On Entropy, Entropy-Like Quantities, and Applications
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On Entropy, Information, and Conservation of Information
entropy Article On Entropy, Information, and Conservation of Information Yunus A. Çengel Department of Mechanical Engineering, University of Nevada, Reno, NV 89557, USA; [email protected] Abstract: The term entropy is used in different meanings in different contexts, sometimes in contradic- tory ways, resulting in misunderstandings and confusion. The root cause of the problem is the close resemblance of the defining mathematical expressions of entropy in statistical thermodynamics and information in the communications field, also called entropy, differing only by a constant factor with the unit ‘J/K’ in thermodynamics and ‘bits’ in the information theory. The thermodynamic property entropy is closely associated with the physical quantities of thermal energy and temperature, while the entropy used in the communications field is a mathematical abstraction based on probabilities of messages. The terms information and entropy are often used interchangeably in several branches of sciences. This practice gives rise to the phrase conservation of entropy in the sense of conservation of information, which is in contradiction to the fundamental increase of entropy principle in thermody- namics as an expression of the second law. The aim of this paper is to clarify matters and eliminate confusion by putting things into their rightful places within their domains. The notion of conservation of information is also put into a proper perspective. Keywords: entropy; information; conservation of information; creation of information; destruction of information; Boltzmann relation Citation: Çengel, Y.A. On Entropy, 1. Introduction Information, and Conservation of One needs to be cautious when dealing with information since it is defined differently Information. Entropy 2021, 23, 779. -
ENERGY, ENTROPY, and INFORMATION Jean Thoma June
ENERGY, ENTROPY, AND INFORMATION Jean Thoma June 1977 Research Memoranda are interim reports on research being conducted by the International Institute for Applied Systems Analysis, and as such receive only limited scientific review. Views or opinions contained herein do not necessarily represent those of the Institute or of the National Member Organizations supporting the Institute. PREFACE This Research Memorandum contains the work done during the stay of Professor Dr.Sc. Jean Thoma, Zug, Switzerland, at IIASA in November 1976. It is based on extensive discussions with Professor HAfele and other members of the Energy Program. Al- though the content of this report is not yet very uniform because of the different starting points on the subject under consideration, its publication is considered a necessary step in fostering the related discussion at IIASA evolving around th.e problem of energy demand. ABSTRACT Thermodynamical considerations of energy and entropy are being pursued in order to arrive at a general starting point for relating entropy, negentropy, and information. Thus one hopes to ultimately arrive at a common denominator for quanti- ties of a more general nature, including economic parameters. The report closes with the description of various heating appli- cation.~and related efficiencies. Such considerations are important in order to understand in greater depth the nature and composition of energy demand. This may be highlighted by the observation that it is, of course, not the energy that is consumed or demanded for but the informa- tion that goes along with it. TABLE 'OF 'CONTENTS Introduction ..................................... 1 2 . Various Aspects of Entropy ........................2 2.1 i he no me no logical Entropy ........................ -
The Topological Entropy Conjecture
mathematics Article The Topological Entropy Conjecture Lvlin Luo 1,2,3,4 1 Arts and Sciences Teaching Department, Shanghai University of Medicine and Health Sciences, Shanghai 201318, China; [email protected] or [email protected] 2 School of Mathematical Sciences, Fudan University, Shanghai 200433, China 3 School of Mathematics, Jilin University, Changchun 130012, China 4 School of Mathematics and Statistics, Xidian University, Xi’an 710071, China Abstract: For a compact Hausdorff space X, let J be the ordered set associated with the set of all finite open covers of X such that there exists nJ, where nJ is the dimension of X associated with ¶. Therefore, we have Hˇ p(X; Z), where 0 ≤ p ≤ n = nJ. For a continuous self-map f on X, let a 2 J be f an open cover of X and L f (a) = fL f (U)jU 2 ag. Then, there exists an open fiber cover L˙ f (a) of X induced by L f (a). In this paper, we define a topological fiber entropy entL( f ) as the supremum of f ent( f , L˙ f (a)) through all finite open covers of X = fL f (U); U ⊂ Xg, where L f (U) is the f-fiber of − U, that is the set of images f n(U) and preimages f n(U) for n 2 N. Then, we prove the conjecture log r ≤ entL( f ) for f being a continuous self-map on a given compact Hausdorff space X, where r is the maximum absolute eigenvalue of f∗, which is the linear transformation associated with f on the n L Cechˇ homology group Hˇ ∗(X; Z) = Hˇ i(X; Z). -
Lecture 4: 09.16.05 Temperature, Heat, and Entropy
3.012 Fundamentals of Materials Science Fall 2005 Lecture 4: 09.16.05 Temperature, heat, and entropy Today: LAST TIME .........................................................................................................................................................................................2� State functions ..............................................................................................................................................................................2� Path dependent variables: heat and work..................................................................................................................................2� DEFINING TEMPERATURE ...................................................................................................................................................................4� The zeroth law of thermodynamics .............................................................................................................................................4� The absolute temperature scale ..................................................................................................................................................5� CONSEQUENCES OF THE RELATION BETWEEN TEMPERATURE, HEAT, AND ENTROPY: HEAT CAPACITY .......................................6� The difference between heat and temperature ...........................................................................................................................6� Defining heat capacity.................................................................................................................................................................6� -
The Enthalpy, and the Entropy of Activation (Rabbit/Lobster/Chick/Tuna/Halibut/Cod) PHILIP S
Proc. Nat. Acad. Sci. USA Vol. 70, No. 2, pp. 430-432, February 1973 Temperature Adaptation of Enzymes: Roles of the Free Energy, the Enthalpy, and the Entropy of Activation (rabbit/lobster/chick/tuna/halibut/cod) PHILIP S. LOW, JEFFREY L. BADA, AND GEORGE N. SOMERO Scripps Institution of Oceanography, University of California, La Jolla, Calif. 92037 Communicated by A. Baird Hasting8, December 8, 1972 ABSTRACT The enzymic reactions of ectothermic function if they were capable of reducing the AG* character- (cold-blooded) species differ from those of avian and istic of their reactions more than were the homologous en- mammalian species in terms of the magnitudes of the three thermodynamic activation parameters, the free zymes of more warm-adapted species, i.e., birds or mammals. energy of activation (AG*), the enthalpy of activation In this paper, we report that the values of AG* are indeed (AH*), and the entropy of activation (AS*). Ectothermic slightly lower for enzymic reactions catalyzed by enzymes enzymes are more efficient than the homologous enzymes of ectotherms, relative to the homologous reactions of birds of birds and mammals in reducing the AG* "energy bar- rier" to a chemical reaction. Moreover, the relative im- and mammals. Moreover, the relative contributions of the portance of the enthalpic and entropic contributions to enthalpies and entropies of activation to AG* differ markedly AG* differs between these two broad classes of organisms. and, we feel, adaptively, between ectothermic and avian- mammalian enzymic reactions. Because all organisms conduct many of the same chemical transformations, certain functional classes of enzymes are METHODS present in virtually all species. -
Topological Invariance of the Sign of the Lyapunov Exponents in One-Dimensional Maps
PROCEEDINGS OF THE AMERICAN MATHEMATICAL SOCIETY Volume 134, Number 1, Pages 265–272 S 0002-9939(05)08040-8 Article electronically published on August 19, 2005 TOPOLOGICAL INVARIANCE OF THE SIGN OF THE LYAPUNOV EXPONENTS IN ONE-DIMENSIONAL MAPS HENK BRUIN AND STEFANO LUZZATTO (Communicated by Michael Handel) Abstract. We explore some properties of Lyapunov exponents of measures preserved by smooth maps of the interval, and study the behaviour of the Lyapunov exponents under topological conjugacy. 1. Statement of results In this paper we consider C3 interval maps f : I → I,whereI is a compact interval. We let C denote the set of critical points of f: c ∈C⇔Df(c)=0.We shall always suppose that C is finite and that each critical point is non-flat: for each ∈C ∈ ∞ 1 ≤ |f(x)−f(c)| ≤ c ,thereexist = (c) [2, )andK such that K |x−c| K for all x = c.LetM be the set of ergodic Borel f-invariant probability measures. For every µ ∈M, we define the Lyapunov exponent λ(µ)by λ(µ)= log |Df|dµ. Note that log |Df|dµ < +∞ is automatic since Df is bounded. However we can have log |Df|dµ = −∞ if c ∈Cis a fixed point and µ is the Dirac-δ measure on c. It follows from [15, 1] that this is essentially the only way in which log |Df| can be non-integrable: if µ(C)=0,then log |Df|dµ > −∞. The sign, more than the actual value, of the Lyapunov exponent can have signif- icant implications for the dynamics. A positive Lyapunov exponent, for example, indicates sensitivity to initial conditions and thus “chaotic” dynamics of some kind. -
Writing the History of Dynamical Systems and Chaos
Historia Mathematica 29 (2002), 273–339 doi:10.1006/hmat.2002.2351 Writing the History of Dynamical Systems and Chaos: View metadata, citation and similar papersLongue at core.ac.uk Dur´ee and Revolution, Disciplines and Cultures1 brought to you by CORE provided by Elsevier - Publisher Connector David Aubin Max-Planck Institut fur¨ Wissenschaftsgeschichte, Berlin, Germany E-mail: [email protected] and Amy Dahan Dalmedico Centre national de la recherche scientifique and Centre Alexandre-Koyre,´ Paris, France E-mail: [email protected] Between the late 1960s and the beginning of the 1980s, the wide recognition that simple dynamical laws could give rise to complex behaviors was sometimes hailed as a true scientific revolution impacting several disciplines, for which a striking label was coined—“chaos.” Mathematicians quickly pointed out that the purported revolution was relying on the abstract theory of dynamical systems founded in the late 19th century by Henri Poincar´e who had already reached a similar conclusion. In this paper, we flesh out the historiographical tensions arising from these confrontations: longue-duree´ history and revolution; abstract mathematics and the use of mathematical techniques in various other domains. After reviewing the historiography of dynamical systems theory from Poincar´e to the 1960s, we highlight the pioneering work of a few individuals (Steve Smale, Edward Lorenz, David Ruelle). We then go on to discuss the nature of the chaos phenomenon, which, we argue, was a conceptual reconfiguration as -
What Is Quantum Thermodynamics?
What is Quantum Thermodynamics? Gian Paolo Beretta Universit`a di Brescia, via Branze 38, 25123 Brescia, Italy What is the physical significance of entropy? What is the physical origin of irreversibility? Do entropy and irreversibility exist only for complex and macroscopic systems? For everyday laboratory physics, the mathematical formalism of Statistical Mechanics (canonical and grand-canonical, Boltzmann, Bose-Einstein and Fermi-Dirac distributions) allows a successful description of the thermodynamic equilibrium properties of matter, including entropy values. How- ever, as already recognized by Schr¨odinger in 1936, Statistical Mechanics is impaired by conceptual ambiguities and logical inconsistencies, both in its explanation of the meaning of entropy and in its implications on the concept of state of a system. An alternative theory has been developed by Gyftopoulos, Hatsopoulos and the present author to eliminate these stumbling conceptual blocks while maintaining the mathematical formalism of ordinary quantum theory, so successful in applications. To resolve both the problem of the meaning of entropy and that of the origin of irreversibility, we have built entropy and irreversibility into the laws of microscopic physics. The result is a theory that has all the necessary features to combine Mechanics and Thermodynamics uniting all the successful results of both theories, eliminating the logical inconsistencies of Statistical Mechanics and the paradoxes on irreversibility, and providing an entirely new perspective on the microscopic origin of irreversibility, nonlinearity (therefore including chaotic behavior) and maximal-entropy-generation non-equilibrium dynamics. In this long introductory paper we discuss the background and formalism of Quantum Thermo- dynamics including its nonlinear equation of motion and the main general results regarding the nonequilibrium irreversible dynamics it entails. -
Lecture 6: Entropy
Matthew Schwartz Statistical Mechanics, Spring 2019 Lecture 6: Entropy 1 Introduction In this lecture, we discuss many ways to think about entropy. The most important and most famous property of entropy is that it never decreases Stot > 0 (1) Here, Stot means the change in entropy of a system plus the change in entropy of the surroundings. This is the second law of thermodynamics that we met in the previous lecture. There's a great quote from Sir Arthur Eddington from 1927 summarizing the importance of the second law: If someone points out to you that your pet theory of the universe is in disagreement with Maxwell's equationsthen so much the worse for Maxwell's equations. If it is found to be contradicted by observationwell these experimentalists do bungle things sometimes. But if your theory is found to be against the second law of ther- modynamics I can give you no hope; there is nothing for it but to collapse in deepest humiliation. Another possibly relevant quote, from the introduction to the statistical mechanics book by David Goodstein: Ludwig Boltzmann who spent much of his life studying statistical mechanics, died in 1906, by his own hand. Paul Ehrenfest, carrying on the work, died similarly in 1933. Now it is our turn to study statistical mechanics. There are many ways to dene entropy. All of them are equivalent, although it can be hard to see. In this lecture we will compare and contrast dierent denitions, building up intuition for how to think about entropy in dierent contexts. The original denition of entropy, due to Clausius, was thermodynamic. -
The Entropy Universe
entropy Review The Entropy Universe Maria Ribeiro 1,2,* , Teresa Henriques 3,4 , Luísa Castro 3 , André Souto 5,6,7 , Luís Antunes 1,2 , Cristina Costa-Santos 3,4 and Andreia Teixeira 3,4,8 1 Institute for Systems and Computer Engineering, Technology and Science (INESC-TEC), 4200-465 Porto, Portugal; [email protected] 2 Computer Science Department, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal 3 Centre for Health Technology and Services Research (CINTESIS), Faculty of Medicine University of Porto, 4200-450 Porto, Portugal; [email protected] (T.H.); [email protected] (L.C.); [email protected] (C.C.-S.); andreiasofi[email protected] (A.T.) 4 Department of Community Medicine, Information and Health Decision Sciences-MEDCIDS, Faculty of Medicine, University of Porto, 4200-450 Porto, Portugal 5 LASIGE, Faculdade de Ciências da Universidade de Lisboa, 1749-016 Lisboa, Portugal; [email protected] 6 Departamento de Informática, Faculdade de Ciências da Universidade de Lisboa, 1749-016 Lisboa, Portugal 7 Instituto de Telecomunicações, 1049-001 Lisboa, Portugal 8 Instituto Politécnico de Viana do Castelo, 4900-347 Viana do Castelo, Portugal * Correspondence: [email protected] Abstract: About 160 years ago, the concept of entropy was introduced in thermodynamics by Rudolf Clausius. Since then, it has been continually extended, interpreted, and applied by researchers in many scientific fields, such as general physics, information theory, chaos theory, data mining, and mathematical linguistics. This paper presents The Entropy -
Multiple Periodic Solutions and Fractal Attractors of Differential Equations with N-Valued Impulses
mathematics Article Multiple Periodic Solutions and Fractal Attractors of Differential Equations with n-Valued Impulses Jan Andres Department of Mathematical Analysis and Applications of Mathematics, Faculty of Science, Palacký University, 17. listopadu 12, 771 46 Olomouc, Czech Republic; [email protected] Received: 10 September 2020; Accepted: 30 September 2020; Published: 3 October 2020 Abstract: Ordinary differential equations with n-valued impulses are examined via the associated Poincaré translation operators from three perspectives: (i) the lower estimate of the number of periodic solutions on the compact subsets of Euclidean spaces and, in particular, on tori; (ii) weakly locally stable (i.e., non-ejective in the sense of Browder) invariant sets; (iii) fractal attractors determined implicitly by the generating vector fields, jointly with Devaney’s chaos on these attractors of the related shift dynamical systems. For (i), the multiplicity criteria can be effectively expressed in terms of the Nielsen numbers of the impulsive maps. For (ii) and (iii), the invariant sets and attractors can be obtained as the fixed points of topologically conjugated operators to induced impulsive maps in the hyperspaces of the compact subsets of the original basic spaces, endowed with the Hausdorff metric. Five illustrative examples of the main theorems are supplied about multiple periodic solutions (Examples 1–3) and fractal attractors (Examples 4 and 5). Keywords: impulsive differential equations; n-valued maps; Hutchinson-Barnsley operators; multiple periodic solutions; topological fractals; Devaney’s chaos on attractors; Poincaré operators; Nielsen number MSC: 28A20; 34B37; 34C28; Secondary 34C25; 37C25; 58C06 1. Introduction The theory of impulsive differential equations and inclusions has been systematically developed (see e.g., the monographs [1–4], and the references therein), among other things, especially because of many practical applications (see e.g., References [1,4–11]). -
Similarity Between Quantum Mechanics and Thermodynamics: Entropy, Temperature, and Carnot Cycle
Similarity between quantum mechanics and thermodynamics: Entropy, temperature, and Carnot cycle Sumiyoshi Abe1,2,3 and Shinji Okuyama1 1 Department of Physical Engineering, Mie University, Mie 514-8507, Japan 2 Institut Supérieur des Matériaux et Mécaniques Avancés, 44 F. A. Bartholdi, 72000 Le Mans, France 3 Inspire Institute Inc., Alexandria, Virginia 22303, USA Abstract Similarity between quantum mechanics and thermodynamics is discussed. It is found that if the Clausius equality is imposed on the Shannon entropy and the analogue of the quantity of heat, then the value of the Shannon entropy comes to formally coincide with that of the von Neumann entropy of the canonical density matrix, and pure-state quantum mechanics apparently transmutes into quantum thermodynamics. The corresponding quantum Carnot cycle of a simple two-state model of a particle confined in a one-dimensional infinite potential well is studied, and its efficiency is shown to be identical to the classical one. PACS number(s): 03.65.-w, 05.70.-a 1 In their work [1], Bender, Brody, and Meister have developed an interesting discussion about a quantum-mechanical analogue of the Carnot engine. They have treated a two-state model of a single particle confined in a one-dimensional potential well with width L and have considered reversible cycle. Using the “internal” energy, E (L) = ψ H ψ , they define the pressure (i.e., the force, because of the single dimensionality) as f = − d E(L) / d L , where H is the system Hamiltonian and ψ is a quantum state. Then, the analogue of “isothermal” process is defined to be f L = const.