Anorthominasragrite
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Phase Equilibria and Thermodynamic Properties of Minerals in the Beo
American Mineralogist, Volwne 71, pages 277-300, 1986 Phaseequilibria and thermodynamic properties of mineralsin the BeO-AlrO3-SiO2-H2O(BASH) system,with petrologicapplications Mlnx D. B.qnroN Department of Earth and SpaceSciences, University of California, Los Angeles,Los Angeles,California 90024 Ansrru,cr The phase relations and thermodynamic properties of behoite (Be(OH)r), bertrandite (BeoSirOr(OH)J, beryl (BerAlrSiuO,r),bromellite (BeO), chrysoberyl (BeAl,Oo), euclase (BeAlSiOo(OH)),and phenakite (BerSiOo)have been quantitatively evaluatedfrom a com- bination of new phase-equilibrium, solubility, calorimetric, and volumetric measurements and with data from the literature. The resulting thermodynamic model is consistentwith natural low-variance assemblagesand can be used to interpret many beryllium-mineral occurTences. Reversedhigh-pressure solid-media experimentslocated the positions of four reactions: BerAlrSiuO,,: BeAlrOo * BerSiOo+ 5SiO, (dry) 20BeAlSiOo(OH): 3BerAlrsi6or8+ TBeAlrOo+ 2BerSiOn+ l0HrO 4BeAlSiOo(OH)+ 2SiOr: BerAlrSiuO,,+ BeAlrOo+ 2H2O BerAlrSiuO,,+ 2AlrSiOs : 3BeAlrOa + 8SiO, (water saturated). Aqueous silica concentrationswere determined by reversedexperiments at I kbar for the following sevenreactions: 2BeO + H4SiO4: BerSiOo+ 2H2O 4BeO + 2HoSiOo: BeoSirO'(OH),+ 3HrO BeAlrOo* BerSiOo+ 5H4Sio4: Be3AlrSiuOr8+ loHro 3BeAlrOo+ 8H4SiO4: BerAlrSiuOrs+ 2AlrSiO5+ l6HrO 3BerSiOo+ 2AlrSiO5+ 7H4SiO4: 2BerAlrSiuOr8+ l4H2o aBeAlsioloH) + Bersio4 + 7H4sio4:2BerAlrsiuors + 14Hro 2BeAlrOo+ BerSiOo+ 3H4SiOo: 4BeAlSiOr(OH)+ 4HrO. -
LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, and COBALT ARSENIDE and SULFIDE ORE FORMATION Nicholas Allin
Montana Tech Library Digital Commons @ Montana Tech Graduate Theses & Non-Theses Student Scholarship Spring 2019 EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION Nicholas Allin Follow this and additional works at: https://digitalcommons.mtech.edu/grad_rsch Part of the Geotechnical Engineering Commons EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION by Nicholas C. Allin A thesis submitted in partial fulfillment of the requirements for the degree of Masters in Geoscience: Geology Option Montana Technological University 2019 ii Abstract Experiments were conducted to determine the relative rates of reduction of aqueous sulfate and aqueous arsenite (As(OH)3,aq) using foils of copper, nickel, or cobalt as the reductant, at temperatures of 150ºC to 300ºC. At the highest temperature of 300°C, very limited sulfate reduction was observed with cobalt foil, but sulfate was reduced to sulfide by copper foil (precipitation of Cu2S (chalcocite)) and partly reduced by nickel foil (precipitation of NiS2 (vaesite) + NiSO4·xH2O). In the 300ºC arsenite reduction experiments, Cu3As (domeykite), Ni5As2, or CoAs (langisite) formed. In experiments where both sulfate and arsenite were present, some produced minerals were sulfarsenides, which contained both sulfide and arsenide, i.e. cobaltite (CoAsS). These experiments also produced large (~10 µm along longest axis) euhedral crystals of metal-sulfide that were either imbedded or grown upon a matrix of fine-grained metal-arsenides, or, in the case of cobalt, metal-sulfarsenide. Some experimental results did not show clear mineral formation, but instead demonstrated metal-arsenic alloying at the foil edges. -
Washington State Minerals Checklist
Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
List of New Mineral Names: with an Index of Authors
415 A (fifth) list of new mineral names: with an index of authors. 1 By L. J. S~v.scs~, M.A., F.G.S. Assistant in the ~Iineral Department of the,Brltish Museum. [Communicated June 7, 1910.] Aglaurito. R. Handmann, 1907. Zeita. Min. Geol. Stuttgart, col. i, p. 78. Orthoc]ase-felspar with a fine blue reflection forming a constituent of quartz-porphyry (Aglauritporphyr) from Teplitz, Bohemia. Named from ~,Xavpo~ ---- ~Xa&, bright. Alaito. K. A. ~Yenadkevi~, 1909. BuU. Acad. Sci. Saint-P6tersbourg, ser. 6, col. iii, p. 185 (A~am~s). Hydrate~l vanadic oxide, V205. H~O, forming blood=red, mossy growths with silky lustre. Founi] with turanite (q. v.) in thct neighbourhood of the Alai Mountains, Russian Central Asia. Alamosite. C. Palaehe and H. E. Merwin, 1909. Amer. Journ. Sci., ser. 4, col. xxvii, p. 899; Zeits. Kryst. Min., col. xlvi, p. 518. Lead recta-silicate, PbSiOs, occurring as snow-white, radially fibrous masses. Crystals are monoclinic, though apparently not isom0rphous with wol]astonite. From Alamos, Sonora, Mexico. Prepared artificially by S. Hilpert and P. Weiller, Ber. Deutsch. Chem. Ges., 1909, col. xlii, p. 2969. Aloisiite. L. Colomba, 1908. Rend. B. Accad. Lincei, Roma, set. 5, col. xvii, sere. 2, p. 233. A hydrated sub-silicate of calcium, ferrous iron, magnesium, sodium, and hydrogen, (R pp, R',), SiO,, occurring in an amorphous condition, intimately mixed with oalcinm carbonate, in a palagonite-tuff at Fort Portal, Uganda. Named in honour of H.R.H. Prince Luigi Amedeo of Savoy, Duke of Abruzzi. Aloisius or Aloysius is a Latin form of Luigi or I~ewis. -
PHASE CHANGES in Cu 2 S AS a FUNCTION of TEMPERATURE 1. PREVIOUS WORK
National Bureau of Standards Special Publication 364, Solid State Chemistry, Proceedings of 5th Materials Research Symposium, issued July 1972. PHASE CHANGES IN cu2s AS A FUNCTION OF TEMPERATURE William R. Cook, Jr. Gould Inc., Gould Laboratories Cleveland, Ohio 44108 and Case Western Reserve University Cleveland, Ohio 44106 The high-'copper phase boundary of Cu2s deviates from stoichiometry above 300 °C, first becoming copper deficient, then above - 1075 °C becoming copper rich. The maximum copper content occurs at the monotectic temperature of 1104 °C. The strong effect of oxygen on the hexagonal-cubic transition in Cu2S was confirmed; the transition was also found to be sensi tive to the type of pretreatment of the material. The high temperature tetragonal "Cu1 96s" phase is stable between Cu1.95S and Cu2s, at temperatures of - 90° to - 140 °C. The tr~nsi tion to the tetragonal phase is extremely sluggish. The true composition of djurleite has been shown to be approximately Cu1.93S. The phases near the chalcocite-digenite region of the diagram may be grouped into those with hexagonal close packing of sulfur atoms and those with cubic close packing of sulfurs. This is important in understanding rates of transformation among the various phases that occur in this area of the diagram. Key words: Chalcocite; cu2s; digenite; djurleite; nonstoichiometry; phase relations. 1. PREVIOUS WORK Fairly thorough explorations of the Cu-s phase diagram between cu2s and cu1• ,shave been made by a number of previous workers [1-8] 1 The resulting diagram may be seen in figure 1 taken largely from Roseboom [7] and Riu [8]. -
SAMPLING for COBALT at BORNITE, ALASKA Ry Jeffrey Y
SAMPLING FOR COBALT AT BORNITE, ALASKA Ry Jeffrey Y. Foley %*9 * * * * * * * * * * * * * * * * * * * * * Field Report - January, l9R 11. S. nEPARTMENT OF THE INTERIOR James S. Watt, Secretary BuREAuA OF MINES TARLE OF CONTENTS Page Introduction ................................................ Economic Geoloqy............................................ Work by the Bureau.......................................... Recommendations............................................. References ................................................. SAMDLING FOR cnRALT AT RORNITE, ALASKA By Jeffrey Y. Foley 1 INTRODIICTION Carrollite (CuCo2S4), an ore mineral of cobalt, is known to occur in the Ruby Creek Cu-Zn deposit at Bornite (fig. 1), in northwest Alaska (5, q). 2 The events leading to mineralization of dolomite and argillite units and the distribution of these rocks in the Bornite district are among the topics covered in a PhD discertation by M. W. Hitzman of Stan- ford University (in progress). Hitzman has identified carkollite and cobaltiferous pyrite at numerous intersections in diamond drill core belonging to Rear Creek Mining Corporation, the present operator of the property. A brief visit to collect bulk samples was made by a Bureau geologist in July, 19R1, as part of the Alaska Critical Metals program. ECONOMIC GEOLOGY Hitzman summarizes the distribution of cobalt as occurring: 1) "...as late cobaltiferous pyrite rims on earlier formed pyrite grains in pyritiferous, ferroan dolo- mite with disseminated sphalerite and massive siderite" 2) "...as carrollite in high-grade hornite, chalcocite, chalcopyrite, and sphalerite ore at higher levels in the deposit." 1 Geologist, U.S. Rureau of Mines, Alaska Field Operations Center, Fairbanks. 2 Underlined numbers in parentheses refer to items in the list of references at the end oF this report. ; - > . ; - .>;. -1,; g n/ /- ; > @ ! - xi #."R-: 3 2 vl- t 7:'i "^. -
New Mineral Names*,†
American Mineralogist, Volume 106, pages 1360–1364, 2021 New Mineral Names*,† Dmitriy I. Belakovskiy1, and Yulia Uvarova2 1Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18 korp. 2, Moscow 119071, Russia 2CSIRO Mineral Resources, ARRC, 26 Dick Perry Avenue, Kensington, Western Australia 6151, Australia In this issue This New Mineral Names has entries for 11 new species, including 7 minerals of jahnsite group: jahnsite- (NaMnMg), jahnsite-(NaMnMn), jahnsite-(CaMnZn), jahnsite-(MnMnFe), jahnsite-(MnMnMg), jahnsite- (MnMnZn), and whiteite-(MnMnMg); lasnierite, manganflurlite (with a new data for flurlite), tewite, and wumuite. Lasnierite* the LA-ICP-MS analysis, but their concentrations were below detec- B. Rondeau, B. Devouard, D. Jacob, P. Roussel, N. Stephant, C. Boulet, tion limits. The empirical formula is (Ca0.59Sr0.37)Ʃ0.96(Mg1.42Fe0.54)Ʃ1.96 V. Mollé, M. Corre, E. Fritsch, C. Ferraris, and G.C. Parodi (2019) Al0.87(P2.99Si0.01)Ʃ3.00(O11.41F0.59)Ʃ12 based on 12 (O+F) pfu. The strongest lines of the calculated powder X-ray diffraction pattern are [dcalc Å (I%calc; Lasnierite, (Ca,Sr)(Mg,Fe)2Al(PO4)3, a new phosphate accompany- ing lazulite from Mt. Ibity, Madagascar: an example of structural hkl)]: 4.421 (83; 040), 3.802 (63, 131), 3.706 (100; 022), 3.305 (99; 141), characterization from dynamic refinement of precession electron 2.890 (90; 211), 2.781 (69; 221), 2.772 (67; 061), 2.601 (97; 023). It diffraction data on submicrometer sample. European Journal of was not possible to perform powder nor single-crystal X-ray diffraction Mineralogy, 31(2), 379–388. -
New Minerals Approved Bythe Ima Commission on New
NEW MINERALS APPROVED BY THE IMA COMMISSION ON NEW MINERALS AND MINERAL NAMES ALLABOGDANITE, (Fe,Ni)l Allabogdanite, a mineral dimorphous with barringerite, was discovered in the Onello iron meteorite (Ni-rich ataxite) found in 1997 in the alluvium of the Bol'shoy Dolguchan River, a tributary of the Onello River, Aldan River basin, South Yakutia (Republic of Sakha- Yakutia), Russia. The mineral occurs as light straw-yellow, with strong metallic luster, lamellar crystals up to 0.0 I x 0.1 x 0.4 rnrn, typically twinned, in plessite. Associated minerals are nickel phosphide, schreibersite, awaruite and graphite (Britvin e.a., 2002b). Name: in honour of Alia Nikolaevna BOG DAN OVA (1947-2004), Russian crys- tallographer, for her contribution to the study of new minerals; Geological Institute of Kola Science Center of Russian Academy of Sciences, Apatity. fMA No.: 2000-038. TS: PU 1/18632. ALLOCHALCOSELITE, Cu+Cu~+PbOZ(Se03)P5 Allochalcoselite was found in the fumarole products of the Second cinder cone, Northern Breakthrought of the Tolbachik Main Fracture Eruption (1975-1976), Tolbachik Volcano, Kamchatka, Russia. It occurs as transparent dark brown pris- matic crystals up to 0.1 mm long. Associated minerals are cotunnite, sofiite, ilin- skite, georgbokiite and burn site (Vergasova e.a., 2005). Name: for the chemical composition: presence of selenium and different oxidation states of copper, from the Greek aA.Ao~(different) and xaAxo~ (copper). fMA No.: 2004-025. TS: no reliable information. ALSAKHAROVITE-Zn, NaSrKZn(Ti,Nb)JSi401ZJz(0,OH)4·7HzO photo 1 Labuntsovite group Alsakharovite-Zn was discovered in the Pegmatite #45, Lepkhe-Nel'm MI. -
^ ^ the Journal Of
^^ The Journal of - Volume 29 No. 5/6 Gemmology January/April 2005 The Gemmological Association and Gem Testing Laboratory of Great Britain Gemmological Association and Gem Testing Laboratory of Great Britain 27 Greville Street, London EC1N 8TN Tel: +44 (0)20 7404 3334 • Fax: +44 (0)20 7404 8843 e-mail: [email protected] • Website: www.gem-a.info President: E A jobbins Vice-Presidents: N W Deeks, R A Howie, D G Kent, R K Mitchell Honorary Fellows: Chen Zhonghui, R A Howie, K Nassau Honorary Life Members: H Bank, D J Callaghan, E A Jobbins, J I Koivula, I Thomson, H Tillander Council: A T Collins - Chairman, S Burgoyne, T M J Davidson, S A Everitt, L Hudson, E A Jobbins, J Monnickendam, M J O'Donoghue, E Stern, P J Wates, V P Watson Members' Audit Committee: A J Allnutt, P Dwyer-Hickey, J Greatwood, B Jackson, L Music, J B Nelson, C H Winter Branch Chairmen: Midlands - G M Green, North East - N R Rose, North West -DM Brady, Scottish - B Jackson, South East - C H Winter, South West - R M Slater Examiners: A J Allnutt MSc PhD FGA, L Bartlett BSc MPhil FGA DCA, Chen Meihua BSc PhD FCA DGA, S Coelho BSc FCA DCA, Prof A T Collins BSc PhD, A G Good FCA DCA, D Gravier FGA, J Greatwood FGA, S Greatwood FGA DCA, G M Green FGA DGA, He Ok Chang FGA DGA, G M Howe FGA DGA, B Jackson FGA DGA, B Jensen BSc (Geol), T A Johne FGA, L Joyner PhD FGA, H Kitawaki FGA CGJ, Li Li Ping FGA DGA, M A Medniuk FGA DGA, T Miyata MSc PhD FGA, M Newton BSc DPhil, C J E Oldershaw BSc (Hons) FGA DGA, H L Plumb BSc FGA DCA, N R Rose FGA DGA, R D Ross BSc FGA DGA, J-C -
INTERNATIONAL GEMMOLOGICAL CONFERENCE Nantes - France INTERNATIONAL GEMMOLOGICAL August 2019 CONFERENCE Nantes - France August 2019
IGC 2019 - Nantes IGC 2019 INTERNATIONAL GEMMOLOGICAL CONFERENCE Nantes - France INTERNATIONAL GEMMOLOGICAL August 2019 CONFERENCE Nantes - France www.igc-gemmology.org August 2019 36th IGC 2019 – Nantes, France Introduction 36th International Gemmological Conference IGC August 2019 Nantes, France Dear colleagues of IGC, It is our great pleasure and pride to welcome you to the 36th International Gemmological Conference in Nantes, France. Nantes has progressively gained a reputation in the science of gemmology since Prof. Bernard Lasnier created the Diplôme d’Université de Gemmologie (DUG) in the early 1980s. Several DUGs or PhDs have since made a name for themselves in international gemmology. In addition, the town of Nantes has been on several occasions recognized as a very attractive, green town, with a high quality of life. This regional capital is also an important hub for the industry (e.g. agriculture, aeronautics), education and high-tech. It has only recently developed tourism even if has much to offer, with its historical downtown, the beginning of the Loire river estuary, and the ocean close by. The organizers of 36th International Gemmological Conference wish you a pleasant and rewarding conference Dr. Emmanuel Fritsch, Dr. Nathalie Barreau, Féodor Blumentritt MsC. The organizers of the 36th International Gemmological Conference in Nantes, France From left to right Dr. Emmanuel Fritsch, Dr. Nathalie Barreau, Féodor Blumentritt MsC. 3 36th IGC 2019 – Nantes, France Introduction Organization of the 36th International Gemmological Conference Organizing Committee Dr. Emmanuel Fritsch (University of Nantes) Dr. Nathalie Barreau (IMN-CNRS) Feodor Blumentritt Dr. Jayshree Panjikar (IGC Executive Secretary) IGC Executive Committee Excursions Sophie Joubert, Richou, Cholet Hervé Renoux, Richou, Cholet Guest Programme Sophie Joubert, Richou, Cholet Homepage Dr. -
Winter 1999 Gems & Gemology
WINTER 1999 VOLUME 35 NO. 4 TABLE OF CONTENTS EDITORIAL 173 Gems & Gemology Turns 65 Richard T. Liddicoat and Alice S. Keller 174 LETTERS FEATURE ARTICLE 176 Classifying Emerald Clarity Enhancement at the GIA Gem Trade Laboratory Shane F. McClure, Thomas M. Moses, Maha Tannous, pg. 185 and John I. Koivula NOTES AND NEW TECHNIQUES 186 Clues to the Process Used by General Electric to Enhance the GE POL Diamonds Karl Schmetzer 192 Diopside Needles as Inclusions in Demantoid Garnet from Russia: A Raman Microspectrometric Study Michael S. Krzemnicki pg. 187 196 Garnets from Madagascar with a Color Change of Blue-Green to Purple Karl Schmetzer and Heinz-Jürgen Bernhardt REGULAR FEATURES 202 Gem Trade Lab Notes 208 Gem News 224 Book Reviews 226 Gemological Abstracts 235 Index pg. 193 ABOUT THE COVER: In response to concerns expressed by the trade over the degree of pg. 201 clarity enhancement in emeralds, GIA Gem Trade Laboratory researchers have devised a methodology to establish the size, number, and position of filled fissures in an emerald, in order to classify the apparent degree of clarity enhancement achieved. The lead article in this issue reports on this research and the resulting classification system. The 10.5 ct emerald crystal in this gold and platinum pendant is from Jos, Nigeria. The pendant was designed by Elena Villa, and manufactured by Hans Dieter Krieger; it is courtesy of Gebrüder Bank, Idar-Oberstein, Germany. Photo © Harold & Erica Van Pelt––Photographers, Los Angeles, California. Color separations for Gems & Gemology are by Pacific Color, Carlsbad, California. Printing is by Fry Communications, Inc., Mechanicsburg, Pennsylvania.