The Development of Forest-Based Biorefineries: Implications for Market Behavior and Policy

Total Page:16

File Type:pdf, Size:1020Kb

The Development of Forest-Based Biorefineries: Implications for Market Behavior and Policy The Development of Forest-based Biorefineries: Implications for Market Behavior and Policy Patrik Söderholm and Robert Lundmark Abstract and the use of biomass is expected to constitute a major In a forest-based biorefinery, the entire potential of share of the future total use of renewable energy sources forest raw materials and byproducts may be used to pro- in Europe (European Commission 1997, 2006). Essential duce a diverse set of products, including transport fuels, components of national energy policies in Europe, there- chemicals, and pulp and paper products. This paper ana- fore, include not only direct promotion of renewable ener- lyzes the general impact on forest raw material markets gy technologies (e.g., investment and R&D support), but following an increased diffusion of biorefineries and high- also carbon dioxide taxes and emissions trading in carbon lights a number of related public policy issues. The analy- dioxide allowances that discourage the use of fossil fuels. The transition from a fossil fuel-based to a carbon-free sis indicates that the character of forest raw material sup- energy system may have important consequences for the ply, in particular the distinction between main products use of raw materials in society, not the least in cases of and byproducts, will have a major influence on the func- agricultural and forest-based resources. Increases in the tioning and the organization of future forest products mar- relative prices of fossil fuels affect a large number of indus- kets. Moreover, the advent of new uses of forest-based bio- trial and end-use sectors of the economy. The reliance on mass will foster an increased competition for (and thus new energy carriers and materials could even induce fun- higher price of) this resource. An important policy lesson, damental structural and technological changes in the way however, is not to directly regulate the allocation of forest goods and services are produced and supplied. resources between different sectors or promote a certain This paper focuses on a potentially critical change in industrial structure. The rationale for policy intervention the way forest resources will be processed and used in the lies instead in identifying situations in which essential future, namely the development of biorefineries. A biorefin- societal costs and benefits do not enter the private deci- ery is a parallel to a petroleum refinery in which a feedstock sion-making process. The presence of external environ- (crude oil) is converted into fuels and selected market prod- mental costs (e.g., damages to the climate) and the public ucts (e.g., fertilizers and synthetic materials). In a biorefin- spillover effects from R&D and innovation activities pro- ery, however, biomass (plants and plant-derived material vide such rationales, but at the same time require careful based on photosynthesis) would be used as feedstock to analysis prior to the introduction of specific policy instru- produce a diverse set of products (e.g., animal feed, fuels, ments. Overall there exists a need to create a better under- energy, pulp and paper, fuels, or chemicals) depending on standing of the linkage between energy and forest prod- ucts markets, with new co- and byproducts included. The authors are, respectively, Professor ([email protected]) and Associate Professor, ([email protected]), Economics Introduction Unit, Luleå University of Technology, SE 971 87 Luleå, Sweden. This An essential component of the European Union’s ener- paper was received for publication in March 2008 and has been gy policy is the promotion of renewable energy sources, through the Journal’s peer-review process. Article No. 10468. I6 JANUARY/FEBRUARY 2009 the resource inputs and the processing techniques used. useful to highlight a number of general market develop- Biorefineries can be based on either agricultural (Audsley ments and policy issues that should constitute the basis and Annetts 2003) or forest-based raw materials (Van for future economic and social scientific work on forest- Heiningen 2006). A major benefit of integrated forest-based based biorefineries. Also some of the key issues present in biorefineries is that they can make use of the infrastructure the Swedish case are highlighted. at existing chemical pulp mills; and, at the same time, they The paper is organized in the following sections. The utilize a larger share of the wood components to produce a next section briefly presents the concept of an integrated diverse set of chemical products and energy carriers in addi- forest biorefinery with particular emphasis on the flow of tion to pulp. To a large extent, the existing pulp industry is forest raw materials and the end products that can be gen- already a multi-product industry producing electricity, heat, erated. Then, changes in forest products market behavior and other products in addition to pulp. With the develop- are analyzed with a focus on the supply of different types ment of new technologies, however, a large number of addi- of products as well as the potential for increased competi- tional products may be processed and generated in integrat- tion for the forest raw materials and processed products ed biorefineries; this raises questions about possible conse- based on these raw materials. Lastly, a number of poten- quences for forest raw materials markets as well as its impli- tial implications for energy and environmental policy fol- cations for public policy in the forest and energy sectors. lowing the development of biorefineries are highlighted. In a recent communication, the European Commission (2008) endorsed a separate minimum target for the share of sustainable biofuels in the European transport sector and The Basics of Biorefineries The primary goal of converting a given chemical pulp stressed the need for analyses of market impacts and inter- mill into an integrated biorefinery is to create more value actions following the advent of increased use of biofuels. from the bio-based raw material provided by the forestry sec- tor.1 Mensink et al. (2007) noted that a biorefinery is charac- [The] Commission is committed to promoting in Tterized by an “efficient use of the entire potential of raw mate- all its policies the rapid development of second rials and by-streams of the forest-based sector towards a generation biofuels. It will closely monitor mar- broad range of high-added value products (by co-operation ket developments and their effects on food, feed, in and between chains)” (p. 3). Wood contains cellulose (40% energy and other industrial uses of biomass, and to 45%), lignin (20% to 30%), hemicellulose (25% to 30%), and take appropriate action if needed. (p. 8) extractives (3% to 4%). But, a considerable share of the har- vested wood, i.e., the forest residues, never enters the pulp Given this statement, the purposes of this paper are to analyze the impacts on forest raw material markets follow- digester, and in the chemical pulping process about 20 to 30 ing an increased diffusion of integrated biorefineries in the percent of the wood weight – primarily lignin and hemicellu- chemical pulp industry and to discuss a number of related lose – dissolve in the waste liquor (Van Heiningen 2006). energy and environmental policy issues. The analysis is Figure 1 illustrates the flow of forest resources and general in scope and does not include in-depth empirical byproducts in an integrated forest-based biorefinery, as work on specific biorefineries. A major share of the ongo- ing research in this field is dominated by engineers and 1 It should be noted that not every pulp mill may be converted to natural scientists (Van Heiningen 2006); it is, therefore, an integrated biorefinery, only selected ones (e.g., kraft pulp mills). Figure 1. — Raw material flows and end use products in a forest-based biorefinery. Source: Based on Axegård (2005) and Backlund and Axegård (2006). FOREST PRODUCTS JOURNAL Vol. 59, No. 1/2 7 well as the possible end products that ultimately could be remove the lignin from the black liquor by acid precipita- generated from the refinery. The new value streams can be tion. Lignin precipitation after pulping can be used to pro- divided into two main categories (Closset et al. 2005). First, duce carbon fibers when mixed with commercial polymers before wood is pulped, hemicelluloses (essentially a form of (such as polyesters) (Kadla et al. 2002). This is a light but sugar) can be extracted by leaching from, for strong material, which, among other things, example, forest residues and/or wood chips. is used in space technology and in produc- Important challenges for effectively using ing sport equipment (e.g., tennis rackets). these raw materials are to keep the lignin The automobile industry may also repre- content low in the extracted hemicellulose ...a transformation sent a major market for composite materials and to ensure that the wood chips entering of at least containing carbon fibers, in this case as a the pulping stage are of good quality. The parts of the pulp substitute for structural steel. Lignin can extracted hemicellulose can be converted to industry...into also be used to generate phenols, which mono-sugars through hydrolysis, which in represent intermediate products used in the turn can be used to produce ethanol through biorefineries is likely. production of, for example, compact discs a fermentation process. Through additional From the pulp industry’s and plywood. fermentation and subsequent processes, point of view, this Although a considerable amount of however, other – potentially higher value- provides an opportunity research is needed to commercialize the added – products may also be produced. For above technologies and processes, a trans- example, hemicellulose can be used to gen- to increase profitability, formation of at least parts of the pulp erate fiber additives in paper mills, barriers, while still making use industry (e.g., kraft pulp mills) into biore- and hydrogels.
Recommended publications
  • Laval University
    LAVAL UNIVERSITY FACULTY OF FORESTRY AND GEOMATICS Department of Wood and Forest Sciences Sponsored by the International Development Center (IDRC) Ottawa, Canada “The Hidden World that Feeds Us: the Living Soil” Seminars given at the International Institute for Trropical Agriculture (ITA) Univeristy of Ibadan, Nigeria at the International Centre of Research in Agroforestry (ICRAF) Nairobi, Kenya and at the Ukrainian Academy of Agricultural Sciences Kiev, Ukraine by Professor Gilles Lemieux Department of Wood and Forestry Science ORIGINAL FRENCH PUBLICATION Nº 59b http://forestgeomat.ffg.ulaval.ca/brf/ edited by Coordination Group on Ramial Wood Depatment of Wood and Forestry Science Québec G1K 7P4 QUÉBEC CANADA TABLE OF CONTENTS I. A brief history: the evolution of ecosystems and man’s anthropocentric behaviour 1 II. The importance of the forest in tropical climates 2 III. The basic composition of wood 3 1. Lignin and its derivatives and their role in doil dynamic 5 IV. Stem wood and ramial wood 6 1. Stem wood and its lignin 6 2. Ramial wood and its lignin 6 3. Agricultural and forestry trials using ramial wood 7 V. “Organic Matter”, one of the basic principles in agriculture 9 1. Some a posteriori thoughts 10 2. The rationale for chipping 10 3. More like a food than a fertilizer 11 4. The principles behind chipping 11 VI. Lignin 13 1.The nutrients question 14 2.The biological cycling of water in tropical climates 15 3.“Chemical” nutrients 15 4.Nitrogen 15 5.Phosphorus 16 VII. A tentative theory 17 1.Too much or too little water 17 2.The soil-structuring role of lignin 17 3.The role of trophic web 18 4.Living beyond the soil’s chemical constraints 18 5.The major cause of tropical soils degradation.
    [Show full text]
  • The Decomposition of Forest Products in Landfills
    International Biodeterioration & Biodegradation Vol. 39, No. 2–3 (1997) 145–158 Published by Elsevier Science Limited Printed in Great Britain PII:S0964-8305(96)00039-X 0964-8305/97 $17.00 + .00 ELSEVIER The Decomposition of Forest Products in Landfills J. A. Micales & K. E. Skog USDA Forest Service, Forest Products Laboratory, One Gifford Pinchot Drive, Madison, WI 53705, USA (Received 3 April 1996; revised version received 25 June 1996; accepted 22 July 1996) Large quantities of forest products are disposed of in landfills annually. The fate of this vast pool of carbon is important since carbon sequestration and the generation of landfill gases have important implications for global warming. Published estimates of methane yields were used to estimate the amount of carbon released into the atmosphere from landfilled forest products. These calculations suggest that maximally only 30%, of the carbon from paper and 0- 3% of the carbon from wood are ever emitted as landfill gas. The remaining carbon, approximately 28 Tg in 1993, remains in the landfill indefinitely. Some of this carbon may be removed during leachate treatment, but a large portion is permanently sequestered where its impact on global warming is negligible. The placement of forest products in landfills serves as a significant carbon sink, and its importance in the global carbon balance should not be overlooked. Published by Elsevier Science Limited INTRODUCTION warming? President Clinton’s Climatic Change Action Plan (Clinton & Gore, 1993) sets a US In 1993, the US Environmental Protection Agency objective of restraining carbon emission growth (EPA) (1994) estimated that 50 Tgl of paper and and increasing sequestration by a total of 100 Tg/ 18.6 Tg of wood were discarded in the United year by the year 2000.
    [Show full text]
  • Influence of Hemicelluloses Content on the Paper Quality Produced with Eucalyptus Globulus Fibres
    CORE Metadata, citation and similar papers at core.ac.uk Provided by Repositório Científico do Instituto Politécnico de Castelo Branco Proceedings of Progress in Paper Physics Seminar 2004, Norway, Trondheim, 21 a 24 de Junho, p. 50-52 Influence of hemicelluloses content on the paper quality produced with Eucalyptus globulus fibres. Ofélia Anjos1, António Santos2, and Rogério Simões2 1Escola Superior de Agrária – 6001-909 Castelo Branco, Portugal, [email protected] 2Universidade da Beira Interior, 6201-001 Covilhã, Portugal, [email protected] Abstract The raw-material composition and the cooking conditions determine the pulp composition and this affect the behaviour of the pulp in the beating process and the papermaking potential. However, at industrial scale the variability of the pulp composition, for a given raw material and a given process, is relatively low and usually it is difficult to quantify the impacts of pulp composition on beating and papermaking. In the present study E. globulus bleached pulps were produced under different cooking conditions by the kraft process in order to obtain pulps with significant different hemicelluloses content (19% versus 14.5%). The behaviour of the pulps in beating and the papermaking potential were investigated under two beating intensities in the PFI mill and at four beating times. The pulp suspensions were characterised in terms of drainability, fibre morphology, wet fibre flexibility and relative bonded area. The paper produced was evaluated in terms of structural, superficial, mechanical and optical properties. The results showed the clear effect of the hemicelluloses content on the beating rate as well as on the paper properties.
    [Show full text]
  • Timber Bridges Design, Construction, Inspection, and Maintenance
    Timber Bridges Design, Construction, Inspection, and Maintenance Michael A. Ritter, Structural Engineer United States Department of Agriculture Forest Service Ritter, Michael A. 1990. Timber Bridges: Design, Construction, Inspection, and Maintenance. Washington, DC: 944 p. ii ACKNOWLEDGMENTS The author acknowledges the following individuals, Agencies, and Associations for the substantial contributions they made to this publication: For contributions to Chapter 1, Fong Ou, Ph.D., Civil Engineer, USDA Forest Service, Engineering Staff, Washington Office. For contributions to Chapter 3, Jerry Winandy, Research Forest Products Technologist, USDA Forest Service, Forest Products Laboratory. For contributions to Chapter 8, Terry Wipf, P.E., Ph.D., Associate Professor of Structural Engineering, Iowa State University, Ames, Iowa. For administrative overview and support, Clyde Weller, Civil Engineer, USDA Forest Service, Engineering Staff, Washington Office. For consultation and assistance during preparation and review, USDA Forest Service Bridge Engineers, Steve Bunnell, Frank Muchmore, Sakee Poulakidas, Ron Schmidt, Merv Eriksson, and David Summy; Russ Moody and Alan Freas (retired) of the USDA Forest Service, Forest Products Laboratory; Dave Pollock of the National Forest Products Association; and Lorraine Krahn and James Wacker, former students at the University of Wisconsin at Madison. In addition, special thanks to Mary Jane Baggett and Jim Anderson for editorial consultation, JoAnn Benisch for graphics preparation and layout, and Stephen Schmieding and James Vargo for photographic support. iii iv CONTENTS CHAPTER 1 TIMBER AS A BRIDGE MATERIAL 1.1 Introduction .............................................................................. l- 1 1.2 Historical Development of Timber Bridges ............................. l-2 Prehistory Through the Middle Ages ....................................... l-3 Middle Ages Through the 18th Century ................................... l-5 19th Century ............................................................................
    [Show full text]
  • Why Is It So Difficult to Make Cellulosic Ethanol? Ethanol Can Be Created from a Variety of Source Materials and Through a Number of Methods
    Why is it so difficult to make cellulosic ethanol? Ethanol can be created from a variety of source materials and through a number of methods. Beer and wine Yeast fermentation uses a well-understood biological process Enzymes in which yeast are fed simple sugars from barley malt or grapes. Yeast digest these sugars to grow and reproduce, and brewers and vintners then harvest the ethanol the microbes create as a waste product. Yeast has special Glucose 2 Ethanol 2 Carbon Dioxide enzymes, or protein catalysts, capable of converting a simple sugar, called glucose, into ethanol as they extract Fermentation equation: enzymes in yeast convert glucose into ethanol and carbon dioxide. energy from the molecule. Creating ethanol from sugar cane, as they do in Brazil, is fairly straightforward Cellulose, like starch, is a complex carbohydrate made because cane juice contains these simple sugars that up of chains of glucose. However, the nature of the links yeast can digest. The production of ethanol becomes holding the glucose together is different in cellulose, more difficult when starting with more complex and there are fewer identified organisms with enzymes carbohydrates from corn grain or other plant materials. that are capable of breaking down cellulose. Enzymes work in a lock and key system; each enzyme matches Starch conversion is also relatively simple. Corn grain and a particular molecule—without the right enzyme potatoes, for example, are heavy in starches, which are you cannot build or degrade a molecule biologically. composed of long chains of glucose molecules. Enzymes that chop the long chains of starch into smaller glucose Starch units are readily available.
    [Show full text]
  • Wood-Based Composite Materials—Panel Products, Glued Laminated
    CHAPTER 11 Wood-Based Composite Materials Panel Products, Glued Laminated Timber, Structural Composite Lumber, and Wood–Nonwood Composites Nicole M. Stark, Research Chemical Engineer Zhiyong Cai, Supervisory Research Materials Engineer Because wood properties vary among species, between Contents trees of the same species, and between pieces from the Conventional Wood-Based Composite Panels 11–2 same tree, solid wood cannot match reconstituted wood Wood Elements 11–3 in the range of properties that can be controlled. Wood Adhesives 11–3 with localized defects (such as knots) can often be utilized effectively in wood-based composites. When wood with Additives 11–6 defects is reduced to wood elements, the influence of these Plywood 11–6 characteristics in the manufactured product is reduced. Oriented Strandboard 11–10 To reinforce sustainable harvesting efforts, wood derived Particleboard 11–11 from small-diameter timber, forest residues, or exotic and invasive species may also be used in wood-based Fiberboard 11–13 composites. Specialty Composite Materials 11–16 Wood-based composite materials can be made up of various Performance and Standards 11–17 wood elements, including fibers, particles, flakes, veneers, Glued Laminated Timber 11–18 or laminates. Properties of such materials can be changed Advantages 11–18 by combining, reorganizing, or stratifying these elements. Types of Glulam Combinations 11–19 When raw material selection is paired with properly selected processing variables, the end result can surpass nature’s best Standards and Specifications 11–19 effort. Manufacture 11–20 The basic element for composite wood products is the fiber, Structural Composite Lumber and Timber with larger particles composed of many fibers (Fig.
    [Show full text]
  • The Impact of Biomass and Acid Loading on Methanolysis During Two-Step Lignin-First Processing of Birchwood
    catalysts Article The Impact of Biomass and Acid Loading on Methanolysis during Two-Step Lignin-First Processing of Birchwood Panos D. Kouris 1,2, Xiaoming Huang 1,3, Xianhong Ouyang 1, Dannie J. G. P. van Osch 1,2, Geert J. W. Cremers 1,2, Michael D. Boot 1,2 and Emiel J. M. Hensen 1,* 1 Laboratory of Inorganic Materials and Catalysis, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands; [email protected] (P.D.K.); [email protected] (X.H.); [email protected] (X.O.); [email protected] (D.J.G.P.v.O.); [email protected] (G.J.W.C.); [email protected] (M.D.B.) 2 Vertoro B.V., Urmonderbaan 22, 6167 RD Geleen, The Netherlands 3 Polymer Technology Group Eindhoven (PTG/e) B.V., P.O. Box 6284, 5600 HG Eindhoven, The Netherlands * Correspondence: to: [email protected]; Tel.: +31-402475178 Abstract: We optimized the solvolysis step in methanol for two-step lignin-first upgrading of woody biomass. Birchwood was first converted via sulfuric acid methanolysis to cellulose pulp and a lignin oil intermediate, which comprises a mixture of lignin oligomers and C5 sugars in the methanol solvent. The impact of reaction temperature (140–200 ◦C), acid loading (0.24–0.81 wt%, dry biomass), methanol/biomass ratio (2.3/1–15.8/1 w/w) and reaction time (2 h and 0.5 h) was investigated. At high biomass loadings (ratio < 6.3/1 w/w), operation at elevated pressure facilitates delignification by keeping methanol in the liquid phase.
    [Show full text]
  • Pretreatments for Converting Wood Into Paper and Chemicals
    Chapter 25 Pretreatments for Converting Wood into Paper and Chemicals William R. Kenealy1, Carl J. Houtman1, Jose Laplaza1, Thomas W. Jeffries1, and Eric G. Horn2 1Forest Service, Forest Products Laboratory, U.S. Department of Agriculture, Madison, WI 53726 2Biopulping International Incorporated, 2912 Syene Road, Madison, WI 53713 Biorefining wood into paper and chemicals is not as easy as making a single traditional paper product. Paper is made from the cellulose-containing fractions of wood and processing may remove lignin and hemicellulose components. The yield and composition of the product depend upon the type of paper being produced. The paper process often alters the non­ cellulose fractions, making them less suitable for conversion to other valuable products. This chapter will review methods of obtaining hemicellulosic sugars and investigate the potential for obtaining sugars by a wood pretreatment before it is made into pulp. As an example of hemicellulose removal the results of a new pretreatment using diethyl oxalate are also described. Hemicellulose removal by this system provides other benefits to the pulping process. 392 © 2007 American Chemical Society 393 Biomass use is touted as a solution to the burgeoning petroleum importation of our nation and as a way to become more energy independent (1). When biomass is targeted for this purpose, carbohydrates are generally converted to products. Corn is used to make ethanol, and it is principally starch that is saccharified to glucose and fermented to ethanol. Sucrose from sugar cane is used to make ethanol in Brazil. Obtaining sugars from lignocellulose is much more difficult. Cellulose has very little solubility in water and a crystalline nature that must be overcome before it can be converted into glucose.
    [Show full text]
  • Fast Hemicellulose Quantification Via a Simple Onestep Acid Hydrolysis
    ARTICLE Fast Hemicellulose Quantification Via a Simple One-Step Acid Hydrolysis Xiadi Gao,1,2,3 Rajeev Kumar,1,2,3 Charles E. Wyman1,2,3 1 Department of Chemical and Environmental Engineering, Bourns College of Engineering, University of California, Riverside, 1084 Columbia Avenue, Riverside, California 92507; telephone: þ951-781-5703; fax: þ951-781-5790; e-mail: [email protected] 2 Center for Environmental Research and Technology, Bourns College of Engineering, University of California, Riverside, 1084 Columbia Avenue, Riverside, California 92507 3 BioEnergy Science Center (BESC), Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 nonrenewable fossil resources (Dale, 2005; Farrell et al., 2006; ABSTRACT: As the second most common polysaccharides in Ragauskas et al., 2006; Wyman et al., 2005). However, the nature, hemicellulose has received much attention in recent plant’s recalcitrance to deconstruction by enzymes or years for its importance in biomass conversion in terms of microbes is the primary obstacle to low cost biological producing high yields of fermentable sugars and value-added production of renewable fuels from lignocellulosic biomass products, as well as its role in reducing biomass recalcitrance. Therefore, a time and labor efficient method that specifically (Himmel et al., 2007; Wyman, 2007). Therefore, versatile analyzes hemicellulose content would be valuable to facilitate approaches are applied to make the conversion from biomass the screening of biomass feedstocks. In this study, a one-step to fuels or chemicals more commercially viable. On one acid hydrolysis method was developed, which applied 4 wt% hand, optimization or improvement of key operations, sulfuric acid at 121 C for 1 h to rapidly quantify XGM including developing effective pretreatment technologies and (xylan þ galactan þ mannan) contents in various types of lignocellulosic biomass and model hemicelluloses.
    [Show full text]
  • Cellulose and Hemicellulose Hydrolysis Models for Application to Current and Novel Pretreatment Processes
    CelluloseCopyright © 2000and byHemicellulose Humana Press Inc. Models 81 All rights of any nature whatsoever reserved. 0273-2289/00/84–86/0081/$14.00 Cellulose and Hemicellulose Hydrolysis Models for Application to Current and Novel Pretreatment Processes SIGRID E. JACOBSEN AND CHARLES E. WYMAN* Chemical and Biochemical Engineering, Thayer School of Engineering, Dartmouth College, Hanover NH 03755-8000, E-mail: [email protected] Abstract Acids catalyze the hydrolysis of cellulose and hemicellulose to produce sugars that organisms can ferment to ethanol and other products. However, advanced low- and no-acid technologies are critical if we are to reduce bioethanol costs to be competitive as a pure fuel. We believe carbohydrate oligomers play a key role in explaining the performance of such hydrolysis processes and that kinetic models would help us understand their role. Vari- ous investigations have developed reaction rate expressions based on an Arrhenius temperature dependence that is first order in substrate concentra- tion and close to first order in acid concentration. In this article, we evaluate these existing hydrolysis models with the goal of providing a foundation for a unified model that can predict performance of both current and novel pretreatment process configurations. Index Entries: Biomass; hydrolysis; kinetics; bioethanol; pretreatment. Introduction When used as a transportation fuel, ethanol produced from lignocel- lulosic biomass, often termed bioethanol, has the potential to provide sig- nificant, and, in many cases, unique, environmental, economic, and strategic benefits. Included are significant reductions in greenhouse gas emissions, disposal of problematic solid wastes, less air pollution (particu- larly when used as a pure fuel in advanced propulsion systems), reduced trade deficits, and improved energy security.
    [Show full text]
  • The Influence of Hydrolytic Enzymes on Tannin Adsorption
    molecules Article The Influence of Hydrolytic Enzymes on Tannin Adsorption- Desorption onto Grape Cell Walls in a Wine-Like Matrix Andrea Osete-Alcaraz 1, Encarna Gómez-Plaza 1,* , Pilar Martínez-Pérez 1 , Florent Weiller 2, Julia Schückel 3,4, William G.T. Willats 5, John P. Moore 2 , José M. Ros-García 1 and Ana B. Bautista-Ortín 1 1 Department of Food Science and Technology, Faculty of Veterinary Science, University of Murcia, Campus de Espinardo, 30100 Murcia, Spain; [email protected] (A.O.-A.); [email protected] (P.M.-P.); [email protected] (J.M.R.-G.); [email protected] (A.B.B.-O.) 2 Department of Viticulture and Oenology, Faculty of AgriSciences, South African Grape and Wine Research Institute, Stellenbosch University, Matieland 7602, South Africa; fl[email protected] (F.W.); [email protected] (J.P.M.) 3 Department of Plant and Environmental Sciences, Faculty of Science, University of Copenhagen, DK-1001 Copenhagen, Denmark; [email protected] 4 Glycospot R&D, Thorvaldsensvej 40, B102, DK-1871 Frederiksberg, Denmark 5 School of Agriculture, Food and Rural Development, Newcastle University, Newcastle-upon-Tyne NE1 4LB, UK; [email protected] * Correspondence: [email protected] Abstract: This study evaluates the capacity of four hydrolytic enzymes to limit the interactions between grape cell-walls and tannins and/or to favor tannin desorption. Adsorption and desorption Citation: Osete-Alcaraz, A.; tests were conducted by mixing a commercial seed tannin with purified skin cell-walls from Syrah Gómez-Plaza, E.; Martínez-Pérez, P.; grapes, in the presence or absence of hydrolytic enzymes, in a model-wine solution.
    [Show full text]
  • Development of Chemical and Biological Processes for Production of Bioethanol. Optimization of the Wet Oxidation Process And
    Ris0-R-967(EN) Development of Chemical and Biological Processes for Production of Bioethanol: Optimization of the Wet Oxidation Process and Characterization of Products EC Elv L Anne Belinda Bjerre and Anette Skammelsen Schmidt APR G 8 #97 OS f Ris0 National Laboratory, Roskilde, Denmark February 1997 Ris0-R-967(EN) Development of Chemical and Biological Processes for Production of Bioethanol: Optimization of R i so i? - the Wet Oxidation Process and Characterization of Products Anne Belinda Bjerre and Anette Skammelsen Schmidt osmamoN of this document is unlimited Ris0 National Laboratory, Roskilde, Denmark February 1997 Abstract The combination of the wet oxidation process (water, oxygen pressure, elevated temperature) and alkaline hydrolysis was proven to be efficient in pretreating agricultural crops for conversion to high-value products. The process was evaluated in order to efficiently solubilise the hemicellulose, degrade the lignin, and open the solid crystalline cellulose structure of wheat straw without generating fermentation inhibitors. The effects of temperature, oxygen pressure, reaction time, and concentration of straw were investigated. The degree of delignification and hemicellulose solubilisation increased with reaction temperature and time. The optimum conditions were 15 minutes at 185°C, producing 9.8 g/L solubilised hemicellulose. For quantification of the solubilised hemicellulose the hydrolysis with 4 %w/v sulfuric acid for 10 minuteswas used. Even though the Aminex HPX-87H column was less sensitive towards impurities than the HPX-87P column. The former gave improved recovery and reproducibility, and was chosen for routine quantification of the hydrolysed hemicellulose sugars. The purity of the solid cellulose fraction also improved with higher temperature.
    [Show full text]