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Safety Data Sheet SAFETY DATA SHEET 1. Identification Product identifier Barium Chlorate (Ba(ClO3)2) powder Other means of identification SDS number 2GS Materion Code 2GS CAS number 13477-00-4 Synonyms Chloric acid, barium salt Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Materion Advanced Chemicals Inc. Address 407 N 13th Street 1316 W. St. Paul Avenue Milwaukee, WI 53233 United States Telephone 414.212.0257 E-mail [email protected] Contact person Noreen Atkinson Emergency phone number Chemtrec 800.424.9300 2. Hazard(s) identification Physical hazards Oxidizing solids Category 1 Health hazards Acute toxicity, oral Category 3 Acute toxicity, inhalation Category 3 Serious eye damage/eye irritation Category 2A Specific target organ toxicity, single exposure Category 3 respiratory tract irritation Environmental hazards Hazardous to the aquatic environment, acute Category 2 hazard Hazardous to the aquatic environment, Category 2 long-term hazard OSHA defined hazards Not classified. Label elements Signal word Danger Hazard statement Toxic if swallowed. May cause fire or explosion; strong oxidizer. Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. Toxic if inhaled. May cause damage to organs (respiratory system) through prolonged or repeated exposure. May cause respiratory irritation. May cause damage to organs (). Toxic to aquatic life with long lasting effects. Material name: Barium Chlorate (Ba(ClO3)2) powder SDS US 2GS Version #: 03 Revision date: 01-19-2018 Issue date: 05-17-2015 1 / 9 Precautionary statement Prevention Keep away from heat. Keep away from clothing and other combustible materials. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Avoid breathing dust/fume. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/eye protection/face protection. Wear fire/flame resistant/retardant clothing. Response If swallowed: Immediately call a poison center/doctor. Rinse mouth. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If on clothing: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. Call a poison center/doctor if you feel unwell. Specific treatment (see this label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. In case of fire: Use appropriate media to extinguish. In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. Collect spillage. Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise None known. classified (HNOC) Supplemental information 100% of the mixture consists of component(s) of unknown acute dermal toxicity. For further information, please contact the Product Stewardship Department at +1.800.862.4118. 3. Composition/information on ingredients Substances Chemical name Common name and synonyms CAS number % barium chlorate Chloric acid, barium salt 13477-00-4 100 *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Call a POISON CENTER or doctor/physician. Skin contact IF ON CLOTHING: rinse immediately contaminated clothing and skin with plenty of water before removing clothes. Wash off with soap and water. If skin irritation occurs: Get medical advice/attention. Eye contact Do not rub eyes. Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting without advice from poison control center. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Most important Narcosis. Behavioral changes. Decrease in motor functions. Severe eye irritation. Symptoms may symptoms/effects, acute and include stinging, tearing, redness, swelling, and blurred vision. Dusts may irritate the respiratory delayed tract, skin and eyes. Proteinuria. Edema. Prolonged exposure may cause chronic effects. Indication of immediate medical Provide general supportive measures and treat symptomatically. In case of shortness of breath, attention and special treatment give oxygen. Keep victim warm. Keep victim under observation. Symptoms may be delayed. needed General information Take off all contaminated clothing immediately. Contact with combustible material may cause fire. In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Wash contaminated clothing before reuse. Material name: Barium Chlorate (Ba(ClO3)2) powder SDS US 2GS Version #: 03 Revision date: 01-19-2018 Issue date: 05-17-2015 2 / 9 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media None known. Specific hazards arising from Strong oxidizer - contact with other material may cause fire. May cause fire or explosion; strong the chemical oxidizer. Greatly increases the burning rate of combustible materials. Containers may explode when heated. During fire, gases hazardous to health may be formed. Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire fighting In case of fire and/or explosion do not breathe fumes. In case of fire: Evacuate area. Fight fire equipment/instructions remotely due to the risk of explosion. Move containers from fire area if you can do so without risk. Use water spray to cool unopened containers. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out. Water runoff can cause environmental damage. General fire hazards May cause fire or explosion; strong oxidizer. Contact with combustible material may cause fire. 6. Accidental release measures Personal precautions, protective Immediately evacuate personnel to safe areas. Keep unnecessary personnel away. Keep people equipment and emergency away from and upwind of spill/leak. Keep away from clothing and other combustible materials. procedures Wear appropriate personal protective equipment. Avoid inhalation of dust. Use a NIOSH/MSHA approved respirator if there is a risk of exposure to dust/fume at levels exceeding the exposure limits. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep containment and cleaning up combustibles (wood, paper, oil, etc.) away from spilled material. Ventilate the contaminated area. Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air). Minimize dust generation and accumulation. Collect dust using a vacuum cleaner equipped with HEPA filter. Wear appropriate protective equipment and clothing during clean-up. Prevent entry into waterways, sewer, basements or confined areas. Stop the flow of material, if this is without risk. Large Spills: Wet down with water and dike for later disposal. Absorb in vermiculite, dry sand or earth and place into containers. Shovel the material into waste container. Following product recovery, flush area with water. Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal. Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Inform appropriate managerial or supervisory personnel of all environmental releases. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. 7. Handling and storage Precautions for safe handling Minimize dust generation and accumulation. Routine housekeeping should be instituted to ensure that dusts do not accumulate on surfaces. Keep away from heat. Take any precaution to avoid mixing
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