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12A- 6 4-4El ATTORNEY 3,039,846 United States Patent Office Patented June 19, 1962 1
June 19, 1962 P. R. OGLE, JR 3,039,846 METHOD FOR THE RECOVERY AND PURIFICATION OF GASEOUS UF FROM GASEOUSPRODUCTS MIXTURES PRODUCEDANDUFNO AND UF, NO THEREBY Filed Oct. 9, 196l. : 8 s O O O O O o O t CN A. "NOISSWSNW.L INVENTOR Pearl R. Ogle, Jr. BY 12a- 6 4-4el ATTORNEY 3,039,846 United States Patent Office Patented June 19, 1962 1. 2 3,039,846 of UF are superimposed. The absorption bands at METHOD FOR THE RECOVERY AND PURIFICA 2320 and 2318, and 549 to 510 cm. are attributed to TION OF GASEOUS UFFROM GASEOUSMX the NO+ and UF ions, respectively, this indicating that TURES AND UFNO AND UFNO PRODUCTS the compound UFNO is a 1:1 addition complex having PRODUCED THEREBY a composition NOF.UF6. This compound has a vapor Pearl R. Ogle, Jr., Chilicothe, Ohio, assignor to the pressure of less than 1 mm. Hg at 25°C. with the vapor 'United States of America as represented by the United over the solid comprising approximately equal molar States Atomic Energy Commission quantities of uranium hexafluoride and nitrosyl fluoride. Filed Oct. 9, 1961, Ser. No. 143,986 Example II 8 Claims. (C. 23-14.5) 10. The present invention relates to a new and useful class This example illustrates the preparation of UFNO2. of chemical reactions involving gaseous uranium hexa The procedure of Example I was used to react UFa fluoride and to a new and useful method of recovering and nitryl fluoride. A greenish-white solid having a and/or purifying gaseous uranium hexafluoride values vapor pressure of 11.6 mm. -
Ucri, 100554 Preprint
UCRI, 100554 PREPRINT x CHEMICAL THERMODYNAMICS OF TECHNETIUM 0 r0 0 0m 0 Joseph A.' Rard z C w1 m This paper was prepared for inclusion in the book CHEMICAL THERMODYNAMICS OF TECHNETIUM (to' be published by the Nuclear Energy Agency, Paris, France) February 1989 This is a preprint of a paper intended for publication in a journal or proceedings. Since changes may be made before publication, this preprint is made available with the understanding that it will not be cited or reproduced without the permission of the author. - DISCILAIMER This document was prepared as an account of work sponsored by asnagency of the United States Government Neither the United States Government nor the University of California nor any of their employees. makes any warranty, express or implieid, or assumes any legal liability or responsibility for the accuracy completeness, or useful- ness of any Information, apparatus. product, or process disclosed. or represents that Its use would not Iafringe privately owned rights. Reference hereln to any specific commercial products, process, or service by trade name. trademark. manufacturer, or otherwise. does not necessarily constitute or Imply its endorsement. recommendation, or favoring by the United States Government or the University of California. The views and opinions of authors expressed hereb do not necessarily state or reflect those of the United States Government or the University of California, and shall not be used for advertising or product endorsement purposes. -W This manuscript by JA Rard is to be part of a book entitled "CHEMICAL THERMODYNAMICS OF TECHNETIUM". It will be published by the Nuclear Energy Agency Data Bank at Saclay, France. -
Cryogenic Solutions and Solubilities in Liquid Flourine
NASA TECHNICAL NOTE 40 Qo N N I n z c 4 m 4 z CRYOGENIC SOLUTIONS AND SOLUBILITIES IN LIQUID FLUORINE by Robert E. Seauer Lewis Research Center Cleueland, Ohio I NATIONAL AERONAUTICS AND SPACE ADMINISTRATION 0 WASHINGTON, D. C. '" 0, JUNE 1964 CRYOGENIC SOLUTIONS AND SOLUBILITIES IN LIQUID FLUORINE By Robert E. Seaver Lewis Research Center Cleveland, Ohio NATIONAL AERONAUTICS AND SPACE ADMINISTRATION For sale by the Office of Technical Services, Department of Commerce, Washington, D.C. 20230 -- Price $0.50 CRYOGENIC SOLUTIONS AND SOLUBILITIES IN LIQUID FLUORINE by Robert E. Seaver Lewis Research Center SUMMARY The solubilities of several substances in liquid fluorine have been deter- mined between 68' and 83' K by vapor-pressure measurements. These experimental data, as well as a summary of literature data on solutions of solids in cryo- genic liquids, are presented and compared with solubilities calculated by as- suming regular solutions. Experimental and calculated values for the solubili- ties of carbon tetrafluoride, perfluorethane, and perchloryl fluoride in liquid fluorine show close agreement, while the solubilities of krypton and xenon in fluorine show considerable deviation from calculated values. Little of the literature data agrees with the calculated solubilities. Deviations from cal- culated values are discussed. INTRODUCTION Only a limited amount of past work has been concerned with the prediction of the solubilities of solids in cryogenic liquids. Information on solutions in liquid fluorine is essentially nonexistent, and in the case of carbon tetra- fluoride the solubility data that are available (ref. 1) appear to be in con- siderable error. This lack of information, together with the importance of cryogenic liquids in space applications and the possible use of fluorine as a rocket propellant, prompted the present investigation. -
Nitrogen Oxychlorides : a Bibliography on Data for Physical and Chemical
NBS Publl - cations NArL INST. OF STAND & TECH NBS SPECIAL PUBLICATION 478 U.S. DEPARTMENT OF COMMERCE / National Bureau of Standards NITROGEN OXYCHLORIDES: A Bibliography on Data for Physical and Chemical Properties of CUNO, CLNO2, and CdNOs NATIONAL BUREAU OF STANDARDS The National Bureau of Standards^ was established by an act of Congress March 3, 1901. The Bureau's overall goal is to' strengthen and advance the Nation's science and technology and facilitate their effective application for public benefit. To this end, the Bureau conducts research and provides: (1) a basis for the Nation's physical measurement system, (2) scientific and technological services for industry and government, (3) a technical basis for equity in trade, and (4) technical services to pro- mote public safety. The Bureau consists of the Institute for Basic Standards, the Institute for Materials Research, the Institute! for Applied Technology, the Institute for Computer Sciences and Technology, the Office for Information Programs, and the Office of Experimental Technology Incentives Program. THE INSTITUTE FOR BASIC STANDARDS provides the central basis within the United States of a complete and consist- ent system of physical measurement; coordinates that system with measurement systems of other nations; and furnishes essen-' tial services leading to accurate and uniform physical measurements throughout the Nation's scientific community, industry,! and commerce. The Institute consists of the Office of Measurement Services, and the following center and divisions: -
In Presenting the Dissertation As a Partial Fulfillment of The
In presenting the dissertation as a partial fulfillment of the requirements for an advanced degree from the Georgia Institute of Technology, I agree that the Library of the Institute shall make it available for inspection and circulation in accordance with its regulations governing materials of this type. I agree that permission to copy from, or to publish from, this dissertation may be granted by the professor under whose direction it was written, or, in his absence, by the Dean of the Graduate Division when such copying or publication is solely for scholarly purposes and does not involve potential financial gain. It is under- stood that any copying from, or publication of, this dis- sertation which involves potential financial gain will not be allowed without written permission. MASS SPECTROMETRIC INVESTIGATION OF THE SYNTHESIS AND MOLECULAR ENERGETICS OF NITROGEN-OXYGEN-FLUORINE COMPOUIVDS A THESIS Presented to The Faculty of the Graduate Division by Paul Anthony Sessa In Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy in the School of Chemical Engineering Georgia Institute of Technology December, 1970 MASS SPECTROMETRIC INVESTIGATION OF THE SYNTHESIS AND MOLECULAR ENERGETICS OF NITROGEN-OXYGEN-FLUORINE COMPOUNDS Date approved by chain&: ,L,/,d,/76 ACKNOWLEDGMENTS The author is grateful to Dr. Henry A. McGee, Jr. , for his sug- gestion of the research problem and his interest and guidance as the work progressed. The suggestions and assistance given by my fellow graduate students, C. T. Kwon, P. Ganguli, and J. K. Holzhauer, are greatly appreciated. I am also indebted to Dr. W. T. Ziegler and Dr. -
Safety Data Sheet CS: 3.4.17
Safety Data Sheet CS: 3.4.17 Page: 1 of 7 Infosafe No ™ 1CH6J Issue Date : November 2020 RE-ISSUED by CHEMSUPP Product Name :SODIUM METAL Classified as hazardous 1. Identification GHS Product SODIUM METAL Identifier Company Name CHEM-SUPPLY PTY LTD (ABN 19 008 264 211) Address 38 - 50 Bedford Street GILLMAN SA 5013 Australia Telephone/Fax Tel: (08) 8440-2000 Number Emergency phone CHEMCALL 1800 127 406 (Australia) / +64-4-917-9888 (International) number E-mail Address www.chemsupply.com.au Recommended use of Tetraethyl and tetramethyl lead, titanium reduction, sodium peroxide, sodium the chemical and hydride, polymerisation catalyst for synthetic rubber, analytical chemistry, restrictions on use to make sodium salts, reducing agent (ketones), laboratory reagent, coolant in nuclear reactors, electric power cable (encased in polyethylene), non-glare lighting for highways and heat transfer agent in solar powered electric generators. Other Names Name Product Code Natrium SODIUM METAL LR SL074 Other Information Chem- Supply Pty Ltd does not warrant that this product is suitable for any use or purpose. The user must ascertain the suitability of the product before use or application intended purpose. Preliminary testing of the product before use or application is recommended. Any reliance or purported reliance upon Chem-Supply Pty Ltd with respect to any skill or judgement or advice in relation to the suitability of this product of any purpose is disclaimed. Except to the extent prohibited at law, any condition implied by any statute as to the merchantable quality of this product or fitness for any purpose is hereby excluded. This product is not sold by description. -
LOS ALAMOS SCIENTIFIC LABORATORY of the University of California LOS ALAMOS ● NEW MEXICO
LA-3871-MS LOS ALAMOS SCIENTIFIC LABORATORY of the University of California LOS ALAMOS ● NEW MEXICO A Bibliography on Nuclear Magnetic Resonance of Inorganic Fluorides 1.. .— t“ l-- — r! UNITED STATES ATOMIC ENERGY COMMISSION CONTRACT W-7405 -ENG. 36 LEGAL NOTICE This reportwas preparedas an accountof Governmentsponsoredwork. Neitherthe United States,nor theCommission,nor any personactingon behalfoftheCommission: A. Makes any warrantyorrepresentation,expressedor implied,withrespecttoiheaccu- racy,completeness,or usefulnessoftheinformationcontainedinthisreport,or thattheuse of any information,apparatus,meihcd,or processdisclosedin thisreportmay not infringe privatelyowned rights;or B. Assumes any liabilitieswithrespecttotheuse of,or fordamages resultingfrom the use ofany information,apparatus,method,or processdisclosedinthisreport. AE used in theabove,“personactingon behalfof the Commission” includesany em- ployeeor contractorof theCommission,or employeeof such contractor,tothe extentthat such empioyeeor contractorof theCommission,or employeeof such contractorprepares, disseminates,or providesaccessto,any informationpursuanitohisemploymentor contract withtheCommission,or hiaemploymentwithsuchcontractor. This report expresses the opinions of the author or authors and does not necessarily reflect the opinions or views of the Los Alamos Scientific Laboratory. Printed in the United States of America. Available from Clearinghouse for Federal Scientific and Technical Information * National Bureau of Standards, U. S. Department of Commerce Springfield, -
Selected Values of Electric Dipole Moments for Molecules in the Gas Phase
WSfona f Bg^rgi A11102 14b22b ranaa feraiy, e-ci Ad|| Bldg. SEP I 3 jggp NSRDS-NBS 10 Selected Values of Electric Dipole Moments for Molecules in the Gas Phase U.S. DEPARTMENT OF COMMERCE NATIONAL BUREAU OF STANDARDS — National Standard Reference Data Series National Bureau of Standards National Standard Reference Data System, Plan of Operation, NSRDS-NBS 1 15 cents* Thermal Properties of Aqueous Uni-univalent Electrolytes NSRDS-NBS 2—45 cents* Selected Tables of Atomic Spectra, Atomic Energy Levels and Multiplet Tables—Si ii. Si hi. Si iv, NSRDS-NBS 3, Section 1—35 cents* Atomic Transition Probabilities, Volume I, Hydrogen Through Neon, NSRDS-NBS 4 $2.50* The Band Spectrum of Carbon Monoxide, NSRDS-NBS 5—70 cents* Tables of Molecular Vibrational Frequencies. Part 1, NSRDS-NBS 6—40 cents* High Temperature Properties and Decomposition of Inorganic Salts. Part 1. Sulfates, NSRDS-NBS 7—35 cents* Thermal Conductivity of Selected Materials. NSRDS-NBS 8—$1.00* Tables of Biomolecular Gas Reactions. NSRDS-NBS 9—In press. Selected Values of Electric Dipole Moments for Molecules in the Gas Phase. NSRDS- NBS 10—40 cents* *Send orders with remittance to: Superintendent of Documents, U.S. Government Printing Office, Washington, D.C. 20402. Remittances from foreign countries should include an additional one-fourth of the purchase price for postage. 1 UNITED STATES DEPARTMENT OF COMMERCE Alexander B. Trowbridge, Secretary, NATIONAL BUREAU OF STANDARDS • A. V. Astin, Director 1 <0 Selected Values of Electric Dipole Moments for Molecules in the Gas Phase Ralph D. Nelson, Jr. Chemistry Department Middlebury College Middlebury, Vermont 05753 AND David R.