Humphry Davy, Poet and Philosopher
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The Early History of Catalysis
The Early History of Catalysis By Professor A. J. B. Robertson Department of Chemistry, King’s College, London One hundred and forty years ago it was Berzelius proceeded to propose the exist- possible for one man to prepare an annual ence of a new force which he called the report on the progress of the whole of “catalytic force” and he called “catalysis” the chemistry, and for many years this task was decomposition of bodies by this force. This undertaken by the noted Swedish chemist is probably the first recognition of catalysis J. J. Berzelius for the Stockholm Academy of as a wide-ranging natural phenomenon. Sciences. In his report submitted in 1835 and Metallic catalysts had in fact been used in published in 1836 Berzelius reviewed a num- the laboratory before 1800 by Joseph Priestley, ber of earlier findings on chemical change in the discoverer of oxygen, and by the Dutch both homogeneous and heterogeneous sys- chemist Martinus van Marum, both of whom tems, and showed that these findings could be made observations on the dehydrogenation of rationally co-ordinated by the introduction alcohol on metal catalysts. However, it seems of the concept of catalysis. In a short paper likely that these investigators regarded the summarising his ideas on catalysis as a new metal merely as a source of heat. In 1813, force, he wrote (I): Louis Jacques Thenard discovered that ammonia is decomposed into nitrogen and “It is, then, proved that several simple or compound bodies, soluble and insoluble, have hydrogen when passed over various red-hot the property of exercising on other bodies an metals, and ten years later, with Pierre action very different from chemical affinity. -
Orme) Wilberforce (Albert) Raymond Blackburn (Alexander Bell
Copyrights sought (Albert) Basil (Orme) Wilberforce (Albert) Raymond Blackburn (Alexander Bell) Filson Young (Alexander) Forbes Hendry (Alexander) Frederick Whyte (Alfred Hubert) Roy Fedden (Alfred) Alistair Cooke (Alfred) Guy Garrod (Alfred) James Hawkey (Archibald) Berkeley Milne (Archibald) David Stirling (Archibald) Havergal Downes-Shaw (Arthur) Berriedale Keith (Arthur) Beverley Baxter (Arthur) Cecil Tyrrell Beck (Arthur) Clive Morrison-Bell (Arthur) Hugh (Elsdale) Molson (Arthur) Mervyn Stockwood (Arthur) Paul Boissier, Harrow Heraldry Committee & Harrow School (Arthur) Trevor Dawson (Arwyn) Lynn Ungoed-Thomas (Basil Arthur) John Peto (Basil) Kingsley Martin (Basil) Kingsley Martin (Basil) Kingsley Martin & New Statesman (Borlasse Elward) Wyndham Childs (Cecil Frederick) Nevil Macready (Cecil George) Graham Hayman (Charles Edward) Howard Vincent (Charles Henry) Collins Baker (Charles) Alexander Harris (Charles) Cyril Clarke (Charles) Edgar Wood (Charles) Edward Troup (Charles) Frederick (Howard) Gough (Charles) Michael Duff (Charles) Philip Fothergill (Charles) Philip Fothergill, Liberal National Organisation, N-E Warwickshire Liberal Association & Rt Hon Charles Albert McCurdy (Charles) Vernon (Oldfield) Bartlett (Charles) Vernon (Oldfield) Bartlett & World Review of Reviews (Claude) Nigel (Byam) Davies (Claude) Nigel (Byam) Davies (Colin) Mark Patrick (Crwfurd) Wilfrid Griffin Eady (Cyril) Berkeley Ormerod (Cyril) Desmond Keeling (Cyril) George Toogood (Cyril) Kenneth Bird (David) Euan Wallace (Davies) Evan Bedford (Denis Duncan) -
1 Evolution of Catalysts Design and Synthesis
3 1 Evolution of Catalysts Design and Synthesis: From Bulk Metal Catalysts to Fine Wires and Gauzes, and that to Nanoparticle Deposits, Metal Clusters, and Single Atoms Wey Yang Teoh 1,2 1University of Malaya, Centre for Separation Science and Technology, Department of Chemical Engineering, 50603 Kuala Lumpur, Malaysia 2The University of New South Wales, School of Chemical Engineering, Sydney 2052, Australia 1.1 The Cradle of Modern Heterogeneous Catalysts The modern discovery of heterogeneous catalysts stretches as far back as 1800 when Joseph Priestley and Martinus van Marum reported the dehydrogenation of alcohol over a heated metal catalyst, although not too much was thought about the role of the metal catalyst at that time except as a heating source. Then in 1813, Louis Jacques Thénard of École Polytechnique in Paris discovered the decomposi- tion of ammonia to nitrogen and hydrogen over “red-hot metals” and recognized that the phenomenon was due to some catalytic reaction [1, 2]. The concept was followed up by Humphry Davy and Michael Faraday at the Royal Institution of London who, in 1817, reported the flameless catalytic combustion of coal gas and air over heated platinum wire producing bright white ignition. Their results were reproducible when using palladium, but not on copper, silver, iron, gold, and zinc [1, 3]. These experiments made clear that there was some form of cat- alytic role associated with the different metals. The discovery soon became the basisfortheinventionofthecoalminesafetylamp,alsoknownastheDavy lamp – although mysteriously but rather practically, the use of inefficient steel iron rather than platinum gauze became the standard for Davy lamps. -
Liebig Buys Platinum from Janety the Younger U by W
Liebig Buys Platinum from Janety the Younger U By W. H. Brock Department of Astronomy and History of Science, University of Leicester In his standard work A History of Platinum, melt as a platinum-arsenic eutectic at an Donald McDonald has described the improve- attainable temperature of 597°C. By skilful ments made to the arsenic process for the control of the temperature, the unwanted purification and conferment of malleability arsenic was volatilised as arsenious oxidc, on platinum by Marc Etienne Janety, or leaving behind a pure button of malleable Jeanety (c.1750--1820) (I). The Swedish metal- platinum. lurgist Heinrich Scheffer had shown in 1751 Janety, a French royal goldsmith, is that heated platinum melts in the presence of probably best known for his preparation of arsenic. By the 1780s the preparation of an the metric standards of weight and length arsenic-platinum mixture had been developed in 1795; however, more important for the into a commercial process for working development of practical and quantitative platinum by French goldsmiths and jewellers. chemistry was the way in which the tech- In their arsenic process, the iron impurities niques he developed enabled his firm to present in South American native platinum supply the growing demand from European were oxidised with “white arsenic” (arsenious chemists for platinum crucibles and other acid), which also induced the platinum to apparatus. The chemist and encyclopaedist Justus von Liebig 1803 - 1873 The centenary of his death recalls the great part played by Liebig when, as Professor at Giessen, he established one of thefLrst laboratories in Europe devoted to experimental instruction in chemistry - a laboratory later to become famous as “a factory for the production of professors”. -
By Conduct and Courage by G
The Project Gutenberg EBook of By Conduct and Courage by G. A. Henty This eBook is for the use of anyone anywhere at no cost and with almost no restrictions whatsoever. You may copy it, give it away or re-use it under the terms of the Project Gutenberg License included with this eBook or online at http://www.gutenberg.org/license Title: By Conduct and Courage Author: G. A. Henty Release Date: March 19, 2009 [Ebook 28357] Language: English ***START OF THE PROJECT GUTENBERG EBOOK BY CONDUCT AND COURAGE*** BY CONDUCT AND COURAGE MR. HENTY’S HISTORICAL TALES. THE CAT OF BUBASTES: A Story of Ancient Egypt. 5s. THE YOUNG CARTHAGINIAN: A Story of the Times of Hanni- bal. 6s. FOR THE TEMPLE: A Tale of the Fall of Jerusalem. 6s. BERIC THE BRITON: A Story of the Roman Invasion. 6s. THE DRAGON AND THE RAVEN: or, The Days of King Alfred. 5s. WULF THE SAXON: A Story of the Norman Conquest. 6s. AKNIGHT OF THE WHITE CROSS: The Siege of Rhodes. 6s. IN FREEDOM’S CAUSE: A Story of Wallace and Bruce. 6s. THE LION OF ST.MARK: A Story of Venice in the 14th Century. 6s. ST.GEORGE FOR ENGLAND: A Tale of Cressy and Poitiers. 5s. AMARCH ON LONDON: A Story of Wat Tyler. 5s. BOTH SIDES THE BORDER: A Tale of Hotspur and Glendower. 6s. AT AGINCOURT: A Tale of the White Hoods of Paris. 6s. BY RIGHT OF CONQUEST: or, With Cortez in Mexico. 6s. ST.BARTHOLOMEW’S EVE: A Tale of the Huguenot Wars. -
Essays in Liberalism
Cornell University Library The original of this book is in the Cornell University Library. There are no known copyright restrictions in the United States on the use of the text. http://www.archive.org/details/cu31924095791095 CORNELL UNIVERSITY LIBRARY 1924 095 791 095 In compliance with current copyright law, Cornell University Library produced this replacement volume on paper that meets the ANSI Standard Z39.48-1992 to replace the irreparably deteriorated original. 2002 Q{0rn0U HnioEraitg Ilibrarg Stljaca. New ^ark BOUGHT WITH THE INCOME OF THE SAGE ENDOWMENT FUND THE GIFT OF HENRY W. SAGE 1891 ESSAYS IN LIBERALISM : ESSAYS IN LIBERALISM BY SIX OXFORD MEN This is true Liberty, wlien freeborn men, Having to advise the public, may speak free Which he who can and will deserves high praise : Who neither can 'nor will may hold his peace. What can be juster in a state than this ? Milton^ after Euripides CASSELL AND COMPANY, Limited LONDON, PARIS & MELBOURNE 1897 ALL RIGHTS RESEKVED Vv TO JOHN MORLEY PREFACE. In these days, when books multiply and men decay, it becomes more than ever the duty of editors to provide some apology for the appearance of a new volume. Since, however, the vogue of the historical school and of popular science makes explanation consist in a r^sum^ of the origin rather than a defence of the end, our task is considerably lightened. The writers of these Essays were drawn together in the political debates and the contested elections of the Oxford Union Society. To that society, and to the stimulating discussions of the Palmerston and Russell Clubs, we owe a common debt of gratitude. -
No Surrender! : a Tale of the Rising in La Vende
HOME. 349 services, but I insisted on his receiving a couple of hundred francs in assignats for the use of his poorer patients. The skipper carried out his instructions to the letter. We got to Honfleur after dark on the day after starting, and he went with me to the cottage of a widow of his acquaintance. "He said to her, 'Mother, I want you to take care of this young sailor; he has broken his arm and wants nursing. He does not want his being here to be known, because he is afraid he might be packed off in one of the ships of war as soon as he recovers. I suppose you can manage that?' "'Oh, yes!' she said; 'I have very few visitors, and no one would guess that I have anyone upstairs.' "'He has plenty of money to pay your charges. Now I will leave him with you, and will look in to-morrow to see how he is getting on.' " I stayed there a fortnight, by which time the inflam mation had pretty well subsided. No one could be kinder than the old woman was. She used to bathe my arm by the hour, and she fed me up with broth. At the end of that time I felt ready for work, though my arm was of course useless. So, having paid my account, I went down boldly to the river and crossed to Harfleur, and then went on to Havre. I stayed there for a couple of days at a sailors' cabaret, where they supposed that I belonged to a vessel in port, and no questions were asked. -
The First Organometallic Compounds WILLIAM CHRISTOPHER ZEISE and HIS PLATINUM COMPLEXES by L
The First Organometallic Compounds WILLIAM CHRISTOPHER ZEISE AND HIS PLATINUM COMPLEXES By L. B. Hunt The Johnson Matthey Group The great interest being taken in the organometallic compounds 0.f thr platinum metals is evident in the current literature, in the .first Inter- national Conference on the Chemistry of the Platinum Group Metals held in Bristol in 1981, and now by the second conference to take placp in Edinburgh in July. This article reviews the preparation o,f the .first such compounds over a hundred and ,ffty years ago and thr acrimonious debate that ensued over their true constitution, continuing with a brief account of the early development o,f a ,further rangr o,f platinum complexes that have come to play an important part in industrial chemistry. During the last thirty years there has the son of the local pharmacist. After leaving developed a concentration of interest upon the school Zeise was himself apprenticed for a time preparation, structure and properties of a wide to Gottfried Becker, Royal Court pharmacist in range of organometallic compounds of the Copenhagen who combined this activity with platinum group of metals, much of this directed lecturing on chemistry at the university there, towards their usefulness in the catalytic syn- but poor health shortly caused him to return to thesis of a number of commercially valuable the family business in Slagelse. Here he con- chemical products. The most familiar industrial tinued to study chemistry and to absorb the examples of this type of reaction include, of new concepts put forward by Lavoisier, while in course, the carbonylation of methanol to acetic 1806 he was able to return to Copenhagen acid, the conversion of ethylene to acetaldehyde where he was taken into the family of Hans and the hydroformylation of olefins to Christian Oersted (1777-185 I) who had aldehydes, while other such large scale applica- recently been appointed extraordinary professor tions will undoubtedly be developed in the near of physics and chemistry in the university. -
Edmund Davy Jaime Wisniak1
Edmund Davy Jaime Wisniak1 Recepción: 2020-02-10. Aceptación: 2020-05-12. Reflexiones Abstract Keywords Edmund Davy (1785-1857) was a British scientist to whom we owe the discovery of acetylene (by accident), potassium carbide, the platinum sponge, the synthesis of a variety acetylene, arsenic, platinum of new platinum compounds, and an electrochemical procedure for determining small and derivatives, potassium amounts of platinum. He carried an extensive research on platinum and its derivatives; in carbide. particular, he studied the reaction of platinum with hydrogen sulfide, oxygen, chlorine, and phosphine, the preparation and properties of simple salts of platinum such as platinum sulfate, and the triple salts of platinum with potassium, sodium, ammonium, aluminum, and barium. Davy also studied the preparation and properties of the fulminates of platinum and silver, and developed a new electrochemical analytical procedure for detecting the presence of arsenic(II) and arsenic(III) oxides. Resumen Palabras clave Edmund Davy (1785-1857), un científico inglés a quien le debemos el descubrimiento acetileno, arsénico, carburo de del acetileno (por accidente), el carburo de potasio, la esponja de platino, la síntesis de potasio, platino y derivados. nuevos compuestos del platino, y un método electroquímico para detectar cantidades mínimas de arsénico. Estudio extensamente el platino y sus derivados, en particular, su reacción con el ácido sulfhídrico, oxígeno, cloro y la fosfina, la preparación y propiedades de sales simples como el sulfato de platino, y las sales triples del platino con potasio, sodio, amoníaco, aluminio y bario. Davy también estudió la preparación y propiedades de los fulminatos de platino y plata y desarrolló un nuevo proceso de análisis electroquímico para detectar la presencia de los óxidos de arsénico(II) y arsénico(III). -
Davy and Alkalies
Redis co very of the Elements Sir Humph ry Davy and the Alkalis I I I James L. Marshall, Beta Eta 1971 , and Virginia R. Marshall, Beta Eta 2003 , Department of Chemistry, University of North Texas, Denton, TX 76203-5070, [email protected] In a previous HEXAGON article on Joseph Black, 1h the three alkalis known in the 1700s were listed: “vegetable alkali” (potash), “mineral alkali” (soda), and “volatile alkali” (ammonia). 1h Figure 1. Royal Institution, 21 Albemarle St. (N51° 30.58 W00° 08.55), was founded in 1799 and has not All were known to react vigorously with acids changed its location since. The Institution was founded by Sir Benjamin Thompson, Count Rumford and “to change the color of syrup of violets to (1753 –1814), an American born British scientist who through observing the boring of cannons realized green.” Ammonia was apparently a compound heat was created by friction. 10,11a of nitrogen and hydrogen ,2d as shown by His colorful history included his 1804 Claude Louis Berthollet (174 8–1822) at his marriage to Marie-Anne Lavoisier, the famous laboratory at Arcueil. 1c It was natural, widow of the famous Antoine Lavoisier. 11a therefore, that Antoine-Laurent Lavoisier (1743 –1794) himself, the “father of modern Figure 2. Royal Institution, appearance in chemistry,” 1b who first recognized the true ele - 1838 (painting by Thomas H. Shepherd, ments and listed 31 that are now found in the 179 3–1864). At this time Michael Periodic Table, 3 would exclude the “fixed alka - Faraday was prominent among its scien - lis” —potash and sod a—from his list, 3 because tists, having succeeded Humphry Davy, they might be compounds of nitrogen as well. -
Short Title Listing of the Pollard Collection of Children’S Books
Short-title listing of the Pollard Collection of children’s books. Letter C Short title listing of the Pollard Collection of children’s books C The cabin by the wayside: a tale for the young By Lady Campbell London: George Routledge & Co., 1854 Box 222 Le cabinet des fées ou Collection choisie des contes des fées, et autres contes merveilleux, ornés de figures. Vol. I Geneva: Barde, Manget & Co., 1785 Box 1552 Le cabinet des fées, ou Collection choisie des contes des fées, et autres contes merveilleux, ornés de figures. Vol. II Geneva: Barde, Manget & Co., 1785 Box 1554 Le cabinet des fées, ou Collection choisie des contes des fées, et autres contes merveilleux, ornés de figures. Vol. III Geneva: Barde, Manget & Co., 1785 Box 1553 Le cabinet des fées, ou Collection choisie des contes des fées, et autres contes merveilleux, ornés de figures. Vol. IV Geneva: Barde, Manget & Co., 1785 Box 1553 Le cabinet des fées, ou Collection choisie des contes des fées, et autres contes merveilleux, ornés de figures. Vol. V Geneva: Barde, Manget & Co., 1785 Box 1554 Le cabinet des fées, ou Collection choisie des contes des fées, et autres contes merveilleux, ornés de figures. Vol. 6 Geneva: Barde, Manget & Co., 1785 Box 1554 Le cabinet des fées, ou Collection choisie des contes des fées, et autres contes merveilleux, ornés de figures. Vol. VII Geneva: Barde, Manget & Co., 1785 Box 1555 Page 1 of 112 Short-title listing of the Pollard Collection of children’s books. Letter C Le cabinet des fées, ou Collection choisie des contes des fées, et autres contes merveilleux, ornés de figures. -
List, Ye Landsmen! : a Romance of Incident
ngn ^-^=^m*^m,m a Digitized by the Internet Archive in 2010 with funding from University of Illinois Urbana-Champaign http://www.archive.org/details/listyelandsmenro01russ LIST, YE LANDSMEN! LIST, YE LANDSMEN! H "Romance of 3ncibent. W. CLARK RUSSELL, AUTHOR OF " THE WRECK OF THE ' GROSYENOR,' " " AN OCEAN TRAGEDY, "THE FROZEN PIRATE," ETC. ETC. In Cf)m Volumtz. Vol. I. CASSELL & COMPANY, Limited LONDON, PARIS # MELBOURNE. 1893. [all rights ehserved.] 3Z3 7^9/ X /6£>3 CONTENTS CHAPTEE I. TAGR I Arrive in the Downs 1 CHAPTER II. I Visit my Uncle at Deal 17 CHAPTER III. *p The Gibbet 33 CHAPTER IV. I Escape from the Press 50 CHAPTER V. Capiain Michael Greaves of the Black Watch . 64 CHAPTER VI. I View the Brig 81 CHAPTL-.R VII. - A Strange Story 98 4> LIST, YE LANDSMEN! CHAPTER VIII. PASS A Startling Proposal 116 CHAPTER IX. I Fight Van Laar 132 CHAPTER X. We Tranship Van Laar 152 CHAPTER XI. The Rebecca 176 CHAPTER XII. The Round Piobin 205 CHAPTER XIII. A Midnight Scare .... ... 228 ! LIST, YE LAXDSMEX CHAPTER I. I ARRIVE IN THE DOWNS. Sailors visit many fine countries ; but there is none —not the very finest—that delights them more than the coast of their own native land when they sight it after a long voyage. The flattest piece of treeless English shore — such a melancholy, sandy, muddy waste, say, as that which the River Stour winds greasily and slimily through past Sandwich, into the salt, green, sparkling waters of the Small Downs-—the English sailor will look at with a thirstier and sharper pleasure than ever could be excited in him by the most majestic and splendid scenery abroad.