Prof. Alexander Pines Glenn T

Total Page：16

File Type：pdf, Size：1020Kb

Interdisciplinary Seminar sponsored by the Departments of Chemistry & Biochemistry and Chemical Engineering, Materials Research Laboratory, and Institute of Terahertz Science & Technology Prof. Alexander Pines Glenn T. Seaborg Professor of Chemistry, University of California, Berkeley “Toward Miniaturization of NMR and MRI” When: Seminar at 4pm on February 13 (Monday), 2012 (RECEPTION FOLLOWS AT 5PM) Where: UCSB Bren School Auditorium, Room 1414 Abstract: Contemporary NMR and MRI instruments are big, immobile and expensive. I shall describe recent advances in our laboratory aimed at translating some of the capabilities of NMR and MRI on to a mobile microfluidic chip platform. Components of the converging methodologies include optical pumping and detection, functionalized biosensors, superconducting quantum interference detection, laser atomic magnetometry and remote microfluidic sensing at low magnetic field. Such developments will contribute to the possibility of targeted molecular and lab-on-a-chip NMR and MRI in physics, chemistry and biomedicine. Biography: Alexander Pines is the Glenn T. Seaborg Professor of Chemistry at the University of California, Berkeley, Senior Scientist in the Materials Sciences Division, Lawrence Berkeley National Laboratory (LBNL), and a Faculty Affiliate at the California Institute of Quantitative Biomedical Research. Pines obtained his Ph.D. in chemical physics at M.I.T. in 1972 and joined the Berkeley faculty later that year. Selected awards and honors include the Michael Faraday Medal, The Royal Society; Dickson Prize, Carnegie Mellon University; ACS Irving Langmuir Award; F. A. Cotton Medal for Excellence in Chemical Research; Russell Varian Prize; Wolf Prize in Chemistry; Member, U.S. National Academy of Sciences; Fellow, American Academy of Arts and Sciences; Foreign Member, The Royal Society; Foreign Honorable Member, NMR Society of Japan; Foreign Fellow, National Academy of Sciences, India; Lord Todd Professor, University of Cambridge; Harvard University; past President, International Society of Magnetic Resonance and several Honorary Doctorates. Alexander Pines is a pioneer in the development and applications of NMR spectroscopy. In his early work, he demonstrated time-reversal of dipole-dipole couplings in many-body spin systems, and introduced cross- polarization high resolution NMR of dilute spins, helping to launch the era of modern solid-state NMR in chemistry. He developed the areas of multiple-quantum spectroscopy, double rotation, and dynamic-angle spinning for quadrupolar nuclei. His combination of optical pumping and cross-polarization made it possible to observe enhanced NMR of surfaces and the selective "lighting up" of solution NMR and MRI. .

Copy Link

Recommended publications

New 78 Covers
NATIONAL ACADEMY OF SCIENCES ROBERT SANDERSON MULLIKEN 1896–1986 A Biographical Memoir by R. STEPHEN BERRY Biographical Memoirs, VOLUME 78 PUBLISHED 2000 BY THE NATIONAL ACADEMY PRESS WASHINGTON, D.C. Photo credit: Photo by Harris & Ewing, Washington, D.C. ROBERT SANDERSON MULLIKEN June 7, 1896-October 31, 1986 BY R. STEPHEN BERRY OBERT S. MULLIKEN WAS a quiet, soft-spoken man, yet so R single-minded and determined in his devotion to under- standing molecules that he came to be called “Mr. Molecule.” If any single person’s ideas and teachings dominated the development of our understanding of molecular structure and spectra, it surely was Robert Mulliken. From the begin- ning of his career as an independent scientist in the mid- 1920s until he published his last scientific papers in the early 1980s, he guided an entire field through his penetrat- ing solutions of outstanding puzzles, his identification (or discovery) and analysis of the new major problems ripe for study, and his creation of a school—the Laboratory of Molecular Structure and Spectroscopy or LMSS at the University of Chicago, during its existence the most impor- tant center in the world for the study of molecules. Robert’s background led him naturally into academic sci- ence. He was born in Newburyport, Massachusetts, in a house built by his great-grandfather in about 1798. His father, Samuel Parsons Mulliken, was a professor of chemistry at MIT, which made him a daily commuter between Newburyport and Boston. Samuel Mulliken and his child- hood friend and later MIT colleague Arthur A. Noyes were 3 4 BIOGRAPHICAL MEMOIRS strong influences stirring Robert’s interests in science.
[Show full text]
Curriculum Vitae Daniel M
CURRICULUM VITAE DANIEL M. NEUMARK Personal: Born March 27, 1955; Chicago, Illinois Degrees: Ph.D., Physical Chemistry, University of California, Berkeley 1984 Thesis Advisor: Professor Yuan T. Lee Thesis Title: High Resolution Reactive Scattering M.A., Chemistry, Harvard University, 1977 B.A., Chemistry and Physics, Harvard University, 1977 (with highest honors) Honors and Awards: Peter Debye Award in Physical Chemistry, American Chemical Society, 2019 Bourke Award, Royal Society of Chemistry, 2018 Member, National Academy of Sciences, 2015 Fellow, Royal Society of Chemistry, 2013 Chemical Dynamics Award, Royal Society of Chemistry, 2013 Herbert P. Broida Prize, American Physical Society, 2013 Fellow, American Chemical Society, 2010 Dudley R. Herschbach Medal, 2009 Irving Langmuir Award in Chemical Physics, American Chemical Society, 2008 William F. Meggers Award, Optical Society of America, 2005 Visiting Röentgen Professor, University of Würzburg, 2002 Bomem-Michelson Award, 2002 ACS Nobel Laureate Signature Award, 2001 (with Martin Zanni) Fellow of American Academy of Arts and Sciences, 2000 Miller Research Professorship, UC Berkeley, 1999 - 2000 Alexander von Humboldt Senior Scientist, 1997 Fellow, American Association for the Advancement of Science, 1994 Invited Professor, University of Paris-Sud, Orsay, France, 1993 Fellow, American Physical Society, 1993 Camille and Henry Dreyfus Teacher-Scholar Award, 1991 Alfred P. Sloan Fellowship, 1989 National Science Foundation Presidential Young Investigator Award, 1988 Office of Naval Research
[Show full text]
Here Science-Based Cost- Effective Pathways Forward?
Sponsors Institute of Atomic and Molecular Sciences, Academia Sinica, Taiwan PIRE-ECCI Program, UC Santa Barbara, USA Max-Planck-Gesellschaft, Germany National Science Council, Taiwan Organizing committee Dr. Kuei-Hsien Chen (IAMS, Academia Sinica, Taiwan) Dr. Susannah Scott (University of California - Santa Barbara, USA) Dr. Alec Wodtke (University of Göttingen & Max-Planck-Gesellschaft, Germany) Table of Contents General Information .............................................................................................. 1 Program for Sustainable Energy Workshop ....................................................... 3 I01 Dr. Alec M. Wodtke Beam-surface Scattering as a Probe of Chemical Reaction Dynamics at Interfaces ........................................................................................................... 7 I02 Dr. Kopin Liu Imaging the steric effects in polyatomic reactions ............................................. 9 I03 Dr. Chi-Kung Ni Energy Transfer of Highly Vibrationally Excited Molecules and Supercollisions ................................................................................................. 11 I04 Dr. Eckart Hasselbrink Energy Conversion from Catalytic Reactions to Hot Electrons in Thin Metal Heterostructures ............................................................................................... 13 I05 Dr. Jim Jr-Min Lin ClOOCl and Ozone Hole — A Catalytic Cycle that We Don’t Like ............... 15 I06 Dr. Trevor W. Hayton Nitric Oxide Reduction Mediated by a Nickel Complex
[Show full text]
Pauling-Linus.Pdf
NATIONAL ACADEMY OF SCIENCES L I N U S C A R L P A U L I N G 1901—1994 A Biographical Memoir by J A C K D. D UNITZ Any opinions expressed in this memoir are those of the author(s) and do not necessarily reflect the views of the National Academy of Sciences. Biographical Memoir COPYRIGHT 1997 NATIONAL ACADEMIES PRESS WASHINGTON D.C. LINUS CARL PAULING February 28, 1901–August 19, 1994 BY JACK D. DUNITZ INUS CARL PAULING was born in Portland, Oregon, on LFebruary 28, 1901, and died at his ranch at Big Sur, California, on August 19, 1994. In 1922 he married Ava Helen Miller (died 1981), who bore him four children: Linus Carl, Peter Jeffress, Linda Helen (Kamb), and Edward Crellin. Pauling is widely considered the greatest chemist of this century. Most scientists create a niche for themselves, an area where they feel secure, but Pauling had an enormously wide range of scientific interests: quantum mechanics, crys- tallography, mineralogy, structural chemistry, anesthesia, immunology, medicine, evolution. In all these fields and especially in the border regions between them, he saw where the problems lay, and, backed by his speedy assimilation of the essential facts and by his prodigious memory, he made distinctive and decisive contributions. He is best known, perhaps, for his insights into chemical bonding, for the discovery of the principal elements of protein secondary structure, the alpha-helix and the beta-sheet, and for the first identification of a molecular disease (sickle-cell ane- mia), but there are a multitude of other important contri- This biographical memoir was prepared for publication by both The Royal Society of London and the National Academy of Sciences of the United States of America.
[Show full text]
Alfred O. C. Nier
CHEMICAL HERITAGE FOUNDATION ALFRED O. C. NIER Transcript of Interviews Conducted by Michael A. Grayson and Thomas Krick at University of Minnesota Minneapolis, Minnesota on 7, 8, 9, and 10 April 1989 (With Subsequent Corrections and Additions) ACKNOWLEDGMENT This oral history is one in a series initiated by the Chemical Heritage Foundation on behalf of the American Society for Mass Spectrometry. The series documents the personal perspectives of individuals related to the advancement of mass spectrometric instrumentation, and records the human dimensions of the growth of mass spectrometry in academic, industrial, and governmental laboratories during the twentieth century. This project is made possible through the generous support of the American Society for Mass Spectrometry Upon Alfred O.C. Nier’s death in 1994, this oral history was designated Free Access. Please note: Users citing this interview for purposes of publication are obliged under the terms of the Chemical Heritage Foundation Oral History Program to credit CHF using the format below: Alfred O.C. Nier, interview by Michael A. Grayson and Thomas Krick at the University of Minnesota, Minneapolis, Minnesota, 7-10 April 1989 (Philadelphia: Chemical Heritage Foundation, Oral History Transcript # 0112). Chemical Heritage Foundation Oral History Program 315 Chestnut Street Philadelphia, Pennsylvania 19106 The Chemical Heritage Foundation (CHF) serves the community of the chemical and molecular sciences, and the wider public, by treasuring the past, educating the present, and inspiring the future. CHF maintains a world-class collection of materials that document the history and heritage of the chemical and molecular sciences, technologies, and industries; encourages research in CHF collections; and carries out a program of outreach and interpretation in order to advance an understanding of the role of the chemical and molecular sciences, technologies, and industries in shaping society.
[Show full text]
Robert Mulliken
NATIONAL ACADEMY OF SCIENCES ROBERT SANDERSON MULLIKEN 1896–1986 A Biographical Memoir by R. STEPHEN BERRY Biographical Memoirs, VOLUME 78 PUBLISHED 2000 BY THE NATIONAL ACADEMY PRESS WASHINGTON, D.C. Photo credit: Photo by Harris & Ewing, Washington, D.C. ROBERT SANDERSON MULLIKEN June 7, 1896-October 31, 1986 BY R. STEPHEN BERRY OBERT S. MULLIKEN WAS a quiet, soft-spoken man, yet so R single-minded and determined in his devotion to under- standing molecules that he came to be called “Mr. Molecule.” If any single person’s ideas and teachings dominated the development of our understanding of molecular structure and spectra, it surely was Robert Mulliken. From the begin- ning of his career as an independent scientist in the mid- 1920s until he published his last scientific papers in the early 1980s, he guided an entire field through his penetrat- ing solutions of outstanding puzzles, his identification (or discovery) and analysis of the new major problems ripe for study, and his creation of a school—the Laboratory of Molecular Structure and Spectroscopy or LMSS at the University of Chicago, during its existence the most impor- tant center in the world for the study of molecules. Robert’s background led him naturally into academic sci- ence. He was born in Newburyport, Massachusetts, in a house built by his great-grandfather in about 1798. His father, Samuel Parsons Mulliken, was a professor of chemistry at MIT, which made him a daily commuter between Newburyport and Boston. Samuel Mulliken and his child- hood friend and later MIT colleague Arthur A. Noyes were 3 4 BIOGRAPHICAL MEMOIRS strong influences stirring Robert’s interests in science.
[Show full text]
1 CURRICULUM VITAE RUDOLPH A. MARCUS Personal Information
CURRICULUM VITAE RUDOLPH A. MARCUS Personal Information Date of Birth: July 21, 1923 Place of Birth: Montreal, Canada Married: Laura Hearne (dec. 2003), 1949 (three sons: Alan, Kenneth, and Raymond) Citizenship: U.S.A. (naturalized 1958) Education B.Sc. in Chemistry, McGill University, Montreal, Canada, 1943 Ph.D. in Chemistry, McGill University, 1946 Professional Experience Postdoctoral Research, National Research Council of Canada, Ottawa, Canada, 1946-49 Postdoctoral Research, University of North Carolina, 1949-51 Assistant Professor, Polytechnic Institute of Brooklyn, 1951-54; Associate Professor, 1954-58; Professor, 1958-64; (Acting Head, Division of Physical Chemistry, 1961-62) Member, Courant Institute of Mathematical Sciences, New York University, 1960-61 Professor, University of Illinois, 1964-78 (Head, Division of Physical Chemistry, 1967-68) Visiting Professor of Theoretical Chemistry, IBM, University of Oxford, England, 1975-76 Professorial Fellow, University College, University of Oxford, 1975-76 Arthur Amos Noyes Professor of Chemistry, California Institute of Technology, 1978-2012 Professor (hon.), Fudan University, Shanghai, China, 1994- Professor (hon.), Institute of Chemistry, Chinese Academy of Sciences, Beijing, China, 1995- Fellow (hon.), University College, University of Oxford, 1995- Linnett Visiting Professor of Chemistry, University of Cambridge, 1996 Honorable Visitor, National Science Council, Republic of China, 1999 Professor (hon.), China Ocean University, Qingdao, China, 2002 - Professor (hon.), Tianjin University, Tianjin, China, 2002- Professor (hon.) Dalian Institute of Chemical Physics, Dalian, China, 2005- Professor (hon.) Wenzhou Medical College, Wenzhou, China, 2005- Distinguished Affiliated Professor, Technical University of Munich, 2008- Visiting Nanyang Professor, Nanyang Institute of Technology, Singapore 2009- Chair Professor (hon.) University System of Taiwan, 2011 Distinguished Professor (hon.), Tumkur University, India, 2012 Arthur Amos Noyes Professor of Chemistry, California Institute of Technology, 1978-2013 John G.
[Show full text]
Scientific Economic and Legal Issues* Hawking Auditorium, Mitchell Institute Texas A&M University April 18, 2016
Energy and the Environment: Scientific Economic and Legal Issues* Hawking Auditorium, Mitchell Institute Texas A&M University April 18, 2016 8:00 AM – 8:30 AM Breakfast 8:30 AM – 9:00 AM Welcome and Introductions Marlan Scully, Director, IQSE John Junkins, Director, TIAS David M. Lee, Nobel Laureate in Physics, 1996 9:00 AM – 10:00 AM Carbon Capture, Utilization and Storage: A Multi‐scale Grand Challenge Christodoulos A. Floudas Director, Texas A&M Energy Institute, TAMU 10:00 AM – 10:30 AM Break 10:30 AM – 11:30 AM Climate Change, Energy and a Sustainable Low Cost Path Forward Steven Chu Nobel Laureate in Physics, 1997 Former U.S. Secretary of Energy 11:30 AM – 12:30 PM Energy and the Environment: Concerns for the Future Bruce A. McCarl Nobel Peace Prize, 2007 12:30 PM – 1:30 PM Lunch 1:30 PM – 2:30 PM Science, Policy and Power: The Supreme Court and Climate Change Kenneth W. Starr President and Chancellor, Baylor University 2:30 PM – 3:30 PM Energy Alternatives in the Economy of Texas Michael K. Young President, Texas A&M University 3:30 PM – 4:00 PM Break 4:00 PM – 5:00 PM A Medley of Molecular Parables Dudley Herschbach Nobel Laureate in Chemistry, 1986 Reception and Dinner at the Clayton W. Williams, Jr. Alumni Center 6:30 PM Reception 7:00 PM Dinner *Sponsored by the Texas A&M University Institute for Advanced Study and the Institute for Quantum Science and Engineering Distinguished Speakers Climate Change, Energy and a Sustainable, Low Cost Path Forward The industrial and agricultural revolutions have profoundly transformed the world, but there have been unintended consequences.
[Show full text]
William H. Miller's Curriculum Vitae
Curriculum Vitae WILLIAM HUGHES MILLER Personal: Born: 16 March 1941, Kosciusko, Mississippi, USA Married: Margaret Ann Westbrook, (two daughters, Alison b. 1970, Emily b. 1972) Education and Positions: 1956-59 Provine High School, Jackson, MS, Valedictorian 1959-63 Georgia Institute of Technology, General Motors National Scholarship, B.S. 1963 (Chemistry), Phi Kappa Phi Cup (Valedictorian) 1963-67 Harvard University, National Science Foundation Fellow, A.M. 1964 (Chemistry) Ph.D. 1967 (Chemical Physics), E. Bright Wilson, Jr., Research Director 1967-68 NATO Postdoctoral Fellow, University of Freiburg, Germany 1967-69 Junior Fellow, Society of Fellows, Harvard University 1969-72 Assistant Professor, Department of Chemistry, University of California, Berkeley 1969-present Staff Senior Scientist, Chemical Sciences Division, Lawrence Berkeley National Laboratory 1972-74 Associate Professor, Department of Chemistry, University of California, Berkeley 1974-2010 Professor, Department of Chemistry, University of California, Berkeley 1984-88 Vice-Chairman, Department of Chemistry, University of California, Berkeley 1989-93 Chairman, Department of Chemistry, University of California, Berkeley 1998-2001 Chancellor’s Research Professor, University of California, Berkeley 1999-2012 Kenneth S. Pitzer Distinguished Professor of Chemistry, University of California, Berkeley 2012-present Kenneth S. Pitzer Distinguished Professor Emeritus, and Professor of the Graduate School, University of California, Berkeley 9/13 1 Honors: Alfred P. Sloan Research
[Show full text]
Ústav Fyzikální Chemie Jaroslava Heyrovského
Ústav fyzikální chemie J. Heyrovského, v.v.i. Akademie věd České republiky zve všechny zájemce na ústavní seminář, na kterém promluví profesor Dudley R. Herschbach (Nobelova cena za chemii 1986) Department of Chemistry and Chemical Bilogy Harvard University Cambridge, MA, U.S.A. na téma GLIMPSES OF CHEMICAL WIZARDRY Seminář se koná v pátek 29.června 2012 od 10:30 hodin v Brdičkově posluchárně ústavu v Praze 8, Dolejškova 3. Těšíme se na Vaši účast. Hosté jsou vítáni. Ústav fyzikální chemie J. Heyrovského, v.v.i. Akademie věd České republiky Glimpses of Chemical Wizardry Dudley R. Herschbach Department of Chemistry & Chemical Biology, Harvard In an evangelical spirit, three vignettes will be presented that have the character of molecular parables: stories with lessons that transcend the specific details. (1) How knowledge of the orientation of a methyl group with respect to a neighboring double bond, obtained from thermodynamics and spectroscopy, enabled chemists to synthesize the single biologically active form of a molecule that has 5 x 1021 different structural isomers. (2) The lack of a single methyl group on a particular amino acid among billions in each DNA molecule on the Y chromosome is found to result in an infertile female rather than a male. This mutation is rare, of frequency ~ 10-5. Consider how different human society would be if it were to become dominant! (3) Remarkable feats, such as synthesis of Indigo, a highly prized dye for many centuries, were achieved in the 19th century. Nothing was yet known about atomic structure and experimental tools were very modest; substances could be characterized just by measuring weights, melting and boiling temperatures, observing colors, odors, and tastes.
[Show full text]
Biography of Michael Polanyi
Short Biographies of Philosophizing Chemists Michael Polanyi (1891-1976) by Mary Jo Nye One of the most novel philosophers of sciences in the 20 th century was the physical chemist Michael Polanyi. His first group of philosophical essays ap- peared in 1946 under the title Science, Faith and Society (Oxford University Press, Oxford, 1946), followed by Personal Knowledge: Towards a Post- Critical Philosophy (University of Chicago Press, Chicago, 1958), The Tacit Dimension (Doubleday, New York, 1966), and other volumes. One of his notable philosophical interventions occurred at a conference in Oxford in 1961, where Thomas S. Kuhn summarized his thesis on paradigms, normal science, and scientific revolutions which would be published as The Structure of Scientific Revolutions (University of Chicago Press, Chicago, 1962). Po- lanyi followed up Kuhn’s presentation with the comment that he had been trying to call attention to the very view that Kuhn now was arguing, which is a view undercutting philosophical preoccupation with logical positivism and falsification. Scientists, Polanyi argued, are not heretics driven by skepticism, but rather are steadfastly committed to established beliefs and dogmas within the scientific community. It is the social scientific community, not a rational scientific method, that is the determining condition of scientific knowledge. 1 By way of example, Polanyi published two essays dealing with chemistry and drawing from his own researches in x-ray crystallography, solid-state science, and adsorption of gases on surfaces. 2 Born in Budapest, Polanyi completed a medical degree in 1913 and a Ph.D. in physical chemistry in 1917 at the University of Budapest.
[Show full text]
Two-Dimensional NMR Investigations of the Dynamic Conformations of Phospholipids and Liquid Crystals
LBNL-42162 |BERKELEY LAB] Two-Dimensional NMR Investigations of the Dynamic Conformations of Phospholipids and Liquid Crystals Mei Hong Materials Sciences Division RECEIVE MAR 1 8 1999 May 1996 Ph.D. Thesis OSTS DISCLAIMER This document was prepared as an account of work sponsored by the United States Government. While this document is believed to contain correct information, neither the United States Government nor any agency thereof, nor The Regents of the University of California, nor any of their employees, makes any warranty, express or implied, or assumes any legal responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by its trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof, or The Regents of the University of California. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof, or The Regents of the University of California. Ernest Orlando Lawrence Berkeley National Laboratory is an equal opportunity employer. DISCLAIMER Portions of this document may be illegible in electronic image products. Images are produced from the best available original document. LBNL-42162 Two-Dimensional NMR Investigations of the Dynamic Conformations of Phospholipids and Liquid Crystals Mei Hong Ph.D. Thesis Department of Chemistry University of California, Berkeley and Materials Sciences Division Ernest Orlando Lawrence Berkeley National Laboratory University of California Berkeley, CA 94720 May 1996 This work was supported by the Director, Office of Energy Research, Office of Basic Energy Sciences, Materials Sciences Division, of the U.S.
[Show full text]