Mineralogy of Pegmatites
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Annual General Meeting 25 November 2016 Creative Resources Leadership Overview § Lepidico is a well funded ASX-listed lithium exploration and development company with an experienced management team § Lepidico’s strategic objective is to become a sustainable lithium producer with a portfolio of assets and pipeline of projects § Lepidico’s exploration initiatives largely focus on hard rock minerals that prior to L-Max® were not traditional sources of lithium § Lepidico is differentiated by having successfully produced lithium carbonate and a suite of by-products from non-traditional hard rock lithium bearing minerals using its patented L-Max® process technology § Lepidico provides exposure to a portfolio of lithium exploration assets through its wholly owned properties, JV’s and IP licence agreements in Asia, Australia, Canada, Europe and South America § At 30 September 2016 Lepidico had A$3.0M in cash and no debt 2 New sources of lithium § Micas and phosphates have been largely overlooked as a source of lithium as no commercially viable process was available to extract the lithium and process through to lithium chemicals prior to L-Max® § Lithium bearing micas Lepidolite and Zinnwaldite contain up to 5% Li2O and like spodumene, are hosted in pegmatites § Lepidolite and Zinnwaldite often occur with tin and tantalum bearing minerals as well as with spodumene § Lithium phosphates such as Amblygonite contain up to 10% Li2O Lepidolite (light purple) Zinnwaldite (dArk grey) Ambygonite/MontebrAsite K(Li,Al,Rb)3(Al,Si)4O10(F,OH)2 KLiFeAl(AlSi3)O10(OH,F)2 -
38Th RMS Program Notes
E.fu\wsoil 'og PROGRAM Thursday Evening, April 14, 2011 PM 4:00-6:00 Cocktails and Snacks – Hospitality Suite 400 (4th Floor) 6:00-7:45 Dinner – Baxter’s 8:00-9:15 THE GUALTERONI COLLECTION: A TIME CAPSULE FROM A CENTURY AGO – Dr. Renato Pagano In 1950, the honorary curator of the Museum of Natural History in Genoa first introduced Dr. Renato Pagano to mineral collecting as a Boy Scout. He has never looked back. He holds a doctorate in electrical engineering and had a distinguished career as an Italian industrialist. His passion for minerals has produced a collection of more than 13,000 specimens, with both systematic and aesthetic subcollections. His wife Adriana shares his passion for minerals and is his partner in collecting and curating. An excellent profile of Renato, Adriana, and their many collections appeared earlier this year in Mineralogical Record (42:41-52). Tonight Dr. Pagano will talk about an historic mineral collection assembled between 1861 and 1908 and recently acquired intact by the Museum of Natural History of Milan. We most warmly welcome Dr. Renato Pagano back to the speakers’ podium. 9:15 Cocktails and snacks in the Hospitality Suite on the 4th floor will be available throughout the rest of the evening. Dealers’ rooms will be open at this time. All of the dealers are located on the 4th floor. Friday Morning, April 15, 2011 AM 9:00 Announcements 9:15-10:15 CRACKING THE CODE OF PHLOGOPITE DEPOSITS IN QUÉBEC (PARKER MINE), MADAGASCAR (AMPANDANDRAVA) AND RUSSIA (KOVDOR) – Dr. Robert F. Martin Robert François Martin is an emeritus professor of geology at McGill University in Montreal. -
Paragenesis of Thb Newry Pegmatite, Maine H
PARAGENESIS OF THB NEWRY PEGMATITE, MAINE H. J. Fnnsnn, Haroard. Uniaersity. The Dunton tourmaline deposit, which occurs in the town of eral assemblagepresent. The deposit has been briefly described by Bastinl and certain rare phosphatesfound there have been discussedby palache.? The deposit was first opened during the summers of 1903 and 1904in a for commercial quantities of pollucite. satisiactory quantities were obtained but mining has now ceased. Due to the care with which Mr. Nevel collected all unusual minerals, it was possible to secure a very complete suite for the Harvard Mineralogical Museum. This suite formed the basis for the mineralogical data in this paper. Acxnowr,roGMENTs Thc writer wishes to acknowledge his great indebtedness to Professor Palache whoseconstant assistanceand constructive criti- cism were of the utmost value during the collection of the data and the preparation of this paper. professor palache made a crys- tallographic study of the tourmalines and constructed the figuies given in this paper. To Mr. H. Berman the writer is obligated for much assistance during the laboratory study of the minerals and the mineral se- quence, Mr. H. Butterfield visited and studied the Newry deposit in 1927 and the writer has drawn freely on his unpublished data. 34e 350 TH E AM ERIC A N M I N ERA LOGIST LocarroN lies at an elevation of about 1525 feet above sea level and 4600 feet west of the main highway. Mining operations were confined to two outcrops, about 250 feet apart, which occur on the western side of the crest of the hill. DBscnrPtroN or PBGuarrrB The wall rock surrounding the outcrops is a light green mica- schist composed essentially of muscovite, actinolite and quartz' This rock has been much disturbed so that near the outcrops, at least, the direction of schistosity is very variable. -
Raman and Infrared Spectroscopic Characterization of Beryllonite, a Sodium and Beryllium Phosphate Mineral – Implications for Mineral Collectors ⇑ Ray L
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 97 (2012) 1058–1062 Contents lists available at SciVerse ScienceDirect Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy journal homepage: www.elsevier.com/locate/saa Raman and infrared spectroscopic characterization of beryllonite, a sodium and beryllium phosphate mineral – implications for mineral collectors ⇑ Ray L. Frost a, , Yunfei Xi a, Ricardo Scholz b, Fernanda M. Belotti c, Luiz Alberto Dias Menezes Filho d a School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, GPO Box 2434, Brisbane Queensland 4001, Australia b Geology Department, School of Mines, Federal University of Ouro Preto, Campus Morro do Cruzeiro, Ouro Preto, MG, 35400-00, Brazil c Federal University of Itajubá, Campus Itabira, Itabira, MG, Brazil d Geology Department, Institute of Geosciences, Federal University of Minas Gerais, Belo Horizonte, MG, 31270-901, Brazil highlights graphical abstract " We have studied the mineral beryllonite. " Be isotopes play an important role in the dating of sediments and in the study of relief evolution. " We have characterized beryllonite using vibrational spectroscopic techniques. " The pegmatitic phosphates are more readily studied by Raman spectroscopy. article info abstract Article history: The mineral beryllonite has been characterized by the combination of Raman spectroscopy and infrared Received 30 May 2012 spectroscopy. SEM–EDX was used for the chemical analysis of the mineral. The intense sharp Raman band Received in revised form 16 July 2012 at 1011 cmÀ1, was assigned to the phosphate symmetric stretching mode. Raman bands at 1046, 1053, Accepted 17 July 2012 1068 and the low intensity bands at 1147, 1160 and 1175 cmÀ1 are attributed to the phosphate antisym- Available online 4 August 2012 metric stretching vibrations. -
Lithium 2017
2017 Minerals Yearbook LITHIUM [ADVANCE RELEASE] U.S. Department of the Interior September 2020 U.S. Geological Survey Lithium By Brian W. Jaskula Domestic survey data and tables were prepared by Annie Hwang, statistical assistant. In the United States, one lithium brine operation with an cobalt oxide and 2,160 kg of lithium-nickel-cobalt-aluminum associated lithium carbonate plant operated in Silver Peak, oxide (Defense Logistics Agency Strategic Materials, 2017). At NV. Domestic and imported lithium carbonate, lithium yearend 2017, the NDS held 540 kg of lithium-cobalt oxide and chloride, and lithium hydroxide were consumed directly 1,620 kg of lithium-nickel-cobalt-aluminum oxide. in industrial applications and used as raw materials for downstream lithium compounds. In 2017, lithium consumption Production in the United States was estimated to be equivalent to The U.S. Geological Survey (USGS) collected domestic 3,000 metric tons (t) of elemental lithium (table 1) [16,000 t production data for lithium from a voluntary canvass of the of lithium carbonate equivalent (LCE)], primarily owing to only U.S. lithium carbonate producer, Rockwood Lithium Inc. demand for lithium-based battery, ceramic and glass, grease, (a subsidiary of Albemarle Corp. of Charlotte, NC). Production pharmaceutical, and polymer products. In 2017, the gross weight and stock data collected from Rockwood Lithium were withheld of lithium compounds imported into the United States increased from publication to avoid disclosing company proprietary data. by 7% and the gross weight of exports increased by 29% from The company’s 6,000-metric-ton-per-year (t/yr) Silver Peak those in 2016. -
A Review of Lithium Occurrences in Africa
A Review of Lithium occurrences in Africa Paul Nex, Kathryn Goodenough, Richard Shaw and Judith Kinnaird Lithium occurrences and exploration activity in Africa are dominated by pegmatite occurrences . Greenbushes, Australia No known brine resources as yet, Mineral Formula although Spodumene LiAl(SiO3)2 Botswana is Petalite LiAlSi4O10 being Eucryptite LiAlSiO4 investigated: Amblygonite (Li,Na)AlPO (F,OH) (by Lithium 4 Consolidated Mineral Lepidolite K(Li,Al)3(Al,Si,Rb)4O10(F,OH) Exploration Ltd-ASX) Pegmatites:typically granitic, enriched in incompatible elements, occurrences correlate with times of collisional orogeny and supercontinent assembly. Pegmatite classification needs reworking, however two types of interest - LCT: Lithium-caesium-tantalum NYF: Niobium-yttrium-fluorine Rubicon (Namibia) Bikita (Zimbabwe) Two dominant genetic models: 1. Products of the fractionation of a parental granite. 2. Products of low volume partial melting of metasediments during post-collisional orogenic collapse associated with decompression Nigeria: Pegmatites are ~probably younger than 560 Ma. Contenders for parental granites are 640-600 Ma Recent research in Norway (Muller et al 2017, or 60-580 Ma “thousands of pegmatites without parental granites”), NW Scotland, Nigeria and Namibia suggests that the low volume partial melting model for the genesis of granitic pegmatites is more prevalent than previously appreciated. In Namibia, potential parental granites are ~25 Ma older than the pegmatites and are deformed while the pegmatites are undeformed Most -
~Ui&£R5itt! of J\Rij!Oua
Minerals and metals of increasing interest, rare and radioactive minerals Authors Moore, R.T. Rights Arizona Geological Survey. All rights reserved. Download date 06/10/2021 17:57:35 Link to Item http://hdl.handle.net/10150/629904 Vol. XXIV, No.4 October, 1953 ~ui&£r5itt! of J\rij!oua ~ul1etiu ARIZONA BUREAU OF MINES MINERALS AND METALS OF INCREASING INTEREST RARE AND RADIOACTIVE MINERALS By RICHARD T. MOORE ARIZONA BUREAU OF MINES MINERAL TECHNOLOGY SERIES No. 47 BULLETIN No. 163 THIRTY CENTS (Free to Residents of Arizona) PUBLISHED BY ~tti£ll~r5itt! of ~rh!Omt TUCSON, ARIZONA TABLE OF CONTENTS INTRODUCTION 5 Acknowledgments 5 General Features 5 BERYLLIUM 7 General Features 7 Beryllium Minerals 7 Beryl 7 Phenacite 8 Gadolinite 8 Helvite 8 Occurrence 8 Prices and Possible Buyers ,........................................ 8 LITHIUM 9 General Features 9 Lithium Minerals 9 Amblygonite 9 Spodumene 10 Lepidolite 10 Triphylite 10 Zinnwaldite 10 Occurrence 10 Prices and Possible Buyers 10 CESIUM AND RUBIDIUM 11 General Features 11 Cesium and Rubidium Minerals 11 Pollucite ..................•.........................................................................., 11 Occurrence 12 Prices and Producers 12 TITANIUM 12 General Features 12 Titanium Minerals 13 Rutile 13 Ilmenite 13 Sphene 13 Occurrence 13 Prices and Buyers 14 GALLIUM, GERMANIUM, INDIUM, AND THALLIUM 14 General Features 14 Gallium, Germanium, Indium and Thallium Minerals 15 Germanite 15 Lorandite 15 Hutchinsonite : 15 Vrbaite 15 Occurrence 15 Prices and Producers ~ 16 RHENIUM 16 -
A Review of Rare-Element (Li-Cs-Ta) Pegmatite Exploration Techniques for the Superior Province, Canada, and Large Worldwide Tantalum Deposits
Exploration and Mining Geology, Vol. 14, Nos. 1-4, pp. 1-30, 2005 © 2006 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved. Printed in Canada. 0964-1823/00 $17.00 + .00 A Review of Rare-Element (Li-Cs-Ta) Pegmatite Exploration Techniques for the Superior Province, Canada, and Large Worldwide Tantalum Deposits JULIE B. SELWAY, FREDERICK W. BREAKS Precambrian Geoscience Section, Ontario Geological Survey 933 Ramsey Lake Road, Sudbury, ON P3E 6B5 ANDREW G. TINDLE Department of Earch Sciences, Open University Milton Keynes, Buckinghamshire, UK MK7 6AA (Received February 16, 2004; accepted September 20, 2004) Abstract — Rare-element pegmatites may host several economic commodities, such as tantalum (Ta- oxide minerals), tin (cassiterite), lithium (ceramic-grade spodumene and petalite), and cesium (pollucite). Key geological features that are common to pegmatites in the Superior province of Ontario and Manitoba, Canada, and in other large tantalum deposits worldwide, can be used in exploration. An exploration project for rare-element pegmatites should begin with an examination of a regional geology map. Rare-element pegmatites occur along large regional-scale faults in greenschist and amphibolite facies metamorphic terranes. They are typically hosted by mafic metavolcanic or metasedimentary rocks, and are located near peraluminous granite plutons (A/CNK > 1.0). Once a peraluminous granite pluton has been identified, then the next step is to determine if the pluton is barren or fertile. Fertile granites have elevated rare element contents, Mg/Li ratio < 10, and Nb/Ta ratio < 8. They commonly contain blocky K-feldspar and green muscovite. Key fractionation indicators can be plotted on a map of the fertile granite pluton to determine the fractionation direction: presence of tourmaline, beryl, and ferrocolumbite; Mn content in garnet; Rb content in bulk K-feldspar; and Mg/Li and Nb/Ta ratios in bulk granite samples. -
Global Lithium Sources—Industrial Use and Future in the Electric Vehicle Industry: a Review
resources Review Global Lithium Sources—Industrial Use and Future in the Electric Vehicle Industry: A Review Laurence Kavanagh * , Jerome Keohane, Guiomar Garcia Cabellos, Andrew Lloyd and John Cleary EnviroCORE, Department of Science and Health, Institute of Technology Carlow, Kilkenny, Road, Co., R93-V960 Carlow, Ireland; [email protected] (J.K.); [email protected] (G.G.C.); [email protected] (A.L.); [email protected] (J.C.) * Correspondence: [email protected] Received: 28 July 2018; Accepted: 11 September 2018; Published: 17 September 2018 Abstract: Lithium is a key component in green energy storage technologies and is rapidly becoming a metal of crucial importance to the European Union. The different industrial uses of lithium are discussed in this review along with a compilation of the locations of the main geological sources of lithium. An emphasis is placed on lithium’s use in lithium ion batteries and their use in the electric vehicle industry. The electric vehicle market is driving new demand for lithium resources. The expected scale-up in this sector will put pressure on current lithium supplies. The European Union has a burgeoning demand for lithium and is the second largest consumer of lithium resources. Currently, only 1–2% of worldwide lithium is produced in the European Union (Portugal). There are several lithium mineralisations scattered across Europe, the majority of which are currently undergoing mining feasibility studies. The increasing cost of lithium is driving a new global mining boom and should see many of Europe’s mineralisation’s becoming economic. The information given in this paper is a source of contextual information that can be used to support the European Union’s drive towards a low carbon economy and to develop the field of research. -
Geology of the Pegmatites and Associated Rocks of Maine
DEPARTMENT OF THE INTERIOR UNITED STATES GEOLOGICAL SURVEY GEORGE OTIS SMITH, DIRECTOR BULLETIN 445 GEOLOGY OF THE PEGMATITES AND ASSOCIATED ROCKS OF MAINE INCLUDING FELDSPAR, QUARTZ, MICA, AND GEM DEPOSITS BY EDSON S. BASTIN WASHINGTON GOVERNMENT PRINTING OFFICE 1911 CONTENTS. Introduction.............................................................. 9 Definition of pegmatite...................................................... 10 Geographic distribution.................................................... 10 Geology.................................................................. 10 Bordering rocks....................................................... 10 Pegmatites in foliated rocks........................................ 11 General statement............................................ 11 Sedimentary foliates........................................... 11 Igneous foliates.....".......................................... 12 Pegmatites in massive granites.................................... 13 'Age.................................................................. 15 General character..................................................... 15 Mineral and chemical composition................................. 15 Mineral constituents.......................................... 15 Relative proportions of minerals............................... 18 Quartzose phases. ..............................^............. 18 Fluidal cavities............................................... 19 Sodium and lithium phases................................... 20 Muscovite -
Roscherite-Group Minerals from Brazil
■ ■ Roscherite-Group Minerals yÜÉÅ UÜté|Ä Daniel Atencio* and José M.V. Coutinho Instituto de Geociências, Universidade de São Paulo, Rua do Lago, 562, 05508-080 – São Paulo, SP, Brazil. *e-mail: [email protected] Luiz A.D. Menezes Filho Rua Esmeralda, 534 – Prado, 30410-080 - Belo Horizonte, MG, Brazil. INTRODUCTION The three currently recognized members of the roscherite group are roscherite (Mn2+ analog), zanazziite (Mg analog), and greifensteinite (Fe2+ analog). These three species are monoclinic but triclinic variations have also been described (Fanfani et al. 1977, Leavens et al. 1990). Previously reported Brazilian occurrences of roscherite-group minerals include the Sapucaia mine, Lavra do Ênio, Alto Serra Branca, the Córrego Frio pegmatite, the Lavra da Ilha pegmatite, and the Pirineus mine. We report here the following three additional occurrences: the Pomarolli farm, Lavra do Telírio, and São Geraldo do Baixio. We also note the existence of a fourth member of the group, an as-yet undescribed monoclinic Fe3+-dominant species with higher refractive indices. The formulas are as follows, including a possible formula for the new species: Roscherite Ca2Mn5Be4(PO4)6(OH)4 • 6H2O Zanazziite Ca2Mg5Be4(PO4)6(OH)4 • 6H2O 2+ Greifensteinite Ca2Fe 5Be4(PO4)6(OH)4 • 6H2O 3+ 3+ Fe -dominant Ca2Fe 3.33Be4(PO4)6(OH)4 • 6H2O ■ 1 ■ Axis, Volume 1, Number 6 (2005) www.MineralogicalRecord.com ■ ■ THE OCCURRENCES Alto Serra Branca, Pedra Lavrada, Paraíba Unanalyzed “roscherite” was reported by Farias and Silva (1986) from the Alto Serra Branca granite pegmatite, 11 km southwest of Pedra Lavrada, Paraíba state, associated with several other phosphates including triphylite, lithiophilite, amblygonite, tavorite, zwieselite, rockbridgeite, huréaulite, phosphosiderite, variscite, cyrilovite and mitridatite. -
Local Peralkalinity in Peraluminous Granitic Pegmatites. I. Evidence
This is the peer-reviewed, final accepted version for American Mineralogist, published by the Mineralogical Society of America. The published version is subject to change. Cite as Authors (Year) Title. American Mineralogist, in press. DOI: https://doi.org/10.2138/am-2021-7790. http://www.minsocam.org/ Revision 1 1 Local peralkalinity in peraluminous granitic pegmatites. I. Evidence 2 from whewellite and hydrogen carbonate in fluid inclusions 3 YONGCHAO LIU1,2, CHRISTIAN SCHMIDT2,*, AND JIANKANG LI1 4 1MNR Key Laboratory of Metallogeny and Mineral Assessment, Institute of Mineral Resources, 5 Chinese Academy of Geological Sciences, Beijing 100037, China 6 2GFZ German Research Centre for Geosciences, Telegrafenberg, 14473 Potsdam, Germany 7 *Corresponding author: [email protected] 8 9 ABSTRACT 10 Fluid inclusions in pegmatite minerals were studied using Raman spectroscopy to 11 determine the carbon species. Carbon dioxide is very abundant in the aqueous liquid and vapor − 12 phases. Occasionally, CH4 was found in the vapor. In the aqueous liquid, HCO3 was detected in 13 fluid inclusions in tantalite-(Mn) from the Morrua Mine and in late-stage quartz from the Muiâne 14 pegmatite and the Naipa Mine, all in the Alto Ligonha District, Mozambique. Moreover, we 15 observed a carbonate (calcite group) in fluid inclusions in garnet from the Naipa Mine and in 16 beryl from the Morrua Mine, both in the Alto Ligonha District, Mozambique, and a calcite-group 17 carbonate and whewellite [CaC2O4∙H2O] in fluid inclusions in topaz from Khoroshiv, Ukraine. 18 The occurrence of oxalate is interpreted to be due to a reaction of some form of carbon (possibly 19 CO or bitumen) with a peralkaline fluid.