npms. phmsa.dot.gov. Learn who operates pipelines in your area and know how to contact them.

– Look for pipeline marker signs and learn who operates the pipelines. – Contact local pipeline operators to discuss the pipelines and emergency response plans in your area. • Promote the use of the state one-call. – State law requires everyone in your community to contact the one-call at least two days prior to excavation, excluding Saturday, Sunday and legal holidays, prior to excavation. The pipeline operator will mark its underground facilities, including any pipelines in the excavation area, and may remain on site during excavation near a pipeline. Remind excavators to use this free service – it’s the law! • Report suspicious activities on or near a pipeline, exposed pipe, or damaged facilities to the pipeline operator. – In our nation’s time of heightened security, it is more important than ever to guard pipelines against dam- age or attack. Homeland Security and infrastructure protection is a shared responsibility. Help protect these valuable assets.

7 PAM21 Underground Storage

Emergency Response for Public Safety What Should I Do If I Suspect An Personnel Emergency? When responding to a storage field incident, your first Notify storage field operator as soon as possible job as an emergency responder is to take all necessary actions to safeguard the public. Such action should Always be aware of wind direction include immediately clearing the area of people, barricading the area and standing by at a safe distance. Walk into the wind, away from possible hazardous Your next step will be to contact the storage field fumes. operator. Keep in mind when setting up emergency response, a storage field incident may involve the Do not drive into a leak or vapor cloud release of product for several days until the specialized emergency response equipment, coordinated by the Monitor combustible atmosphere, if equipment is storage field operator, becomes available. It is also available important for emergency responders to know and Determine hazardous area and escape routes understand the type of product being released. If ignition has not occurred, precautions should be taken The emergency phone number can be found on all to prevent ignition, such as rerouting vehicle traffic, air pipeline markers and all wellhead locations traffic and shutting down nearby railroads. When ignition has occurred, prevent the spread of fire but do not attempt to extinguish the burning product. It is important for emergency responders to know where all storage fields are located within your response area and the products they contain. As well, emergency responders need to know who the storage field operators are and to meet on a regular basis to discuss emergency response.

8 PAM21 Regional Matrix

Emergency Contact Numbers by Homeland Security Region and County

H B

A F C

I

D

G E

9 PAM21 Region A

Emergency Pipeline Company Ray Clay Cass Pettis Bates Platte

Contact Henry Saline Carroll Benton Jackson Johnson Lafayette

BP Pipelines (North America), Inc. 1-800-548-6482 X X X X X Buckeye Partners, L.P. 1-866-514-8380 X X X Empire District Gas Company 1-800-406-9220 X X X X X X X 1-800-858-5253 Enbridge / Platte Pipe Line Company / Texas Eastern Transmission LP X X X X X X 1-800-231-7794 Enterprise Products Operating LLC (Mid-America) 1-888-883-6308 X X X X Liberty Utilities 1-800-548-6482 X X X Magellan Midstream Partners, L.P. 1-800-720-2417 X X X X X X ONEOK North System 1-888-844-5658 X Panhandle Eastern Pipe Line 1-800-225-3913 X X X X X Phillips 66 Pipeline LLC 1-877-267-2290 X X X Sinclair Transportation Company 1-800-321-3994 X X X 1-800-582-1234 Spire X X X 1-800-887-4173 Summit Natural Gas 1-800-927-0787 X X Tallgrass Energy (Rockies Express Pipeline) 1-877-436-2253 X Tallgrass Energy (Tallgrass Interstate Gas Transmission) 1-888-763-3690 X X TC Energy / Keystone Pipeline 1-800-447-8066 X

10 PAM21 Region B

Emergency Pipeline Company Linn Ralls Knox Adair Clark

Contact Lewis Macon Marion Shelby Monroe Putnam Sullivan Chariton Schuyler Scotland Randolph

BP Pipelines (North America), Inc. 1-800-548-6482 X X X X X X X X X X X X Buckeye Partners, L.P. 1-866-514-8380 X X Empire District Gas Company 1-800-406-9220 X X

Enbridge / Platte Pipe Line Company / 1-800-858-5253 X X X X X X Texas Eastern Transmission LP 1-800-231-7794 Enterprise Products Operating LLC (Mid-America) 1-888-883-6308 X X X X X X X X X Flint Hills Resources 1-800-688-7564 X X X X X Liberty Utilities 1-855-644-8134 X X X X X X X X X Magellan Midstream Partners, LP 1-800-720-2417 X X X NuStar Pipeline Operating Partnership L.P. 1-800-759-0033 X X X X Panhandle Eastern Pipe Line 1-800-225-3913 X X X Phillips 66 Pipeline LLC 1-877-267-2290 X Sinclair Transportation Company 1-800-321-3994 X X X X X X X Tallgrass Energy (Rockies Express Pipeline) 1-877-436-2253 X X X TC Energy / ANR Pipeline 1-800-447-8066 X X TC Energy / Keystone Pipeline 1-800-447-8066 X X

11 PAM21 Region C

Emergency Pipeline Company Pike

Contact Perry Lincoln Warren Franklin Jefferson Saint Louis Washington Saint Francis Saint Charles Saint Louis City Sainte Genevieve BP Pipelines (North America), Inc. 1-800-548-6482 X X X Buckeye Partners, L.P. 1-800-331-4115 X X Enable Mississippi River Transmission 1-800-325-4005 X X X X X 1-800-858-5253 Enbridge / Platte Pipe Line Company / Texas Eastern Transmission LP X X 1-800-231-7794 Explorer 1-888-876-0036 X X X Flint Hills Resources 1-800-688-7594 X X Liberty Utilities 1-855-644-8134 X Magellan Midstream Partners, LP 1-800-720-2417 X Marathon Pipe Line LLC 1-800-537-6644 X X X MoGas Pipeline LLC 1-800-282-4916 X X X X NuStar Pipeline Operating Partnership L.P. 1-800-759-0033 X X X Panhandle Eastern Pipe Line 1-800-225-3913 X Permian Express Partners 1-800-753-5531 X Phillips 66 Pipeline LLC 1-877-267-2290 X X X 1-800-582-1234 Spire X X X X 1-800-887-4173 Tallgrass Energy (Rockies Express Pipeline) 1-877-436-2253 X TC Energy / Keystone Pipeline 1-800-447-8066 X X

12 PAM21 Region D

Emergency Pipeline Company Polk Barry Dade Stone

Contact Taney Cedar Dallas Barton Jasper Vernon Hickory Greene Newton Webster Christian Lawrence McDonald Saint Clair

Empire District Gas Company 1-800-406-9220 X Enable Gas Transmission 1-800-474-1954 X Explorer 1-888-876-0036 X X X X X X X Liberty Utilities 1-855-644-8134 X Magellan Midstream Partners, LP 1-800-720-2417 X X X X X X X X Marathon Pipe Line LLC 1-800-537-6644 X X X X X X X Phillips 66 Pipeline LLC 1-877-267-2290 X X X X Summit Natural Gas 1-800-927-0787 X X X X X X

13 PAM21 Region E

Emergency Pipeline Company Iron Scott

Contact Butler Ripley Wayne Dunklin Madison Bollinger Stoddard Pemiscot Mississippi New Madrid Cape Girardeau

Enable Mississippi River Transmission 1-800-325-4005 X X X X X X 1-800-858-5253 Enbridge / Platte Pipe Line Company / Texas Eastern Transmission LP X X X X 1-800-231-7794 Enterprise Products Operating LLC (TE Products) 1-888-883-6308 X X X X Liberty Utilities 1-855-644-8134 X X X X X X X X X X X X Permian Express Partners 1-800-753-5531 X X X X

14 PAM21 Region F

Emergency Pipeline Company Cole

Contact Miller Boone Osage Cooper Morgan Howard Audrain Camden Callaway Moniteau Gasconade Montgomery

1-573-592-3170 City of Fulton X 1-573-592-3180 Empire District Gas Company 1-800-406-9220 X X X 1-800-858-5253 Enbridge / Platte Pipe Line Company / Texas Eastern Transmission LP X X 1-800-231-7794 Explorer 1-888-876-0036 X X Flint Hills Resources 1-800-688-7594 X X Magellan Midstream Partners, LP 1-800-720-2417 X X X X X X Marathon Pipe Line LLC 1-800-537-6644 X X MoGas Pipeline LLC 1-800-282-4916 X NuStar Pipeline Operating Partnership L.P. 1-800-759-0033 X X X Panhandle Eastern Pipe Line 1-800-225-3913 X X X X X X X X Phillips 66 Pipeline LLC 1-877-267-2290 X X X X X Summit Natural Gas 1-877-267-2290 X X X Tallgrass Energy (Rockies Express Pipeline) 1-877-436-2253 X TC Energy / Keystone Pipeline 1-800-447-8066 X X

15 PAM21 Region G

Emergency Pipeline Company Texas

Contact Ozark Carter Wright Howell Oregon Douglas Shannon Reynolds

NuStar Pipeline Operating Partnership L.P. 1-800-759-0033 X X Permian Express Partners 1-800-753-5531 X Summit Natural Gas 1-800-927-0787 X X X X

16 PAM21 Region H

Emergency Pipeline Company Holt

Contact Worth Gentry Mercer Clinton DeKalb Andrew Daviess Grundry Caldwell Harrison Atchison Nodaway Buchanan Livingston

Buckeye Partners, L.P. 1-866-514-8380 X X X X X X X X X Empire District Gas Company 1-800-406-9220 X X X X X X

Enbridge / Platte Pipe Line Company / 1-800-858-5253 X X X Texas Eastern Transmission LP 1-800-231-7794 Enterprise Products Operating LLC (Mid-America) 1-888-883-6308 X X X Flint Hills Resources 1-800-688-7594 X X X Magellan Midstream Partners, LP 1-800-720-2417 X X X X X X X X X ONEOK North System 1-888-844-5658 X X Summit Natural Gas 1-800-927-0787 X X X Tallgrass Energy (Rockies Express Pipeline) 1-877-436-2253 X X X TC Energy / ANR Pipeline 1-800-447-8066 X X X X X X TC Energy / Keystone Pipeline 1-800-447-8066 X X X

17 PAM21 Region I

Emergency Pipeline Company

Contact Dent Maries Phelps Pulaski Laclede Crawford

Explorer 1-888-876-0036 X X X Marathon Pipe Line LLC 1-800-537-6644 X X X MoGas Pipeline LLC 1-800-282-4916 X X X X NuStar Pipeline Operating Partnership L.P. 1-800-759-0033 X X X Omega Pipeline Company LLC 1-573-329-3382 X Summit Natural Gas 1-800-927-0787 X

18 PAM21 Pipeline Association of Missouri Members

BP Pipelines (North America), Inc...... 20 Buckeye Partners, L.P...... 22 City of Fulton...... 24 Empire District Gas Company...... 25 Enable Midstream Partners, LP...... 27 Enbridge / Platte Pipe Line Company / Texas Eastern Transmission LP...... 28 Enterprise Products Operating LLC...... 29 Explorer Pipeline Company...... 31 Flint Hills Resources...... 33 Liberty Utilities...... 35 Magellan Midstream Partners, L.P...... 36 Marathon Pipe Line LLC...... 38 MoGas Pipeline LLC...... 40 NuStar Pipeline Operating Partnership, L.P...... 41 Omega Pipeline Company, LLC...... 42 ONEOK North System LLC...... 43 Panhandle Eastern Pipe Line...... 45 Permian Express Partners...... 46 Phillips 66 Pipeline LLC...... 47 Sinclair Transportation Company...... 49 Spire...... 50 Summit Natural Gas...... 51 Tallgrass Energy / Rockies Express Pipeline...... 52 TC Energy / ANR Pipeline...... 54 TC Energy / Keystone Pipeline...... 56

Note: The enclosed information to assist in emergency response planning is delivered by Paradigm Liaison Services, LLC on behalf of the above sponsoring companies. Visit the National Pipeline Mapping System at www.npms.phmsa.dot.gov to determine additional companies operating in your area.

19 PAM21 BP Pipelines (North America), Inc.

30 South Wacker Drive Chicago, IL 60606 Phone: 1-800-548-6482 Website: www.bp.com

COMPANY PROFILE • Internal pipeline inspections are conducted periodically by EMERGENCY CONTACT: BP’s U.S. Pipelines and Logistics sophisticated computerized 1-800-548-6482 business (USPL) moves and delivers equipment called “smart pigs”. the energy that helps power economic PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: growth, serving both the Midwest and • Cathodic Protection on our pipelines Crude Oil 1267 128 Pacific Northwest regions. Every day, protects pipelines from external Diesel Fuel 1993 128 USPL manages more than 3,200 miles corrosion through the use of an of electrostatic current. MISSOURI pipelines carrying 1.1 million barrels of • BP is a member and/or participant COUNTIES OF OPERATION: crude oil, natural gas liquids and refined of numerous damage prevention products. It also has an ownership stake associations and a member of the Adair Linn in close to 1,500 miles of additional “one-call” systems in every state Carroll Macon pipelines. The combined network of in which we have pipeline facilities Cass Marion pipelines that USPL owns or manages within. Chariton Monroe is long enough to stretch from Chicago Clark Pike to London. As of late 2020, the business • Emergency preparedness and Jackson Ralls will maintain 70 above-ground storage planning measures are in place Johnson St Charles tanks with a combined capacity of about at BP in the event that a pipeline Knox Scotland 5.3 million barrels. incident occurs. The company also Lafayette Shelby works closely with local emergency Lincoln Sullivan COMMITMENT TO SAFETY, HEALTH response organizations to educate ______AND ENVIRONMENT them regarding our pipelines and how Changes may occur. Contact the operator to to respond in the unlikely event of an discuss their pipeline systems and areas of Safety is the foundation of everything operation. emergency. BP does, every single day. Its goals are clear: no accidents, no harm to people “The pipeline system operated by and no damage to the environment. BP is a key element of the economic That’s a huge responsibility — one BP and security infrastructure of the does not take for granted. United States,” says Clive Christison, Senior vice president fuel supply and In fact, whether looking at oil and midstream for BP’s North American gas production or refining and fuels business. “Our extensive network petrochemicals, BP’s rate of Tier 1 of pipes safely and reliably delivers events is below the published industry the energy that America needs to heat sector average. BP is proud of this 1-800-548-6482 homes, businesses and schools, and it progress, but also recognizes that it also delivers the energy that fuels the cannot rest on past achievements. vehicles, airplanes and machines that Complacency undermines safety, which make modern life possible.” is why BP is working every day to become even better, even safer. Even as BP has prepared to respond to an accident, it also has worked hard to ensure that such a response is never needed. Among its many initiatives are: • Visual inspections of BP’s pipeline right-of-ways are conducted by air and/or ground patrols. • Above ground marker signs are displayed along the right-of-ways to alert the public and contractors to the existence of our pipelines.

20 PAM21 BP Pipelines (North America), Inc. CKY CKY U U E E NT NT SSE SSE KE KE NNE NNE TE TE IS OIS N NO LI LI IL IL s Loui Lou is

St St WA WA IO IO ANSAS ANSAS URI URI K K O O AR SS AR SS MI MI ty ty nsas nsas Ci Ci Ka Ka MA MA HO HO LA LA NSAS NSAS OK OK KA KA a a ls ls Tu Tu BRASKA BRASKA NE NE

21 PAM21 Buckeye Partners, L.P.

Wesley Pekarek 1315 North Sterling Ave. Sugar Creek, MO 64054 Phone: (219) 713-6913 Website: www.buckeye.com

ABOUT BUCKEYE PARTNERS, L.P. COMMITMENT TO HEALTH, SAFETY, AND THE ENVIRONMENT EMERGENCY CONTACT: Buckeye Partners, L.P. (Buckeye) 1-866-514-8380 for Northern MO provides mid-stream energy logistics Buckeye is committed to preventing 1-800-331-4115 for St. Louis Area services. Buckeye owns and operates hazards to the public, to the one of the nation’s largest independent environment, and to Buckeye’s facilities. PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: petroleum products common carrier Buckeye utilizes various programs Diesel Fuel 1202 128 pipeline networks providing refiners, to ensure the safety of its pipelines. Gasoline 1203 128 wholesalers, marketers, airlines, Our control centers operate 24 hours Heating Oil 1202 128 railroads, and other commercial end- a day, 7 days a week monitoring Jet Fuel 1863 128 users with dependable, all-weather our pipeline leak detection system. Kerosene 1223 128 transportation of liquid petroleum Our Integrity Management Program products through approximately 6,000 consists of corrosion control, risk MISSOURI miles of pipelines. Buckeye transports engineering, geographic information COUNTIES OF OPERATION: liquid petroleum products by pipeline systems, and pipeline inspection. principally in the Northeastern and We also perform pipeline patrols and Andrew Jackson upper Midwestern states. Buckeye various other inspections. Our Public Atchison Livingston also operates and maintains pipelines Awareness Program is designed to Buchanan Nodaway it does not own, primarily in the Gulf establish communications and provide Caldwell Putnam Coast region, under contracts with information necessary to help the Clay Ray major oil and petrochemical companies. public understand that pipelines are Clinton St. Louis City The combination of experienced and the major transportation system for Daviess St. Louis County responsive professional staff, technical petroleum products and natural gas Grundy Sullivan expertise, and modern transportation in the United States, how pipelines ______facilities has earned Buckeye a function, and the public’s responsibilities Changes may occur. Contact the operator to reputation for providing high-quality, to help prevent damage to pipelines. discuss their pipeline systems and areas of operation. safe, reliable, and efficient pipeline Accordingly, heightened awareness and transportation services. a better understanding by the public of Buckeye’s pipeline operations will In addition to pipeline transportation supplement and enhance our current • Public Safety / Evacuation services, Buckeye provides terminalling, maintenance, operations, and safety • Responder Safety storage, and liquid petroleum product policies and procedures. For more • Traffic Control distribution services. Buckeye owns information about these programs, • Vapor Suppression more than 115 liquid petroleum products please visit Buckeye’s website • Site Security terminals with an aggregate storage listed above or call Buckeye’s non- • Firefighting capacity of over 118 million barrels, and emergency Public Education number markets liquid petroleum products in • Product Containment at 866-432-4960. certain regions served by its pipeline Federal regulations require specific and terminal operations. Buckeye’s qualifications to operate pipeline EMERGENCY RESPONSE flagship marine terminal in the Bahamas, equipment; therefore, Buckeye Buckeye Bahamas Hub, is one of the Since pipelines are the safest and employees will perform these duties. largest crude oil and petroleum products most efficient method of transporting DO NOT attempt to operate any pipeline storage facilities in the world, serving the petroleum products, pipeline incidents equipment, such as valves, because international markets as a premier global are rare. Buckeye appreciates the hard doing so could make the situation worse. logistics hub. work and effort of the many emergency responders that may be involved in Additional information on how to To learn more about Buckeye, log on helping us return the community to respond to incidents involving pipelines to www.buckeye.com. To view the normal in the event of an incident. In is available by contacting Buckeye or approximate location of pipelines in an emergency, Buckeye may utilize by obtaining training materials from your area, visit the National Pipeline the Incident Command System during the National Association of State Mapping System at www.npms. a response to a pipeline incident. The Fire Marshals’ sponsored Pipeline phmsa.dot.gov. For general information following are examples of critical tasks Emergencies Program. This training can about pipelines, visit would need to be considered during a be found at https://nasfm-training.org/ www.pipeline101.com. pipeline release: pipeline/.

22 PAM21 Buckeye Partners, L.P.

BUCKEYE’S RESPONSE IN AN ACTIVITY ON THE RIGHT OF WAY your local law enforcement agency. EMERGENCY Lastly, if you see power lines down on Always be sure to call 811 before any or near Buckeye’s pipeline right of way, Buckeye is engaged in constant activity digging activities occur. Accidental immediately call Buckeye’s emergency to maintain safe pipeline operations. damage caused by excavation, number listed on this page. Electricity In the event of a pipeline release, construction, farming activities, and discharging to the ground can damage Buckeye will take the following steps homeowner projects is one of the buried pipelines. to ensure public safety and protect the greatest threats to pipeline safety. For environment: more information on safe digging, see www.call811.com. If you hit a pipeline, • Shut down the pipeline you must report it to the pipeline • Close valves to isolate the problem operator. Even if damage looks minor or • Identify hazardous areas nonexistent, it is critical that the operator • Dispatch personnel to the scene inspects the pipeline. A minor scratch, • Excavate & repair the damaged line scrape, gouge, or dent to the pipeline • Work with emergency responders and or coating has the potential to cause a the public in the affected area. safety issue in the future. Also, if you see suspicious activity on or near the Buckeye’s emergency response plan is pipeline right of way, immediately notify available upon request.

23 PAM21 City of Fulton

1303 Westminster Ave. Fulton, MO 65251 Phone: 573-592-3170 Fax: 573-592-3179 Website: http://fultonmo.org

The City of Fulton owns and operates meter it is once again reduced in a municipal natural gas system that pressure. The City serves residential EMERGENCY CONTACT: serves approximately 4,000 customers. customers at 1/4 psi, and commercial 573-592-3170 The city installed the first natural and industrial customers from 1/4 psi to (Between 7:30 AM and 4:00 PM CST) gas meter in the year 1936. The city 2 psi depending on individual loads. 573-592-3180 purchases natural gas from the Kansas (After hours or on weekends) The City owns and maintains and Oklahoma natural gas fields and approximately 116 miles of natural gas PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: transports the gas by contract over the mains. In the early 1970’s the City began Panhandle Eastern Pipe Line (PEPL) Natural Gas 1971 115 installing plastic pipe gas mains on all to the City’s connection to PEPL near new construction. The City has replaced MISSOURI Hatton, Missouri. The natural gas is then all cast iron and ductile iron gas mains COUNTIES OF OPERATION: transported on an 8-inch steel coated with plastic mains as part of the City’s pipeline owned and maintained by the gas main replacement program. Callaway City of Fulton (see attached map). The ______natural gas is transported on this line COMMITMENT TO SAFETY, HEALTH Changes may occur. Contact the operator to at a pressure of 340 psi (pounds per discuss their pipeline systems and areas of & ENVIRONMENT square inch) to the City’s north town operation. border station. The City of Fulton’s goal is to provide safe, reliable, and efficient gas service Once the natural gas is transported to to our customers. • The City of Fulton is a member of the the City, 10 regulator stations reduce Missouri State One Call program. the pressure for the distribution system. • Our pipeline falls under the regulatory The pressure is reduced at 1 regulator oversight of the Office of Pipeline • Emergency preparedness and station 440 psi to 52 psi, 4 regulator Safety and the U.S. Department of planning measures are in place at stations 340 psi to 55 psi and 5 regulator Transportation and Missouri Public the City of Fulton in the event of an stations 55 psi to 25 psi. Once the Service Commission. emergency. natural gas reaches the customer’s • Visual inspections are taken on a • The City Gas Department has tools regular basis with above ground available to shut down gas lines in markers along the pipeline route. case of an emergency • Rectifiers are used to protect the pipeline for cathodic protection.

24 PAM21 Empire District Gas Company

PO Box 127 Joplin, MO 64802 Phone: 1-800-406-9220 Website: www.empiredistrict.com

COMPANY PROFILE Missouri One-Call or 811 “Call before you dig” hotline to allow all EMERGENCY CONTACT: Empire District Gas, A Liberty Utilities buried utilities a chance to mark the 1-800-406-9220 Company, operates 86 miles of gas underground facilities in the area before transmission pipeline as part of its digging begins. PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: natural gas distribution system serving Natural Gas 1971 115 over 42,000 residential, commercial, and Empire maintains regional service industrial customers in central, western, centers supplied with equipment and MISSOURI and northern Missouri. Our transmission materials to respond to incidents COUNTIES OF OPERATION: and feeder pipelines transport natural should they occur. We have the gas to our distribution mains, where we committed company employees and Andrew Linn then deliver the natural gas to homes contractor resources available for Atchison Livingston and businesses. Underground pipeline prompt responses to any nature of Chariton Morgan transportation is the safest method natural gas pipeline emergency. Empire Cooper Nodaway to move natural gas to help meet our maintains a 24 hour emergency call Grundy Pettis nation’s energy needs. center and members of our staff are Henry Platte on call 24 hours a day, 7 days a week Holt Ray COMMITMENT TO PIPELINE to respond to and investigate any Howard Saline SAFETY, HEALTH & ENVIRONMENT suspected pipeline incident. Our goal is Johnson Vernon the safe delivery of natural gas and the Prevention is Empire’s primary focus to Lafayette preservation of public health and safety ensure the safety of its gas system and ______and the environment. to protect the health and welfare of the Changes may occur. Contact the operator to discuss their pipeline systems and areas of public which includes our customers COMMUNITY AWARENESS AND operation. and employees. We work to maintain PARTNERSHIP the integrity of our pipeline systems and keep them safe from any potential Empire is proud of its long history ADDITIONAL INFORMATION threat. Our goal is that everyone who of safely delivering natural gas to ABOUT EMPIRE lives or works near our pipeline facilities its customers. We understand that is aware of them, adopts safe digging maintaining a strong safety record To find out more information about practices, learns the signs of a potential requires the partnership of many Empire District Gas, A Liberty Utilities pipeline leak and knows how to quickly stakeholders. Empire considers its Company, visit our website at www. respond if a problem is suspected. employees, customers and the public empiredistrict.com – OR – contact an Though we monitor our assets regularly near our pipelines, local government Empire District Gas representative at the by various patrols, we also request your officials, and emergency responders all number listed above. help to maintain a safe, secure, and partners in our goal of providing safe You can also find out where Empire’s reliable pipeline system. If you observe reliable natural gas services. To that end, and other companies’ pipelines are any unusual or suspicious activity near empire provides training and educational in your area by going to the National our pipeline facilities or in the unlikely materials to each stakeholder group Pipeline Mapping System website at event an emergency occurs, please throughout the year to help ensure each www.npms.phmsa.dot.gov. call us at any time using the emergency party is aware of the role they play in number listed in this document. maintaining a safe natural gas delivery WHAT ARE THE SIGNS OF A system. This publication provides System failures are rare along the NATURAL GAS PIPELINE LEAK? detailed information about understanding nation’s network of interstate natural what a pipeline is, how to recognize • Blowing or hissing sound gas pipeline facilities, however most of where a pipeline is located and various the ones that do occur are caused by • Dust blowing from a hole in the pipeline marking methods. Information damage from others digging near the ground is also provided about the properties of pipeline. We watch for unauthorized the products moved by pipeline, how • Continuous bubbling in wet or flooded digging, but we request your help too. to recognize a pipeline incident and areas We are members of the Missouri One- what your role as a stakeholder is in Call and strongly encourage those who • Gaseous or hydrocarbon odor responding to that incident. are going to dig to call • Dead or discolored vegetation in a green area • Flames, if a leak has ignited

25 PAM21 Empire District Gas Company

WHAT SHOULD I DO IF I SUSPECT • Do not start/turn off motor vehicles/ PIPELINE LOCATION AND A PIPELINE LEAK? electrical equipment MARKERS Your personal safety should be your first • Call 911 or contact local fire or law Pipeline markers are used to indicate concern: enforcement the approximate location of a natural gas pipeline and to provide contact • Evacuate the area and prevent • Notify the pipeline company information. Aerial patrol planes also anyone from entering • Do not attempt to extinguish a natural use the markers to identify the pipeline • Abandon any equipment being used gas fire route. Markers should never be removed near the area or relocated by anyone other than a • Do not attempt to operate any pipeline pipeline operator. • Avoid any open flames valves • Avoid introducing any sources of We stay in contact with industry and ignition to the area (such as cell government to monitor potential threats phones, pagers, 2-way radios) and study new technologies that will help keep our facilities as safe and secure as possible.

26 PAM21 Enable Midstream Partners, LP

Enable Gas Transmission, LLC Enable Mississippi River Transmission, LLC

Enable Midstream owns interstate COMMITMENT TO SAFETY, HEALTH and intrastate natural gas pipelines, & ENVIRONMENT EMERGENCY CONTACT: as well as a gas gathering operation, Enable Mississippi River Transmission Enable Midstream Partners is committed processing and treating services. In 1-800-325-4005 to the safe and reliable operations of its addition, we own crude oil gathering Enable Gas Transmission pipelines in your community. According and hazardous liquid lines. In Missouri, 1-800-474-1954 to the National Transportation Safety we operate Enable Gas Transmission Board, pipelines are the safest and (EGT) and Enable Mississippi River PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: most economical method of transporting Transmission (EMRT), our interstate Natural Gas 1971 115 products. We monitor the op­eration of natural gas transmission lines. our pipelines from our control centers, MISSOURI 24 hours a day, seven days a week. Our COUNTIES OF OPERATION: LOCATING PIPELINES pipelines are designed, installed, tested, To view and/or download maps of operated and main­tained in accordance EMRT: all pipelines in your county, see the with all applicable federal and state Butler St. Francois National Pipeline Mapping System requirements. Our safety education Iron St. Louis website (www.npms.phmsa.dot.gov), efforts include outreach with excavating Jefferson St. Louis (city) an online mapping program managed contractors, emergency response Madison Ste. Genevieve by the Federal Government. Pipeline officials, appropriate public officials, Ripley Stoddard markers are placed along the pipeline farmers and affected public. Wayne route to indicate the approximate If a gas pipeline emergency were to EGT: McDonald location of the line and to identify where occur, Enable Midstream personnel the pipeline intersects with a street, will work directly with local emergency ______highway, railway or river. Markers responders. Our priorities at the scene Changes may occur. Contact the operator to display the material transported in the discuss their pipeline systems and areas of of a pipeline emergency are the same operation. line, the name of the pipeline operator as yours-- protect people, property and an emergency telephone number. and the environment. Many Enable They do not indicate the exact location Midstream field personnel are trained CONTACTS or depth of the pipeline. in Incident Command Structure (ICS) and familiar with how to work with local Enable Midstream Partners, L.P. responders within the ICS framework. Public Awareness Specialist Our personnel will restrict the flow of gas 4900 W. Sheridan Ave and implement other operating actions Suite 1500, M/C 760 as needed to minimize the impact of the Oklahoma City, OK 73102 emergency. Public safety officials and Phone: 800-829-9922 other non-company personnel should not attempt to operate pipeline valves. Improper operation of pipeline valves can cause additional accidents to occur. For more information about Enable Midstream pipeline safety programs, emergency response plans, or our Integrity Management Program visit our website at www.enablemidstream.com.

27 PAM21 Enbridge / Platte Pipe Line Company / Texas Eastern Transmission LP

5400 Westheimer Court Houston, TX 77056 Public Awareness: 1-888-293-7867 Email: [email protected] Website: www.enbridge.com

Life takes energy: to heat Emergency responder EMERGENCY CONTACT: our homes, to feed our education program 1-800-858-5253 (Liquids) families, to fuel our vehicles. Enbridge offers a free online 1-800-231-7794 (Gas) education program to provide public Enbridge connects people PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: safety and local public officials to the energy they need to Crude Oil 1267 128 with the information needed to Natural Gas 1971 115 help fuel their quality of life. safely and effectively respond to a pipeline emergency. This program MISSOURI COUNTIES OF OPERATION focuses on information specific to (LIQUIDS) the disciplines of firefighting, law In the United States alone, more than enforcement, 9-1-1 dispatch, Audrain Clinton Montgomery two million miles of pipelines deliver emergency medical services, Bates Johnson Randolph petroleum and natural gas products. emergency management and local Buchanan Lafayette Saline Caldwell Lewis Shelby Every year, Enbridge invests in the latest government. Additionally, course Carroll Lincoln St. Charles technology and training to meet the high completion may count for state- environmental and safety standards our Cass Macon level continuing education (CE) Chariton Marion neighbors expect, and to keep pipelines credits. Register for the training at the safest, most efficient and most www.mypipelinetraining.com. MISSOURI COUNTIES OF OPERATION reliable way to move energy resources. (GAS) Butler Scott Our safety measures Call or click before you dig Dunklin Stoddard Safety is, and always will be, our number 811 and ClickBeforeYouDig.com are ______one priority. Our team devotes hundreds free services designed to keep you safe Changes may occur. Contact the operator to when digging. Calling or clicking is always discuss their pipeline systems and areas of of thousands of hours every year to operation. keep our systems running smoothly the safest option anytime you are moving and without incident. We invest heavily dirt. At least two to three business days before your project (depending on state in safety measures including: You can also find out where other law), simply call 811 or visit companies’ pipelines are in your area • High-quality pipeline material and www.ClickBeforeYouDig.com with by going to the National Pipeline protective coating important details about your work, Mapping System website at • Pressure tests on new and existing including: pipelines https://www.npms.phmsa.dot.gov. • Inspection and preventative • The type of work you’ll be doing and a maintenance programs description of the area • Round-the-clock monitoring for • The date and time your project will pipelines and facilities begin • Aerial and ground patrols along the • Your worksite’s address, the road on pipeline right-of-way which it’s located and the nearest • Automatic shut-off and remote control intersection • Driving directions or GPS coordinates valves • Within two to three business days, • Emergency response training professional locators will mark and drills for employees and local underground utility lines—including emergency responders pipelines (marked with yellow flags or • Inspection and preventative paint)—so you can work around them, maintenance programs saving yourself from possible injury or property damage. What if there is an emergency? Enbridge facilities are designed to be Pipeline location and markers quickly isolated with block valves for All pipeline markers provide the name rapid containment in the event of an of the pipeline operator, product being emergency. We have pre-arranged plans transported and a telephone number for with local emergency personnel and reporting pipeline emergencies. These periodically conduct emergency drills markers should never be used as a with these groups. reference for a pipeline’s exact location.

28 PAM21 Enterprise Products Operating LLC

1100 Louisiana Houston, TX 77002 Website: www.enterpriseproducts.com

COMPANY INFORMATION, ASSETS address, visit our website at: www. & PRODUCTS TRANSPORTED enterpriseproducts.com/pipeline-safety/ EMERGENCY CONTACT: pipeline-viewer. Please note the asset 1-888-883-6308 Enterprise Products Partners L.P. is map and pipeline viewer tool are for a leading North American provider informational purposes only. PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: of midstream energy services to Diesel 1202/1993 128 producers and consumers of natural EMERGENCY RESPONSE PLAN Ethane 1035 115 gas, Natural Gas Liquids (NGL), crude Ethane Propane Mix 1961 115 oil, refined products and petrochemicals. An Emergency Response Plan (ERP) Gasoline 1203 128 Enterprise transports natural gas, NGLs, is developed for each pipeline facility Iso-Butane 1075 115 petrochemicals and crude oil through to contain, control and mitigate the Jet Fuel 1863 128 a network of pipelines throughout the various types of emergency conditions/ Naphthalene 1334 133 United States. situations that could occur at one of our Natural Gasoline 1203 128 facilities. For more information regarding N-Butane 1075 115 The Mid-America Pipeline (MAPL) Enterprise Products emergency response System operates approximately 400 Propane 1075 115 plans and procedures, contact us at Raffinate 1203 128 miles of pipelines throughout the state of [email protected]. Missouri transporting Ethane/Propane mix MISSOURI and Propane. You can also find out where other companies’ pipelines are in your area by COUNTIES OF OPERATION: The TE Products Pipeline System extends going to the National Pipeline Mapping over 9,000 miles of NGL pipelines System website at Mid-America Pipeline System through 13 states. In Missouri, it operates www.npms.phmsa.dot.gov. Adair Livingston approximately 140 miles throughout the Caldwell Macon state. The products transported through EMERGENCY RESPONSE Carroll Platte this system include: Ethane, Iso-Butane, CAPABILITIES Chariton Randolph Normal Butane, Diesel, Gasoline, Jet Clay Ray Fuel, Naphthalene, Natural Gasoline, The Company’s qualified personnel are Clinton Schuyler Propane and Raffinate. For additional trained in safe operations and emergency Knox Scotland information about Enterprise, visit response activities and participate in Linn Sullivan www.enterpriseproducts.com. exercises reflecting various types of emergency scenarios and environmental TE Products Pipeline System LOCATING ENTERPRISE PIPELINES sensitivities. The Company utilizes the Butler Scott – PIPELINE VIEWER TOOL First Responder/Emergency Response Dunklin Stoddard Team concept to handle emergency ______To find more information regarding incidents at its facilities. Employees Changes may occur. Contact the operator to discuss their pipeline systems and areas of location and products transported in our receive hands on training in fire fighting, operation. pipelines within one (1) mile of a specific hazardous material spill response and

29 PAM21 Enterprise Products Operating LLC rescue/medical/first aid training. In • Public safety personnel and others CONTACTS addition, we maintain a well trained team unfamiliar with the pipeline should not TE Products System of employees from various Company attempt to operate any of the valves Matt Jarrell locations as members of the Corporate on the pipeline, unless instructed to do 3134 Doron Road Emergency Organization. This team, so by Enterprise Products personnel. Creal Springs, IL 62922 as well as an array of emergency Improper operation of the pipeline Cell: 812-374-3082 response equipment (including, but not valves could make the situation worse Email: [email protected] limited to, cell phones, fire extinguisher, and cause other accidents to happen. supplied breathing air, and air monitoring Mid-America Pipeline System equipment), can be mobilized and INCIDENT COMMAND SYSTEM Robert Hornung deployed to assist in handling emergency Enterprise Products utilizes an 1015 N. Jefferson St situations that may occur at a Company expandable Incident Command System. Kearney, MO 64060 facility or pipeline location. Depending upon the size and complexity Phone: 816-858-7801 Enterprise Products utilizes its 24- of an incident, additional Company or [email protected] hour/365 day a year, Pipeline Operations contract personnel may be added as Control Center (888-883-6308) as a needed. Additional federal, state or local hub of communications in emergency agencies may be integrated into the response situations. Our manned control Incident Command System by utilizing a center monitors the flow, pressure, Unified Command Structure. temperatures, and other conditions throughout the pipeline systems and is an SPILL RESPONSE EQUIPMENT integral part of our communication during CAPABILITIES emergency situations. We maintain emergency response equipment at some of our facilities. We ENTERPRISE PRODUCTS’ also have agreements with Hazmat RESPONSE IN AN EMERGENCY Response (Certified Oil Spill Response • We will immediately dispatch personnel Organization) to provide the appropriate to help handle the emergency at the level of response with spill response site. equipment including trailers containing • We will provide information to public spill booms, sorbent materials, boats, safety officials to aid in their response motors, hand tools, power tools, pumps, to the emergency. hoses, personal protective equipment, first aid and miscellaneous supplies. • We will take necessary operating These companies also have expert actions such as closing and opening personnel trained in emergency response valves to minimize the impact of the and cleanup methods. leak.

30 PAM21 Explorer Pipeline Company

P.O. Box 2650 Tulsa, OK 74101 Phone: 918-493-5100 Emergency Contact: 1-888-876-0036 Website: www.expl.com

Explorer Pipeline is a common carrier Awareness Plan receives management’s pipeline transportation company who full support throughout the organization. EMERGENCY CONTACT: operates approximately an 1,900-mile Top-level management involved itself 1-888-876-0036 system transporting refined petroleum in the development of the program, products and other products including and participates in its administration PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: refinery feedstocks and diluent from and the evaluation of the program’s Diesel Fuel 1202/1993 128 the Gulf Coast through the Midwest. effectiveness. Diluent 1203 128 Explorer is based in Tulsa, Oklahoma Gasoline 1203 128 Explorer developed a comprehensive and also serves Houston, Dallas, Fort Jet Fuel 1863 128 damage prevention program to address Worth, St. Louis and Chicago. Naptha 1268 128 an increasing threat to the safety of its Raffinate 1203 128 Through connections with other products pipeline operations and the communities Toluene 1294 130 pipelines, Explorer serves more than 70 it serves. Explorer Pipeline’s Damage major population centers in 16 states. Prevention Program is not only in MISSOURI Major tankage and terminals are located place to educate third parties about COUNTIES OF OPERATION: at Port Arthur, Houston, Arlington, safety when working around pipelines, Greenville and Grapevine, Texas; but to educate its employees on the Camden Lawrence Glenpool, Oklahoma; Wood River, Illinois importance of delivering the safety Dade Maries and Hammond, Indiana. message throughout its system. Dallas Newton Explorer’s 1,900-mile system begins Our company values are: Safety, Doing Franklin Polk with a 28 inch pipeline in Port Arthur, the right thing; Being a good neighbor; Gasconade Pulaski Texas then runs through Houston, Texas Serving our customers’ needs; Meeting Greene St. Charles and on to Tulsa, Oklahoma. At Tulsa or exceeding all regulatory standards; Jasper St. Louis City the line becomes a 24 inch pipeline Respecting and valuing each other’s Laclede and runs through St. Louis, Missouri contributions and differences. ______Changes may occur. Contact the operator to on its way to the Chicago suburb of • Name of system: Explorer Pipeline discuss their pipeline systems and areas of Hammond, Indiana. Our capacity is operation. Company augmented with a 10-inch pipeline which stretches between Houston • Name of owner and operator: and Arlington, Texas along with many Explorer Pipeline Company lateral lines for connections to delivery • Type of system: Transmission points throughout the system. Explorer system currently transports refined products with more than 72 different product • Length of system (Missouri): 295 specifications for over 60 different miles shippers. The company does not buy or • List of products transported sell petroleum products; it only provides in system: Diesel Fuel, Diluent, transportation services. Gasoline, Jet Fuel, Naptha, Raffinate, Explorer Pipeline Company and its Toluene. management are fully committed to • Range of diameter of pipelines in operating a safe and reliable hazardous system: Pipe diameter can vary from liquids pipeline. Explorer is also 3”, 6”, 8”, 10”, 12”, 14”, 16”, 20”, 24” & committed to meeting or exceeding 28”. the guidelines set forth by API RP 1162 for public awareness. The Public In effort to make our maps, contact information and emergency response plan information available to you, please access Explorer Pipeline’s emergency portal at http://response-planning. com/explorer

31 PAM21 Explorer Pipeline Company

EMERGENCY RESPONSE • Do not light a match, start an engine, • Do what needs to be done to protect INFORMATION FOR GOVERNMENT use a telephone, turn light switches lives and property AND SAFETY OFFICIALS on/off or do anything that may make a For online training, visit National spark. During a pipeline emergency on the Association of State Fire Marshalls Explorer Pipeline system, take the • Do prevent release from entering website: following steps: waterways, sewers, basements, or https://nasfm-training.org/pipeline/ confined spaces. • Notify Explorer Pipeline at (888) 876- To learn more please contact the 0036 of the type (leak, rupture, fire, • Do divert the release to an open area, following: etc.) and location of the emergency. if possible. Sam Sansone • Establish a safety zone around the • Do cover storm drains and sewers (918) 798-7305 emergency site and control access. If ahead of the release. 1312 West 126th Street South necessary, evacuate people within the Jenks, OK 74037 Explorer Pipeline will: safety zone. Ronnie McGee • Eliminate the flow of petroleum. • Be aware of wind direction and (618) 567-8089 potential ignition sources. • Immediately dispatch trained 1355 Robbins Road personnel to the site to help handle Hartford, IL 62048 • Do not attempt to operate pipeline the situation and provide information valves. to public safety officials.

32 PAM21 Flint Hills Resources

4111 E 37th St N Wichita, KS 67220 Telephone: 855-831-6353 Email: [email protected] Website: www.fhr.com

Flint Hills Resources owns and/or operates over 4,000 miles of pipeline systems that transport crude oil, refined petroleum products, chemicals and natural gas liquids, EMERGENCY CONTACT: efficiently, reliably, and safely. In Missouri, Flint Hills Resources operates the Wood River 1-800-688-7594 Pipeline system which stores and transports crude oil and refined petroleum products. PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: FLINT HILLS RESOURCES INTEGRITY MANAGEMENT PROGRAM Crude Oil 1267 128 Gasoline 1203 128 Flint Hills Resources is committed to maintaining the highest standards in safety. Flint Hills Resources has an Integrity Management Program that is designed to protect the MISSOURI mechanical integrity, safety, and reliability of its pipelines. Flint Hills Resources adheres COUNTIES OF OPERATION: to federal and state regulations and also partners with local emergency responders to verify that this integrity management plan is appropriate for each section of its pipelines. Audrain Linn Montgomery Grundy Macon Randolph Harrison Mercer St. Charles Contact the Missouri one call center by calling 811 at least 48 Lincoln Monroe Sullivan hours, but not to exceed 14 calendar days before you want to dig. ______The one call center will notify Flint Hills Resources and other utilities Changes may occur. Contact the operator to discuss their pipeline systems and areas of of your intent to dig. operation.

Wait for facility owners to mark their underground facilities using paint, flags and/or stakes. Confirm that all facilities have been marked. If you know or believe that facilities have not been properly marked, you must make another call to the one call center before beginning any excavation work.

When digging within 25 feet of a Flint Hills Resources pipeline, a representative from the company must be present during the excavation. Expose the underground facility by carefully hand-digging or using other non-mechanized equipment until the location and route is confirmed. Continue to use caution even after the facility is exposed. Obey safe excavating practices and your state laws.

RECOGNIZE REACT REPORT Your sense of sight, sound and smell DO stop work immediately. • Call 911 or the local fire or police may help you recognize the signs of a DO turn off and leave equipment and department. pipeline leak. vehicles. • When it is safe to do so, call the Flint Sight – Seeing a pool of liquid, a DO immediately leave the area, on foot, Hills Resources 24-hour emergency white cloud or fog, discolored in an upwind or crosswind direction, number 1-800-688-7594 vegetation, flames or vapors, away from any vapors or fumes. oily sheen or water bubbling DO warn others to stay away. near a pipeline without DO NOT do anything that might ignite obvious reason. the leaking product, including Sound – Hearing a hissing, roaring or making a phone call, starting bubbling sound from the ground an engine or driving a vehicle, or water near a pipeline. lighting a match, or even switching on or off a light. – Smelling a strange or unusual Smell DO NOT operate any pipeline valves. smell, such as a strong DO NOT touch or inhale the product. petroleum odor or “rotten eggs” near a pipeline.

33 PAM21 Flint Hills Resources

CALL BEFORE YOU DIG Before you dig, drill, blast, or move any ground near a pipeline, call 811. This free call notifies your local one call center to have representatives of underground utilities come out and mark their facilities at no charge to you. Required by law, calling 811 can save your life and decrease the cost and damage to our underground pipeline transportation system.

One Call Center Phone Number Website

811 National 811 www.call811.com

Missouri One Call 1-800-344-7483 www.mo1call.com

34 PAM21 Liberty Utilities

2751 N. High St. Jackson, MO 63755

Phone: 1-855-872-3242 Website: www.libertyutilities.com

Liberty Utilities is a value-driven COMMITMENT TO SAFETY, HEALTH company. Our brand values shape our & ENVIRONMENT EMERGENCY CONTACT: corporate culture and unite our national, 1-855-644-8134 Safety is a main concern of Liberty collective efforts to deliver quality water, Utilities. We believe that nothing can gas and electric distribution services to PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: justify endangering our customers, our small and mid-sized communities across Natural Gas 1971 115 communities or our employees. Safety the United States. Water at Liberty Utilities is the responsibility of With more than 750,000 customers, every employee regardless of his or her MISSOURI Liberty Utilities is committed to local position. Liberty Utilities is committed to: COUNTIES OF OPERATION: decision making that directly meets the • Providing a safe, healthy and stable needs of its customers. This means work environment for all employees Adair Mississippi providing walk in customer service Bates New Madrid centers, creating jobs, and providing • Delivering safe, reliable and efficient Butler Pemiscot responsive and reliable service. As a service to its customers Cape Girardeau Pike company, Liberty Utilities promotes • Enhancing general public safety Cass Ralls local conservation and energy efficiency through safe work practices and public Clark Ripley initiatives and programs for businesses education Dunklin St. Clair and residential customers, including Henry Schuyler the low-income sector. The company • Complying with federal, state and local Iron Scotland measures its performance on customer regulations as they pertain to Liberty Knox Scott experience, public and workplace safety, Utilities’ daily operations Lewis Stoddard and service reliability. Liberty Utilities Macon Wayne currently operates in Arizona, Arkansas, Marion California, Georgia, Illinois, Iowa, ______Kansas, Massachusetts, Missouri, New Changes may occur. Contact the operator to Hampshire, Oklahoma, and Texas. discuss their pipeline systems and areas of operation.

35 PAM21 Magellan Midstream Partners, L.P.

One Williams Center Magellan Pipeline Company, LP Tulsa, OK 74172 Magellan Crude Oil Pipeline Company LP Magellan Pipelines Holdings LP (Headquarters) (800) 574-6671 Magellan Terminals Holdings LP (Local Toll Free) (800) 772-0480 Magellan Operating Company, LLC Website: www.magellanlp.com

SYSTEM OVERVIEW COMMITMENT TO SAFETY, HEALTH & ENVIRONMENT EMERGENCY CONTACT:

Name of system: (800) 720-2417 Magellan Midstream Partners, L.P. Magellan Midstream Partners, L.P is committed to the safe, reliable delivery Name of operator: PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: of refined products, and crude oil. Magellan Midstream Partners, L.P. Butane 1075 115 Our pipelines are designed, installed, Diesel Fuel 1202/1993 128 Type of system: Transmission tested,operated, and maintained Gasoline 1971 115 according to strict standards employed List of products transported in Jet Fuel 1863 128 by our company, the pipeline industry system: Butane, Propane, Refined Propane 1075/1978 115 and the federal government. Safety, Petroleum Products (Diesel Fuel, honesty, responsibility, and efficiency Gasoline), and Jet Fuel. MISSOURI are at the core of Magellan’s business. COUNTIES OF OPERATION: OPERATOR OVERVIEW FREQUENTLY ASKED QUESTIONS Andrew Daviess Moniteau Magellan Midstream Partners, L.P. is 1. How can an emergency responder Audrain Dekalb Monroe a publicly traded limited partnership, or LEPC obtain maps of the Barry Gentry Morgan principally engaged in the transportation, pipeline? Barton Greene Nodaway storage and distribution of refined Benton Harrison Pettis products and crude oil. Magellan Emergency responders and Boone Henry Platte operates a 9,800 mile refined products local planning/zoning authorities Callaway Jackson Ralls pipeline system with 54 connected may obtain detailed maps of our Cedar Jasper St. Charles terminals as well as 25 independent system from field operations staff Clay Lawrence St. Clair terminals not connected to our pipeline or contact us directly via email at: Clinton Marion Vernon system, two marine terminals (one of damageprevention@ magellanlp.com Cooper McDonald Worth which is owned through joint venture) or call 888-945-2255. In addition, the ______and a 2,200 mile crude oil pipeline National Pipeline Mapping System Changes may occur. Contact the operator to system. (www.npms.phsa.dot.gov) provides discuss their pipeline systems and areas of operation. a list of pipeline operators in your community as well as the location of pipelines and other information. 3. How can an emergency responder 2. How will Magellan and response learn more about the company’s agencies work together during official emergency plans? Pipeline Emergencies? If interested in learning more about Local response agencies are our facility response plan, please expected to play a key role in the first contact your local Magellan field few hours of a response, protecting representative or contact Magellan the public, isolating the area and Corporate directly via email at: using local materials such as dirt damageprevention@ magellanlp.com. or sand to help safely contain the event. Magellan personnel will join a 4. How can responders learn more Unified Command and can provide about pipeline responding training key response equipment such as air opportunities? monitors, vacuum trucks, emergency Visit www.pipelineemergencies.com. spill contractors, heavy construction or visit www.magellanlp.com for more equipment and specialized command information and additional resources. post contractors Our pipeline markers can be typically identified by the black and red bands at the top.

36 PAM21 Magellan Midstream Partners, L.P.

Iowa

Nebraska

Illinois

Kansas Missouri

Kentucky Oklahoma LEGEND Petroleum & Natural Gas Liquids Arkansas Petroleum Tennessee

37 PAM21 Marathon Pipe Line LLC

EMERGENCYEMERGENCY NUMBER: NUMBER: 1-833-MPL-1234 1-800-537-6644 (1-833-675-1234)

About Marathon Pipe Line LLC • Call MPL’s emergency number 1-833-675-1234 and provide the EMERGENCY CONTACT: Marathon Pipe Line LLC (MPL) following information: 1-833-675-1234 operates underground pipelines that o transport crude oil, petroleum products Location; PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: and natural gas to and from terminals, o Nature of the problem; and Crude Oil 1267 128 refineries and other pipelines across the nation. Movement of these liquids o A telephone number at which a MISSOURI and gas through pipelines is the safest responsible person can be contacted. COUNTIES OF OPERATION: method of transporting energy. To learn more about MPL, log on to www. Emergency Preparedness Camden Lawrence marathonpipeline.com. Although you are familiar with the Dade Maries steps required to safeguard the public, Dallas Newton Commitment to Safety, Health & the MPL has planned responses to unique Franklin Polk Environment emergency situations that may arise Gasconade Pulaski MPL is committed to experiencing no with its pipeline facilities and operations. Greene Saint Charles accidents, no harm to people, and Here are a few key topics that you Jasper Saint Louis no damage to the environment. MPL should review prior to the unlikely event Laclede utilizes a comprehensive risk-based of a pipeline emergency: ______Changes may occur. Contact MPL to discuss Integrity Management Program to their pipeline systems and areas of operation. ensure the safety of the pipelines, Emergency Response Plans where a pipeline release could affect a MPL has developed extensive response densely populated area, drinking water, plans for all of its facilities based on ecological area, or a commercially Public Safety and Evacuations the knowledge of its own personnel, navigable waterway. These available equipment, tools and Evacuation plans and procedures should management programs include routine materials. These plans are accessible at reflect the available assets and in-line inspection, maintenance, leak every facility. This document provides a capabilities of your own organization. detection, surveillance, and corrosion general overview of MPL’s capabilities. Expert knowledge of your area is key control. You can find more information For more detailed information or to to creating the best evacuation, traffic at the MPL website listed above or by review the Emergency Response Plan, control and rerouting, and railroad contacting a nearby MPL area office. please call 1-855-888-8056. MPL can stoppage plans in order to limit public provide assistance in planning your exposure and minimize accidental Emergency Response emergency procedures, recognizing that ignition. When an emergency occurs, gain the primary authority lies with you, the control of the situation as quickly as local emergency response organization. Fire or Explosion possible with the following objectives: MPL does not have dedicated fire Communicating with MPL During an • Assess the situation. Determine the response personnel and must rely on Emergency hazards and risks. the capabilities of local responders. If a pipeline event occurs, emergency Petroleum and natural gas emergencies • Only enter a hazardous area if response officials will be notified and present unique challenges for response personnel are properly trained and MPL operations personnel will be personnel, so proper training is crucial. equipped. dispatched to the site. MPL personnel Contact your state fire marshall for • Never enter a hazardous area without a and/or contractors will be at the site as pipeline emergency training. The properly trained and equipped backup. quickly as possible. U.S. Department of Transportation Emergency Response Guidebook • Rescue any injured person, if safe to do If you or another emergency response provides information on potential so. organization has set up an Incident hazards, public safety and emergency Command Post prior to the arrival of • Evacuate persons in any endangered response. MPL personnel, the first MPL employee area. to arrive at the site should be introduced • Prohibit the public from entering the to the Incident Commander as the MPL area. representative. • Control ignition sources.

38 PAM21 Marathon Pipe Line LLC

Rescue or Medical Duties Right-of-Way Activity MPL employees are not trained to One of the greatest threats to safe conduct rescue operations of any kind. pipeline operation is the accidental Emergency response personnel will be damage caused by excavation, contacted to assist with any needed construction, farming activities, rescue. Coordination will be made with and homeowner construction and emergency services or with a local maintenance. Awareness is crucial hospital or medical provider in the event in preventing these accidents. Call of a medical emergency. IMMEDIATELY if you see suspicious or questionable activity near the pipeline Pipeline Equipment and Facilities right of way. No one should conduct Federal law requires specific training to blasting, digging, ditching, drilling, operate pipeline equipment; therefore, leveling or plowing near the pipeline MPL employees will handle these right of way without first contacting the duties. DO NOT attempt to operate any state one call center. pipeline equipment, such as valves, in Be aware that pipelines frequently share an emergency because doing so may rights of way with other utilities (electric Closure worsen the situation. power lines, additional pipelines) or The information above provides an modes of transportation (roadways, Security Threats outline of points to remember when railroads, etc.). Incidents such as dealing with a pipeline emergency. MPL relies on the public to be its eyes lightning strikes, fires, train derailments, Remember, MPL personnel are trained and ears along the pipeline. If you etc. on or near the right of way can to deal with such emergencies. Without witness any act of vandalism, loitering, damage an underground pipeline. Should their input, the risk to those involved receive a bomb threat involving an incidents such as these occur and a can be greatly increased. Therefore, MPL facility or other suspicious activity pipeline operated by MPL is nearby, contacting MPL in the event of any along the right of way or pipeline facility, please call the MPL emergency number pipeline emergency is critical. please report it immediately to the MPL at 1-833-675-1234 to report the incident. Pipeline Operations Center at 1-833-675-1234. Pipeline Systems Map To learn more about the pipeline location Natural Disasters and products transported through it, log When a natural disaster (hurricane, on to www.marathonpipeline.com or storm, flood, tornado, volcano or download the FREE Marathon Pipeline earthquake) strikes or is pending, the Finder App from the App Store or Google area will be closely monitored. Pipeline Play. You may also visit www.npms. facilities will be inspected after the phmsa.dot.gov to view the approximate disaster. MPL station personnel may location of pipelines in your area. contact emergency officials to identify any road closures that may hamper access to the facility.

For more information, use the email address or voice mailbox number below:

CONTACT [email protected] | 1-855-888-8056 | www.marathonpipeline.com US Emergency Number: 1-833-675-1234

39 PAM21 MoGas Pipeline LLC

329 Joesphville Road Wentzville, MO 63385 Phone: 1-636-856-8035 Website: www.mogaspipe.com

MoGas Pipeline LLC is a limited liability public awareness, pipeline integrity company based in Wentzville, Missouri. management, and operator qualification EMERGENCY CONTACT: The company operates 263 miles of programs. These programs mandate 1-800-282-4916 high pressure natural gas transmission pipeline operators take the necessary pipeline located in eastern and south steps to make their pipelines safe and PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: central Missouri and western Illinois, avoid incidents. Some examples of Natural Gas 1971 115 ranging in diameter from 4’’ to 16’’. The how MoGas Pipeline LLC takes action company’s primary mission is to take against unintended incidents and other MISSOURI receipt of natural gas from interstate threats to safety include: COUNTIES OF OPERATION: pipelines and to redeliver natural gas to • A Supervisory Control and Data suburbs of St. Louis and communities Crawford Phelps Acquisition (SCADA) system that along Interstate 44. Dent Pike gathers and analyzes real time Franklin Pulaski operational data 24-hours a day, 365 COMMITMENT TO SAFETY, HEALTH Gasconade St. Charles days a year & ENVIRONMENT Lincoln • Continuous ROW inspection, ______Dedicated to striving towards excellence including foot patrol and aerial Changes may occur. Contact the operator to in our Health, Safety, and Environment inspection discuss their pipeline systems and areas of operation. (HSE) programs, MoGas Pipeline LLC, • Internal inspection of pipelines views HSE as a fundamental core value. to identify anomalies in need of Aiming to achieve the safe uninterrupted remediation Pipeline LLC via our website or phone supply of natural gas throughout eastern • Cathodic protection systems to number. Finally, because MoGas Pipeline and south central Missouri, all operations mitigate corrosion LLC operates in both Missouri and are managed in a manner that protects • Emergency response training with Illinois, we would like to remind the public the environment, maintains the health local emergency responders of the appropriate One Call numbers to and safety of employees, contractors, • Employee qualification programs contact depending upon location: and the public, and complies with to ensure procedures are correctly applicable laws and regulations. followed • Missouri One Call: 1-800-344-7483 (811) or http://www.mo1call.com/ MoGas Pipeline LLC realizes these If an emergency responder would like commitments by implementing more information about our emergency • Illinois One Call: 1-800-892-0123 and adhering to programs such as response plan, please contact MoGas (811) or http://www.illinois1call.com/

Pike

Lincoln

Illinois Madison St. Charles

Gasconade Franklin Missouri

Crawford

Phelps System Coverage Overview Pulaski MoGas Pipeline LLC

MOGAS January 30, 2014 Dent Pipeline Centerline Asset County µ State Boundary

Data provided by: ©2014 ESRI, ESRIBIS AND Tele Atlas Note: ©1984 - 2014 Tele Atla s, Rel. 12/2008 This map has been carefull y compiled from the best existing Po rtions ©1984-2011 Tele Atla s and Valassis Lists, Rel. 01/2014 sources available at the time of preparatio n, but PARADIGM ©2014 The Paradigm Alliance, Inc does not guarantee the accuracy of the map nor the titles This work and all rights therein and thereto, including copyright deli neated thereo n, nor does PA RADIGM assu me any and/or patent rights, trademark and trad e dress, are owned by responsibility or li ability for any reliance thereon. The Paradigm Alliance, Inc.

40 PAM21 NuStar Pipeline Operating Partnership, L.P.

NuStar Energy - Central East Region 7340 West 21st North Suite 200 Wichita, KS 67205 Phone Number: 316-773-9000 Website: www.nustarenergy.com

ABOUT NUSTAR PIPELINE and the protection of the environment OPERATING PARTNERSHIP L.P. are core business values. NuStar is EMERGENCY CONTACT: committed to achieving health, safety 1-800-759-0033 The goal of the NuStar Energy Pipeline and environmental (HSE) excellence Public Awareness Program is to enhance throughout the organization. NuStar PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: safety and environmental protection emphasizes its HSE commitment Anhydrous Ammonia 1005 125 through increased public awareness through internal audits, public and knowledge. Public awareness awareness, damage prevention, MISSOURI programs should raise the awareness of pipelines integrity management, COUNTIES OF OPERATION: the affected public and key stakeholder emergency response preparedness, audiences of the presence of pipelines AAudrain AMontgomery in their communities and increase their and other programs. In addition, most of NuStar’s pipelines are operated via AClark APhelps understanding of the role of pipelines in ACrawford APike transporting energy. satellite communication systems from a central control room located in San ADent Ralls NuStar Pipeline Operating Partnership Antonio, TX. This control center is Gasconade St. Charles L.P. is a subsidiary of NuStar Energy equipped with state-of-the-art computer Howell Texas L.P. Our business unit consists of systems designed to continuously Lewis Warren pipeline systems that transports refined monitor real-time operational data, Marion petroleum products, including gasoline, operate equipment associated with the ______Changes may occur. Contact the operator to diesel and propane throughout Kansas, delivery of crude oil, refined products, discuss their pipeline systems and areas of Nebraska, Iowa, South Dakota, and anhydrous ammonia, and control operation. North Dakota and Minnesota. We safety measures to ensure smooth and also operate an anhydrous ammonia safe operation of our pipelines. pipeline system in Louisiana, Arkansas, also utilizes aerial surveillance and/or Missouri, Illinois, Indiana, Iowa and WHAT DOES NUSTAR PIPELINE on-ground observers to identify potential Nebraska. Anhydrous ammonia is OPERATING PARTNERSHIP L.P. dangers. Control center personnel primarily used as agricultural fertilizer DO IF A LEAK OCCURS? continually monitor the pipeline system and used as a feedstock to a number of and assess changes in pressure and To prepare for the event of a leak, industrial applications. flow. They notify field personnel if there pipeline companies regularly Is a possibility of a leak. Automatic Please read and keep these important communicate, plan and train with shutoff valves are sometimes utilized to safety messages located in the local emergency responders. Upon Isolate a leak. brochure and company profile provided the notification of an incident or leak in the event you need to reference them the pipeline company will immediately Gas transmission and hazardous liquid in the future. dispatch trained personnel to assist pipeline operators have developed Contact us for more information about emergency responders. supplemental hazard and assessment programs known as Integrity our Integrity Management Program or Pipeline operators and emergency Management Programs (IMPs). Specific Emergency Response Plan. responders are trained to protect life, information about NuStar Pipeline property and facilities in the case of an Operating Partnership L.P.’s program COMMITMENT TO SAFETY, emergency. HEALTH & ENVIRONMENT may be found on our Web site, or by Pipeline operators will also take steps contacting us directly. At NuStar, the health and safety of our to minimize the amount of product that personnel, customers, and neighbors leaks out and to isolate the pipeline HOW TO GET emergency. ADDITIONAL INFORMATION MAINTAINING SAFETY AND For an overview of NuStar INTEGRITY OF PIPELINES Pipeline Operating NuStar Pipeline Operating Partnership Partnership L.P.‘s IMP or LP. invests significant time and capital Emergency Response Plan, maintaining the quality and integrity go to www.nustarenergy.com of their pipeline systems. Most active or contact us at pipelines are monitored 24 hours a day 1-800-759-0033. via manned control centers. NuStar Pipeline Operating Partnership L.P.

41 PAM21 Omega Pipeline Company, LLC

299 Ordinance Road Building 2570 PO Box 2861 Fort Leonard Wood, MO 65473-2861 Phone: 1-573-329-3382 Website: www.omegapipeline.com

Omega Pipeline Company, LLC for heating commercial and residential (Omega) is a local distribution company buildings, as well as for creating steam EMERGENCY CONTACT: which owns and operates the natural needed in industrial processes. 1-573-329-3382 gas pipeline and propane air plant • Omega has a 24 hour answering on the Fort Leonard Wood military PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: service that monitors all incoming gas installation in Central Missouri. Omega Natural Gas 1971 115 calls and notifies Omega personnel of also provides gas marketing services to Propane/Synthetic any gas related issues or concerns. nearby towns and industrial customers. Natural Gas 1978 115 Omega personnel are available 24 hours a day, 7 days a week to COMMITMENT TO SAFETY, HEALTH MISSOURI respond to any gas situations that & ENVIRONMENT COUNTIES OF OPERATION: may arise. Omega is committed to providing • Omega’s field personnel conduct Pulaski safe and reliable natural gas products routine maintenance on the pipeline ______and services to its customers while Changes may occur. Contact the operator to and facilities year round. Additionally, working to protect the environment. The discuss their pipeline systems and areas of Omega’s pipeline and facilities are operation. Company strives to be a partner in the inspected annually by the Missouri community in part by providing training Public Service Commission. Omega and education to customers, safety complies with applicable state and • Whenever Omega is required to dig officials and end users of the natural federal regulations. up part of its underground pipeline, gas it transports. Omega is proud of its the Company aims to maintain its safety record and continually strives to • Omega meets with and provides work site in a manner that best exceed both customer and regulatory training for emergency response protects public safety. In addition, expectations. personnel as well as participating Omega will return all work sites to in various safety programs. In The gas supplied to Omega is their original states at completion of a addition, Omega provides educational transported across Missouri through a project. materials and brochures covering high pressure underground pipeline. natural gas related topics such as gas Omega aims to continually improve its Upon entering Omega’s system, the safety measures to new personnel performance and to exceed customer pressure is reduced and sent through and their families. and community expectations. Omega Omega’s distribution system to end encourages feedback and works to users. Omega’s distribution system is • Omega aims to reduce third-party incorporate suggestions to provide primarily comprised of underground pipe damage caused by various types of constantly improving performance. If you with above ground pressure reducing digging and excavation activities, have questions or concerns about the stations and meter sets. In addition to the leading cause of pipeline Omega pipeline or natural gas safety, transporting and distributing natural gas, accidents in the US, by installing please do not hesitate to contact us. Omega operates a propane air plant numerous pipeline markers indicating that can provide synthetic natural gas approximate locations of gas lines, in times of peak demand. Natural gas and participating in public awareness Pulaski County supplied by Omega is routinely used programs. These pipeline markers Pulaski County

Fort Leonard provide information about whom Wood to contact if you need additional information about a pipeline location. Omega participates in the “Dig Rite” or Missouri One Call System which allows for line locator services to be provided upon request. In addition Fort Leonard Wood excavation permits are required before any digging is performed. Please contact DPW for additional information.

42 PAM21 ONEOK North System LLC

Local Office ONEOK Plaza 100 W. 5th St 100 West Fifth Street Tulsa, OK 74103 Tulsa, OK 74103 Phone: 918-588-7000 Website: www.oneok.com

ABOUT ONEOK, INC. and sustainable manner. Environmental, safety and health is our primary focus EMERGENCY CONTACT: ONEOK, Inc. is a leading midstream at ONEOK. ONEOK is purposeful in 1-888-844-5658 service provider that owns one of the improving employee and process safety. nation’s premier natural gas liquids Our key performance indicators keep PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: systems, connecting NGL supply in ONEOK focused improving results. Butanes 1011 115 the Mid-Continent, Permian and Rocky We continue to make improvements in Natural Gasoline 1203 128 Mountain regions with key market reducing our environmental impact by Propane 1075/1978 115 centers and an extensive network of conserving resources, recycling and Diesel 1202/1993 128 natural gas gathering, processing, utilizing efficient technologies. Raw Feed storage and transportation assets. ONEOK applies our core capabilities EMERGENCY NOTIFICATION(S) : MISSOURI of gathering, processing, fractionating, COUNTIES OF OPERATION: Call 911 first when requiring assistance in transporting, storing and marketing responding to a pipeline event. natural gas and NGLs through vertical Buchanan Platte integration across the midstream value Call ONEOK’s 24 hour emergency Clinton chain to provide our customers with number 888-844-5658 and provide the ______Changes may occur. Contact the operator to premium services while generating following information: discuss their pipeline systems and areas of consistent and sustainable earnings • Location; operation. growth. • Nature of the problem; and ONEOK North System, L.L.C. operates • A telephone number at which a FERC-regulated NGL pipelines in responsible person can be contacted. and other emergency responders. We Kansas, Missouri, Nebraska, Iowa, Illinois meet with responders to discuss our and Indiana that span approximately EMERGENCY RESPONSE emergency response plans and each 1,600 miles and has a capacity to PERSONNEL plan is designed to protect people, the transport up to 134,000 barrels per day, environment and property. Although Emergency Officials are familiar with additional capacity under lease. with the steps required to safeguard the If a pipeline event occurs, emergency The pipeline transports NGL purity public, ONEOK has planned responses response officials will be notified, and products and various refined products, to unique emergency situations that ONEOK operations personnel will be including unleaded gasoline and diesel may arise with its pipeline facilities and dispatched to the site. ONEOK response fuel throughout the Midwest markets, operations. It is important that ONEOK personnel will respond putting safety first particularly near Chicago, Illinois. practice their emergency response efforts in their response efforts. These NGL products are then stored or to be prepared when an unlikely event distributed to our customers, such as If you or another emergency response occurs. petrochemical manufacturers, heating organization established an Incident fuel users, ethanol producers, refineries, Command Center prior to the arrival of EMERGENCY RESPONSE PLANS exporters and propane distributors. This ONEOK personnel, the first ONEOK system includes approximately 978,000 ONEOK has developed specific facility employee who arrives at the site should barrels of storage capacity, both mined response plans based on the knowledge be introduced to the Incident Commander cavern and above-ground storage tanks, of its own personnel, available as the ONEOK Representative.. 22 mainline pumping stations and eight equipment, tools and materials. These NGL propane, butane and 14# natural plans are accessible at each facility. This PUBLIC SAFETY AND gas truck loading terminals. A portion document provides a general overview of EVACUATIONS of the North System transports refined ONEOK’s capabilities. For more detailed Evacuation plans and procedures should petroleum products, including unleaded information or to review the Emergency reflect your department’s available assets gasolines and diesel, from Kansas to Response Plan, please contact Donnie and capabilities of your emergency Iowa which consists of three refined- Krumsiek at response organization. Expert knowledge products terminals and connecting 918-561-8019. of your area is key to creating the best pipelines. Pipeline diameter is 10”. evacuation, traffic control and rerouting, MUTUAL UNDERSTANDING and railroad stoppage plans in order COMMITMENT TO SAFETY, HEALTH In the unlikely event of a pipeline to limit public exposure and minimize & THE ENVIRONMENT emergency, ONEOK employees are accidental ignition. ONEOK is committed to operating in a prepared to respond in coordination ONEOK will provide product hazard safe, reliable, environmentally responsible with local police and fire departments information to the emergency responders

43 PAM21 ONEOKONEOK North North System System LLC to assist in establishing safe zones attempt to operate pipeline valve or accidents. Call IMMEDIATELY if you see relative to the products which are being equipment. In doing so, these actions suspicious or questionable activity near transported through the pipeline system. may worsen an event. the pipeline right of way. These established safe zones will assist Be aware that pipelines frequently share in identification of those whom may be BOMB OR SECURITY THREAT rights of way with other utilities (electric requested to evacuate the area. ONEOK relies on the public to be its power lines, additional pipelines) or eyes and ears along the pipeline. If modes of transportation (roadways, FIRE OR EXPLOSION you witness any act of vandalism, railroads, etc.). Incidents such as ONEOK does not employ dedicated loitering, receive a bomb threat involving lightning strikes, fires, train derailments, fire response personnel and must a ONEOK facility or other suspicious etc. on or near the right of way can rely on the capabilities of local activity along the right of way or pipeline damage an underground pipeline. Should emergency responders. ONEOK facility, please report it immediately to incidents such as these occur and a through memberships in state the ONEOK’s Pipeline Control Center at pipeline operated by ONEOK is nearby, pipeline associations, provide training 888-844-5658. please call the ONEOK emergency opportunities to Emergency Responders. number at 888-844-5658 to report the Other agencies, including the State NATURAL DISASTERS incident. Fire Marshall’s office may also provide When a natural disaster (hurricane, pipeline emergency response training. NATIONAL PIPELINE MAPPING storm, flood, tornado, volcano or The U.S. Department of Transportation SYSTEM earthquake) strikes or is pending, Emergency Response Guidebook the area will be closely monitored. The US Department of Transportation, provides information on potential hazards, Pipeline facilities will be inspected after Pipeline and Hazardous Materials Safety public safety and emergency response. the disaster. ONEOK personnel may Administration, Office of Pipeline Safety contact emergency officials to assist has created a web-based system to RESCUE OR MEDICAL DUTIES in identifying any road closures that assist emergency responders in locating Emergency response personnel will be may hamper accessibility to the facility. and identifying pipelines within their area contacted to assist with any needed If damage occurs in your area please as well as the Operator of the pipeline rescue. Coordination will be made with contact ONEOK and a field employee will system. emergency services and/or with a local respond to the concern or damage which Not all of ONEOK pipelines are hospital or medical provider in the event has been reported. included in the NPMS mapping system. of a medical emergency. Production, distribution and gathering RIGHT-OF-WAY ACTIVITY pipelines are exempt from reporting PIPELINE EQUIPMENT AND One of the greatest threats to safe pipe- pipelines into the National Pipeline FACILITIES line operation is the accidental damage Mapping System. Federal law requires that pipeline caused by excavation, construction, operators to have specific training when farming activities, and homeowner INTEGRITY MANAGEMENT operating a pipeline system. ONEOK construction and maintenance. In accordance with federal regulatory requests that Emergency Officials not Awareness is crucial in preventing these requirements, ONEOK has developed a hazard assessment program known as an Integrity Management Plan (IMP). This plan focuses on the identification and mitigation of hazards to the pipeline system. Specific information about ONEOK’s program may be found by contacting our Integrity Manager, Scott Henderson at ScottBrian.Henderson@ oneok.com.

CLOSURE ONEOK values Emergency Officials and Responders. We appreciate the knowledge and capabilities each responder brings when assisting in a pipeline emergency. If ONEOK can offer your department any additional information, please contact us.

CONTACT [email protected] | 1-918-561-8019 | www.oneok.com US Emergency Number: 1-888-844-5658

44 PAM21 Panhandle Eastern Pipe Line

1300 Main St. Houston, TX 77002 Phone: (713) 989-7000 Website: www.energytransfer.com

Energy Transfer Partners, a Texas- • Midstream Operations – based energy company founded in 1995 approximately 40,000 miles of natural EMERGENCY CONTACT: as a small intrastate natural gas pipeline gas gathering pipelines and more 1-800-225-3913 company, is now one of the largest than 60 processing, treating and and most diversified master limited conditioning plants. PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: partnerships in the United States. Natural Gas 1971 115 • NGL Transportation and Services – Strategically positioned in all of approximately 4,800 miles of NGL the major U.S. production basins, MISSOURI pipelines, three processing plants, four the company owns and operates a COUNTIES OF OPERATION: fractionation facilities and NGL storage geographically diverse portfolio of facilities with aggregate working energy assets, including midstream, Audrain Johnson storage capacity of approximately 53 intrastate and interstate transportation Boone Marion million Bbls. and storage assets. Energy Transfer Callaway Moniteau operates more than 90,000 miles of Panhandle Eastern Pipe Line Cass Montgomery natural gas, crude oil, natural gas liquids Company is an approximately 6,000- Cole Pettis and refined products pipelines and mile natural gas pipeline system with Cooper Pike related facilities, including terminalling, access to diverse supply sources and Henry Ralls storage, fractionation, blending and extends from producing areas in the Howard Randolph various acquisition and marketing assets Anadarko Basin of Texas, Oklahoma Jackson in 38 states. and Kansas through Missouri, Illinois, ______Changes may occur. Contact the operator to Indiana, Ohio and into Michigan. Our • Intrastate Transportation and Storage discuss their pipeline systems and areas of Midwest customer base includes operation. Operations – approximately 7,900 some of the nation’s largest utility and miles of natural gas pipelines and industrial natural gas users. three storage facilities. For more information about local Audrain, Boone, Callaway, Howard, • Interstate Transportation and Storage operations of Panhandle Eastern Pipe Marion, Montgomery, Pike, Ralls and Operations – approximately 19,000 Line Company, please contact us: Randolph counties: miles of natural gas pipelines; 10,770 Dan Barton - Operations Manager miles of crude oil pipelines; and 2,200 Mark Shedd - Area Director Phone: 217-734-3221 (wk), miles of refined products pipelines Phone: 913-837-4811 (wk), 217-430-2511 (cell) along with 40 refined products 573-819-1475 (cell) Email: marketing terminals. Email: [email protected] [email protected]

Cass, Henry, Jackson and Johnson counties: Ron Boline - Operations Manager Phone: 913-837-4821 (wk), 913-634-1097 (cell) Email: [email protected]

Cole, Cooper, Howard, Johnson. Moniteau and Pettis counties: Kenneth Pullam - Operations Manager Phone: 660-568-1221 (wk), 407-415-7056 (cell) Email: [email protected]

45 PAM21 Permian Express Partners

1300 Main St. Houston, TX 77002 Phone: (713) 989-7000 Website: www.energytransfer.com

Energy Transfer Partners, a Texas- Permian Express Partners is an based energy company founded in 1995 approximately 1,700-mile crude oil EMERGENCY CONTACT: as a small intrastate natural gas pipeline pipeline system and extends from 1-800-753-5531 company, is now one of the largest producing areas in the Permian Basin of and most diversified master limited Texas through to Louisiana, Arkansas, PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: partnerships in the United States. Missouri and Illinois. Permian Express, Crude Oil 1267 128 Strategically positioned in all of a joint venture, is operated by Sunoco the major U.S. production basins, Pipeline. MISSOURI the company owns and operates a COUNTIES OF INACTIVE PIPE: For more information about local geographically diverse portfolio of operations of Permian Express Partners, energy assets, including midstream, Bollinger Perry please contact us: intrastate and interstate transportation Carter Ripley and storage assets. Energy Transfer Jason Maxey Madison Wayne operates more than 90,000 miles of Operations Supervisor ______Changes may occur. Contact the operator to natural gas, crude oil, natural gas liquids 618-431-0825 (wk) 618-315-0542 (cell) discuss their pipeline systems and areas of and refined products pipelines and [email protected] operation. related facilities, including terminalling, storage, fractionation, blending and various acquisition and marketing assets in 38 states. Atchison Worth

Nodaway Putnam Mercer Schuyler Harrison Scotland • Intrastate Transportation and Storage Clark Gentry Holt Sullivan Adair Operations – approximately 7,900 Grundy Andrew Knox Daviess Lewis miles of natural gas pipelines and DeKalb

Linn three storage facilities. Livingston Macon Buchanan Shelby Marion Caldwell Clinton • Interstate Transportation and Storage MISSOURI Chariton Platte Carroll Monroe Ralls Operations – approximately 19,000 Clay Ray Randolph miles of natural gas pipelines; 10,770 Pike Audrain Saline Howard miles of crude oil pipelines; and 2,200 Jackson Lafayette

Boone Lincoln

miles of refined products pipelines Montgomery Cooper Johnson Callaway along with 40 refined products Cass Pettis Warren St. Charles marketing terminals. Moniteau St. Louis CountySt. Louis city Cole Henry Morgan Osage Gasconade Bates • Midstream Operations – Benton Franklin

Miller Jefferson approximately 40,000 miles of natural Maries St. Clair Camden Hickory gas gathering pipelines and more Vernon Crawford Washington Phelps Pulaski than 60 processing, treating and Cedar Ste. Genevieve Dallas Polk Laclede St. Francois conditioning plants. Barton Iron Perry Dent Dade

• NGL Transportation and Services – Madison Jasper Greene Webster Texas Wright Reynolds Cape Girardeau Bollinger approximately 4,800 miles of NGL Lawrence Shannon Wayne pipelines, three processing plants, four Newton Christian Douglas Scott fractionation facilities and NGL storage Carter Barry Stone McDonald Howell Stoddard facilities with aggregate working Taney Mississippi Ozark Oregon Butler storage capacity of approximately 53 Ripley New Madrid million Bbls.

Pemiscot Dunklin

46 PAM21 Phillips 66 Pipeline LLC

Missouri Office: Headquarters: 411 South Keeler Phillips 66 Pipeline LLC Bartlesville, OK 74004 2331 CityWest Blvd. Phone: 918-661-1656 Houston, TX 77042

PHILLIPS 66 PIPELINE LLC OWNS OR OPERATES 24-Hour Emergency Contact: APPROXIMATELY 600 MILES OF PIPELINE AND 5 STORAGE TERMINALS IN OR VERY NEAR MISSOURI. 1-877-267-2290 PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: Gasoline 1203 128 Operating with Integrity Incident Command System HVL Products Pipelines are the most reliable method Phillips 66 Pipeline LLC utilizes an to move en­ergy products, helping to expandable Incident Command System. MISSOURI meet our nation’s grow­ing economic and Personnel and federal, state and local COUNTIES OF OPERATION: energy needs. They operate under many agencies may be integrated into the Cass Moniteau government regulations and industry Unified Command Structure, scalable to Cole Monroe standards. These measures address all the size and complexity of an incident. Franklin Morgan aspects of pipeline operation, such as Gasconade Newton where and how they are built, operated Spill Response Equipment Jasper Osage and maintained -- and Phillips 66 Phillips 66 Pipeline LLC maintains Jefferson Pettis Pipeline LLC strives to exceed each emergency response trailers and Johnson St. Louis require­ment and best practice. equipment at strategically-lo­cated Lawrence St. Clair facilities. Response equipment may ______Committed to Safety and Reliability include spill boom (as needed and Changes may occur. Contact the operator to discuss their pipeline systems and areas of Our commitment to safety goes further, of various types, sizes and lengths), operation. with the goal that everyone who lives absorbent materials, boats, motors, or works near our as­sets is aware of hand and power tools, pumps, hoses, our lines and facilities, adopts safe personal protective equipment (PPE), Response Plans and Maps digging practices, learns the signs of a first aid and miscel­laneous supplies. potential pipeline leak and knows how Each trailer is inspected; equip­ment is To view and download emergency to quickly respond if he or she suspects deployed during drills on a regular basis. response plans and procedures, visit a problem. As part of our on-going http://response-planning.com/ERPP/ damage prevention program, we employ Oil Spill Contractors p66. To view and obtain GIS map files of many tactics to ensure the safety of our our locations, visit Certified Oil Spill Response communi­ties. https://www.npms.phmsa.dot.gov/. Organizations (OSROs) are under contract by Phillips 66 Pipeline LLC for Emergency Response Capabilities Contact Phillips 66 Pipeline LLC use in this area. Marine Spill Response Phillips 66 Pipeline LLC has committed Corp. (MSRC) and associated STAR Phillips 66 Pipeline LLC Headquarters resources­ to prepare and implement Contractors are used globally, while 2331 CityWest Blvd. its emergency response plans and OSROs that are close to assets in Houston, TX 77042 has obtained, through contract, the this area are also identified and under www.phillips66pipeline.com necessary private personnel and contract for use in an incident. Non-Emergency Phone Number equipment to respond to a worst case The Phillips 66 Pipeline LLC Emergency 800-231-2566 discharge, to the maximum extent Response Action Plan (ERAP) practical. contains specific contact and resource information for these companies. In Communications addition, these OSROs are invited to Phillips 66 Pipeline LLC employs a participate in training and pre-planning 24-hour Control Center as a hub of exercises with Phillips 66 Pipeline LLC communication in emergency response local and regional response teams. situations. On-site communications OSROs and Co-Ops can be relied upon are conducted using cellular phones; for an appropriate level of response, and portable radios and/or land-line with spill response equipment and telephone systems from facilities and trained personnel. offices.

47 PAM21 Phillips 66 Pipeline LLC

Additional Information and Resources Visit the following industry and government sites for important safety refer­ences and educational materials.

National Association of State Fire Marshal’s “Pipeline Emergencies” www.pipelineemergencies.com

PHMSA Emergency Response Guidebook https://www.phmsa.dot.gov/hazmat/erg/emergency-response-guidebook-erg

National Pipeline Mapping System https://www.npms.phmsa.dot.gov/

Pipelines and Informed Planning Alliance http://primis.phmsa.dot.gov/comm/pipa/landuseplanning.htm

This document is for informational purposes only and does not replace, substitute or preempt any interaction or agreements with Phillips 66 Pipeline LLC or its representatives. For specific information, including state-specific questions, contact 800-231-2566.

48 PAM21 Sinclair Transportation Company

26036 Old Highway 24 Carrollton, Missouri 64633 Phone: 1-660-542-0206 Website: www.sinclairoil.com

Sinclair Transportation Company is a COMMITMENT TO SAFETY, HEALTH division of Sinclair Oil Corporation, a & ENVIRONMENT EMERGENCY CONTACT: privately held company based in Salt 1-800-321-3994 Lake City Utah. Sinclair operates two Public and environmental safety is refineries with a combined refining the highest priority in the operation PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: capacity of 108,000 BPD. Take to the and maintenance of Sinclair’s pipeline Diesel Fuel 1202/1993 128 highway in twenty-two states in the West system. Sinclair employs a qualified staff Gasoline 1203 128 and Midwest and you’ll discover over of professionals that are committed to 2,600 retail stations and convenience safely transporting petroleum products. MISSOURI stores proudly displaying the Sinclair In the event of a pipeline emergency COUNTIES OF OPERATION: Dinosaur. We operate 8 refined product our field personnel are trained and fully terminals and close to 1,000 miles of prepared to respond. Our response Adair Knox pipeline transporting crude oil, and personnel coordinate their efforts with Carroll Linn refined products. Our Mid-Continent local police and fire departments and Chariton Macon Pipeline District includes a 210 mile other emergency responders. Clark Ray refined products pipeline that supplies Jackson Scotland fuel to our Carrollton, Missouri and ______Changes may occur. Contact the operator to Montrose, Iowa terminals. discuss their pipeline systems and areas of operation.

49 PAM21 Spire

Spire Inc. 700 Market Street Saint Louis, MO 63101 Website: www.SpireEnergy.com

WORKING TOGETHER TO KEEP OUR COMMUNITIES SAFE EMERGENCY CONTACT: Every day, we have the pleasure of serving millions of people with our five natural gas 1-800-582-1234 delivery businesses. We also maintain an underground natural gas storage field and a Kansas City and Western Missouri liquid propane pipeline. 1-800-887-4173 We know it’s our responsibility to keep those we serve along our pipelines safe. And St. Louis and Eastern Missouri though underground pipes are the safest most reliable way to transport natural gas and other petroleum products, accidents can always happen. PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: Natural Gas 1971 115 That’s why we routinely monitor, patrol and inspect our pipelines via aircraft, vehicles Propane Vapor 1978/1075 115 and on foot. We also work to promote safety and pipeline awareness through first- Liquid Propane 1978/1075 115 responder training courses and many customer communications like bill inserts, customer guides and more. MISSOURI COUNTIES OF OPERATION: We do all this—and so much more—because at Spire, safety is a value. And our values drive everything we do. So our promise is to always work with the communities we Cass St. Charles serve and our first responder partners to keep our pipelines safe. Franklin St. Louis With that in mind, here’s a look at where our pipelines are located, how they’re marked Jackson City of St. Louis and who to call should you ever be in an emergency situation. Platte ______Changes may occur. Contact the operator to discuss their pipeline systems and areas of operation.

Spire service area

50 PAM21 Summit Natural Gas

116 Chiefs Court Branson, MO 65616 Phone: 1-800-927-0787 Website: www.SummitNaturalGas.com

Summit Natural Gas of Missouri • SNG-MO is available 24 hours a day, (SNG-MO) is committed to providing 7 days a week and can be reached EMERGENCY CONTACT: safe, reliable and efficient natural gas by calling our emergency contact 1-800-927-0787 to communities throughout Missouri. number. SNG-MO regularly inspects In total, we operate approximately its system by ionization leak survey PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: 1,410 miles which consist of 301 miles and by visual methods. Above ground Natural Gas 1971 115 of transmission and 1,061 miles of marker signs are displayed frequently distribution and all vary in size from 8” to along our facilities to alert the public MISSOURI 1”. SNG-MO brings natural gas access and excavators to the presence of the COUNTIES OF OPERATION: to tens of thousands of Missouri families pipeline. to use for home heating, cooking, and Barry Lawrence • SNG-MO’s Public Awareness Plan water heating. Benton Miller promotes pipeline education to Caldwell Morgan multiple groups, including emergency COMMITMENT TO SAFETY, HEALTH Camden Pettis response personnel, public officials, & ENVIRONMENT Daviess Stone contractors and consumers alike. Douglas Taney SNG-MO’s leading commitment is to Participation in the Missouri 811 Dig Greene Texas public safety and compliance with the Rite utility notification helps prevent Harrison Webster Public Service Commission’s rules and damage to our pipeline and helps Howell Wright regulations. Summit works diligently to protect the general public. If a pipeline Laclede promote pipeline safety in a variety of incident occurs, SNG-MO is well ______ways, including inspection programs, prepared to respond. Emergency Changes may occur. Contact the operator to public education, pipeline markers, preparedness and planning measures discuss their pipeline systems and areas of operation. facility mapping, surveys, patrolling, are in place if a pipeline incident pressure monitoring, odorization and occurs. SNG-MO works closely liaising with public officials. Summit with local emergency response also recognizes that protecting the organizations to educate them about environment is vital to our operations, our pipelines and how to respond in which is why we are taking part in the the unlikely event of an emergency.

U.S. Environmental Protection Agency’s • Natural gas pipelines are among the Methane Challenge Program, aimed at safest fuel transportation systems reducing methane emissions within the in the world. With more than 2.5 natural gas industry. The company is million miles of natural gas pipelines proud of its safety and environmental nationwide, natural gas serves nearly efforts. 67 million homes, almost 200,000 factories and 5.4 million businesses. Natural gas pipelines are tested, monitored, and maintained 24 hours a day, 365 days a year. In addition, natural gas utilities spend more than $22 billion annually to enhance PIPELINE MARKER INFORMATION the safety of their distribution and • Indicates area of pipeline operations transmission systems. • Indicates company name, phone number, type of product • Does not show exact location • Does not indicate depth • Does not indicate pipeline pressure

51 PAM21 Tallgrass Energy / Rockies Express Pipeline

Rockies Express Pipeline Tallgrass Interstate Gas Transmission Website: www.tallgrassenergy.com

ROCKIES EXPRESS PIPELINE Missouri. To help balance seasonal loads, TIGT also owns the Huntsman EMERGENCY CONTACT: Rockies Express Pipeline (REX) is one natural gas storage facility, located in Tallgrass Interstate Gas Transmission of the United States’ largest pipelines Cheyenne County, Neb., which has 1-888-763-3690 and is transforming into the nation’s approximately 16 billion cubic feet Rockies Express Pipeline northernmost bi-directional natural 1-877-436-2253 gas header system. The pipeline is of storage capacity. The pipeline is jointly owned by Tallgrass Energy (75 constructed of between 2- and 24- inch steel pipe, and has an average PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: percent) and Phillips 66 (25 percent). Natural Gas 1971 115 REX became fully operational in 2009 MAOP of 750. TIGT serves, through local distribution companies (LDCs), and stretches about 1,700 miles from MISSOURI largely rural residential, commercial northwestern Colorado and Wyoming to COUNTIES OF OPERATION: eastern Ohio. Built with 42- and 36-inch and agricultural customers in Colorado, diameter steel pipe, REX taps major Kansas, Nebraska, Wyoming and Tallgrass Interstate Gas supply basins in the Rocky Mountain Missouri. TIGT also delivers natural gas Transmission (TIGT) for a significant number of commercial and Appalachian regions and serves Cass Jackson energy markets across a vast segment and industrial loads, including ethanol of North America. REX’s Zone 3, which and power plants. Rockies Express Pipeline (REX) spans from eastern Illinois to eastern Audrain Clinton Ohio, is bi-directional and can flow up to COMMITMENT TO SAFETY, HEALTH Buchanan Pike 4.4 billion cubic feet per day of natural AND ENVIRONMENT Caldwell Randolph gas. West-to-east long-haul capacity Tallgrass Energy operates Pony Express Carroll Ralls on REX is 1.8 billion cubic feet per day. Pipeline, Rockies Express Pipeline, Chariton REX has an MAOP of 1,480. Tallgrass Interstate Gas Transmission ______and Trailblazer Pipeline. Tallgrass takes Changes may occur. Contact the operator to TALLGRASS INTERSTATE GAS seriously its responsibility to ensure the discuss their pipeline systems and areas of operation. TRANSMISSION health and safety of our employees, the Tallgrass Interstate Gas Transmission general public and the environment. (TIGT) owns and operates We comply with all federal, state and approximately 4,650 miles of natural local laws and regulations, and we gas transportation pipelines in Colorado, meet or exceed industry standards Wyoming, Kansas, Nebraska and and best practices. Highly trained and

52 PAM21 Tallgrass Energy / Rockies Express Pipeline experienced personnel monitor our We have emergency shut-down systems active member of Common Ground pipelines 24 hours a day, 7 days a week that can isolate anomalies anywhere in Alliance, working together to educate using sophisticated Supervisory Control our system quickly and safely. As part of stakeholders on pipeline safety and to and Data Acquisition (SCADA) systems our ongoing education efforts, we work promote safe excavation. so we have real-time information regularly with first responders – using For more information about our regarding the safety and integrity of our tools such as tabletop exercises and commitment to safety and our public pipeline. We patrol our pipelines by foot, hands-on mock drills – to ensure they awareness, damage prevention and vehicle and aircraft to ensure safety are familiar with our assets and know emergency preparedness activities and and identify potential concerns such as what to do in the unlikely event of an resources, visit our web site or contact encroachments. emergency. In addition, Tallgrass is an Tallgrass directly at 303-763-2950.

De Kalb Kane Whiteside Lee Aurora Des Moines Kendall Joliet Rock Island Bureau Henry La Salle Grundy Douglas Mercer Putnam Sarpy Stark Marshall Knox Cass Woodford Livingston Henderson Warren Peoria Peoria

Otoe Illinois Ford Worth Putnam Schuyler Scotland McDonough Fulton I llinois Atchison Mercer Clark Hancock Ta zewell McLean Nemaha Nodaway Harrison

Gentry Sullivan Mason Adair De Witt Champaign Knox Schuyler Richardson Holt Grundy Lewis Logan Menard Piatt Andrew Daviess Adams Brown Cass De Kalb Springfield Linn Macon Brown Macon Marion Douglas Nemaha Doniphan Livingston Shelby Morgan Buchanan Caldwell Scott Moultrie Clinton Pike Sangamon Atchison Ralls Christian Chariton Monroe Jackson Carroll Randolph Platte Clay Shelby Ray Pike Greene Jefferson Macoupin Audrain Calhoun Leavenworth Montgomery Topeka Saline Howard Wyandotte Jersey Lafayette Lincoln Fayette Shawnee Jackson Boone Montgomery Kansas City Bond Cooper Callaway Madison Douglas Johnson Warren St. Charles Clay Johnson Pettis Osage St. Louis Marion Cass Moniteau Cole St. Louis Clinton Franklin Miami St. Louis City St. Clair Wayne Lyon Missouri Gasconade Henry Franklin Morgan Osage Washington Benton Jefferson Bates Jefferson Monroe Coffey Anderson Linn Miller Maries Randolph Perry St. Clair Camden Crawford Franklin Hickory Washington Woodson Allen Ste. Genevieve Bourbon Vernon Phelps Pulaski St. Francois Jackson Cedar Williamson Dallas Perry Laclede Iron Polk Dent Wilson Neosho Crawford Barton Madison Union Elk Dade Johnson Reynolds Cape Girardeau Greene Texas Webster Wright Bollinger Pulaski Montgomery Labette Jasper Alexander Cherokee Springfield Shannon Lawrence Wayne Scott Christian Douglas Carter Newton Stoddard Ottawa Mississippi Nowata Craig Stone Howell Washington Barry Oregon Butler McDonald Taney Ozark Ripley Osage New Madrid

Delaware Rogers Mayes

Dunklin Pemiscot Missouri Operations Wagoner Tulsa Cherokee Adair Tallgrass Interstate Rockies Express Pipeline Gas Transmission Okmulgee Muskogee Sequoyah Okfuskee McIntosh PAM21 Hughes Haskell 53

Le Flore Pittsburg Latimer TC Energy / ANR Pipeline

EMERGENCY CONTACT: 1-800-447-8066

TC Energy operates one of the most sophisticated pipeline systems in the world. Our network of more than 56,000 miles of natural gas pipelines connect virtually every EMERGENCY CONTACT: major natural gas supply basin and market, transporting 25% of the natural gas 1-800-447-8066 consumed in North America. PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: You may obtain access to view maps for TC Energy / ANR Pipeline facilities by Natural Gas 1971 115 following the instructions at: http://www.npms.phmsa.dot.gov MISSOURI COUNTIES OF OPERATION: For more detailed information on TC Energy’s ANR Pipeline facilities, please use the Public Awareness contact information shown below. Gentry Nodaway Harrison Putnam Holt Schuyler TC Energy / ANR Pipeline Contact Information: Mercer Worth EMERGENCY CONTACT: 1-800-447-8066 ______Changes may occur. Contact the operator to discuss their pipeline systems and areas of Public Awareness: 1-855-458-6715 or operation. [email protected]

TC Energy / ANR Pipeline Markers and Signs

Right of Way Signs A. Pipeline Markers are placed along the Right of Way, at Road Crossings, at Railroad Crossings and where each pipeline enters or leaves a fenced facility. Pipeline markers similar to these shown below are located above and near the pipe centerline. They display the name of the operator, product and emergency contact number.

MARKER MARKER MARKER SIGNS “BULLET” POST “SLAT” POST

Facility Markers B. Danger signs are located along the perimeter of gas facilities, and at DANGER roadway entrance gates. These signs are to warn visitors and inform Emergency Responders of high pressure natural gas precautions. NO SMOKING, NO OPEN FLAMES, NO TRESPASSING HIGH PRESSURE GAS

54 PAM21 TC Energy / ANR Pipeline

55 PAM21 TC Energy / Keystone Pipeline

EMERGENCY CONTACT: 1-866-920-0007

TC Energy is meeting the growing demand for energy across North America — and maximizing our pipeline infrastructure — through innovative and strategic pipeline EMERGENCY CONTACT: solutions that will transport Canadian crude oil, as well as U.S. domestic crude oil to 1-866-920-0007 key U.S. markets in the Midwest and U.S. Gulf Coast. PRODUCTS/DOT GUIDEBOOK ID#/GUIDE#: KEYSTONE PIPELINE SYSTEM Crude Oil 1267 128

The Keystone Pipeline System, stretching 2,687 miles in length, plays a key role in MISSOURI delivering Canadian and U.S. crude oil supplies to markets around North America. COUNTIES OF OPERATION: Follow link for more information: https://www.transcanada.com/en/operations/oil-and- liquids/keystone-pipeline-system/ Audrain Clinton The Canadian portion of the pipeline runs from Hardisty, Alberta, Canada east into Buchanan Lincoln Manitoba, Canada where it turns south and crosses the border into North Dakota. From Caldwell Montgomery there, the 30” pipeline runs south through South Dakota to Steele City, Neb., where Carroll Randolph it splits – one arm running east through Missouri for deliveries into Wood River and Chariton St Charles Patoka, Ill., with the other 36” diameter pipeline running south through Oklahoma to ______Changes may occur. Contact the operator to Cushing and onward to Port Arthur and Houston, Texas. discuss their pipeline systems and areas of operation.

COMMITMENT TO SAFETY, HEALTH in your area are ready to respond to TC Energy Keystone Pipeline & ENVIRONMENT any pipeline emergency, no matter Company how remote the possibility may be. Contact Information Pipeline system safeguards are in TC Energy has developed a detailed place to protect the public and prevent Public Awareness at: (855) 458-6715 Emergency Management System emergencies from occurring. Our or (EMS). We train our staff to know our employees, community officials and the via email at: systems and exactly what to do if an police, fire, medical and relief agencies [email protected] emergency occurs. As part of our Public Awareness Program, we regularly inform local first responders and community officials of what they can expect from us and how to jointly co-ordinate a response. We provide information and direction to safely respond to a pipeline emergency.

Typical TC Energy Keystone marker sign on the pipeline right of way (ROW) at road / railway and canal crossings

56 PAM21 TC Energy / Keystone Pipeline

57 PAM21 ...... Emergency Response Guidebook Product Information

Product INFORMATION

The Emergency Response Guidebook is available at: https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/2020-08/ERG2020-WEB.pdf

This app is only available on the App Store for iOS devices.

58 PAM21 Product Table of Contents

ANHYDROUS AMMONIA (NH3)...... 60 BUTANE: N-BUTANE, ISO-BUTANE, BUTANE MIX...... 61 CRUDE OIL...... 62 DIESEL FUEL...... 63 ETHANE...... 64 ETHANE PROPANE MIX...... 65 GASOLINE...... 66 HEATING OIL...... 67 JET FUEL (A, JP, TURBINE FUEL)...... 68 KEROSENE...... 69 LIQUEFIED PETROLEUM GAS...... 70 NAPHTHA...... 71 NAPHTHALENE...... 72 NATURAL GAS...... 73 NATURAL GASOLINE...... 74 PROPANE...... 75 PROPANE/SYNTHETIC NATURAL GAS...... 76 RAFFINATE...... 77 TOLUENE...... 78

Safety Data Sheets contained in this section have been compiled from the Emergency Response Guidebook and only include the products transported by the operators represented. Information contained in these sheets is believed to be up-to-date and correct at the time of printing. Further product-specific information may be found in the US Department ofTransportation (DOT) Emergency Response Guidebook for First Responders. The Guidebook is available at: https://www.phmsa.dot.gov/sites/phmsa.dot.gov/files/2020-08/ERG2020-WEB.pdf

59 PAM21 ANHYDROUS AMMONIA (NH3)

POTENTIAL HAZARDS HEALTH PUBLIC SAFETY manufacturer. It may provide little or no • TOXIC; may be fatal if inhaled, ingested • CALL Emergency Response Telephone thermal protection. or absorbed through skin. Number on Shipping Paper first. If • Structural firefighters’ protective clothing • Vapors are extremely irritating and Shipping Paper not available or no provides limited protection in fire situations corrosive. answer, refer to appropriate telephone ONLY; it is not effective in spill situations • Contact with gas or liquefied gas may number listed on the inside back cover. where direct contact with the substance is cause burns, severe injury and/or frostbite. • As an immediate precautionary measure, possible. • Fire will produce irritating, corrosive and/or isolate spill or leak area for at least 100 toxic gases. meters (330 feet) in all directions. EVACUATION • Runoff from fire control may cause • Keep unauthorized personnel away. Spill pollution. • Stay upwind. • See Table 1 - Initial Isolation and Protective • Many gases are heavier than air and will Action Distances for highlighted materials. FIRE OR EXPLOSION spread along ground and collect in low For non-highlighted materials, increase, in • Some may burn but none ignite readily. or confined areas (sewers, basements, the downwind direction, as necessary, the • Vapors from liquefied gas are initially tanks). isolation distance shown under “PUBLIC heavier than air and spread along ground. • Keep out of low areas. SAFETY”. • Some of these materials may react • Ventilate closed spaces before entering. Fire violently with water. • If tank, rail car or tank truck is involved • Cylinders exposed to fire may vent and PROTECTIVE CLOTHING in a fire, ISOLATE for 1600 meters (1 release toxic and/or corrosive gas through • Wear positive pressure self-contained mile) in all directions; also, consider initial pressure relief devices. breathing apparatus (SCBA). evacuation for 1600 meters (1 mile) in all • Containers may explode when heated. • Wear chemical protective clothing that directions. • Ruptured cylinders may rocket. is specifically recommended by the

EMERGENCY RESPONSE

FIRE use unmanned hose holders or monitor valve or other proper respiratory medical Small Fire nozzles. device. • Dry chemical or CO2. • Cool containers with flooding quantities of • Administer oxygen if breathing is difficult. Large Fire water until well after fire is out. • Remove and isolate contaminated clothing • Water spray, fog or regular foam. • Do not direct water at source of leak or and shoes. • Move containers from fire area if you can safety devices; icing may occur. • In case of contact with liquefied gas, thaw do it without risk. • Withdraw immediately in case of rising frosted parts with lukewarm water. • Do not get water inside containers. sound from venting safety devices or • In case of contact with substance, • Damaged cylinders should be handled only discoloration of tank. immediately flush skin or eyes with running by specialists. • ALWAYS stay away from tanks engulfed in water for at least 20 minutes. Fire involving Tanks fire. • In case of contact with Hydrogen fluoride, • Fight fire from maximum distance or anhydrous (UN1052), flush skin and SPILL OR LEAK eyes with water for 5 minutes; then, for • Fully encapsulating, vapor protective skin exposures rub on a calcium/jelly DOT GUIDEBOOK ID #: GUIDE #: clothing should be worn for spills and leaks combination; for eyes flush with a water/ 1005 125 with no fire. calcium solution for 15 minutes. • Do not touch or walk through spilled • Keep victim warm and quiet. CHEMICAL NAMES: material. • Keep victim under observation. • Ammonia • Stop leak if you can do it without risk. • Effects of contact or inhalation may be • Liquid Ammonia • If possible, turn leaking containers so that delayed. • Nitrol-Sil gas escapes rather than liquid. • Ensure that medical personnel are aware • Spirit of Hartshorn • Prevent entry into waterways, sewers, of the material(s) involved and take • NH3 basements or confined areas. precautions to protect themselves. ______• Do not direct water at spill or source of leak. CHEMICAL FAMILY: • Use water spray to reduce vapors or divert Inorganic Base (Gas) vapor cloud drift. Avoid allowing water ______runoff to contact spilled material. • Isolate area until gas has dispersed. COMPONENTS: N/A - PURE NH3, USUALLY 99-100% FIRST AID • Move victim to fresh air. • Call 911 or emergency medical service. • Give artificial respiration if victim is not breathing. • Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way

60 PAM21 BUTANE: N-BUTANE, ISO-BUTANE, BUTANE MIX

POTENTIAL HAZARDS FIRE OR EXPLOSION HEALTH or confined areas (sewers, basements, • EXTREMELY FLAMMABLE. • Vapors may cause dizziness or tanks). • Will be easily ignited by heat, sparks or asphyxiation without warning. • Keep out of low areas. flames. • Some may be irritating if inhaled at high • Will form explosive mixtures with air. concentrations. PROTECTIVE CLOTHING • Vapors from liquefied gas are initially • Contact with gas or liquefied gas may • Wear positive pressure self-contained heavier than air and spread along ground. cause burns, severe injury and/or frostbite. breathing apparatus (SCBA). CAUTION: Hydrogen (UN1049), • Fire may produce irritating and/or toxic • Structural firefighters’ protective clothing Deuterium (UN1957), Hydrogen, gases. will only provide limited protection. refrigerated liquid (UN1966) and • Always wear thermal protective clothing Methane (UN1971) are lighter than air PUBLIC SAFETY when handling refrigerated/cryogenic and will rise. Hydrogen and Deuterium • CALL Emergency Response Telephone liquids. fires are difficult to detect since they Number on Shipping Paper first. If burn with an invisible flame. Use an Shipping Paper not available or no EVACUATION alternate method of detection (thermal answer, refer to appropriate telephone Large Spill camera, broom handle, etc.) number listed on the inside back cover. • Consider initial downwind evacuation for at • Vapors may travel to source of ignition and • As an immediate precautionary measure, least 800 meters (1/2 mile). flash back. isolate spill or leak area for at least 100 Fire • Cylinders exposed to fire may vent and meters (330 feet) in all directions. • If tank, rail car or tank truck is involved release flammable gas through pressure • Keep unauthorized personnel away. in a fire, ISOLATE for 1600 meters (1 relief devices. • Stay upwind. mile) in all directions; also, consider initial • Containers may explode when heated. • Many gases are heavier than air and will evacuation for 1600 meters (1 mile) in all • Ruptured cylinders may rocket. spread along ground and collect in low directions.

EMERGENCY RESPONSE FIRE Large Fire • Prevent spreading of vapors through • DO NOT EXTINGUISH A LEAKING GAS • Water spray or fog. sewers, ventilation systems and confined FIRE UNLESS LEAK CAN BE STOPPED. • Move containers from fire area if you can areas. CAUTION: HYDROGEN (UN1049), do it without risk. • Isolate area until gas has dispersed. DEUTERIUM (UN1957) AND Fire involving Tanks CAUTION: When in contact with HYDROGEN, REFRIGERATED LIQUID • Fight fire from maximum distance or refrigerated/cryogenic liquids, many (UN1966) BURN WITH AN INVISIBLE use unmanned hose holders or monitor materials become brittle and are likely FLAME. HYDROGEN AND METHANE nozzles. to break without warning. MIXTURE, COMPRESSED (UN2034) • Cool containers with flooding quantities of MAY BURN WITH AN INVISIBLE FLAME. water until well after fire is out. FIRST AID Small Fire • Do not direct water at source of leak or • Move victim to fresh air. • Dry chemical or CO2. safety devices; icing may occur. • Call 911 or emergency medical service. • Withdraw immediately in case of rising • Give artificial respiration if victim is not sound from venting safety devices or breathing. DOT GUIDEBOOK ID #: GUIDE #: discoloration of tank. • Administer oxygen if breathing is difficult. 1011/1075 115 • ALWAYS stay away from tanks engulfed in • Remove and isolate contaminated clothing fire. and shoes. CHEMICAL NAMES: • For massive fire, use unmanned hose • Clothing frozen to the skin should be N-BUTANE: holders or monitor nozzles; if this is thawed before being removed. • “Normal” Butane impossible, withdraw from area and let fire • In case of contact with liquefied gas, thaw • Butyl Hydride burn. frosted parts with lukewarm water. • LP Gas In case of burns, immediately cool affected • LPG • • Liquefied Butane SPILL OR LEAK skin for as long as possible with cold water. ISO-BUTANE: • ELIMINATE all ignition sources (no Do not remove clothing if adhering to skin. • 2-Methylpropane smoking, flares, sparks or flames in • Keep victim warm and quiet. • “Iso” immediate area). • Ensure that medical personnel are aware ______• All equipment used when handling the of the material(s) involved and take product must be grounded. precautions to protect themselves. CHEMICAL FAMILY: • Do not touch or walk through spilled Petroleum Hydrocarbon, Aliphatic Hy- material. drocarbon, Alkane, Paraffin • Stop leak if you can do it without risk. ______• If possible, turn leaking containers so that gas escapes rather than liquid. COMPONENTS: • Use water spray to reduce vapors or divert Butane: n-Butane, Iso-Butane, Pro- vapor cloud drift. Avoid allowing water pane, Butylenes, Pentane and heavier runoff to contact spilled material. Hydrocarbons Iso-Butane: Iso-Butane, • Do not direct water at spill or source of n-Butane, Propane, Butylenes leak.

61 PAM21 CRUDE OIL

POTENTIAL HAZARDS FIRE OR EXPLOSION HEALTH PROTECTIVE CLOTHING • HIGHLY FLAMMABLE: Will be easily • Inhalation or contact with material may • Wear positive pressure self-contained ignited by heat, sparks or flames. irritate or burn skin and eyes. breathing apparatus (SCBA). • Vapors may form explosive mixtures with • Fire may produce irritating, corrosive and/ • Structural firefighters’ protective clothing air. or toxic gases. will only provide limited protection. • Vapors may travel to source of ignition and • Vapors may cause dizziness or suffocation. flash back. • Runoff from fire control or dilution water EVACUATION • Most vapors are heavier than air. They will may cause pollution. Large Spill spread along ground and collect in low • Consider initial downwind evacuation for at or confined areas (sewers, basements, PUBLIC SAFETY least 300 meters (1000 feet). tanks). • CALL Emergency Response Telephone Fire • Vapor explosion hazard indoors, outdoors Number on Shipping Paper first. If • If tank, rail car or tank truck is involved or in sewers. Shipping Paper not available or no in a fire, ISOLATE for 800 meters (1/2 • Those substances designated with a “P” answer, refer to appropriate telephone mile) in all directions; also, consider initial may polymerize explosively when heated number listed on the inside back cover. evacuation for 800 meters (1/2 mile) in all or involved in a fire. • As an immediate precautionary measure, directions. • Runoff to sewer may create fire or isolate spill or leak area for at least 50 explosion hazard. meters (150 feet) in all directions. • Containers may explode when heated. • Keep unauthorized personnel away. • Many liquids are lighter than water. • Stay upwind. • Substance may be transported hot. • Keep out of low areas. • If molten aluminum is involved, refer to • Ventilate closed spaces before entering. GUIDE 169.

EMERGENCY RESPONSE FIRE • Use water spray or fog; do not use straight FIRST AID CAUTION: All these products have a very streams. • Move victim to fresh air. low flash point: Use of water spray when • Move containers from fire area if you can • Call 911 or emergency medical service. fighting fire may be inefficient. do it without risk. • Give artificial respiration if victim is not CAUTION: For mixtures containing breathing. alcohol or polar solvent, alcohol-resistant Fire involving Tanks or Car/Trailer Loads • Administer oxygen if breathing is difficult. foam may be more effective. • Fight fire from maximum distance or • Remove and isolate contaminated clothing Small Fire use unmanned hose holders or monitor and shoes. • Dry chemical, CO2, water spray or regular nozzles. • In case of contact with substance, foam. • Cool containers with flooding quantities of immediately flush skin or eyes with running Large Fire water until well after fire is out. water for at least 20 minutes. • Water spray, fog or regular foam. • Withdraw immediately in case of rising • Wash skin with soap and water. sound from venting safety devices or • In case of burns, immediately cool affected discoloration of tank. skin for as long as possible with cold water. DOT GUIDEBOOK ID #: GUIDE #: • ALWAYS stay away from tanks engulfed in Do not remove clothing if adhering to skin. 1267 128 fire. • Keep victim warm and quiet. • For massive fire, use unmanned hose • Ensure that medical personnel are aware CHEMICAL NAMES: holders or monitor nozzles; if this is of the material(s) involved and take • Crude Oil - “Sour” (Contains H2S, impossible, withdraw from area and let fire precautions to protect themselves. please see Hydrogen Sulfide fact sheet) burn. • Crude Oil - “Sweet” (No H2S) • Petroleum SPILL OR LEAK • Mineral Oil, Rock Oil, Coal Oil, Seneca • ELIMINATE all ignition sources (no Oil, Earth Oil smoking, flares, sparks or flames in ______immediate area). • All equipment used when handling the CHEMICAL FAMILY: product must be grounded. Petroleum Hydrocarbon Mixture: Chiefly • Do not touch or walk through spilled of Paraffins (Alkanes), Cycloparaffins, material. Cyclic Aromatic Hydrocarbons, Benzene • Stop leak if you can do it without risk. Hydrocarbons, Inorganic Compounds • Prevent entry into waterways, sewers, ______basements or confined areas. • A vapor suppressing foam may be used to COMPONENTS: Hydrocarbons (Aromatic & Paraffinic), reduce vapors. Benzene, Hydrogen Sulfide, Nitrogen • Absorb or cover with dry earth, sand Compounds, Sulfur Compounds, or other non-combustible material and Oxygenated Compounds transfer to containers. • Use clean non-sparking tools to collect absorbed material.

62 PAM21 DIESEL FUEL

POTENTIAL HAZARDS FIRE OR EXPLOSION • If molten aluminum is involved, refer to • Keep unauthorized personnel away. • HIGHLY FLAMMABLE: Will be easily GUIDE 169. • Stay upwind. ignited by heat, sparks or flames. • Keep out of low areas. • Vapors may form explosive mixtures with HEALTH • Ventilate closed spaces before entering. air. • Inhalation or contact with material may • Vapors may travel to source of ignition and irritate or burn skin and eyes. PROTECTIVE CLOTHING flash back. • Fire may produce irritating, corrosive and/ • Wear positive pressure self-contained • Most vapors are heavier than air. They will or toxic gases. breathing apparatus (SCBA). spread along ground and collect in low • Vapors may cause dizziness or suffocation. • Structural firefighters’ protective clothing or confined areas (sewers, basements, • Runoff from fire control or dilution water will only provide limited protection. tanks). may cause pollution. • Vapor explosion hazard indoors, outdoors EVACUATION or in sewers. PUBLIC SAFETY Large Spill • Those substances designated with a “P” • CALL Emergency Response Telephone • Consider initial downwind evacuation for at may polymerize explosively when heated Number on Shipping Paper first. If least 300 meters (1000 feet). or involved in a fire. Shipping Paper not available appropriate Fire • Runoff to sewer may create fire or telephone numbers can be found in the • If tank, rail car or tank truck is involved explosion hazard. Emergency Response Guidebook. in a fire, ISOLATE for 800 meters (1/2 • Containers may explode when heated. • As an immediate precautionary measure, mile) in all directions; also, consider initial • Many liquids are lighter than water. isolate spill or leak area for at least 50 evacuation for 800 meters (1/2 mile) in all • Substance may be transported hot. meters (150 feet) in all directions. directions.

EMERGENCY RESPONSE FIRE • Move containers from fire area if you can • Water spray may reduce vapor; but may CAUTION: All these products have a very do it without risk. not prevent ignition in closed spaces. low flash point: Use of water spray when fighting fire may be inefficient. Fire involving Tanks or Car/Trailer Loads FIRST AID CAUTION: For mixtures containing • Fight fire from maximum distance or • Move victim to fresh air. alcohol or polar solvent, alcohol-resistant use unmanned hose holders or monitor • Call 911 or emergency medical service. foam may be more effective. nozzles. • Give artificial respiration if victim is not Small Fire • Cool containers with flooding quantities of breathing. • Dry chemical, CO2, water spray or regular water until well after fire is out. • Administer oxygen if breathing is difficult. foam. • Withdraw immediately in case of rising • Remove and isolate contaminated clothing Large Fire sound from venting safety devices or and shoes. • Water spray, fog or regular foam. discoloration of tank. • In case of contact with substance, • Use water spray or fog; do not use straight • ALWAYS stay away from tanks engulfed in immediately flush skin or eyes with running streams. fire. water for at least 20 minutes. • For massive fire, use unmanned hose • Wash skin with soap and water. holders or monitor nozzles; if this is • In case of burns, immediately cool affected DOT GUIDEBOOK ID #: GUIDE #: impossible, withdraw from area and let fire skin for as long as possible with cold water. 1202/1993 128 burn. Do not remove clothing if adhering to skin. • Keep victim warm and quiet. CHEMICAL NAME & SYNONYMS: SPILL OR LEAK • Ensure that medical personnel are aware • Diesel Fuel • ELIMINATE all ignition sources (no of the material(s) involved and take • No. 2 Diesel smoking, flares, sparks or flames in precautions to protect themselves. • Motor Vehicle Diesel Fuel immediate area). • Locomotive/Marine Diesel Fuel • All equipment used when handling the ______product must be grounded. • Do not touch or walk through spilled CHEMICAL FAMILY: material. Petroleum Hydrocarbons, Paraffins • Stop leak if you can do it without risk. (Alkanes), Aromatic Hydrocarbons • Prevent entry into waterways, sewers, ______basements or confined areas. • A vapor suppressing foam may be used to COMPONENTS: reduce vapors. Petroleum distillate (Predominately, Hydrocarbons ranging from C10 -C16) • Absorb or cover with dry earth, sand Naphthalene, Xylene or other non-combustible material and transfer to containers. • Use clean non-sparking tools to collect absorbed material. Large Spill • Dike far ahead of liquid spill for later disposal.

63 PAM21 ETHANE

POTENTIAL HAZARDS FIRE OR EXPLOSION HEALTH or confined areas (sewers, basements, • EXTREMELY FLAMMABLE • Vapors may cause dizziness or tanks). • Will be easily ignited by heat, sparks or asphyxiation without warning. • Keep out of low areas. flames. • Some may be irritating if inhaled at high • Will form explosive mixtures with air. concentrations. PROTECTIVE CLOTHING • Vapors from liquefied gas are initially • Contact with gas or liquefied gas may • Wear positive pressure self-contained heavier than air and spread along ground. cause burns, severe injury and/or frostbite. breathing apparatus (SCBA). CAUTION: Hydrogen (UN1049), • Fire may produce irritating and/or toxic • Structural firefighters’ protective clothing Deuterium (UN1957), Hydrogen, gases. will only provide limited protection. refrigerated liquid (UN1966) and Methane • Always wear thermal protective clothing (UN1971) are lighter than air and will PUBLIC SAFETY when handling refrigerated/cryogenic rise. Hydrogen and Deuterium fires are • CALL Emergency Response Telephone liquids. difficult to detect since they burn with an Number on Shipping Paper first. If invisible flame. Use an alternate method Shipping Paper not available or no EVACUATION of detection (thermal camera, broom answer, refer to appropriate telephone Large Spill handle, etc.) number listed on the inside back cover. • Consider initial downwind evacuation for at • Vapors may travel to source of ignition and • As an immediate precautionary measure, least 800 meters (1/2 mile). flash back. isolate spill or leak area for at least 100 Fire • Cylinders exposed to fire may vent and meters (330 feet) in all directions. • If tank, rail car or tank truck is involved release flammable gas through pressure • Keep unauthorized personnel away. in a fire, ISOLATE for 1600 meters (1 relief devices. • Stay upwind. mile) in all directions; also, consider initial • Containers may explode when heated. • Many gases are heavier than air and will evacuation for 1600 meters (1 mile) in all • Ruptured cylinders may rocket. spread along ground and collect in low directions.

EMERGENCY RESPONSE FIRE Large Fire sewers, ventilation systems and confined • DO NOT EXTINGUISH A LEAKING GAS • Water spray or fog. areas. FIRE UNLESS LEAK CAN BE STOPPED. • Move containers from fire area if you can • Isolate area until gas has dispersed. CAUTION: Hydrogen (UN1049), do it without risk. CAUTION: When in contact with Deuterium (UN1957) and Hydrogen, refrigerated/cryogenic liquids, many refrigerated liquid (UN1966) burn with Fire involving Tanks materials become brittle and are likely an invisible flame. Hydrogen and • Fight fire from maximum distance or to break without warning. Methane mixture, compressed (UN2034) use unmanned hose holders or monitor may burn with an invisible flame. nozzles. FIRST AID Small Fire • Cool containers with flooding quantities of • Move victim to fresh air. • Dry chemical or CO2. water until well after fire is out. • Call 911 or emergency medical service. • Do not direct water at source of leak or • Give artificial respiration if victim is not safety devices; icing may occur. breathing. • Withdraw immediately in case of rising • Administer oxygen if breathing is difficult. DOT GUIDEBOOK ID #: GUIDE #: sound from venting safety devices or • Remove and isolate contaminated clothing 1035 115 discoloration of tank. and shoes. • ALWAYS stay away from tanks engulfed in • Clothing frozen to the skin should be CHEMICAL NAMES: fire. thawed before being removed. • Ethane • For massive fire, use unmanned hose • In case of contact with liquefied gas, thaw • Bimethyl holders or monitor nozzles; if this is frosted parts with lukewarm water. • Dimethyl impossible, withdraw from area and let fire • In case of burns, immediately cool affected • Methyl Methane burn. skin for as long as possible with cold water. • Ethyl Hydride Do not remove clothing if adhering to skin. ______SPILL OR LEAK • Keep victim warm and quiet. • ELIMINATE all ignition sources (no • Ensure that medical personnel are aware CHEMICAL FAMILY: smoking, flares, sparks or flames in of the material(s) involved and take Petroleum Hydrocarbon, Aliphatic immediate area). precautions to protect themselves. Hydrocarbon, Paraffin, Alkane • All equipment used when handling the ______product must be grounded. COMPONENTS: • Do not touch or walk through spilled Ethane, Methane, Carbon Dioxide, material. Propane, Propylene, Ethylene, • Stop leak if you can do it without risk. Iso-Butane, n-Butane, Higher • If possible, turn leaking containers so that Hydrocarbons gas escapes rather than liquid. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • Do not direct water at spill or source of leak. • Prevent spreading of vapors through 64 PAM21 ETHANE PROPANE MIX

POTENTIAL HAZARDS FIRE OR EXPLOSION HEALTH or confined areas (sewers, basements, • EXTREMELY FLAMMABLE • Vapors may cause dizziness or tanks). • Will be easily ignited by heat, sparks or asphyxiation without warning. • Keep out of low areas. flames. • Some may be irritating if inhaled at high • Will form explosive mixtures with air. concentrations. PROTECTIVE CLOTHING • Vapors from liquefied gas are initially • Contact with gas or liquefied gas may • Wear positive pressure self-contained heavier than air and spread along ground. cause burns, severe injury and/or frostbite. breathing apparatus (SCBA). CAUTION: Hydrogen (UN1049), • Fire may produce irritating and/or toxic • Structural firefighters’ protective clothing Deuterium (UN1957), Hydrogen, gases. will only provide limited protection. refrigerated liquid (UN1966) and • Always wear thermal protective clothing Methane (UN1971) are lighter than air PUBLIC SAFETY when handling refrigerated/cryogenic and will rise. Hydrogen and Deuterium • CALL Emergency Response Telephone liquids. fires are difficult to detect since they Number on Shipping Paper first. If burn with an invisible flame. Use an Shipping Paper not available or no EVACUATION alternate method of detection (thermal answer, refer to appropriate telephone Large Spill camera, broom handle, etc.) number listed on the inside back cover. • Consider initial downwind evacuation for at • Vapors may travel to source of ignition and • As an immediate precautionary measure, least 800 meters (1/2 mile). flash back. isolate spill or leak area for at least 100 Fire • Cylinders exposed to fire may vent and meters (330 feet) in all directions. • If tank, rail car or tank truck is involved release flammable gas through pressure • Keep unauthorized personnel away. in a fire, ISOLATE for 1600 meters (1 relief devices. • Stay upwind. mile) in all directions; also, consider initial • Containers may explode when heated. • Many gases are heavier than air and will evacuation for 1600 meters (1 mile) in all • Ruptured cylinders may rocket. spread along ground and collect in low directions.

EMERGENCY RESPONSE FIRE Large Fire • Prevent spreading of vapors through • DO NOT EXTINGUISH A LEAKING GAS • Water spray or fog. sewers, ventilation systems and confined FIRE UNLESS LEAK CAN BE STOPPED. • Move containers from fire area if you can areas. CAUTION: Hydrogen (UN1049), do it without risk. • Isolate area until gas has dispersed. Deuterium (UN1957) and Hydrogen, CAUTION: When in contact with refrigerated liquid (UN1966) burn with Fire involving Tanks or Car/Trailer Loads refrigerated/cryogenic liquids, many an invisible flame. Hydrogen and • Fight fire from maximum distance or materials become brittle and are likely Methane mixture, compressed (UN2034) use unmanned hose holders or monitor to break without warning. may burn with an invisible flame. nozzles. Small Fire • Cool containers with flooding quantities of FIRST AID • Dry chemical or CO2. water until well after fire is out. • Move victim to fresh air. • Do not direct water at source of leak or • Call 911 or emergency medical service. safety devices; icing may occur. • Give artificial respiration if victim is not • Withdraw immediately in case of rising breathing. DOT GUIDEBOOK ID #: GUIDE #: sound from venting safety devices or • Administer oxygen if breathing is difficult. 1961 115 discoloration of tank. • Remove and isolate contaminated clothing • ALWAYS stay away from tanks engulfed in and shoes. CHEMICAL NAMES: fire. • Clothing frozen to the skin should be • ETHANE • For massive fire, use unmanned hose thawed before being removed. Bimethyl, Dimethyl, Methyl Methane, holders or monitor nozzles; if this is • In case of contact with liquefied gas, thaw Ethyl Hydride impossible, withdraw from area and let fire frosted parts with lukewarm water. • PROPANE burn. • In case of burns, immediately cool affected Propyl Hydride, Dimethyl Methane skin for as long as possible with cold water. ______SPILL OR LEAK Do not remove clothing if adhering to skin. • ELIMINATE all ignition sources (no • Keep victim warm and quiet. CHEMICAL FAMILY: smoking, flares, sparks or flames in • Ensure that medical personnel are aware Petroleum Hydrocarbons, Paraffins, immediate area). of the material(s) involved and take Alkanes • All equipment used when handling the precautions to protect themselves. ______product must be grounded. COMPONENTS: • Do not touch or walk through spilled Ethane material. Propane • Stop leak if you can do it without risk. Possibly: Methane, Iso Butane, • If possible, turn leaking containers so that n-Butane, Propylene and higher gas escapes rather than liquid. hydrocarbons • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • Do not direct water at spill or source of leak.

65 PAM21 GASOLINE

POTENTIAL HAZARDS FIRE OR EXPLOSION • If molten aluminum is involved, refer to • Keep unauthorized personnel away. • HIGHLY FLAMMABLE: Will be easily GUIDE 169. • Stay upwind. ignited by heat, sparks or flames. • Keep out of low areas. • Vapors may form explosive mixtures with HEALTH • Ventilate closed spaces before entering. air. • Inhalation or contact with material may • Vapors may travel to source of ignition and irritate or burn skin and eyes. PROTECTIVE CLOTHING flash back. • Fire may produce irritating, corrosive and/ • Wear positive pressure self-contained • Most vapors are heavier than air. They will or toxic gases. breathing apparatus (SCBA). spread along ground and collect in low • Vapors may cause dizziness or suffocation. • Structural firefighters’ protective clothing or confined areas (sewers, basements, • Runoff from fire control or dilution water will only provide limited protection. tanks). may cause pollution. • Vapor explosion hazard indoors, outdoors EVACUATION or in sewers. PUBLIC SAFETY Large Spill • Those substances designated with a “P” • CALL Emergency Response Telephone • Consider initial downwind evacuation for at may polymerize explosively when heated Number on Shipping Paper first. If least 300 meters (1000 feet). or involved in a fire. Shipping Paper not available or no Fire • Runoff to sewer may create fire or answer, refer to appropriate telephone • If tank, rail car or tank truck is involved explosion hazard. number listed on the inside back cover. in a fire, ISOLATE for 800 meters (1/2 • Containers may explode when heated. • As an immediate precautionary measure, mile) in all directions; also, consider initial • Many liquids are lighter than water. isolate spill or leak area for at least 50 evacuation for 800 meters (1/2 mile) in all • Substance may be transported hot. meters (150 feet) in all directions. directions.

EMERGENCY RESPONSE FIRE • Move containers from fire area if you can • Water spray may reduce vapor; but may CAUTION: All these products have a very do it without risk. not prevent ignition in closed spaces. low flash point: Use of water spray when fighting fire may be inefficient. Fire involving Tanks or Car/Trailer Loads FIRST AID CAUTION: For mixtures containing • Fight fire from maximum distance or • Move victim to fresh air. alcohol or polar solvent, alcohol-resistant use unmanned hose holders or monitor • Call 911 or emergency medical service. foam may be more effective. nozzles. • Give artificial respiration if victim is not Small Fire • Cool containers with flooding quantities of breathing. • Dry chemical, CO2, water spray or regular water until well after fire is out. • Administer oxygen if breathing is difficult. foam. • Withdraw immediately in case of rising • Remove and isolate contaminated clothing Large Fire sound from venting safety devices or and shoes. • Water spray, fog or regular foam. discoloration of tank. • In case of contact with substance, • Use water spray or fog; do not use straight • ALWAYS stay away from tanks engulfed in immediately flush skin or eyes with running streams. fire. water for at least 20 minutes. • For massive fire, use unmanned hose • Wash skin with soap and water. holders or monitor nozzles; if this is • In case of burns, immediately cool affected DOT GUIDEBOOK ID #: GUIDE #: impossible, withdraw from area and let fire skin for as long as possible with cold water. 1203 128 burn. Do not remove clothing if adhering to skin. • Keep victim warm and quiet. Leaded Regular, Regular Unleaded, SPILL OR LEAK • Ensure that medical personnel are aware Premium Unleaded, Silver Lead-Free, • ELIMINATE all ignition sources (no of the material(s) involved and take Ultimate Lead-Free Premium smoking, flares, sparks or flames in precautions to protect themselves. CHEMICAL NAMES: immediate area). Gasoline, Petrol, Petroleum Naphtha, • All equipment used when handling the Light Petroleum Distillate, Benzin product must be grounded. ______• Do not touch or walk through spilled material. CHEMICAL FAMILY: • Stop leak if you can do it without risk. Petroleum Hydrocarbon Mix: • Prevent entry into waterways, sewers, Paraffins (Alkanes), Olefins (Alkenes), basements or confined areas. Cycloalkanes, Aromatic Hydrocarbons, • A vapor suppressing foam may be used to Naphthenes, Alcohols and Ethers reduce vapors. ______• Absorb or cover with dry earth, sand or other non-combustible material and COMPONENTS: transfer to containers. Alkanes, n-Hexane, Cycloalkanes, • Use clean non-sparking tools to collect t-Butyl Methyl Ether, Alkenes, absorbed material. Pseudocumene, Aromatic Large Spill Hydrocarbons, Cyclohexane, • Dike far ahead of liquid spill for later Xylenes, Ethylbenzene, Toluene, disposal. Naphthalene, Benzene

66 PAM21 HEATING OIL

POTENTIAL HAZARDS FIRE OR EXPLOSION • If molten aluminum is involved, refer to • Keep unauthorized personnel away. • HIGHLY FLAMMABLE: Will be easily GUIDE 169. • Stay upwind. ignited by heat, sparks or flames. • Keep out of low areas. • Vapors may form explosive mixtures with HEALTH • Ventilate closed spaces before entering. air. • Inhalation or contact with material may • Vapors may travel to source of ignition and irritate or burn skin and eyes. PROTECTIVE CLOTHING flash back. • Fire may produce irritating, corrosive and/ • Wear positive pressure self-contained • Most vapors are heavier than air. They will or toxic gases. breathing apparatus (SCBA). spread along ground and collect in low • Vapors may cause dizziness or suffocation. • Structural firefighters’ protective clothing or confined areas (sewers, basements, • Runoff from fire control or dilution water will only provide limited protection. tanks). may cause pollution. • Vapor explosion hazard indoors, outdoors EVACUATION or in sewers. PUBLIC SAFETY Large Spill • Those substances designated with a “P” • CALL Emergency Response Telephone • Consider initial downwind evacuation for at may polymerize explosively when heated Number on Shipping Paper first. If least 300 meters (1000 feet). or involved in a fire. Shipping Paper not available appropriate Fire • Runoff to sewer may create fire or telephone numbers can be found in the • If tank, rail car or tank truck is involved explosion hazard. Emergency Response Guidebook. in a fire, ISOLATE for 800 meters (1/2 • Containers may explode when heated. • As an immediate precautionary measure, mile) in all directions; also, consider initial • Many liquids are lighter than water. isolate spill or leak area for at least 50 evacuation for 800 meters (1/2 mile) in all • Substance may be transported hot. meters (150 feet) in all directions. directions.

EMERGENCY RESPONSE FIRE • Move containers from fire area if you can • Water spray may reduce vapor; but may CAUTION: All these products have a very do it without risk. not prevent ignition in closed spaces. low flash point: Use of water spray when fighting fire may be inefficient. Fire involving Tanks or Car/Trailer Loads FIRST AID CAUTION: For mixtures containing • Fight fire from maximum distance or • Move victim to fresh air. alcohol or polar solvent, alcohol-resistant use unmanned hose holders or monitor • Call 911 or emergency medical service. foam may be more effective. nozzles. • Give artificial respiration if victim is not Small Fire • Cool containers with flooding quantities of breathing. • Dry chemical, CO2, water spray or regular water until well after fire is out. • Administer oxygen if breathing is difficult. foam. • Withdraw immediately in case of rising • Remove and isolate contaminated clothing Large Fire sound from venting safety devices or and shoes. • Water spray, fog or regular foam. discoloration of tank. • In case of contact with substance, • Use water spray or fog; do not use straight • ALWAYS stay away from tanks engulfed in immediately flush skin or eyes with running streams. fire. water for at least 20 minutes. • For massive fire, use unmanned hose • Wash skin with soap and water. holders or monitor nozzles; if this is • In case of burns, immediately cool affected DOT GUIDEBOOK ID #: GUIDE #: impossible, withdraw from area and let fire skin for as long as possible with cold water. 1202 128 burn. Do not remove clothing if adhering to skin. • Keep victim warm and quiet. CHEMICAL NAME & SYNONYMS: SPILL OR LEAK • Ensure that medical personnel are aware • Heating Oil, Light • ELIMINATE all ignition sources (no of the material(s) involved and take • High Sulfur No. 2 Heating Oil smoking, flares, sparks or flames in precautions to protect themselves. • Fuel Oil No. 2 immediate area). • Heating X-Grade Oil • All equipment used when handling the ______product must be grounded. • Do not touch or walk through spilled CHEMICAL FAMILY: material. Petroleum Hydrocarbons, Paraffins • Stop leak if you can do it without risk. (Alkanes), Aromatic Hydrocarbons • Prevent entry into waterways, sewers, ______basements or confined areas. • A vapor suppressing foam may be used to COMPONENTS: reduce vapors. Petroleum distillate (Predominately, Hydrocarbons ranging from C10 -C16) • Absorb or cover with dry earth, sand Naphthalene, Xylene or other non-combustible material and transfer to containers. • Use clean non-sparking tools to collect absorbed material. Large Spill • Dike far ahead of liquid spill for later disposal.

67 PAM21 JET FUEL (A, JP, TURBINE FUEL)

POTENTIAL HAZARDS FIRE OR EXPLOSION HEALTH PROTECTIVE CLOTHING • HIGHLY FLAMMABLE: Will be easily • Inhalation or contact with material may • Wear positive pressure self-contained ignited by heat, sparks or flames. irritate or burn skin and eyes. breathing apparatus (SCBA). • Vapors may form explosive mixtures with • Fire may produce irritating, corrosive and/ • Structural firefighters’ protective clothing air. or toxic gases. will only provide limited protection. • Vapors may travel to source of ignition and • Vapors may cause dizziness or suffocation. flash back. • Runoff from fire control or dilution water EVACUATION • Most vapors are heavier than air. They will may cause pollution. Large Spill spread along ground and collect in low • Consider initial downwind evacuation for at or confined areas (sewers, basements, PUBLIC SAFETY least 300 meters (1000 feet). tanks). • CALL Emergency Response Telephone Fire • Vapor explosion hazard indoors, outdoors Number on Shipping Paper first. If • If tank, rail car or tank truck is involved or in sewers. Shipping Paper not available or no in a fire, ISOLATE for 800 meters (1/2 • Those substances designated with a “P” answer, refer to appropriate telephone mile) in all directions; also, consider initial may polymerize explosively when heated number listed on the inside back cover. evacuation for 800 meters (1/2 mile) in all or involved in a fire. • As an immediate precautionary measure, directions. • Runoff to sewer may create fire or isolate spill or leak area for at least 50 explosion hazard. meters (150 feet) in all directions. • Containers may explode when heated. • Keep unauthorized personnel away. • Many liquids are lighter than water. • Stay upwind. • Substance may be transported hot. • Keep out of low areas. • If molten aluminum is involved, refer to • Ventilate closed spaces before entering. GUIDE 169.

EMERGENCY RESPONSE FIRE • Use water spray or fog; do not use straight FIRST AID CAUTION: All these products have a very streams. • Move victim to fresh air. low flash point: Use of water spray when • Move containers from fire area if you can • Call 911 or emergency medical service. fighting fire may be inefficient. do it without risk. • Give artificial respiration if victim is not CAUTION: For mixtures containing breathing. alcohol or polar solvent, alcohol-resistant Fire involving Tanks or Car/Trailer Loads • Administer oxygen if breathing is difficult. foam may be more effective. • Fight fire from maximum distance or • Remove and isolate contaminated clothing Small Fire use unmanned hose holders or monitor and shoes. • Dry chemical, CO2, water spray or regular nozzles. • In case of contact with substance, foam. • Cool containers with flooding quantities of immediately flush skin or eyes with running Large Fire water until well after fire is out. water for at least 20 minutes. • Water spray, fog or regular foam. • Withdraw immediately in case of rising • Wash skin with soap and water. sound from venting safety devices or • In case of burns, immediately cool affected discoloration of tank. skin for as long as possible with cold water. DOT GUIDEBOOK ID #: GUIDE #: • ALWAYS stay away from tanks engulfed in Do not remove clothing if adhering to skin. 1863 128 fire. • Keep victim warm and quiet. • For massive fire, use unmanned hose • Ensure that medical personnel are aware CHEMICAL NAMES: holders or monitor nozzles; if this is of the material(s) involved and take • Kerosene Mix impossible, withdraw from area and let fire precautions to protect themselves. ______burn.

CHEMICAL FAMILY: SPILL OR LEAK Petroleum Hydrocarbon Mix: Alkanes, • ELIMINATE all ignition sources (no Alkenes, Aromatic HC’s, Naphthenes smoking, flares, sparks or flames in ______immediate area). • All equipment used when handling the COMPONENTS: product must be grounded. Jet Fuel (A) • Do not touch or walk through spilled Kerosene material. Naphthalene • Stop leak if you can do it without risk. Xylene • Prevent entry into waterways, sewers, Bicyclic & Tricyclic-Hydrocarbons basements or confined areas. Jet Fuel (JP, Turbine Fuel) • A vapor suppressing foam may be used to Kerosene Hydrotreated Naphtha (Heavy) reduce vapors. Naphtha (Light) • Absorb or cover with dry earth, sand Minor Additives or other non-combustible material and Benzene transfer to containers. Naphthalene • Use clean non-sparking tools to collect Xylene absorbed material.

68 PAM21 KEROSENE

POTENTIAL HAZARDS FIRE OR EXPLOSION • If molten aluminum is involved, refer to • Keep unauthorized personnel away. • HIGHLY FLAMMABLE: Will be easily GUIDE 169. • Stay upwind. ignited by heat, sparks or flames. • Keep out of low areas. • Vapors may form explosive mixtures with HEALTH • Ventilate closed spaces before entering. air. • Inhalation or contact with material may • Vapors may travel to source of ignition and irritate or burn skin and eyes. PROTECTIVE CLOTHING flash back. • Fire may produce irritating, corrosive and/ • Wear positive pressure self-contained • Most vapors are heavier than air. They will or toxic gases. breathing apparatus (SCBA). spread along ground and collect in low • Vapors may cause dizziness or suffocation. • Structural firefighters’ protective clothing or confined areas (sewers, basements, • Runoff from fire control or dilution water will only provide limited protection. tanks). may cause pollution. • Vapor explosion hazard indoors, outdoors EVACUATION or in sewers. PUBLIC SAFETY Large Spill • Those substances designated with a “P” • CALL Emergency Response Telephone • Consider initial downwind evacuation for at may polymerize explosively when heated Number on Shipping Paper first. If least 300 meters (1000 feet). or involved in a fire. Shipping Paper not available appropriate Fire • Runoff to sewer may create fire or telephone numbers can be found in the • If tank, rail car or tank truck is involved explosion hazard. Emergency Response Guidebook. in a fire, ISOLATE for 800 meters (1/2 • Containers may explode when heated. • As an immediate precautionary measure, mile) in all directions; also, consider initial • Many liquids are lighter than water. isolate spill or leak area for at least 50 evacuation for 800 meters (1/2 mile) in all • Substance may be transported hot. meters (150 feet) in all directions. directions.

EMERGENCY RESPONSE FIRE • Move containers from fire area if you can • Water spray may reduce vapor; but may CAUTION: All these products have a very do it without risk. not prevent ignition in closed spaces. low flash point: Use of water spray when fighting fire may be inefficient. Fire involving Tanks or Car/Trailer Loads FIRST AID CAUTION: For mixtures containing • Fight fire from maximum distance or • Move victim to fresh air. alcohol or polar solvent, alcohol-resistant use unmanned hose holders or monitor • Call 911 or emergency medical service. foam may be more effective. nozzles. • Give artificial respiration if victim is not Small Fire • Cool containers with flooding quantities of breathing. • Dry chemical, CO2, water spray or regular water until well after fire is out. • Administer oxygen if breathing is difficult. foam. • Withdraw immediately in case of rising • Remove and isolate contaminated clothing Large Fire sound from venting safety devices or and shoes. • Water spray, fog or regular foam. discoloration of tank. • In case of contact with substance, • Use water spray or fog; do not use straight • ALWAYS stay away from tanks engulfed in immediately flush skin or eyes with running streams. fire. water for at least 20 minutes. • For massive fire, use unmanned hose • Wash skin with soap and water. holders or monitor nozzles; if this is • In case of burns, immediately cool affected DOT GUIDEBOOK ID #: GUIDE #: impossible, withdraw from area and let fire skin for as long as possible with cold water. 1223 128 burn. Do not remove clothing if adhering to skin. • Keep victim warm and quiet. CHEMICAL NAME & SYNONYMS: SPILL OR LEAK • Ensure that medical personnel are aware • Kerosene • ELIMINATE all ignition sources (no of the material(s) involved and take • Kerosine smoking, flares, sparks or flames in precautions to protect themselves. • Coal Oil immediate area). • Fuel Oil #1 • All equipment used when handling the • Turbine Fuel product must be grounded. ______• Do not touch or walk through spilled material. CHEMICAL FAMILY: • Stop leak if you can do it without risk. Petroleum Hydrocarbons, Paraffins • Prevent entry into waterways, sewers, (Alkanes), Aromatic Hydrocarbons basements or confined areas. ______• A vapor suppressing foam may be used to reduce vapors. COMPONENTS: Petroleum distillate (Predominately, • Absorb or cover with dry earth, sand Hydrocarbons ranging from C10 -C16) or other non-combustible material and Naphthalene, Xylene transfer to containers. • Use clean non-sparking tools to collect absorbed material. Large Spill • Dike far ahead of liquid spill for later disposal.

69 PAM21 LIQUEFIED PETROLEUM GAS

POTENTIAL HAZARDS FIRE OR EXPLOSION HEALTH or confined areas (sewers, basements, • EXTREMELY FLAMMABLE. • Vapors may cause dizziness or tanks). • Will be easily ignited by heat, sparks or asphyxiation without warning. • Keep out of low areas. flames. • Some may be irritating if inhaled at high • Will form explosive mixtures with air. concentrations. PROTECTIVE CLOTHING • Vapors from liquefied gas are initially • Contact with gas or liquefied gas may • Wear positive pressure self-contained heavier than air and spread along ground. cause burns, severe injury and/or frostbite. breathing apparatus (SCBA). CAUTION: Hydrogen (UN1049), • Fire may produce irritating and/or toxic • Structural firefighters’ protective clothing Deuterium (UN1957), Hydrogen, gases. will only provide limited protection. refrigerated liquid (UN1966) and • Always wear thermal protective clothing Methane (UN1971) are lighter than air PUBLIC SAFETY when handling refrigerated/cryogenic and will rise. Hydrogen and Deuterium • CALL Emergency Response Telephone liquids. fires are difficult to detect since they Number on Shipping Paper first. If burn with an invisible flame. Use an Shipping Paper not available appropriate EVACUATION alternate method of detection (thermal telephone numbers can be found in the Large Spill camera, broom handle, etc.) Emergency Response Guidebook. • Consider initial downwind evacuation for at • Vapors may travel to source of ignition and • As an immediate precautionary measure, least 800 meters (1/2 mile). flash back. isolate spill or leak area for at least 100 Fire • Cylinders exposed to fire may vent and meters (330 feet) in all directions. • If tank, rail car or tank truck is involved release flammable gas through pressure • Keep unauthorized personnel away. in a fire, ISOLATE for 1600 meters (1 relief devices. • Stay upwind. mile) in all directions; also, consider initial • Containers may explode when heated. • Many gases are heavier than air and will evacuation for 1600 meters (1 mile) in all • Ruptured cylinders may rocket. spread along ground and collect in low directions.

EMERGENCY RESPONSE FIRE Large Fire • Prevent spreading of vapors through • DO NOT EXTINGUISH A LEAKING GAS • Water spray or fog. sewers, ventilation systems and confined FIRE UNLESS LEAK CAN BE STOPPED. • Move containers from fire area if you can areas. CAUTION: Hydrogen (UN1049), do it without risk. • Isolate area until gas has dispersed. Deuterium (UN1957) and Hydrogen, CAUTION: When in contact with refrigerated liquid (UN1966) burn with Fire involving Tanks refrigerated/cryogenic liquids, many an invisible flame. Hydrogen and • Fight fire from maximum distance or materials become brittle and are likely Methane mixture, compressed (UN2034) use unmanned hose holders or monitor to break without warning. may burn with an invisible flame. nozzles. Small Fire • Cool containers with flooding quantities of FIRST AID • Dry chemical or CO2. water until well after fire is out. • Move victim to fresh air. • Do not direct water at source of leak or • Call 911 or emergency medical service. safety devices; icing may occur. • Give artificial respiration if victim is not • Withdraw immediately in case of rising breathing. DOT GUIDEBOOK ID #: GUIDE #: sound from venting safety devices or • Administer oxygen if breathing is difficult. 1075 115 discoloration of tank. • Remove and isolate contaminated clothing • ALWAYS stay away from tanks engulfed in and shoes. CHEMICAL NAME & SYNONYMS: fire. • Clothing frozen to the skin should be • Liquid Propane • For massive fire, use unmanned hose thawed before being removed. • LP Gas holders or monitor nozzles; if this is • In case of contact with liquefied gas, thaw • LPG, Y-Grade impossible, withdraw from area and let fire frosted parts with lukewarm water. • Demethanized Gasoline burn. • In case of burns, immediately cool affected • “Raw Feed” skin for as long as possible with cold water. • Demethanized “Raw Feed Mix” SPILL OR LEAK Do not remove clothing if adhering to skin. ______• ELIMINATE all ignition sources (no • Keep victim warm and quiet. smoking, flares, sparks or flames in • Ensure that medical personnel are aware CHEMICAL FAMILY: immediate area). of the material(s) involved and take Petroleum Hydrocarbon Mix: Aliphatic • All equipment used when handling the precautions to protect themselves. Hydrocarbons, Paraffins (Alkanes), product must be grounded. Cycloparaffins, Aromatic Hydrocarbons • Do not touch or walk through spilled material. ______• Stop leak if you can do it without risk. • If possible, turn leaking containers so that COMPONENTS: Complex combination consisting gas escapes rather than liquid. primarily of saturated aliphatic • Use water spray to reduce vapors or divert hydrocarbons ranging from C1 to C12, vapor cloud drift. Avoid allowing water Benzene, Cyclohexane, Xylene, Toluene runoff to contact spilled material. • Do not direct water at spill or source of leak.

70 PAM21 NAPHTHA

POTENTIAL HAZARDS FIRE OR EXPLOSION HEALTH PROTECTIVE CLOTHING • HIGHLY FLAMMABLE: Will be easily • Inhalation or contact with material may • Wear positive pressure self-contained ignited by heat, sparks or flames. irritate or burn skin and eyes. breathing apparatus (SCBA). • Vapors may form explosive mixtures with • Fire may produce irritating, corrosive and/ • Structural firefighters’ protective clothing air. or toxic gases. will only provide limited protection. • Vapors may travel to source of ignition and • Vapors may cause dizziness or suffocation. flash back. • Runoff from fire control or dilution water EVACUATION • Most vapors are heavier than air. They will may cause pollution. Large Spill spread along ground and collect in low • Consider initial downwind evacuation for at or confined areas (sewers, basements, PUBLIC SAFETY least 300 meters (1000 feet). tanks). • CALL Emergency Response Telephone Fire • Vapor explosion hazard indoors, outdoors Number on Shipping Paper first. If • If tank, rail car or tank truck is involved or in sewers. Shipping Paper not available appropriate in a fire, ISOLATE for 800 meters (1/2 • Those substances designated with a (P) telephone numbers can be found in the mile) in all directions; also, consider initial may polymerize explosively when heated Emergency Response Guidebook. evacuation for 800 meters (1/2 mile) in all or involved in a fire. • As an immediate precautionary measure, directions. • Runoff to sewer may create fire or isolate spill or leak area for at least 50 explosion hazard. meters (150 feet) in all directions. • Containers may explode when heated. • Keep unauthorized personnel away. • Many liquids are lighter than water. • Stay upwind. • Substance may be transported hot. • Keep out of low areas. • Ventilate closed spaces before entering.

EMERGENCY RESPONSE FIRE • Move containers from fire area if you can Large Spill CAUTION: All these products have a very do it without risk. • Dike far ahead of liquid spill for later low flash point: Use of water spray when Fire involving Tanks or Car/Trailer Loads disposal. fighting fire may be inefficient. • Fight fire from maximum distance or • Water spray may reduce vapor; but may CAUTION: For mixtures containing use unmanned hose holders or monitor not prevent ignition in closed spaces. alcohol or polar solvent, alcohol-resistant nozzles. foam may be more effective. • Cool containers with flooding quantities of FIRST AID Small Fire water until well after fire is out. • Move victim to fresh air. • Dry chemical, CO2, water spray or regular • Withdraw immediately in case of rising • Call 911 or emergency medical service. foam. sound from venting safety devices or • Give artificial respiration if victim is not Large Fire discoloration of tank. breathing. • Water spray, fog or regular foam. • ALWAYS stay away from tanks engulfed in • Administer oxygen if breathing is difficult. • Do not use straight streams. fire. • Remove and isolate contaminated clothing • For massive fire, use unmanned hose and shoes. holders or monitor nozzles; if this is • In case of contact with substance, DOT GUIDEBOOK ID #: GUIDE #: impossible, withdraw from area and let fire immediately flush skin or eyes with running 1268 128 burn. water for at least 20 minutes. • Wash skin with soap and water. CHEMICAL NAME & SYNONYMS: SPILL OR LEAK • In case of burns, immediately cool affected • Light Naphtha • ELIMINATE all ignition sources (no skin for as long as possible with cold water. • SNG Naphtha smoking, flares, sparks or flames in Do not remove clothing if adhering to skin. • Light Cat Naphtha immediate area). • Keep victim warm and quiet. • Sweet Virgin Naphtha • All equipment used when handling the • Ensure that medical personnel are aware • Light CR Gasoline product must be grounded. of the material(s) involved and take ______• Do not touch or walk through spilled precautions to protect themselves. material. CHEMICAL FAMILY: • Stop leak if you can do it without risk. Aromatic Hydrocarbon • Prevent entry into waterways, sewers, ______basements or confined areas. • A vapor suppressing foam may be used to COMPONENTS: reduce vapors. N - Pentane > 70% • Absorb or cover with dry earth, sand 2 - Methylpentane > 1% 3 - Methylpentane > 1% or other non-combustible material and Cyclopentane > 1% transfer to containers. 2,2 - Dimethylbutane > 1% • Use clean non-sparking tools to collect absorbed material.

71 PAM21 NAPHTHALENE

POTENTIAL HAZARDS FIRE OR EXPLOSION • Contact with molten substance may cause PROTECTIVE CLOTHING • Flammable/combustible material. severe burns to skin and eyes. • Wear positive pressure self-contained • May be ignited by friction, heat, sparks or • Runoff from fire control may cause breathing apparatus (SCBA). flames. pollution. • Structural firefighters’ protective clothing • Some may burn rapidly with flare burning will only provide limited protection. effect. PUBLIC SAFETY • Powders, dusts, shavings, borings, • CALL Emergency Response Telephone EVACUATION turnings or cuttings may explode or burn Number on Shipping Paper first. If Large Spill with explosive violence. Shipping Paper not available or no • Consider initial downwind evacuation for at • Substance may be transported in a molten answer, refer to appropriate telephone least 100 meters (330 feet). form at a temperature that may be above number listed on the inside back cover. Fire its flash point. • As an immediate precautionary measure, • If tank, rail car or tank truck is involved • May re-ignite after fire is extinguished. isolate spill or leak area for at least 25 in a fire, ISOLATE for 800 meters (1/2 meters (75 feet) in all directions. mile) in all directions; also, consider initial HEALTH • Keep unauthorized personnel away. evacuation for 800 meters (1/2 mile) in all • Fire may produce irritating and/or toxic • Stay upwind. directions. gases. • Keep out of low areas. • Contact may cause burns to skin and eyes.

EMERGENCY RESPONSE FIRE water until well after fire is out. FIRST AID Small Fire • For massive fire, use unmanned hose • Move victim to fresh air. • Dry chemical, CO2, sand, earth, water holders or monitor nozzles; if this is • Call 911 or emergency medical service. spray or regular foam. impossible, withdraw from area and let fire • Give artificial respiration if victim is not Large Fire burn. breathing. • Water spray, fog or regular foam. • Withdraw immediately in case of rising • Administer oxygen if breathing is difficult. • Move containers from fire area if you can sound from venting safety devices or • Remove and isolate contaminated clothing do it without risk. discoloration of tank. and shoes. Fire Involving Metal Pigments or Pastes • ALWAYS stay away from tanks engulfed in • In case of contact with substance, (e.g. “Aluminum Paste”) fire. immediately flush skin or eyes with running • Aluminum Paste fires should be treated as water for at least 20 minutes. a combustible metal fire. Use DRY sand, SPILL OR LEAK • Removal of solidified molten material from graphite powder, dry sodium chloride • ELIMINATE all ignition sources (no skin requires medical assistance. based extinguishers, G-1® or Met-L-X® smoking, flares, sparks or flames in • Keep victim warm and quiet. powder. Also, see GUIDE 170. immediate area). • Ensure that medical personnel are aware Fire involving Tanks or Car/Trailer Loads • Do not touch or walk through spilled of the material(s) involved and take • Cool containers with flooding quantities of material. precautions to protect themselves. Small Dry Spill • With clean shovel place material into DOT GUIDEBOOK ID #: GUIDE #: clean, dry container and cover loosely; 1334 128 move containers from spill area. Large Dry Spill CHEMICAL NAMES: • Wet down with water and dike for later • Petroleum Naphtha disposal. • Petroleum Spirits • Prevent entry into waterways, sewers, • Benzin basements or confined areas. • Ligroine ______

CHEMICAL FAMILY: Aromatic Hydrocarbon ______

COMPONENTS: N - Pentane > 70% 2 - Methylpentane > 1% 3 - Methylpentane > 1% Cyclopentane > 1% 2,2 - Dimethylbutane > 1%

72 PAM21

NATURAL GAS

POTENTIAL HAZARDS FIRE OR EXPLOSION HEALTH or confined areas (sewers, basements, • EXTREMELY FLAMMABLE. • Vapors may cause dizziness or tanks). • Will be easily ignited by heat, sparks or asphyxiation without warning. • Keep out of low areas. flames. • Some may be irritating if inhaled at high • Will form explosive mixtures with air. concentrations. PROTECTIVE CLOTHING • Vapors from liquefied gas are initially • Contact with gas or liquefied gas may • Wear positive pressure self-contained heavier than air and spread along ground. cause burns, severe injury and/or frostbite. breathing apparatus (SCBA). CAUTION: Hydrogen (UN1049), • Fire may produce irritating and/or toxic • Structural firefighters’ protective clothing Deuterium (UN1957), Hydrogen, gases. will only provide limited protection. refrigerated liquid (UN1966) and • Always wear thermal protective clothing Methane (UN1971) are lighter than air PUBLIC SAFETY when handling refrigerated/cryogenic and will rise. Hydrogen and Deuterium • CALL Emergency Response Telephone liquids. fires are difficult to detect since they Number on Shipping Paper first. If burn with an invisible flame. Use an Shipping Paper not available or no EVACUATION alternate method of detection (thermal answer, refer to appropriate telephone Large Spill camera, broom handle, etc.) number listed on the inside back cover. • Consider initial downwind evacuation for at • Vapors may travel to source of ignition and • As an immediate precautionary measure, least 800 meters (1/2 mile). flash back. isolate spill or leak area for at least 100 Fire • Cylinders exposed to fire may vent and meters (330 feet) in all directions. • If tank, rail car or tank truck is involved release flammable gas through pressure • Keep unauthorized personnel away. in a fire, ISOLATE for 1600 meters (1 relief devices. • Stay upwind. mile) in all directions; also, consider initial • Containers may explode when heated. • Many gases are heavier than air and will evacuation for 1600 meters (1 mile) in all • Ruptured cylinders may rocket. spread along ground and collect in low directions.

EMERGENCY RESPONSE FIRE Large Fire • Isolate area until gas has dispersed. • DO NOT EXTINGUISH A LEAKING GAS • Water spray or fog. CAUTION: When in contact with FIRE UNLESS LEAK CAN BE STOPPED. • Move containers from fire area if you can refrigerated/cryogenic liquids, many CAUTION: Hydrogen (UN1049), do it without risk. materials become brittle and are likely Deuterium (UN1957) and Hydrogen, to break without warning. refrigerated liquid (UN1966) burn with an Fire involving Tanks invisible flame. Hydrogen and Methane • Fight fire from maximum distance or use FIRST AID mixture, compressed (UN2034) may burn unmanned hose holders or monitor nozzles. • Move victim to fresh air. with an invisible flame. • Cool containers with flooding quantities of • Call 911 or emergency medical service. Small Fire water until well after fire is out. • Give artificial respiration if victim is not • Dry chemical or CO2. • Do not direct water at source of leak or breathing. safety devices; icing may occur. • Administer oxygen if breathing is difficult. • Withdraw immediately in case of rising • Remove and isolate contaminated clothing sound from venting safety devices or and shoes. DOT GUIDEBOOK ID #: GUIDE #: discoloration of tank. • Clothing frozen to the skin should be 1971 115 • ALWAYS stay away from tanks engulfed in thawed before being removed. fire. • In case of contact with liquefied gas, thaw CHEMICAL NAMES: • For massive fire, use unmanned hose frosted parts with lukewarm water. • Natural Gas holders or monitor nozzles; if this is • In case of burns, immediately cool affected • Methane impossible, withdraw from area and let fire skin for as long as possible with cold water. • Marsh Gas burn. Do not remove clothing if adhering to skin. • Well Head Gas SPILL OR LEAK • Keep victim warm and quiet. • Fuel Gas • ELIMINATE all ignition sources (no • Ensure that medical personnel are aware • Lease Gas smoking, flares, sparks or flames in of the material(s) involved and take • Sour Gas* immediate area). precautions to protect themselves. ______• All equipment used when handling the product must be grounded. CHEMICAL FAMILY: • Do not touch or walk through spilled Petroleum Hydrocarbon Mix: Aliphatic material. Hydrocarbons (Alkanes), Aromatic Hydrocarbons, Inorganic Compounds • Stop leak if you can do it without risk. • If possible, turn leaking containers so that ______gas escapes rather than liquid. COMPONENTS: • Use water spray to reduce vapors or divert Methane, Iso-Hexane, Ethane, vapor cloud drift. Avoid allowing water Heptanes, Propane, Hydrogen Sulfide*, runoff to contact spilled material. (In “Sour” Gas), Iso-Butane, Carbon, • Do not direct water at spill or source of Dioxide, n-Butane, Nitrogen, Pentane leak. Benzene, Hexane, Octanes • Prevent spreading of vapors through sewers, ventilation systems and confined areas. 73 PAM21

NATURAL GASOLINE

POTENTIAL HAZARDS FIRE OR EXPLOSION • Skin: Prolonged or repeated contact telephone numbers can be found in the • Danger Extremely Flammable! with the skin can lead to skin irritation, Emergency Response Guidebook. • Highly flammable vapors, which are defatting, dermatitis or skin tumors. • Evacuate the area. heavier than air, may accumulate in low • Inhalation: High vapor concentrations • Ventilate to avoid accumulation of areas. may irritate nose, throat and respiratory explosive vapors. Equipment must be • Vapors may travel long distances to a point tract or cause dizziness or headaches. explosion proof. of ignition and flashback. H2S may be present which can cause • If H2S is present, additional evacuation • Liquid propane will vaporize rapidly at well loss of consciousness and death at and/or site security measures around the below ambient temperatures and readily concentrations greater than 300 ppm. release area may be warranted. form flammable mixtures with air. • Ingestion: May irritate the mouth, throat • Flames impinging on product storage and stomach leading to nausea and PROTECTIVE CLOTHING vessels above the liquid level will cause vomiting. Aspiration into lungs can produce • Wear NIOSH or MSHA approved self- sudden vessel failure, resulting in a chemical pneumonia. contained breathing apparatus (SCBA) if BLEVE (Boiling Liquid Expanding Vapor • Pre-existing eye, skin and respiratory vapor or mists are present or whenever Explosion), unless the vessel surfaces are disorders may be aggravated by exposure H2S may be present. kept cool with water. to condensate. • Firefighters must use proper protective • Toxic carbon oxides and/or sulfur oxides • Contains Benzene, a carcinogen that may equipment including self-contained may be released when burned. cause leukemia and other blood diseases breathing apparatus (SCBA) in enclosed after prolonged or repeated exposures at areas, high fume, vapor and/or smoke HEALTH high concentration. concentrations. • H2S can cause systemic toxicity and rapid • Wear goggles and/or face shield for spray death due to respiratory paralysis. PUBLIC SAFETY or mist or if splashing is possible. • Eye: Vapor acts as a slight to moderate • CALL Emergency Response Telephone • Wear gloves and footwear that is resistant irritant. H2S in condensate can cause eye Number on Shipping Paper first. If to chemicals and petroleum distillates. irritation. Liquid can burn eyes. Shipping Paper not available appropriate

EMERGENCY RESPONSE FIRE Explosion), unless the vessel surfaces are • Skin: Thoroughly wash affected skin with • Extinguishing media: Use dry chemical kept cool with water. soap and water. If irritation persists, seek powder, foam or carbon dioxide (CO2). medical attention.Wash contaminated • Water may be ineffective on flames but SPILL OR LEAK clothing thoroughly before reuse. Properly should be used to cool fire-exposed • Remove all ignition sources. Use discard clothing or leather goods that containers. Flames impinging on product explosion-proof equipment and non- cannot be cleaned. storage vessels above the liquid level will sparking tools in areas where explosive • Ingestion: Do not induce vomiting. Seek cause sudden vessel failure, resulting in vapors may form. immediate medical attention. Never give a BLEVE (Boiling Liquid Expanding Vapor • Stop flow and contain spill if possible. anything by mouth to an unconscious • Prevent entry into sewers and waterways. or convulsing victim.of the material(s) • Avoid breathing vapors.Wear self- involved and take precautions to protect contained breathing apparatus, if themselves. DOT GUIDEBOOK ID #: GUIDE #: necessary. 1972 115 • Use water spray to disperse vapors and to provide protection for personnel attempting CHEMICAL NAME & SYNONYMS: to stop the leak. • Natural Gas Liquids • Materials that have absorbed this product • Casinghead Gasoline may release flammable vapors and should • Condensate be properly stored/disposed of to prevent • Drip Gas spontaneous combustion or fire in the ______presence of an ignition source.

CHEMICAL FAMILY: Petroleum Hydrocarbons, Aliphatic FIRST AID Hydrocarbons, Alkanes, Paraffins, • Inhalation: Move victim to area of fresh Cycloparaffins, Aromatic Hydrocarbons air. For respiratory distress, administer ______cardiopulmonary resuscitation if needed. Seek medical attention. Victim should be COMPONENTS: kept quiet and warm until medical care is Complex combination consisting obtained. primarily of saturated aliphatic • Eye: Flush eyes gently with water for at hydrocarbons ranging from C4 to least 15 minutes while holding eyelids C12Benzene, Cyclohexane open. Seek medical attention.

74 PAM21 PROPANE

POTENTIAL HAZARDS FIRE OR EXPLOSION HEALTH or confined areas (sewers, basements, • EXTREMELY FLAMMABLE.. • Vapors may cause dizziness or tanks). • Will be easily ignited by heat, sparks or asphyxiation without warning. • Keep out of low areas. flames. • Some may be irritating if inhaled at high • Will form explosive mixtures with air. concentrations. PROTECTIVE CLOTHING • Vapors from liquefied gas are initially • Contact with gas or liquefied gas may • Wear positive pressure self-contained heavier than air and spread along ground. cause burns, severe injury and/or frostbite. breathing apparatus (SCBA). CAUTION: Hydrogen (UN1049), • Fire may produce irritating and/or toxic • Structural firefighters’ protective clothing Deuterium (UN1957), Hydrogen, gases. will only provide limited protection. refrigerated liquid (UN1966) and • Always wear thermal protective clothing Methane (UN1971) are lighter than air PUBLIC SAFETY when handling refrigerated/cryogenic and will rise. Hydrogen and Deuterium • CALL Emergency Response Telephone liquids. fires are difficult to detect since they Number on Shipping Paper first. If burn with an invisible flame. Use an Shipping Paper not available or no EVACUATION alternate method of detection (thermal answer, refer to appropriate telephone Large Spill camera, broom handle, etc.) number listed on the inside back cover. • Consider initial downwind evacuation for at • Vapors may travel to source of ignition and • As an immediate precautionary measure, least 800 meters (1/2 mile). flash back. isolate spill or leak area for at least 100 Fire • Cylinders exposed to fire may vent and meters (330 feet) in all directions. • If tank, rail car or tank truck is involved release flammable gas through pressure • Keep unauthorized personnel away. in a fire, ISOLATE for 1600 meters (1 relief devices. • Stay upwind. mile) in all directions; also, consider initial • Containers may explode when heated. • Many gases are heavier than air and will evacuation for 1600 meters (1 mile) in all • Ruptured cylinders may rocket. spread along ground and collect in low directions.

EMERGENCY RESPONSE FIRE Large Fire • Prevent spreading of vapors through • DO NOT EXTINGUISH A LEAKING GAS • Water spray or fog. sewers, ventilation systems and confined FIRE UNLESS LEAK CAN BE STOPPED. • Move containers from fire area if you can areas. CAUTION: Hydrogen (UN1049), do it without risk. • Isolate area until gas has dispersed. Deuterium (UN1957) and Hydrogen, CAUTION: When in contact with refrigerated liquid (UN1966) burn with Fire involving Tanks refrigerated/cryogenic liquids, many an invisible flame. Hydrogen and • Fight fire from maximum distance or materials become brittle and are likely Methane mixture, compressed (UN2034) use unmanned hose holders or monitor to break without warning. may burn with an invisible flame. nozzles. Small Fire • Cool containers with flooding quantities of FIRST AID • Dry chemical or CO2. water until well after fire is out. • Move victim to fresh air. • Do not direct water at source of leak or • Call 911 or emergency medical service. safety devices; icing may occur. • Give artificial respiration if victim is not • Withdraw immediately in case of rising breathing. DOT GUIDEBOOK ID #: GUIDE #: sound from venting safety devices or • Administer oxygen if breathing is difficult. 1075 115 discoloration of tank. • Remove and isolate contaminated clothing • ALWAYS stay away from tanks engulfed in and shoes. CHEMICAL NAMES: fire. • Clothing frozen to the skin should be • Propane • For massive fire, use unmanned hose thawed before being removed. • Propyl Hydride holders or monitor nozzles; if this is • In case of contact with liquefied gas, thaw • Dimethylmethane impossible, withdraw from area and let fire frosted parts with lukewarm water. • LP Gas • In case of burns, immediately cool affected • LPG SPILL OR LEAK skin for as long as possible with cold water. • Liquefied Petroleum Gas • ELIMINATE all ignition sources (no Do not remove clothing if adhering to skin. • Commercial-Grade Liquefied Propane smoking, flares, sparks or flames in • Keep victim warm and quiet. • “P-Rich Furnace Feed” immediate area). • Ensure that medical personnel are aware ______• All equipment used when handling the of the material(s) involved and take product must be grounded. precautions to protect themselves. CHEMICAL FAMILY: • Do not touch or walk through spilled Petroleum Hydrocarbon, Aliphatic material. Hydrocarbon, Paraffin, Alkane • Stop leak if you can do it without risk. ______• If possible, turn leaking containers so that gas escapes rather than liquid. COMPONENTS: Propane Propylene • Use water spray to reduce vapors or divert Butane Iso-Butane vapor cloud drift. Avoid allowing water Ethane Ethyl Mercaptan runoff to contact spilled material. Sulfur • Do not direct water at spill or source of leak.

75 PAM21 PROPANE/SYNTHETIC NATURAL GAS

POTENTIAL HAZARDS FIRE OR EXPLOSION HEALTH or confined areas (sewers, basements, • EXTREMELY FLAMMABLE.. • Vapors may cause dizziness or tanks). • Will be easily ignited by heat, sparks or asphyxiation without warning. • Keep out of low areas. flames. • Some may be irritating if inhaled at high • Will form explosive mixtures with air. concentrations. PROTECTIVE CLOTHING • Vapors from liquefied gas are initially • Contact with gas or liquefied gas may • Wear positive pressure self-contained heavier than air and spread along ground. cause burns, severe injury and/or frostbite. breathing apparatus (SCBA). CAUTION: Hydrogen (UN1049), • Fire may produce irritating and/or toxic • Structural firefighters’ protective clothing Deuterium (UN1957), Hydrogen, gases. will only provide limited protection. refrigerated liquid (UN1966) and • Always wear thermal protective clothing Methane (UN1971) are lighter than air PUBLIC SAFETY when handling refrigerated/cryogenic and will rise. Hydrogen and Deuterium • CALL Emergency Response Telephone liquids. fires are difficult to detect since they Number on Shipping Paper first. If burn with an invisible flame. Use an Shipping Paper not available or no EVACUATION alternate method of detection (thermal answer, refer to appropriate telephone Large Spill camera, broom handle, etc.) number listed on the inside back cover. • Consider initial downwind evacuation for at • Vapors may travel to source of ignition and • As an immediate precautionary measure, least 800 meters (1/2 mile). flash back. isolate spill or leak area for at least 100 Fire • Cylinders exposed to fire may vent and meters (330 feet) in all directions. • If tank, rail car or tank truck is involved release flammable gas through pressure • Keep unauthorized personnel away. in a fire, ISOLATE for 1600 meters (1 relief devices. • Stay upwind. mile) in all directions; also, consider initial • Containers may explode when heated. • Many gases are heavier than air and will evacuation for 1600 meters (1 mile) in all • Ruptured cylinders may rocket. spread along ground and collect in low directions.

EMERGENCY RESPONSE FIRE Large Fire • Prevent spreading of vapors through • DO NOT EXTINGUISH A LEAKING GAS • Water spray or fog. sewers, ventilation systems and confined FIRE UNLESS LEAK CAN BE STOPPED. • Move containers from fire area if you can areas. CAUTION: Hydrogen (UN1049), do it without risk. • Isolate area until gas has dispersed. Deuterium (UN1957) and Hydrogen, CAUTION: When in contact with refrigerated liquid (UN1966) burn with Fire involving Tanks refrigerated/cryogenic liquids, many an invisible flame. Hydrogen and • Fight fire from maximum distance or materials become brittle and are likely Methane mixture, compressed (UN2034) use unmanned hose holders or monitor to break without warning. may burn with an invisible flame. nozzles. Small Fire • Cool containers with flooding quantities of • Dry chemical or CO2. water until well after fire is out. FIRST AID • Do not direct water at source of leak or • Move victim to fresh air. safety devices; icing may occur. • Call 911 or emergency medical service. • Withdraw immediately in case of rising • Give artificial respiration if victim is not DOT GUIDEBOOK ID #: GUIDE #: sound from venting safety devices or breathing. 1978 115 discoloration of tank. • Administer oxygen if breathing is difficult. • ALWAYS stay away from tanks engulfed in • Remove and isolate contaminated clothing CHEMICAL NAMES: fire. and shoes. • Synthetic Natural Gas • For massive fire, use unmanned hose • Clothing frozen to the skin should be • SNG holders or monitor nozzles; if this is thawed before being removed. • Mixture of ethane, propane & n-butane impossible, withdraw from area and let fire • In case of contact with liquefied gas, thaw frosted parts with lukewarm water. ______SPILL OR LEAK • In case of burns, immediately cool affected • ELIMINATE all ignition sources (no skin for as long as possible with cold water. CHEMICAL FAMILY: smoking, flares, sparks or flames in Do not remove clothing if adhering to skin. Alkane Hydrocarbon immediate area). • Keep victim warm and quiet. ______• All equipment used when handling the • Ensure that medical personnel are aware COMPONENTS: product must be grounded. of the material(s) involved and take Propane • Do not touch or walk through spilled precautions to protect themselves. Propylene material. Butane • Stop leak if you can do it without risk. Iso-Butane • If possible, turn leaking containers so that Ethane gas escapes rather than liquid. • Use water spray to reduce vapors or divert vapor cloud drift. Avoid allowing water runoff to contact spilled material. • Do not direct water at spill or source of leak.

76 PAM21 RAFFINATE

POTENTIAL HAZARDS FIRE OR EXPLOSION • If molten aluminum is involved, refer to • Keep unauthorized personnel away. • HIGHLY FLAMMABLE: Will be easily GUIDE 169. • Stay upwind. ignited by heat, sparks or flames. • Keep out of low areas. • Vapors may form explosive mixtures with HEALTH • Ventilate closed spaces before entering. air. • Inhalation or contact with material may • Vapors may travel to source of ignition and irritate or burn skin and eyes. PROTECTIVE CLOTHING flash back. • Fire may produce irritating, corrosive and/ • Wear positive pressure self-contained • Most vapors are heavier than air. They will or toxic gases. breathing apparatus (SCBA). spread along ground and collect in low • Vapors may cause dizziness or suffocation. • Structural firefighters’ protective clothing or confined areas (sewers, basements, • Runoff from fire control or dilution water will only provide limited protection. tanks). may cause pollution. • Vapor explosion hazard indoors, outdoors EVACUATION or in sewers. PUBLIC SAFETY Large Spill • Those substances designated with a “P” • CALL Emergency Response Telephone • Consider initial downwind evacuation for at may polymerize explosively when heated Number on Shipping Paper first. If least 300 meters (1000 feet). or involved in a fire. Shipping Paper not available or no Fire • Runoff to sewer may create fire or answer, refer to appropriate telephone • If tank, rail car or tank truck is involved explosion hazard. number listed on the inside back cover. in a fire, ISOLATE for 800 meters (1/2 • Containers may explode when heated. • As an immediate precautionary measure, mile) in all directions; also, consider initial • Many liquids are lighter than water. isolate spill or leak area for at least 50 evacuation for 800 meters (1/2 mile) in all • Substance may be transported hot. meters (150 feet) in all directions. directions.

EMERGENCY RESPONSE FIRE • Move containers from fire area if you can • Water spray may reduce vapor; but may CAUTION: All these products have a very do it without risk. not prevent ignition in closed spaces. low flash point: Use of water spray when fighting fire may be inefficient. Fire involving Tanks or Car/Trailer Loads FIRST AID CAUTION: For mixtures containing • Fight fire from maximum distance or • Move victim to fresh air. alcohol or polar solvent, alcohol-resistant use unmanned hose holders or monitor • Call 911 or emergency medical service. foam may be more effective. nozzles. • Give artificial respiration if victim is not Small Fire • Cool containers with flooding quantities of breathing. • Dry chemical, CO2, water spray or regular water until well after fire is out. • Administer oxygen if breathing is difficult. foam. • Withdraw immediately in case of rising • Remove and isolate contaminated clothing Large Fire sound from venting safety devices or and shoes. • Water spray, fog or regular foam. discoloration of tank. • In case of contact with substance, • Use water spray or fog; do not use straight • ALWAYS stay away from tanks engulfed in immediately flush skin or eyes with running streams. fire. water for at least 20 minutes. • For massive fire, use unmanned hose • Wash skin with soap and water. holders or monitor nozzles; if this is • In case of burns, immediately cool affected DOT GUIDEBOOK ID #: GUIDE #: impossible, withdraw from area and let fire skin for as long as possible with cold water. 1203 128 burn. Do not remove clothing if adhering to skin. • Keep victim warm and quiet. CHEMICAL NAMES: SPILL OR LEAK • Ensure that medical personnel are aware • Light Iso-Siv • ELIMINATE all ignition sources (no of the material(s) involved and take • Heavy Iso-Siv smoking, flares, sparks or flames in precautions to protect themselves. • Iso-Siv Blend immediate area). • Paraffinic Naptha • All equipment used when handling the • Petroleum Paraffin product must be grounded. ______• Do not touch or walk through spilled material. CHEMICAL FAMILY: • Stop leak if you can do it without risk. Paraffinic Hydrocarbon • Prevent entry into waterways, sewers, ______basements or confined areas. • A vapor suppressing foam may be used to COMPONENTS: Cyclohexane reduce vapors. Ethylbenzene • Absorb or cover with dry earth, sand Hexane or other non-combustible material and Toluene transfer to containers. Xylene • Use clean non-sparking tools to collect absorbed material. Large Spill • Dike far ahead of liquid spill for later disposal.

77 PAM21 TOLUENE

POTENTIAL HAZARDS FIRE OR EXPLOSION HEALTH • Stay upwind. • HIGHLY FLAMMABLE: Will be easily • May cause toxic effects if inhaled or • Keep out of low areas. ignited by heat, sparks or flames. absorbed through skin. • Ventilate closed spaces before entering. • Vapors may form explosive mixtures with • Inhalation or contact with material may air. irritate or burn skin and eyes. PROTECTIVE CLOTHING • Vapors may travel to source of ignition and • Fire will produce irritating, corrosive and/or • Wear positive pressure self-contained flash back. toxic gases. breathing apparatus (SCBA). • Most vapors are heavier than air. They will • Vapors may cause dizziness or suffocation. • Structural firefighters’ protective clothing spread along ground and collect in low • Runoff from fire control or dilution water will only provide limited protection. or confined areas (sewers, basements, may cause pollution. tanks). EVACUATION • Vapor explosion hazard indoors, outdoors PUBLIC SAFETY Large Spill or in sewers. • CALL Emergency Response Telephone • Consider initial downwind evacuation for at • Those substances designated with a “P” Number on Shipping Paper first. If least 300 meters (1000 feet). may polymerize explosively when heated Shipping Paper not available or no Fire or involved in a fire. answer, refer to appropriate telephone • If tank, rail car or tank truck is involved • Runoff to sewer may create fire or number listed on the inside back cover. in a fire, ISOLATE for 800 meters (1/2 explosion hazard. • As an immediate precautionary measure, mile) in all directions; also, consider initial • Containers may explode when heated. isolate spill or leak area for at least 50 evacuation for 800 meters (1/2 mile) in all • Many liquids are lighter than water. meters (150 feet) in all directions. directions. • Keep unauthorized personnel away.

EMERGENCY RESPONSE FIRE Fire involving Tanks or Car/Trailer Loads FIRST AID CAUTION: All these products have a very • Fight fire from maximum distance or • Move victim to fresh air. low flash point: Use of water spray when use unmanned hose holders or monitor • Call 911 or emergency medical service. fighting fire may be inefficient. nozzles. • Give artificial respiration if victim is not Small Fire • Cool containers with flooding quantities of breathing. • Dry chemical, CO2, water spray or regular water until well after fire is out. • Administer oxygen if breathing is difficult. foam. • Withdraw immediately in case of rising • Remove and isolate contaminated clothing Large Fire sound from venting safety devices or and shoes. • Water spray, fog or regular foam. discoloration of tank. • In case of contact with substance, • Do not use straight streams. • ALWAYS stay away from tanks engulfed in immediately flush skin or eyes with running • Move containers from fire area if you can fire. water for at least 20 minutes. do it without risk. • For massive fire, use unmanned hose • Wash skin with soap and water. holders or monitor nozzles; if this is • In case of burns, immediately cool affected impossible, withdraw from area and let fire skin for as long as possible with cold water. burn. Do not remove clothing if adhering to skin. • Keep victim warm and quiet. DOT GUIDEBOOK ID #: GUIDE #: SPILL OR LEAK • Effects of exposure (inhalation, ingestion 1294 130 • ELIMINATE all ignition sources (no or skin contact) to substance may be smoking, flares, sparks or flames in delayed. CHEMICAL NAMES: immediate area). • Ensure that medical personnel are aware • Methylbenzene • All equipment used when handling the of the material(s) involved and take • Toluol product must be grounded. precautions to protect themselves. • Phenylethane • Do not touch or walk through spilled • Methacide material. ______• Stop leak if you can do it without risk. • Prevent entry into waterways, sewers, CHEMICAL FAMILY: basements or confined areas. Aromatic Hydrocarbon • A vapor suppressing foam may be used to ______reduce vapors. • Absorb or cover with dry earth, sand COMPONENTS: Negligible - Chemical grade 99% pure or other non-combustible material and product transfer to containers. • Use clean non-sparking tools to collect absorbed material. Large Spill • Dike far ahead of liquid spill for later disposal. • Water spray may reduce vapor; but may not prevent ignition in closed spaces.

78 PAM21 Emergency Response

Emergency Response Plans for Gas and Hazardous Liquid Pipeline Operators Federal regulations for both gas and hazardous liquid pipelines require operators to have written procedures for responding to emergencies involving their pipeline facility. Because pipelines are often located in public space, the regulations further require that operators include procedures for planning with emergency and other public officials to ensure a coordinated response. Please contact your local pipeline operators for information regarding their company specific emergency response plan. Natural Gas Each operator shall establish written procedures to minimize the hazard resulting from a gas pipeline emergency. At a minimum, the procedures must provide for the following: • Receiving, identifying, and classifying notices of events which require immediate response by the operator. • Establishing and maintaining adequate means of communication with appropriate fire, police, and other public officials. • Prompt and effective response to a notice of each type of emergency, including the following: 1. Gas detected inside or near a building. 2. Fire located near or directly involving a pipeline facility. 3. Explosion occurring near or directly involving a pipeline facility. 4. Natural disaster. • The availability of personnel, equipment, tools, and materials, as needed at the scene of an emergency. • Actions directed toward protecting people first and then property. • Emergency shutdown and pressure reduction in any section of the operator’s pipeline system necessary to minimize hazards to life or property. • Making safe any actual or potential hazard to life or property. • Notifying appropriate fire, police, and other public officials of gas pipeline emergencies and coordinating with them both planned responses and actual responses during an emergency. • Safely restoring any service outage. • Each operator shall establish and maintain liaison with appropriate fire, police, and other public officials to: 1. Learn the responsibility and resources of each government organization that may respond to a gas pipeline emergency; 2. Acquaint the officials with the operator’s ability in responding to a gas pipeline emergency; 3. Identify the types of gas pipeline emergencies of which the operator notifies the officials; and 4. Plan how the operator and officials can engage in mutual assistance to minimize hazards to life or property. *Reference 49 CFR 192.615 Hazardous Liquids (a) General: Each operator shall prepare and follow for each pipeline system a manual of written procedures for conducting normal operations and maintenance activities and handling abnormal operations and emergencies. This manual shall be reviewed at intervals not exceeding 15 months, but at least once each calendar year, and appropriate changes made as necessary to insure that the manual is effective. This manual shall be prepared before initial operations of a pipeline system commence, and appropriate parts shall be kept at locations where operations and maintenance activities are conducted. Emergencies. The manual required by paragraph (a) of this section must include procedures for the following to provide safety when an emergency condition occurs: • Receiving, identifying, and classifying notices of events which need immediate response by the operator or notice to fire, police, or other appropriate public officials and communicating this information to appropriate operator personnel for corrective action. • Prompt and effective response to a notice of each type emergency, including fire or explosion occurring near or directly involving a pipeline facility, accidental release of hazardous liquid or carbon dioxide from a pipeline facility, operational failure causing a hazardous condition, and natural disaster affecting pipeline facilities. • Having personnel, equipment, instruments, tools, and material available as needed at the scene of an emergency. • Taking necessary action, such as emergency shutdown or pressure reduction, to minimize the volume of hazardous liquid or carbon dioxide that is released from any section of a pipeline system in the event of a failure. • Control of released hazardous liquid or carbon dioxide at an accident scene to minimize the hazards, including possible intentional ignition in the cases of flammable highly volatile liquid. • Minimization of public exposure to injury and probability of accidental ignition by assisting with evacuation of residents and assisting with halting traffic on roads and railroads in the affected area, or taking other appropriate action. • Notifying fire, police, and other appropriate public officials of hazardous liquid or carbon dioxide pipeline emergencies and coordinating with them preplanned and actual responses during an emergency, including additional precautions necessary for an emergency involving a pipeline system transporting a highly volatile liquid. • In the case of failure of a pipeline system transporting a highly volatile liquid, use of appropriate instruments to assess the extent and coverage of the vapor cloud and determine the hazardous areas. • Providing for a post accident review of employee activities to determine whether the procedures were effective in each emergency and taking corrective action where deficiencies are found. *Reference 49 CFR 195.402

79 PAM21 Emergency Response

Hazard Area Radius

Evacuation Radius- Radiant Heat

80 PAM21 Overview

Pipeline Purpose and Reliability • Critical national infrastructure • Over 2.7 million miles of pipeline provide 65% of our nation’s energy • 20 million barrels of liquid product used daily • 21 trillion cubic feet of natural gas used annually Safety Initiatives • Pipeline location ° Existing right-of-way (ROW) • ROW encroachment prevention ° No permanent structures, trees or deeply rooted plants • Hazard awareness and prevention methods • Pipeline maintenance activities ° Cleaning and inspection of pipeline system Product Hazards and Characteristics Petroleum (flow rate can be hundreds of thousands of gallons per hour) • Flammable range may be found anywhere within the hot zone • H2S can be a by-product of crude oil Type 1 Products Flash Point Ignition Temperature Gasoline - 45 °F 600 °F Jet Fuel 100 °F 410 °F Kerosene 120 °F 425 °F Diesel Fuel 155 °F varies Crude Oil 25 °F varies Natural Gas (flow rate can be hundreds of thousands of cubic feet per hour) • Flammable range may be found anywhere within the hot zone • Rises and dissipates relatively quickly • H2S can be a by-product of natural gas – PPM = PARTS PER MILLION ° 0.02 PPM Odor threshold ° 10.0 PPM Eye irritation ° 100 PPM Headache, dizziness, coughing, vomiting ° 200-300 PPM Respiratory inflammation within 1 hour of exposure ° 500-700 PPM Loss of consciousness/possible death in 30-60 min. ° 700-900 PPM Rapid loss of consciousness; death possible ° Over 1000 PPM Unconsciousness in seconds; death in minutes • Incomplete combustion of natural gas may release carbon monoxide • Storage facilities may be present around populated areas/can be depleted production facilities or underground caverns • Gas travel may be outside the containment vessel along the natural cavern between the pipe and soil Propane, Butane and Other Similar Products • Flammable range may be found anywhere within the hot zone • Products cool rapidly to sub-zero temperatures once outside the containment vessel • Vapor clouds may be white or clear Type 3 Products Flash Point Ignition Temperature Propane - 150 °F 920-1120 °F Butane - 60 °F 725-850 °F Line Pressure Hazards • Transmission pipelines – steel (high pressure: average 800-1200psi) • Local gas pipeline transmission – steel (high pressure: average 200-1000psi) • Local gas mains and services – steel and/or plastic (low to medium pressure) ° Mains: up to 300psi ° Service lines: up to regulator - Average 30-45psi and below - Can be up to 60-100psi in some areas • At regulator into dwelling: ounces of pressure

81 PAM21 Overview

Leak Recognition and Response • Sight, sound, smell – indicators vary depending on product • Diesel engines – fluctuating RPMs • Black, dark brown or clear liquids/dirt blowing into air/peculiar odors/dead insects around gas line/dead vegetation • Rainbow sheen on the water/mud or water bubbling up/frozen area on ground/frozen area around gas meter • Any sign, gut feeling or hunch should be respected and taken seriously • Take appropriate safety actions ASAP High Consequence Area (HCA) Regulation • Defined by pipeline regulations 192 and 195 • Requires specialized communication and planning between responders and pipeline/gas personnel • May necessitate detailed information from local response agencies to identify HCAs in area Emergency Response Basics • Always follow pipeline/gas company recommendations – pipeline representatives may need escort to incident site • Advance preparation ° Get to know your pipeline operators/tour their facilities if possible ° Participate in their field exercises/request on-site training where available ° Develop response plans and practice • Planning partners ° Pipeline & local gas companies ° Police – local/state/sheriff ° Fire companies/HAZMAT/ambulance/hospitals/Red Cross ° LEPC/EMA/public officials ° Environmental management/Department of Natural Resources ° Army Corps of Engineers/other military officials ° Other utilities • Risk considerations ° Type/volume/pressure/location/geography of product ° Environmental factors – wind, fog, temperature, humidity ° Other utility emergencies • Incident response ° Always approach from upwind/park vehicle a safe distance away/if vehicle stalls – DO NOT attempt to restart ° Gather information/establish incident command/identify command structure ° Initiate communications with pipeline/gas company representative ASAP ° Control/deny entry: vehicle, boat, train, aircraft, foot traffic, media – refer all media questions to pipeline/gas reps • Extinguish fires only ° To aid in rescue or evacuation ° To protect exposures ° When controllable amounts of vapor or liquid present • Incident notification – pipeline control center or local gas company number on warning marker ° In Pipeline Emergency Response Planning Information Manual ° Emergency contact list in Program Guide ° Call immediately/provide detailed incident information • Pipeline security – assist by noting activity on pipeline/gas facilities ° Report abnormal activities around facilities - Suspicious excavation/abandoned vehicles/non-company personnel/non-company vehicles - Freshly disturbed soil/perimeter abnormalities One-Call • One-Call centers are not responsible for marking lines • Each state has different One-Call laws. Familiarize yourself with the state you are working in • Not all states require facility owners to be members of a One-Call • You may have to contact some facility owners on your own if they are not One-Call members • In some states, homeowners must call before they dig just like professional excavators

82 PAM21 Training Presentation

83 PAM21 Training Presentation

84 PAM21 Training Presentation

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86 PAM21 Training Presentation

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89 PAM21 Pipeline Damage Reporting Law / Websites

PIPELINE DAMAGE REPORTING LAW AS OF 2007

H.R. 2958 Emergency Alert Requirements

Any person, including a government employee or contractor, who while engaged in the demolition, excavation, tunneling, or construction in the vicinity of a pipeline facility;

A. Becomes aware of damage to the pipeline facility that may endanger life or cause serious bodily harm or damage to property; or

B. Damages the pipeline facility in a manner that may endanger life or cause serious bodily harm or damage to property, shall promptly report the damage to the operator of the facility and to other appropriate authorities. ______

Websites:

Association of Public-Safety Communications Officials - International (APCO) www.apcointl.org/

Common Ground Alliance www.commongroundalliance.com

Federal Emergency Management Agency www.fema.gov

Federal Office of Pipeline Safety www.phmsa.dot.gov

Government Emergency Telecommunications www.dhs.gov/government-emergency-telecommunications-service-gets

Infrastructure Protection – NIPC www.dhs.gov/national-infrastructure-protection-plan

National Emergency Number Association https://www.nena.org/?

National Fire Protection Association (NFPA) www.nfpa.org

National Pipeline Mapping System www.npms.phmsa.dot.gov

National Response Center www.nrc.uscg.mil or 800-424-8802

Paradigm Liaison Services, LLC www.pdigm.com

United States Environmental Protection Agency (EPA) www.epa.gov/cameo

Wireless Information System for Emergency Responders (WISER) www.wiser.nlm.nih.gov

FOR MORE INFORMATION ON THE NASFM PIPELINE EMERGENCIES PROGRAM www.pipelineemergencies.com

FOR EMERGENCY RESPONSE INFORMATION, REFER TO DOT GUIDEBOOK. FOR COPIES: (202) 366-4900 www.phmsa.dot.gov/hazmat/erg/emergency-response-guidebook-erg

90 PAM21 Presenter/Contact Information: Key Take-Aways: P P P P P Comments to Remember

Questions to Ask

New Concepts to Explore

91 PAM21 University of Missouri Fire Missouri Emergency Rescue Training Institute Response Commission

EMERGENCY CONTACT LIST

COMPANY EMERGENCY NUMBER BP Pipelines (North America)...... 1-800-548-6482 Buckeye Partners, L.P. (Northern Missouri)...... 1-866-514-8380 Buckeye Partners, L.P. (St. Louis Area)...... 1-800-331-4115 City of Fulton (Between 7:30 AM and 4:00 PM CST)...... 1-573-592-3170 City of Fulton (After hours or on weekends)...... 1-573-592-3180 Empire District Gas Company...... 1-800-406-9220 Enable Gas Transmission, LLC...... 1-800-474-1954 Enable Mississippi River Transmission, LLC...... 1-800-325-4005 Enbridge / Platte Pipe Line Company / Texas Eastern Transmission LP (Gas)...... 1-800-858-5253 Enbridge / Platte Pipe Line Company / Texas Eastern Transmission LP (Liquids).....1-800-858-5253 Enterprise Products Operating LLC...... 1-888-883-6308 Explorer Pipeline...... 1-888-876-0036 Flint Hills Resources...... 1-800-688-7594 Liberty Utilities...... 1-855-644-8134 Magellan Midstream Partners, L.P...... 1-800-720-2417 Marathon Pipe Line LLC...... 1-833-675-1234 MoGas Pipeline LLC...... 1-800-282-4916 NuStar Pipeline Operating Partnership, L.P...... 1-800-759-0033 Omega Pipeline Company, LLC...... 1-573-329-3382 ONEOK North System...... 1-888-844-5658 Panhandle Eastern Pipe Line...... 1-800-225-3913 Permian Express Partners...... 1-800-753-5531 Phillips 66 Pipeline LLC...... 1-877-267-2290 Rockies Express Pipeline...... 1-877-436-2253 Sinclair Transportation Company...... 1-800-321-3994 Spire (Kansas City and Western Missouri)...... 1-800-582-1234 Spire (St. Louis and Eastern Missouri)...... 1-800-887-4173 Summit Natural Gas...... 1-800-927-0787 Tallgrass Interstate Gas Transmission...... 1-888-763-3690 TC Energy / ANR Pipeline...... 1-800-447-8066 TC Energy / Keystone Pipeline...... 1-866-920-0007

______Note: The above numbers are for emergency situations. Additional pipeline operators may exist in your area. Visit the National Pipeline Mapping System at www.npms.phmsa.dot.gov for companies not listed above.

ONE-CALL SYSTEM PHONE NUMBER Missouri One Call System...... 1-800-344-7483 National One-Call Referral Number...... 1-888-258-0808 National One-Call Dialing Number...... 811

92 PAM21 Foreword Public safety and environmental protection are top priorities in any pipeline incident response. While serious pipeline incidents are rare, pipeline operators appreciate the hard work and effort of those emergency officials who are involved in helping return a community affected by an incident to normal. Because pipeline operators care about the safety of the community, they developed this resource covering the critical tasks that need to be considered when responding to a pipeline incident. General information about pipelines and damage prevention is also included to help The Missouri Underground Facility Safety and Damage Prevention statute (RSMo Chapter 319) provides for a notification center to be used by participating utilities to support your National Incident Management receive locate requests. Missouri One Call System, Inc. (MOCS), operating as a non- System (NIMS), National Association of State profit Missouri corporation, is such a notification center providing a single-point of contact Fire Marshals (NASFM) and agency training, for notification to its members through a state wide toll-free telephone number operating knowledge and other best practices. 24 hours a day, seven days a week. MOCS was established in 1986 and currently is providing statewide services to utilities and excavators to comply with the law. This law Please become familiar with the information in applies to any person excavating in the state of Missouri. this resource and be prepared to work together with the operator in the unlikely event of a MOCS was established as a means to protect underground facilities and assist pipeline incident in your community. excavators and utilities in complying with Missouri’s statute and OSHA Rules 1926.651. By using the service that MOCS provides, the general public’s safety and the environment also are protected.

Using the MOCS system correctly is easy, if you know how.

When you call or use the internet to contact MOCS, you will be asked for specifics about the planned excavation. Once this information is processed by the computer, you will be given a list of member utilities that will be notified of your excavation.The computer then sends this locate request to all member utilities with facilities in your dig site area. After the utility has been notified of the planned excavation, they will mark the “approximate location” of their underground lines or advise you there are no facilities in your area. Table of Contents After it is determined that markings are required, the locate request will be dispatched to a field locator who will locate and mark the excavation site with paint, stakes, or flags. Understanding Pipelines...... 1 Members mark their facilities according to specific guidelines and color codes. Locating Pipelines...... 2 Recognizing a Pipeline Incident...... 3 Upon agreement of the excavator and the facility owner, location may be provided by Responding to a Pipeline Incident...... 4 alternative means such as an on-site meeting or other conference. Preventing Pipeline Damage...... 6 Underground Storage...... 8 Either party may request an on-site meeting to clarify markings, which must occur prior to Regional Matrix...... 9 the start date and time as described in the request. PAM Member Listings...... 19 Emergency Response Guidebook...... 59 Additional information can be found by visiting us at mo1call.com. Safety Data Sheets...... 60 Emergency Response...... 79 Overview...... 81 Training Presentation...... 83 Additional Information...... 90 Emergency Contact List...... 92

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