Form-I Paras Polymer-BY Chetan

FORM-I

for

PROPOSED SYNTHETIC ORGANIC CHEMICALS MANUFACTURING UNIT

M/s. PARAS PHARMA CHEM

PLOT NO. C-235, G.I.D.C. INDUSTRIAL ESTATE, SAYKHA, TAL: VAGRA, DIST: BHARUCH-392140, GUJARAT

APPENDIX I FORM 1 (I) Basic Information Sr. Item Det ails No. 1. Name of the Project/s Paras Pharma Chem 2. S.No. in the Schedule 5 (f) 3. Proposed capacity/area/length/tonna ge Please refer Annexure -1. to be handled/command area/lease area/number of wells to be drilled 4. New/Expansion/Modernization Ne w 5. Existing capacity/area etc. N.A. 6. Category of project i.e. ‘A’ or ‘B’ ‘B’ 7. Does it attract the general condition? If N.A. yes, please specify. 8. Does it attract the specific condition? If N.A. yes, please specify. 9. Location Plot No. C-235 , Saykha Industrial Estate , Tal: Vagra, Di st : Bharuch-392140, Gujarat Plot/Survey/Khasra No. Plot. No. C-235 , Village GIDC Saykha Tehsil Vagra District Bharuch State Gujarat 10 . Nearest railway station/airport along Nearest R ailway Station : Bh aruch : 30 kms with distance in kms. Nearest Airport: Baroda: 90 kms 11. Nearest Town, city, District Headquarters Nearest town: Bharuch : 30 kms, Nearest District Head along with distance in km quarter: Bharuch : 30 kms 12. Village Panchayats, zilla parisha d, Village: Saykha , Tal: Vagra, Di st : Bharuch -391340 , Municipal corporation, Local body Gujarat.

13. Name of the applicant Paras Pharma Chem 14. Registered address Plot No. C-235 , Saykha Industrial Estate , Tal: Vagra, Dist: Bharuch-392140, Gujarat. 15 . Address for correspondence: Name Mr.Paras Ram Choudhary Designation (Owner/Partner/CEO) Partner Address M/s. Paras Pharma Chem Plot No. 10,11,12 Industrial Estate,Pali Marwar. Pin Code 306401 E-Mail [email protected] [email protected]

Telephone No. Tel.: 02932-280806 Mob.: 9414120806 Fax No. -- 16. Details of Alternative Sites examined, if No any location of these sites should be shown on a topo sheet. 17. Interlinked Projects No 18. Whether separate application of Not applicable interlinked project has been submitted? 19. If Yes, date of submission Not applicable 20. If no., reason Not applicable 21. Whether the proposal involves Not applicable, as the project is located in notified approval/clearance under: If yes, details industrial estate. of the same and their status to be given. (a) The Forest (Conservation) Act, 1980? (b) The Wildlife (Protection) Act, 1972? 22. Whether there i s any Government No order/policy relevant/relating to the site? 23. Forest land involved (hectares) No 24. Whether there is any litigation pending No against the project and/or land in which the project is propose to be set up? (a) Name of the Court (b) Case No. (c) Orders/directions of the Court, if any and its relevance with the project.

(II) Activity 1. Construction, operation or decommissioning of the Project involving actions, which will cause physical changes in the locality (topography, land use, changes in water bodies, etc.)

Sr. Information/Checklist confirmation Yes Details thereof (with approximate No. /No? quantities / rates, wherever possible) with source of information data 1.1 Permanent or temporary change in land No Proposed Project is within Saykha GIDC use, land cover or topography including Estate increase in intensity of land use (with respect to local land use plan) 1.2 Clearance of existing land, vegetation Yes Minor site clearance activities shall be and buildings? carried out to clear shrubs and weed. 1.3 Creation of new land uses? No -- 1.4 Pre-construction investigations e.g. bore No -- houses, soil testing? 1.5 Construction works? Yes Plant layout is attached as Annexure: 1. 1.6 Demolition works? No -- 1.7 Temporary sites used for construction No -- workers or housing of construction workers? 1.8 Above ground buildings, structures or Yes Plant layout is attached as Annexure: 1. Earthworks including linear structures, cut and fill or excavations 1.9 Underground works including mining or No -- tunneling? 1.10 Reclamation works? No -- 1.11 Dredging? No -- 1.12 Offshore structures? No -- 1.13 Production and manufacturing Yes List of Products is attached Annexure: 2 and manufacturing process attached as Annexure: 3. 1.14 Facilities for storage of goods or Yes Dedicated storage area for storage of materials? Raw Materials and finished products, solvents, etc. shall be provided. 1.15 Facilities for treatment or disposal of Yes Effluent Treatment Plant will be solid waste or liquid effluents? installed to treat effluent so as to achieve the GPCB norms. Details of water consumption & effluent generation with segregation of effluent streams are attached as Annexure: 4. Details of proposed Effluent Treatment

Plant IS attached as Annexure: 5. Details of Solid Hazardous waste generation and disposal is attached as Annexure: 6. 1.16 Facilities for long term housing of No -- operational workers? 1.17 New road, rail or sea traffic during No -- construction or operation? 1.18 New road, rail, air waterborne or other No -- airports etc? 1.19 Closure or diversion of existing No -- transport routes or infrastructure leading to changes in traffic movements? 1.20 New or diverted transmission lines or No -- pipelines? 1.21 Impoundment, damming, converting, No -- realignment or other changes to the hydrology of watercourses or aquifers? 1.22 Stream crossings? No -- 1.23 Abstraction or transfers or the water Yes No ground water shall be used. The form ground or surface waters? requirement of raw water shall be met through GIDC Water Supply. 1.24 Changes in water bodies or the land No -- surface affecting drainage or run-off? 1.25 Transport of personnel or materials for Yes Through hired Services construction, operation or decommissioning? 1.26 Long-term dismantling or No There is no dismantling of any sort. Not decommissioning or restoration works? applicable. 1.27 Ongoing activity during No No Impact on the Environment decommissioning which could have an impact on the environment? 1.28 Influx of people to an area in either Yes This is a well developed Industrial Area temporarily or permanently? and due to project, 50 people shall be employed for operation. 1.29 Introduction of alien species? No 1.30 Loss of native species of genetic No diversity? 1.31 Any other actions? No

(III) Use of Natural resources for construction or operation of the Project (such as land, water, materials or energy, especially any resources which are non-renewable or in short supply): Sr. Information/checklist confirmation Yes/ Details there of (with approximate No No? quantities/rates, wherever possible) with source of information data 2.1 Land especially undeveloped or No

agriculture land (ha) 2.2 Water (expected source & competing Yes Water requirement will be met through users) unit: KLD the GIDC Water Supply. For detail water balance is refer as Annexure – 3. 2.3 Minerals (MT) No Not applicable 2.4 Construction material –stone, Yes Company shall use Sand, stone, Cement aggregates, sand / soil (expected and Structural Steel for Construction as source MT) required. 2.5 Forests and timber (source – MT) No No wood shall be used as construction material or as a fuel. 2.6 Energy including electricity and fuels Yes Power required from DGVCL is 125 KVA. source, competing users Unit: fuel Stand by power supply from (MT), energy (MW) D.G. set – Proposed: 125 KVA & 65 KVA

FUEL: Solid Fuel-White Coal, Fire Wood=1 MT/Day Briquettes of Bio-Coal=10 MT/Day Coal=7 MT/Day Fuel for DG set- HSD: 450 Lit/Day

Any other natural resources (use No 2.7 -- appropriates standard units)

3. Use, storage, transport, handling or production of substances or materials, which could be harmful to human health or the environment or raise concerns about actual or perceived risks to human health.

Sr. Information / Checklist confirmation Yes/ Details thereof (with approximate No. No? quantities / rates wherever possible) with source of information data 3.1 Use of substances or materials, which Yes Please refer Annexure : 8. are hazardous (as per MSIHC rules) to human health or the environment (flora, fauna, and water supplies)

3.2 Changes in occurrence of disease or No Not applicable as site is located in Saykha affect disease vectors (e.g. insect or Industrial Area, Saykha. water borne diseases) 3.3 Affect the welfare of people e.g. by No Not applicable as site is located in Saykha changing living conditions? Industrial Area, Saykha. 3.4 Vulnerable groups of people who could No Not applicable as site is located in Saykha be affected by the project e.g. hospital Industrial Area, Saykha. patients, children, the elderly etc., 3.5 Any other causes No

(IV) Production of solid wastes during construction or operation or decommissioning MT/month)

Sr. Information/Checklist confirmation Yes/ Details thereof (with approximate No. No? quantities / rates, wherever possible) with source of information data 4.1 Spoil, overburden or mine wastes No -- 4.2 Municipal waste (domestic and or No -- commercial wastes) 4.3 Hazardous wastes (as per Hazardous Yes Please refer Annexure: 6 Waste Management Rules) 4.4 Other industrial process wastes Yes Please refer Annexure: 6 4.5 Surplus product No -- 4.6 Sewage sludge or other sludge from Yes Please refer Annexure: 6 effluent treatment 4.7 Construction or demolition wastes No Construction waste shall be utilized for leveling, land filling in the premises. 4.8 Redundant machinery or equipment No -- 4.9 Contaminated soils or other materials No -- 4.10 Agricultural wastes No -- 4.11 Other solid wastes No --

(V) Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr)

Sr. Information/Checklist confirmation Yes/ Details thereof (with approximate No. No? quantities/rates, wherever possible) with source of information data 5.1 Emissions from combustion of fossil Yes Details of flue & process gas emission fuels From stationary or mobile sources are attached as Annexure: 7 5.2 Emissions from production processes Yes Details of emission levels from process are attached as Annexure: 7 Details of Air Pollution Control

measures are attached as Annexure: 7 5.3 Emissions from materials handling Yes All liquid raw materials shall be including storage or transport procured in bulk tankers and shall be transferred through a closed circuit pipe lines by pumps. Solid raw material shall be handled in closed charging rooms with proper ventilation and charged through close pipeline into reactors. 5.4 Emissions from construction activities No Utmost care will be taken during including plant and equipment construction activity and water sprinklers shall be utilized whenever necessary. 5.5 Dust or odours from handling of No All the waste shall be stored in materials including construction designated places and shall be materials, sewage and waste transported to TSDF or Incineration Site in their own approved closed vehicles. 5.6 Emissions from incineration of waste No 5.7 Emissions from burning of waste in No open air (e.g. slash materials, construction debris) 5.8 Emissions from any other sources No

6. Generation of Noise and Vibration, and Emissions of Light and Heat:

Sr. Information/Checklist confirmation Yes/ Details there of (with approximate No. No? Quantities /rates, wherever possible) With source of source of information data 6.1 From operation of equipment e.g. Yes There are few activities due to which engines, ventilation plant, crushers noise would be generated. The equipments resulting in noise generation are machinery of plant and Diesel generator. Adequate noise control measures will be provided whenever required. Proper and timely oiling, lubrication and preventive maintenance will be carried out for the machineries & equipments to reduce noise generation. Use of PPE like ear plugs and ear muffs will be made compulsory near the high

noise generating machines. Noise monitoring shall be done regularly in plant area. The D.G. Set will be installed in a closed room and provided with acoustic enclosure. The unit will carry out plantation in the proposed greenbelt within the premises which will prevent the noise pollution in surrounding area. 6.2 From industrial or similar processes Yes All machinery / equipment shall be well maintained, shall be proper foundation with anti vibrating pads wherever applicable and noise levels within permissible limits. Acoustic enclosures shall be provided for DG set. 6.3 From construction or demolition No 6.4 From blasting or piling No 6.5 From construction or operational traffic No 6.6 From lighting or cooling systems No Acoustic enclosures shall be provided for 6.7 From any other sources Yes DG set.

7. Risks of contamination of land or water from releases of pollutants into the ground or into sewers, surface waters, groundwater, coastal waters or the sea:

Sr. Information/Checklist confirmation Yes/ Details thereof (with approximate No No? quantities / rates, wherever possible) with source of information data 7.1 From handling, storage, use or spillage Yes All the raw material shall be stored of hazardous materials separately in designated storage area and safely. Bund walls shall be provided around raw materials storage tanks for containing any liquid spillage. Other materials shall be stored in bags / drums on pallets with concrete flooring and no spillage is likely to occur. Please refer Annexure : 8. 7.2 From discharge of sewage or other No Sewage effluent shall be treated in effluents to water or the land Septic Tank & Soak Pit. (expected mode and place of The treated effluent shall be reused in

discharge) boiler & cooling.

7.3 By deposition of pollutants emitted to No The factory is located in Saykha air into the land or into water Industrial Area. The emissions shall conform to the CPCB norms of discharge. The treated effluent shall be reused in boiler & cooling. 7.4 From any other sources No Not applicable 7.5 Is there a risk of long term build up of No Full- fledged Environmental pollution in the environment from Management System (EMS) will be these sources? installed. i.e. ETP,RO, Air Pollution Control systems, Solid Hazardous Waste Handling and Management as per norms, etc. which will eliminates the possibility of building up of pollution.

8. Risks of accident during construction or operation of the Project, which could affect human health or the environment: Sr. Information/Checklist confirmation Yes/ Details thereof (with approximate No No? quantities / rates, wherever possible) with source of information data 8.1 From explosions, spillages, fires, etc. Yes The risk assessment will be carried out from storage, handling, use or and all mitigative measures shall be production of hazardous substances taken to avoid accidents. 8.2 From any other causes No Not applicable 8.3 Could the project be affected by natural No -- disasters causing environmental damage (e.g. floods, earthquakes, landslides, cloudburst etc)?

9. Factors which should be considered (such as consequential development) which could lead to environmental effects or the potential for cumulative impacts with other existing or planned activities in the locality

Sr. Information/Checklist confirmation Details thereof (with approximate Yes/ No. quantities / rates, wherever possible) No? with source of information data 9.1 Lead to development of supporting No Site is located in Saykha Industrial Area, facilities, ancillary development or Saykha, having the entire required development stimulated by the project infrastructure. which could have impact on the This industrial zone is having existing road environment e.g.: infrastructure, power supply are to be * Supporting infrastructure (roads, utilized.

power supply, waste or waste water Local people will be employed and no treatment, etc.) housing is required. • housing development Please refer Annexure – 9. • extractive industries • supply industries • other 9.2 Lead to after-use of the site, which No could have an impact on the -- environment 9.3 Set a precedent for later developments No Not applicable 9.4 Have cumulative effects due to No The ETP of the company shall be designed proximity to Other existing or planned such that the treated effluent conforms to projects with similar effects the statutory requirement. The treated effluent shall be reused in boiler & cooling.

(VI) Environmental Sensitivity

Sr. Information/Checklist confirmation Name / Aerial distance (within 25 km). No Identity Proposed Project Location Boundary. 1 Areas protected under international Yes Site is located in Saykha Industrial Area, conventions national or local Saykha, Tal. Vagra, Dist. Bharuch, legislation for their ecological, Gujarat. landscape, cultural or other related value 2 Areas which are important or sensitive Yes Site is located in Saykha Industrial Area, for Ecological reasons – Wetlands, Saykha, Dist. Bharuch, Gujarat. watercourses or other water bodies, Forest area of Rajpipla is 100 kms away. coastal zone, biospheres, mountains, forests 3 Areas used by protected, important or Yes Site is located in saykha Industrial Area, sensitive species of flora or fauna for Saykha, Tal: Vagra, Dist. Bharuch, breeding, nesting, foraging, resting, Gujarat. over wintering, migration 4 Inland, coastal, marine or underground Yes Arabian Sea = 25 Kms waters River Narmada = 10 Kms 5 State, National boundaries Yes -- 6 Routes or facilities used by the public No Not applicable for to recreation or other tourist, pilgrim areas. 7 Defense installations No NIL 8 Densely populated or built-up area Yes Bharuch city – 4 lakh population

9 Areas occupied by sensitive man-made No land community facilities) 10 Areas containing important, high Yes The project being in notified industrial quality or scarce resources (ground area does not affect agricultural land. water resources, surface resources, forestry, agriculture, fisheries, tourism, tourism, minerals) 11 Areas already subjected to pollution or Yes Site is located in Saykha Industrial Area, environmental damage. (those where Saykha, Tal: Vagra, Dist. Bharuch, existing legal environmental standards Gujarat. are exceeded) 12 Are as susceptible to natural hazard which - N.A. coul d cause the project to present environmental problems (earthquake s, subsidence, landslides, flooding erosion, or extreme or adverse climatic conditions)

IV). Proposed Terms of Reference for EIA studies: For detail please refer Annexure – 10.

I hereby given undertaking that, the data and information given in the application and enclosures are true to the best of my knowledge and belief and I am aware that if any part of the data and information submitted is found to be false or misleading at any stage the project will be rejected and clearance given, if any to the project will be revoked at our risk and cost.

Date: 07.08.2019

Place: Saykha

NOTE: 1. The projects involving clearance under Coastal Regulation Zone Notification, 1991 shall be submitted with the application a C.R.Z. map duly demarcated by one of the authorized agencies, showing the project activities, w.r.t. C.R.Z. (at the stage of TOR) and the recommendations of the State Coastal Zone Management Authority (at the stage of EC). Simultaneous action shall also be taken to obtain the requisite clearance under the provisions of the C.R.Z. Notification, 1991 for the activities to be located in the CRZ. 2. The projects to be located within 60 km of the National Parks, Sanctuaries, Biosphere Reserves, Migratory Corridors of Wild Animals, the project proponent shall submit the map duly authenticated by Chief Wildlife Warden showing these features vis-à-vis the project location and the recommendations or comments of the Chief Wildlife Warden thereon (at the stage of EC). 3. 3. All correspondence with the Ministry of Environment & Forests including submission of application for TOR/Environmental Clearance, subsequent clarifications, as may be required from time to time, participation in the EAC Meeting on behalf of the project proponent shall be made by the authorized signatory only. The authorized signatory should also submit a document in support of his claim of being an authorized signatory for the specific project.

ANNEXURES 1 PLANT LAYOUT 2 LIST OF PRODUCTS WITH PRODUCTION CAPACITY AND RAW MATERIALS 3 BRIEF MANUFACTRING PROCESS, CHEMICAL REACTION AND MASS BALANCE 4 WATER CONSUMPTION AND EFFLUENT GENERATION WITH SEGREGATION OF EFFLUENT STREAMS 5 DETAILS OF PROPOSED EFFLUENT TREATMENT PLANT 6 DETAILS OF HAZARDOUS SOLID WASTE MANAGEMENT AND DISPOSAL 7 DETAILS OF AIR POLLUTION CONTROL MEASURES 8 DETAILS OF HAZARDOUS CHEMICAL STORAGE FACILITY 9 SOCIO – ECONOMIC IMPACTS 10 PROPOSED TERMS OF REFERENCES 11 GIDC PLOT ALLOTMENT LETTER 12 GIDC WATER SUPPLY LETTER

ANNEXURE: 1

PLANT LAYOUT

Annexure-2 LIST OF PRODUCTS WITH PRODUCTION CAPACITY

Sr. Product Name CAS No. Proposed End Use Of Product No Quantity (MT/Month) 1. 1,3 DICHLORO DIMETHYL 112-36-7 Pharma & Water Treatment HYDANTOIN 2. 1,3 Dibromo-5,5- Dimethyl 77-48-5 Pharma Industries Hydantion 3. 5,5 Dimethyl Hydantion 77-71-4 Pharma Industries 4. 2,2-Azobisisobutyronitrile 78-67-1 Pharma, Polymer,Paint And Pesticides Industries 5. Benzoyl Peroxide 94-36-0 Paint & Polymer Industries 6. MEK Peroxide 1338-23-4 Paint & Polymer Industries 750 7. LABSA 27176-87-0 Use in Detergents Industries 8. Methyl Methacrylate (MMA) 80-62-6 Acrylic Resin, Paint & Plastic Industries 9. Acrylic Emulsion 25067-01-0 Textile, Paper & Leather Industries, 10. VAM Emulsion 108-05-4 Textile, Paint Industries 11. Sodium Hypochlorite 7681-52-9 Textile & Paper Bleaching 12 Calcium Chloride 7440-70-2 Paint & Dyes Industries 13 Benzalkonium Chloride (BKC-50) 8001-54-5 Clinical Products 14 Benzalkonium Chloride (BKC-80) 8001-54-5 Clinical Products 15 Amine Oxides 1643-20-5 Clinical Products 16 Pearl Essence 8039-79-0 Used in Paint and Plastic Industries 17 Cobalt Octate 13586-82-8 350 Paint & FRP Plastic Industries 18 TRO Turky Red Oil 8002-33-3 Antifoaming Agent & Textile Industries 19 Coco Diethanolamide 68603-42-9 Cosmetic & Toiletries 20 Solvent Based Paints ---- Use in Wooden,Metal, Household & Industrial Use TOTAL: 1100

LIST OF RAW MATERIALS

Sr No. Name of the Products Name of raw materials CAS No. of Quantity Raw MT/MONTH Material 1 1,3 DICHLORO DIMETHYL 5,5 Dimethyl Hydantoin 77-71-4 787.5 HYDANTOIN Caustic Lye 1310-73-2 75 Chlorine 7782-50-5 225 2 1,3 Dibromo-5,5- Dimethyl 5,5 Dimethyl Hydantoin 77-71-4 Hydantion 787.5 Caustic Lye 75 Chlorine 7782-50-5 225 Bromine 7726-95-6 150 3 5,5 DIMETHYL HYDANTOIN Acetone Cyanohydrin 75-86-5 750 Ammonium Bicarbonate 1066-33-7 187.5 Liquid Ammonia 7664-41-7 112.5 4 2,2- Acetone Cyanohydrin 75-86-5 450 AZOBISISOBUTYRONITRILE Hydrazine Hydrate 7803-57-8 337.5 Chlorine 7782-50-5 225 Caustic Soda 1310-73-2 37.5 5 Benzoyl Peroxide Benzoyl Chloride 98-88-4 450 Hydrogen Peroxide 7722-84-1 225 Caustic Lye 1310-73-2 37.5 Benzoic Acid 65-85-0 75 6 MEK Peroxide Methyl Ethyl Ketone 78-93-3 450 Hydrogen Peroxide 7722-84-1 150 Dibuthyl Phthalate 131-11-3 150 7 LABSA Linear alkylbenzene 67774-74-7 637.5 Sulphuric Acid 7664-93-9 300 8 Methyl Methacrylate Acetone Cyanohydrin 75-86-5 375 (MMA) Sulphuric Acid 7664-93-9 187.5 Methanol 67-56-1 375 9 Acrylic Emulsion Butyl Acrylic Monomer 141-32-2 112.5 Styrene Monomer 100-42-5 187.5 MMA Monomer 80-62-6 37.5 Acrylic Acid 79-10-7 15 Acrylamide 79-06-1 18.75 Catalyst - 1.5 2 Ethyl Hexyl Acrylate 103-11-7 37.5 10 VAM Emulsion Vinyl Acetate Monomer 108-05-4 300 Poly Vinyl Alcohol 9002-89-5 75 Plasticizer ----- 37.5

Catalyst ----- 1.5 11 SODIUM HYPOCHLORITE Caustic Lye 1310-73-2 87.5 Chlorine 7782-50-5 70 12 Calcium Chloride Lime Stone 1317-65-3 315 Hydrochloric Acid 7647-01-0 210 13 Benzalkonium Chloride Dimethyl lauryl Amine 111-42-2 113.75 (BKC-50) Benzyl Chloride 112-18-5 61.25 14 Benzalkonium Chloride Dimethyl lauryl Amine 111-42-2 182 (BKC-80) Benzyl Chloride 112-18-5 98 Solvents ----- 17.5 15 Amine Oxides Dimethyl lauryl Amine 111-42-2 108.5 Hydrogen peroxide 7782-84-1 31.5 16 PEARL ESSENSE Lead Carbonate 598-63-0 87.5 MICA 12001-26-2 35 Titanium Dioxide 13463-67-7 52.5 Nitrocelluolose 9004-70-0 17.5 Butayl Acetate 123-86-4 43.75 Benzophenone 119-61-9 8.75 Bismuth Oxychloride 7787-59-9 35 IPA 67-63-0 35 Acetone 67-64-1 35 17 Cobalt Octate 2-Ethyl Hexnoic Acid 149-57-5 88.9 Cobalt Sulphate 10026-24-1 70 Sodium Hydroxide 1310-73-2 23.1 Toulene 108-88-3 420 18 TRO Turky Red Oil Castor Oil 8001-79-4 245 Sulphuric Acid 7664-93-9 87.5 Caustic Lye 1310-73-2 17.5 19 Coco Diehthanolamide Coconut Oil 8001-37-8 210 (CDEA) Diethylamine 10-89-7 105 Casutic Potash 1310-58-3 35 20 SOLVENT BASED PAINTS NC Thinner ---- 140 Nitrocellulose 9004-70-0 35 Benzophenone 119-61-9 17.5 Titanium Dioxide 13463-67-7 70 Pigment Dyes ----- 3.5 Butayl Acetate 123-86-4 35 Acetone 67-64-1 24.5 IPA 67-63-0 24.5

ANNEXURE: 3

BRIEF MANUFACTRING PROCESS, CHEMICAL REACTION AND MASS BALANCE WITH FLOW DIAGRAM

1. 1,3 DICHLORO DIMETHYL HYDANTOIN

Detail of Manufacturing process 5,5 Dimethyl Hydantoin add with water in batch reactor. After proper mixing add caustic lye and flow chlorine gas for maintain temperature cooling with water in batch reactor. After complete reaction filter material through notch & centrifuge or drying.

Chemical Reaction:

(CH 3)2C7H14 N2O2 +2Cl 2 +2H 2O → 2HOBr + Cl 2C7H14 N2O2

Chemical Structure

Material Balance Input Qty/Batch Output Qty/ Batch 5,5 Dimethyl 1050 DCDMH 1000 Hydantoin Caustic Lye 250 Waste Water 2800 Chlorine 500

Water 2000

Total Qty 3800 Total Qty 3800

FLOW CHART

5,5 Dimethyl Hydantoin 1050 Batch Reactor Caustic Lye 250 Chlorine 500 Water 2000

Filter Notch Waste Water 2300

Centrifugal Machine Waste Water 250

Dryer Water Water 250

DCDMH 1000 Kgs

2. 1,3 Dibromo-5,5- Dimethyl Hydantion

Detail of Manufacturing process 5,5 Dimethyl Hydantoin add with water in batch reactor. After proper mixing add bromine and caustic lye and flow chlorine gas for maintain temperature cooling with water in batch reactor. After complete reaction filter material through notch & centrifuge or drying.

Chemical Reaction:

(CH 3)2C7H14 N2O2 +2Br 2 +2H 2O → 2HOBr + Br 2C7H14 N2O2

Chemical Structure:

Material Balance Input Qty/Batch Output Qty/ Batch 5,5 Dimethyl 1050 DDH 1000 Hydantoin Caustic Lye 100 Waste Water 2900 Chlorine 500 Bromine 250 Water 2000 Total Qty 3900 Total Qty 3900

FLOW CHART

5,5 Dimethyl Hydantoin 1050 Batch Reactor Caustic Lye 100 Chlorine 500 Bromine 250 Water 2000

Filter Notch Waste Water 2300

Centrifugal Machine Waste Water

Water Water 350 Dryer

DDH 1000 Kgs

3. 5,5 DIMETHYL HYDANTOIN

Detail of Manufacturing process Acetone Cyanohydrin react with ammonium bicarbonate and liquid ammonia in batch reactor for temperature steam in batch reactor. After complete reaction filter material through notch.

Chemical Reaction: C7NH 16 O2 + NH 3 + NH 4HCO 3 → C 7H14 N2O2 + Waste Liquid

Chemical Structure

Material Balance Input Qty/Batch Output Qty/ Batch Acetone 1000 DMH 1000 Cyanohydrin Ammonium 250 Waste Liquid 400 Bicarbonate Liquid Ammonia 150

Total Qty 1400 Total Qty 1400

FLOW CHART

Acetone Cyanohydrin 1000 Batch Reactor Ammonium Biocaronate 250 Liquid Ammonia 150

Filter Notch Waste liquid 400

DMH 1000 Kgs 22

4. 2,2-AZOBISISOBUTYRONITRILE

Detail of Manufacturing process

ACETONE CYANOHYDRIN reacted with HYDRAZINE HYDRATE in batch reactor and mix it through stirrer, after complete of reaction filter through notch and add to second batch reactor with water and flow liquid chlorine with caustic lye solution in batch reactor. After complete reaction stop the chlorine and discharged the material in the filter notch and washing through Centrifugal machine. After that add it into the dryer and on completion of drying process pack the material in the Corrugated Box or Fiber drums. Chemical Reaction:

2(CH 3)2C(CN)OH + N 2H4 → [(CH 3)2C(CN)] 2N2H2 + 2H 2O

[(CH 3)2C(CN)] 2N2H2 + Cl 2 → [(CH 3)2C(CN)] 2N2 + 2HCl

Material Balance Input Qty/Batch Output Qty/ Batch Acetone Cyanohydrin 600 AIBN 1000 Hydrazine Hydrate 450 Waste Water 3200 Chlorine 500 Caustic Soda 150 Water 2500 Total Qty 4200 Total Qty 4200

FLOW CHART

Hydrazine Hydrate 450 1St Batch Acetone Cyanohydrin 600 Water500 Reactor

Filter Notch Waste Water 550

Chlorine 500 2nd Batch Caustic Lye 150 Reactor Water 2000

Filter Notch Waste Water 2000

Centrifugal Machine Waste Water 500

Dryer Waste Water 150

AIBN 1000 Kgs

5. Benzoyl Peroxide

Detail of Manufacturing process Benzoyl chloride reaction with hydrogen peroxide in batch reactor and alkaline solution and benzoic acid. After proper reaction filter through centrifugal machine and drying and packing.

Chemical Reaction:

2C 6H5C(O)Cl + H 2O2 + 2NaOH → (C 6H5CO) 2O2 + 2NaCl + 2H2O

Material Balance Input Qty/Batch Output Qty/ Batch Benzoyl Chloride 600 Benzoyl Peroxide 1000 Hydrogen Peroxide 300 Waste Water 250 Caustic Lye 50 Benzoic Acid 100 Water 200 Total Qty 1250 Total Qty 1250

FLOW CHART

Benzoyl Peroxide 600 Batch Reactor Hydrogen Peroxide 300 Caustic Lye 50 Bnezoic Acid 100 Water 200

Centrifugal Machine Waste Water 250

Benzoyl Peroxide 1000 KGS

6. MEK Peroxide

Detail of Manufacturing process Methyl Ethyl Ketone react with hydrogen peroxide in batch reactor and add dibutyl phthalate. After proper reaction filter and packing.

Chemical Reaction:

C5H10 O + C 10 H10 O4 + H 2O2 ‰ (C8H18 O6)2

Chemical Structure

Material Balance Input Qty/Batch Output Qty/ Batch Methyl Ethyl 600 MEK Peroxide 1000 Ketone Hydrogen Peroxide 200

Dibuthyl Phthalate 200

Total Qty 1000 Total Qty 1000

FLOW CHART

Methyl Ethyl Ketone 600 Batch Reactor

Hydrogen Peroxide 200

Dimethyl Phthalate 200

MEK Peroxide 1000 KGS

7. LABSA

Detail of Manufacturing process Linear alkylbenzene reaction with sulphuric acid in batch reactor and for temperature pass on steam in reactor after proper reaction. Cooling and separation spaint sulphuric acid and packing.

Chemical Reaction:

C6H5-R+ SO 3 Ï C6H6SO 3-R

Material Balance Input Qty/Batch Output Qty/ Batch Linear 850 LABSA Monomer 1000 alkylbenzene Sulphuric Acid 400 Spaint Acid 250 Total Qty 1250 Total Qty 1250

FLOW CHART

Linear Alkylbenzene 850 Batch Reactor Sulphuric Acid 400

Separation Unit Spaint Acid 250

LABSA 1000 KGS

8. Methyl Methacrylate (MMA)

Detail of Manufacturing process ACETONE CYANOHYDRIN reacted with Sulphuric Acid in 1 St batch reactor after proper reaction add it in cracker unit After convert in methacrylamide sulphate. The metheacrylamide sulphate is then esterified with aqueous methanol in reactor 2 nd to produce MMA and ammonium bisulphate( By Product). The steam proceeds to through several separation and purification.

Reaction

(CH 3)2C(OH)CN + 2H2SO 4 + CH 3OH ‰ MMA + NH 4HSO 4 + H2SO 4

Material Balance Input Qty/Batch Output Qty/ Batch Acetone 500 MMA 1000 Cyanohydrin Sulphuric Acid 250 Diluted Sulphuric 100 Acid Methanol 500 Ammonium 150 Bisulphate Total Qty 1250 Total Qty 1250

FLOW CHART

Sulphuric Acid 250 1St Batch Acetone Cyanohydrin 500 Reactor

Cracker Diluted Sulphuric Acid 100

2nd Batch Methanol 500 Reactor

Separation Ammonium Bisulphate 150

MMA 1000 Kgs

9. Acrylic Emulsion

Detail of Manufacturing process First add water in batch reactor and steam after temperature 60°c add raw materials and catalyst. Start the polymerized material addition start monomers. After complete addition cooling and packing.

Chemical Reaction:

C7H12 O2 + C 5H8O2 + C 2H3O2 + C 3H4O2 + C 3H5NO + H2O ‰ (C 5H8O2)4 + H2O +NO

Material Balance

Input Qty/Batch Output Qty/ Batch Butyl Acrylic 150 Acrylic Emulsion 1000 Monomer Styrene Monomer 250 Evaporated Water 47 MMA Monomer 50 Acrylic Acid 20 Acrylamide 25 Catalyst 2 2 Ethyl Hexyl 50 Acrylate Water 500 Total Qty 1047 Total Qty 1047

FLOW CHART

Water Evaporates 47

Butyl Acrylic Monomer 150 Batch Reactor Catalyst 2 Styrene Monomer 250 MMA Monomer 50 2 Ethyl Hexyl 50 Acrylic Acid 20 Acrylamide 25 Water 500

Acrylic Emulsion 1000 KGS

10. VAM Emulsion

Chemical Reaction:

C4H4O2 + 2(C 2H4O)OH + H 2O + Plasticizer ‰ 2(C4H4O2) + 5H 2O

Material Balance

Input Qty/Batch Output Qty/ Batch Vinyl Acetate 400 VAM Emulsion 1000 Monomer Poly Vinyl Alcohol 100 Evaporated Water 52

Plasticizer 50 Catalyst 2 Water 500 Total Qty 1052 Total Qty 1052

FLOW CHART

Vinyl Acetate Monomer 400 Batch Reactor Poly Vinyl Alcohol 100 Water Evaporated 52 Plasticizer 50 Catalyst 2 Water 500

VAM Emulsion 1000 KGS

11. SODIUM HYPOCHLORITE

Detail of Manufacturing process Add water and caustic lye in batch reactor and after proper mixing add chlorine gas for maintain temperature cooling with water in batch reactor. After complete reaction material is ready for packing.

Chemical Reaction: 2NaOH + Cl2 ‰ 2NaClO + H2

Chemical Structure

Material Balance Input Qty/Batch Output Qty/ Batch Caustic Lye 250 Sodium 1000 Hypochlorite Chlorine 200 Water 550 Total Qty 1000 Total Qty 1000

FLOW CHART

Caustic Lye 250 Batch Reactor Chlorine 200 Water 550

HYPOCHLORI TE 1000 KGS

12. Calcium Chloride

Detail of Manufacturing process First limestone add in hydrochloric acid tank solution. After proper solution add solution in vessel & heating. After evaporate water material in paste form. Then material is put to dry & material converts in solid lumps form the packing.

Formula CaCO3 + 2HCl(diluted) = CaCl2 + CO2↑ + H2O.

Material Balance Input Qty/Batch Output Qty/ Batch Lime Stone 900 Calcium Chloride 1000 Hydrochloric Acid 600 Water Evaporate 500 Total Qty 1500 Total Qty 1500

FLOW CHART

Limestone 900 Solution tank

Hydrochloric Acid 600

Vessel Water Evaporates 400

Drying Water Evaporates 100

Calcium Chloride 1000 KGS

13. Benzalkonium Chloride (BKC-50)

Detail of Manufacturing process Dimethyl lauryl amine is quarternized with benzyl chloride at controlled temperature. The product is digested and sufficiently diluted to produce finished product containing 50% active. The liquid product is directly filled in containers.

Chemical Reaction:

C7H7Cl+ C 2H6N-R‰(C 9H14 N)Cl

Material Balance Input Qty/Batch Output Qty/ Batch Dimethyl lauryl 325 Benzalkonium 1000 Amine Chloride 50 Benzyl Chloride 175 Water 500 Total Qty 1000 Total Qty 1000

FLOW CHART

Dimethyl Lauryl Amine 325 Batch Reactor Benzyl Chloride 175

Water 500 Quaternization

Digestion

Cooling

BKC 50%

1000 KGS

14. Benzalkonium Chloride (BKC-80)

Detail of Manufacturing process Dimethyl lauryl amine is quarternized with benzyl chloride at controlled temperature. The product is digested and sufficiently diluted to produce finished product containing 50% active. Solvent is also added to the product to keep the product in flow able form. The liquid product is directly filled in containers.

Chemical Reaction:

C7H7Cl+ C 2H6N-R‰(C 9H14 N)Cl

Material Balance Input Qty/Batch Output Qty/ Batch Dimethyl lauryl 520 Benzalkonium 1000 Amine Chloride 80 Benzyl Chloride 280 Solvents 50 Water 150 Total Qty 1000 Total Qty 1000

FLOW CHART

Dimethyl Lauryl Amine 520 Batch Reactor Benzyl Chloride 280

Quaternization Water 150 Solvent 50

Digestion

Cooling

BKC 80% 1000 KGS

15. Amine Oxides

Detail of Manufacturing process

Oxidation reaction of Dimethyl Lauryl amine is carried out by using hydrogen peroxide 50 % at atmospheric pressure. After the oxidation is over product is digested and then cooled. The product is suitably diluted with water and filled in containers.

Chemical Reaction: C2H6N-R+H 2O2‰C2H6NO-R+Vapour

Material Balance Input Qty/Batch Output Qty/ Batch Dimethyl lauryl 310 Amine Oxide 1000 Amine Hydrogen peroxide 90 Water 600 Total Qty 1000 Total Qty 1000

FLOW CHART

Dimethyl Lauryl Amine 310 Batch Reactor Hydrogen Peroxide 90

Water 600 Oxydation Heat

Digestion

Quaternization

Cooling

Amine Oxide 1000 KGS

16. PEARL ESSENSE

Detail of Manufacturing process

Add raw material in batch reactor and after proper mixing put the material for packing.

Chemical Reaction:

PbCO3+ TiO 2+ [C 6H7(NO 2)3O5]n+MICA+ C6H12 O2+ C13 H10 O+ C3H6O+ C3H8O+ BiOCl

‰PEARL ESSENCE

Material Balance Input Qty/Batch Output Qty/ Batch Lead Carbonate 250 Pearl Essence 1000 MICA 100 Titanium Dioxide 150 Nitrocelluolose 50 Butayl Acetate 125 Benzophenone 25 Bismuth Oxychloride 100 IPA 100 Acetone 100 Total Qty 1000 Total Qty 1000

FLOW CHART

Lead Carbonate 250 Batch Reactor MICA 100 Benzophenone 25 Titanium Dioxide 150 IPA 100 Nitrocellulose 50 Acetone 100 Butyl Acetate 125 Bismuth Oxychloride 100

Pearl Essence 1000 KGS

17. Cobalt Octate

Detail of Manufacturing process

2-Ethyl Hexanoic acid and cobalt sulphate is reacted in the presence of sodium hydroxide solution. It is then extracted with toluene and concentrated.

Chemical Reaction:

C8H16 O2+CoSO 4+H 2O+NaOH+C7H8‰[C 8H15 O2]2Co

Material Balance

Input Qty/Batch Output Qty/ Batch 2-Ethyl Hexnoic 254 Cobalt Octate 1000 Acid Cobalt Sulphate 200 Waste Water 250 Water 266 Toulene 726 Sodium Hydroxide 66 Toulene Vapour 10 Loss Toulene 1200 Total Qty 1986 Total Qty 1986

FLOW CHART

2-Ethyl Hexanoic Acid 254

Cobalt Sulphate 200 Batch Reactor

Sodium Hydroxide Solution (266+66)

Extraction Toulene 1200 Waste Water 250 Kg

Concentration Toulene Recovery +Vapour loss (726+10)

Cobalt Octate 1000 KGS

18. TRO Turky Red Oil

Detail of Manufacturing process First add in batch reactor castor oil and add sulphuric acid after proper mixing add for neutralization caustic lye and packing.

Chemical Reaction: Castor Oil+ NaOH+H2SO4+H2O ‰TRO Turky Oil

Material Balance Input Qty/Batch Output Qty/ Batch Castor Oil 700 TRO Turky Red Oil 1000

Sulphuric Acid 250 Caustic Lye 50 Total Qty 1000 Total Qty 1000

FLOW CHART

Castor Oil 700 Batch Reactor

Sulphuric Acid 250

Casutic Lye 50

TRO Truky Red Oil 1000 KGS

19. Coco Diehthanolamide (CDEA)

Detail of Manufacturing process

All the raw materials are properly mixed in batch reactor. After mixing passed through filtration and packing.

Chemical Reaction: KOH+Coconut Oil+C 4H11 N‰ CocoDiethanolamide

Material Balance

Input Qty/Batch Output Qty/ Batch Coconut Oil 600 Coco 1000 Diethanolamide Diethylamine 300 Casutic Potash 100 Total Qty 1000 Total Qty 1000

FLOW CHART

Coconut Oil 600 Batch Reactor Diethylamine 300 Caustic Potash 100

Filtration

Coco Diethanolamide 1000 Kgs

20. SOLVENT BASED PAINTS

Detail of Manufacturing process Add raw material in bead mill reactor. After proper mixing pass on through high speed disperser. After disperser filter and packing.

Chemical Reaction:

Thinner+Pigment Dyes+ TiO 2+ [C 6H7(NO 2)3O5]n+ C6H12 O2+ C13 H10 O+ C3H6O+ C3H8O‰ Solvent Based Paints

Material Balance Input Qty/Batch Output Qty/ Batch NC Thinner 400 Solvent Based 1000 Paints Nitrocellulose 100 Benzophenone 50 Titanium Dioxide 200 Pigment Dyes 10 Butayl Acetate 100 Acetone 70 IPA 70 Total Qty 1000 Total Qty 1000

FLOW CHART

Nc Thinner 400 Batch Reactor Ntrocellulose 100 Butayl Acetate 100 Benzophenone 50 Acetone 70 Titanium Dioxide 200 IPA 70 Pigment Dyes 10

High speed dispenser

Solvent Based Paints 1000 KGS

ANNEXURE: 4 WATER CONSUMPTION AND EFFLUENT GENERATION

Proposed

Proposed (KL/day) WATER CONSUMPTION Wastewater Generation (A) Domestic 3 2 (B) Gardening 10 0 (C) Industrial Process 37 40 Washing 30 29 Boiler 9.5 1 Cooling 8.5 1 Others (Scrubber) 2 2.795 Total 100 75 .795

WATER BALANCE DIAGRAM

Raw Water: 100 (Fresh Water: 32 +RO Permeate: 60+Condensate Water:8)

Dom: 3.0 Ind: 87 Gardening: 10

Septic Tank & Soak Pit : 2

Process Washing Boiler Cooling Other : 2 37 30 9.5 8.5 (Scrubbing)

40 29 1 1 2.795

Steam-I 69 KLD Low COD & TDS Steam Will be reused or Steam: II 2 sold to end users ETP (69) KLD Utilities having permission (Primary, Secondary, Tertiary) steam under Rule-9.

RO:71 RO Permeate :60 Reuse/recycle RO Reject : 11

Single Stage Evaporator

Condensate water: 8 Condenser Reuse/Recycle in boiler or cooling

Salt to sludge drying bed

ANNEXURE: 5 ETP DETAILS

Stream I (RAW EFFLUENT Stream) (69 KLD)

First all non-toxic and biodegradable (streams I) of wastewater shall pass through Oil & Grease Removal Tank (OGRT-01) where floating O & G shall be removed manual from top and collected in O & G Collection Tank (OGCT-01). Then effluent shall be collected in Equalization cum Neutralization Tank (ENT-01) where the continuous addition and stirring of Lime solution is done to maintain neutral pH of wastewater from Lime Dosing Tanks (LDT-01-A/B) as per requirement with help of Lime Dosing Pumps. Then after, neutralized wastewater shall go to Flash Mixer (FM-01) by gravity. Alum shall be dosed from Alum Dosing Tanks (ADT-01-A/B) with help of Dosing Pumps. Then after, coagulated wastewater shall be settled in Primary Settling Tank-1 (PST-01). Clear supernatant from PST-01 shall be passed in Aeration Tank (AT-01). Here, biodegradation of organic matter of the wastewater shall be carried out by bacteria (suspended growth) in the AT-01 and for that oxygen shall be supplied by 2 nos. of air blowers (B-02) through diffusers. Air blowers also keep MLSS in suspension.

Then after, wastewater shall go to Secondary Settling Tank (SST-01). Here, the suspended solids shall be settled at bottom. Sludge shall be removed from bottom of SST-01 and pumped to AT-1 to maintain MLSS and excess activated sludge shall be sent to Sludge Sump (SS-01). Clear supernatant from SST-01 shall be collected in Intermediate Sump (IS-01) by gravity.

Thereafter, the wastewater shall be passed through Pressure Sand Filter (PSF-01) to remove left out TSS and Activated Carbon Filter (ACF-01) for final effluent polishing. After tertiary treatment, effluent shall be collected in Treated Effluent Sump (TES-01) before sent to RO-01 for further treatment. RO-01 permeate water shall be collected in RO Treated Water Tank (ROTWT-01) before reuse in plant. RO-01 reject shall be sent to Single Stage Evaporator (SSE-01). Condensate water from SSE-01 shall be reuse/recycle in boiler or cooling for future treatment.

Sludge settled in PST-01 and excess sludge from SST-01 shall be collected in Sludge Sumps (SS-01) then sludge shall be pumped to Centrifuge (CF-01) where poly shall be mixed from poly Dosing Tank-2 (PDT- 02) with sludge to increase efficiency of centrifuge sludge dewatering. Then, dewatered sludge shall be stored in in HWSA and then ultimate disposal to TSDF. Leachate from CF-01 and backwash from PSF-01 and ACF-01 shall be collected in Drain Pit and pumped back to ENT-01 for further treatment.

DETAILS OF UNITS: (FOR STREAMS - I) (80 KLD)

Sr. Size in Meters Name of Unit Tag No. Nos. MOC No. (L X B X (LD+FB) Inlet Units RCC M30+ A/A 1. O & G Removal Tank OGRT 2.5 x 1.0 (1.0 + 0.5) 1 Bk. Lining RCC M30+ A/A 2. O & G Removal Tank OGRT 1 KL 1 Bk. Lining Equalization cum RCC M30+ A/A 3. ENT-01 3.5 x 3.5 x (3.0+0.5) 1 Neutralization Tank Bk. Lining Primary Treatment 4. Flash Mixer-1 FM-01 1.5 x 1.5 x (1.5 + 0.5) 1 RCC M30 Primary Settling 3.0 x 1.5 x (2.0 SWD + RCC M30 5. PST-01 1 tank -1 0.5) Secondary Treatment 6. Aeration Tank AT-01 8.0 x 4.0 (3.5 + 0.5) 1 RCC M30 4.0 x 2.0 x (2.5 SWD + RCC M30 7. Secondary Settling Tank SST-01 1 0.5) Tertiary + sludge dewatering Treatment+ Dosing Tanks 8. Intermediate Sump IS-01 3.0 x 3.0 (2.0 + 0.5) 1 RCC M30 9. Pressure Sand Filter PSF-01 4.5 M3/hr 1 MSEP 10. Activated Carbon Filter ACF-01 4.5 m3/hr 1 MSEP 11. Treated Effluent Sump TES-01 6.0 x 3.0 (4.0 + 0.3) 1 RCC M30 12. RO Unit RT-01 71 m3/D 1 SS304 13. RO Permeate Tank ROPT-01 3.0 x 2.0 (2.0+0.5) 1 RCC M30 14. Single Stage Evaporator SSE-01 11 m3/D 1 SS304 Condensate Storage RCC M30 15. CST-01 1.0 x 1.0 (1.0+0.5) 1 Tank 16. Sludge Sump SS-01 2.0 x 2.0 x (2.0+0.3) 1 RCC M30 17. Centrifuge CFG-01 69 m3/D 1 SS304 Lime Dosing Tanks LDT-01 2500 Lit. 1 HDPE/PP Alum Dosing Tank ADT-01 2000 Lit 1 HDPE/PP PDT- Poly Dosing Tanks 1000 Lit 2 HDPE 01/02 Nutrient Dosing Tank1 NDT-01 1000 Lit 1 HDPE

ETP FLOW DIAGRAM:

ANNEXURE: 6 DETAILS OF HAZARDOUS SOLID WASTE MANAGEMENT AND DISPOSAL Sr. Type/Name Specific Source of Category & Quantity Management of HW no. of Hazardous generation ( Name Schedule as (MT/ waste of the Activity, per HW Annum) Product etc.) Rules. 1 Discarded Raw Material and Sch-I/ 45 Collection, Storage, Transportation Drums/Bags Storage 33.1 and sell to Register Re-processors after decontamination. 2 Used / Spent Equipment & Sch-I/ 200 Lit/ Collection, Storage, Transportation Oil Machinery 5.1 Year and sell to registered recycler. 3 ETP Sludge ETP Sch-I/ 216 Collection, Storage, Transportation 35.3 and sent to common TSDF of M/s. BEIL. 4 Distillation Distillation Sch-I/ 100.68 Collection, Storage, Transportation Residue 20.3 and sent for co-processing in cement industries or sent to common incineration of M/s. BEIL. 5 Spent Catalyst Process (Product Sch-I/ 5 Collection, Storage, Transportation No:9,10) 28.3 and sent to registered regenerator under Rule-9 permission. 6 NaCl (15%) Scrubber SCH-1/26.1 280 Collection, Storage, Transportation and sold to end user having permission under rule-9. 7 NaOCl (12%) Scrubber SCH-1/26.1 270 Collection, Storage & convert to product and than sell as main product. 8 Sodium Scrubber Sch-II/ 316.8 Collection, Storage, Transportation Sulphite (25%) B36 and sold to end user having 9 Spent Process Sch-I/ 2529 permission under rule-9. Sulphuric Acid (Product No:7,8) 26.3 (50%) 10 Ammonium Scrubber + Sch-II/ 1350 sulphate Process B15 (15%) (Product No:8) 11 Spent Solvent Process (Product Sch-I/ 3045 Collection, Storage, Distillation and No;17) 28.6 Reuse within premises. 12 Off From mfg. Sch-I/ 20 Collection, Storage, Transportation Specification Process 28.4 and sent for co-processing in Products (Batch failure) cement industries or Disposal at common incineration site. 13. Salt Condeser SCH-1/26.1 1080 Collection, Storage, Transportation and send to slude drying bed.

ANNEXURE: 7 DETAILS OF FLUE & PROCESS GAS EMISSION Flue Gas Emission

Source of Type of Stack Quantity of Air Pollution Control Sr. emission Type of emissions Height Fuel Measures no. With Fuel i.e. Air (meter) MT/Day (APCM) Capacity Pollutants Boiler 18 Solid Fuel- 1 MT/Day / SPM Multi-cyclone (Capacity: White 1 MT/Day SO 2 Separator with Bag 500 Coal, Fire NOx Filter + Scrubber 1 KG/PH) Wood/ Briquettes of Bio-Coal Boiler 18 Briquettes 5 MT/Day SPM Multi-cyclone 2 (Capacity: of Bio- / 4 MT/Day SO 2 separator with bag 1 TPH) Coal/ Coal NOx filter + Scrubber Thermic 18 Briquettes 4 MT/Day / SPM Multi-cyclone fluid of Bio- 3 MT/Day SO 2 separator with bag heater Coal/ Coal NOx filter + Scrubber 3 (Capacity: 1 Lakh Kcal/ Hr) D. G. Set 11 HSD 150 Lit/Day SPM Adequate Stack Height 4 (65 KVA) SO 2 NOx D. G. Set 11 HSD 300 Lit/Day SPM Adequate Stack Height 5 (125 KVA) SO 2 NOx

Process Gas Emissions

Specific Source of Stack/Vent Sr. emission Type of Air Pollution Control Measures Height no. (Name of the Product emission (APCM) (meter) & Process) Process Vent Cl 2 11 Two Stage Caustic Scrubber (Chlorination) HCl 1 (Product Name: AIBN, DDH, DCDH) Process Vent SO 2 11 Two Stage Water + Caustic (Sulphonation) scrubber 2 (Product Name: MMA and LABSA)

Process Vent NH 3 11 Two Stage Acid scrubber 3 (Ammoniation) (Product Name: DMH)

ANNEXURE: 8 DETAILS HAZARDOUS CHEMICAL STORAGE FACILITY

Sr. Name of the Maximum Mode of Actual State & Possible type of No. Hazardous Storage Storage Storage Operating Hazards Substance pressure & temperature 1 Chlorine 10 MT Tonner 0.9 MT X 11 NTP Corrosive 2 Bromine 5 MT Bottle 0.6 MT X 8 NTP Corrosive 3 Acetone 25 MT Tank/Dr 30 MT x 1 NTP Toxic cynohydrin um 4 Liquid 5 MT Drum 5 MT x 1 NTP Toxic Ammonia 5 Benzoyl 20 MT Drum 20 MT x 1 NTP Flammable/ Chloride Toxic 6 Hydrogen 5 MT Drum 5 MT x 1 NTP Toxic peroxide 7 Dibuthyl 5 MT Drum 5 MT x 1 NTP Toxic Phthalate 8 H2SO4 10 MT Tank/Dr 10 MT x 1 NTP Corrosive um 9 Methanol 10 MT Tank/Dr 10 MT x 1 NTP Flammable/ um Toxic 10 Acetone 5 MT Drum 5 MT x 1 NTP Flammable 11 IPA 5 MT Drum 5 MT x 1 NTP Flammable 12 Toluene 15 MT Tank/Dr 20 MT x 1 NTP Flammable um 13 Diethylamine 5 MT Drum 5 MT x 1 NTP Flammable/ Toxic 14 2- 5 MT Drum 5 MT x 1 NTP Toxic Ethylhexanoic acid 15 Hydrochloric 10 MT Drum 10 MT x 1 NTP Toxic Acid 16 Hydrazine 10 MT Drum 10 MT x 1 NTP Toxic/ Hydrate Flammable/ Corrosive

ANNEXURE 9 SOCIO - ECONOMIC IMPACTS

1) EMPLOYMENT OPPORTUNITIES The manpower requirement for the proposed project is expected to generate some permanent jobs and secondary jobs for the operation and maintenance of plant. This will increase direct / indirect employment opportunities and ancillary business development to some extent for the local population. This phase is expected to create a beneficial impact on the local socio-economic environment.

2) INDUSTRIES Required raw materials and skilled and unskilled labors will be utilized maximum from the local area. The increasing industrial activity will boost the commercial and economical status of the locality, to some extent.

3) PUBLIC HEALTH The company regularly examines, inspects and tests its emission from sources to make sure that the emission is below the permissible limit. Hence, there will not be any significant change in the status of sanitation and the community health of the area, as sufficient measures have been taken and proposed under the EMP.

4) TRANSPORTATION AND COMMUNICATION In brief, as a result of the proposed project there will be no adverse impact on sanitation, communication and community health, as sufficient measures have been proposed to be taken under the EMP. The proposed project is not expected to make any significant change in the existing status of the socio - economic environment of this region.

ANNEXURE – 10 PROPOSED DRAFT TERMS OF REFERENCE:

1. Project Description • Justification of project. • Promoters and their back ground • Project site location along with site map of 5 km area and site details providing various industries, surface water bodies, forests etc. • Project cost • Project location and Plant layout. • Existing infrastructure facilities • Water source and utilization including proposed water balance. • List of Products & their capacity • Details of manufacturing process of proposed products • List of hazardous chemicals • Mass balance of each product • Storage and Transportation of raw materials and products.

2. Description of the Environment and Baseline Data Collection • Micrometeorological data for wind speed, direction, temperature, humidity and rainfall in 5 km area. • Existing environmental status Vis a Vis air, water, noise, soil in 5 km area from the project site. • Ground water quality at 5 locations within 5 km. • Complete water balance

3. Socio Economic Data • Existing socio-economic status, land use pattern and infrastructure facilities available in the study area were surveyed.

4. Impacts Identification And Mitigatory Measures • Identification of impacting activities from the proposed project during construction and operational phase. • Impact on air and mitigation measures including green belt • Impact on water environment and mitigation measures • Soil pollution source and mitigation measures • Noise generation and control. • Solid waste quantification and disposal. • Control of fugitive emissions

5. Environmental Management Plan • Details of pollution control measures • Environment management team • Proposed schedule for environmental monitoring including post project

6. Risk Assessment • Objectives, Philosophy and methodology of risk assessment • Details on storage facilities • Process safety, transportation, fire fighting systems, safety features and emergency capabilities to be adopted. • Identification of hazards • Consequence analysis • Recommendations on the basis of risk assessment done • Disaster Management Plan.

7. Information for Control of Fugitive Emissions 8. Information on Rain Water Harvesting 9. Green Belt Development plan

Annexure-11 G.I.D.C. Plot Allotment Letter

60 z 61

Annexure-12 G.I.D.C. Water Supply Letter