Depok, 4th December 2015

Subject : Invitation to join MCEE workshop

Attachment : 5 pages

Dear Rodiansono, Dr. Eng At Lambung Mangkurat University

Paper Title : Synthesis of Ni/Pd-M (M= Ag, Co, and Fe) alloy catalysts for hydrogenolysis/ hydrodeoxygenation of bio-oil and liquefied low rank coal into chemicals and fuels.

On behalf of the Program Committee. I am delighted to inform that your abstract has been accepted as ORAL PRESENTATION at the Materials Chemistry for Energy and the Environment Workshop which will be held on January 26th – 29th, 2016 at Novotel Bogor, . Please also have your poster ready for display. We appreciate your participation and look forward to welcoming you to MCEE Workshop in Bogor, 26th -29th January 2016.

Warm regards,

Dr. Yuni K. Krisnandi Co-Host MCEE Workshop

Attachment 1: List of Participants from Indonesia

Affiliation No Name 1 Aldes Lesbani 2 Kusmiyati University Surakarta 3 Fitria Rahmawati 4 Catherina M. Bijang Pattimura University 5 Elvina Dhiaul Iftitah Brawijaya University 6 Rodiansono Lambung Mangkurat University 7 Muhammad Zakir Hasanudin University 8 Suwardiyanto Jember University 9 Is Fatimah Univ Islam Negri Jogjakarta 10 Kun Harismah University Muhammadiyah Surakarta 11 Muliadi Ramli University of Syiah Kuala 12 Rahmat Wibowo 13 Arie wibowo ITB 14 Indri Badria Adilina LIPI - Chemistry 15 Nazarudin University of 16 Siti Alaa’ Mataram University 17 Kartika Afriani AKA 18 Boy Fachri Jember University 19 Hedi Surachman Universitas Indonesia

Attachment 2: Time Table of MCEE Workshop 1ST Day : Tuesday, 26th January 2016

08.30 -09.00 Opening remarks Yuni Krisnandi, Russell Howe 09.00 -09.30 Catalytic Materials in Petroleum Fuel Hery Haerudin, Pertamina Processing 09.30-10.30 Introduction meetings (with coffee) 10.30-11.30 A Molecular Perspective of David Lennon, University of Heterogeneous Catalysis Glasgow 11.30-12.00 Catalytic Oxidative Desulfurisation of Aldes Lesbani, Sriwijaya Benzothiphene using Supported University Polyoxometallate Catalysts 12.00-12.30 Electric Field Assisted Chemical Russell Binions, Queen Vapour Deposition of Enhanced Mary University of London Photocatalytic Materials 12.30-13.00 Increasing the Concentration of Kusmiyati, University Bioethanol Fuel by Dehydration Muhammadiyah Surakarta Process Using Molecular Sieve 13.00 – 14.00 Lunch 14.00-15.00 Boron-doped Diamond Electrodes for Ivan Tribidisari, University Electrocatalysis Applications of Indonesia 15.00-15.30 Oxygen Reduction at Nanoscale Veronica Celorrio, Transition Metal Oxides University of Bristol

15.30-16.00 Tea/coffee 16.00-16.30 Photocatalytic hydrogen production Fitria Rahmawati, Sebelas with TiO2/Graphite as a catalyst Maret University 16.30-17.00 Rhodium and molybdenum based Marco Conte, University of catalysts for the selective oxidation of Sheffield organic substrates: autoxidation and structure-activity correlations 17.00-17.30 Study on cyclisation and Elvina Dhiaul Iftitah, hydrogenation of (r)-(+)-Citronelal Brawijaya University based on ZnBr2/γ-Al2O3 and Ni/ γ- Al2O3 catalysts 17.30-18.00 Hierarchically porous zeolites for Volkan Degirmenci, energy and environment applications University of Warwick 18.00-19.00 Poster session 19.00 Evening meal

2nd Day : Tuesday, 27th January 2016

08.30-09.30 Atomic-ensemble effects and non- Angel Cuesta, University of covalent interactions at the electrode- Aberdeen electrolyte interface 09.30-10.00 Synthesis of Ni/Pd-M (M= Ag, Co, Rodiansono, Lambung and Fe) alloy catalysts for Mangkurat University hydrogenolysis/ hydrodeoxygenation of bio-oil and liquefied low rank coal into chemicals and fuels. 10.00-10.30 Tea/coffee 10.30-11.00 Challenges in the in-situ structural Yvonne Gründer, University characterisation of electrochemical of Liverpool interfaces 11.00-11.30 Development of novel carbon Muhammad Zakir, nanoporous materials from biomass University Hasanudin based resources 11.30-12.00 Low-Dimensional Carbon and TiO2 Robert Menzel, University Nanostructures for Applications in of Leeds. Heterogeneous Catalysis and CO2 Storage 12.00-12.30 Highly Active Mo/ZSM-5 Catalysts Suwardiyanto, Jember for Methane Dehydroaromatization. University 12.30-13.00 Mechanochemical synthesis of Manuel Ojeda, advanced nanomaterials for catalytic Heriot-Watt University applications. 13.00-14.00 Lunch 14.00-15.00 Preparation and Characterization of Jarnuzi Gunlazuardi, Highly Ordered Titania Nanotubes for Universitas Indonesia Development of Modified CdS Sensitized Solar Cell Having Catalytic Zone as Artificial Photosyntesis for Hyndrogen Production 15.00-15.30 Preparation of Cu/TiO2-pillared clays Is Fatimah, University Islam and Sn/TiO2-pillared clays Negri Jogjakarta Photocatalyst for Dye Degradation 15.30-16.00 Tea/coffee 16.00-16.30 A new synthetic route for an effective Paramaconi Rodriguez, preparation of metal alloy University of Birmingham nanoparticles and its use as active electrocatalyst and photocatalyst 16.30-17.00 Synthesis of N-(2-hexyldecyl)-2,7- Kun Harismah, University linked Carbazole Polymers by Suzuki Muhammadiyah Surakarta Coupling Reaction for LED Applications 17.00-17.30 Designing supported bimetallic Sankar Meenakshisundaram, nanoalloy catalysts for a green and Cardiff University sustainable future. 17.30-18.00 Modification of Aceh Dolomite Muliadi Ramli, University Mineral as Solid Inorganic Base of Syiah Kuala Catalyst and Its Application on Transesterification Reaction for Biodesel Synthesis 18.00-19.00 Poster session 19.00 Evening meal

3rd Day : Tuesday, 28th January 2016

08.30-09.30 Metal-Oxide/ZSM-5 as Heterogeneous Yuni Krisnandi, University Catalysts in Biomass Conversion of Indonesia 09.30-10.00 Carbon Nitrides: New Electroactive Ana Jorge, University Materials for Energy Applications College London 10.00-10.30 Coffee/tea 10.30-11.00 Electrochemical reduction of CO2 Rahmat Wibowo, University using Cu based catalyst of Indonesia 11.00-11.30 Probing the Carbonaceous Fallout in Stephen Sproules, MTG Catalysis by Magnetic University of Glasgow, Resonance 11.30-12.00 Simple Preparation of Iron Oxide Arie Wibowo, Institute of Nanoparticles at Cellulose and Their Technology Bandung Photochemical Catalytic Behavior 12.00-12.30 Materials and devices for Mark D. Symes, University electrochemical water splitting: a fresh of Glasgow look at some old catalysts and some new catalysts for old applications 12.30-13.00 Design and modification of bentonite Indri Badria Adilina, LIPI clays as efficient heterogeneous Chemistry catalysts for environmentally friendly conversions of biomass to innovative chemicals 13.00-14.00 Lunch 14.00-15.00 Exploring Reaction Pathways in Russell Howe, University of Catalysis through Spectroscopy Aberdeen 15.00-15.30 Gold Catalysts for Sustainable Xiao-Dong Wang, Chemical Processing University of Aberdeen 15.30-16.00 Tea/coffee 16.00-16.30 Aplications of Porous Materials from Nazarudin, University of Industrial Wastes Jambi 16.30-17.00 Enantioselective Heterogeneous David Watson, University of Catalysis Surrey, 17.00-17.30 Design of Bentonite Acid Modified Catherina M. Bijang, Electrodes in Cyanide Biosensors University Pattimura 17.30-18.00 Material and reactor innovation for Jin Xuan, Heriot-Watt low carbon energy University 18.00-19.00 Poster session 19.00 Evening meal

4th Day : Tuesday, 29th January 2016

08.30-09.00 Royal Society of Chemistry and Sarah Thomas, Royal research collaborations Society of Chemistry 09.00-09.30 British Council and research Speaker from British collaborations Council to be advised 09.30-10.00 Indonesian funding for research Eko Prasetyo, LPDP collaborations 10-11.30 Break-out sessions 1 Three parallel sessions: catalysis, photocatalysis, electrochemistry (accompanied by coffee and tea) 11.30-13.30 Friday prayers and lunch 13.30-15.00 Break-out sessions 2 Three parallel sessions: catalysis, photocatalysis, electrochemistry 15.00-16.30 Reports from breakout sessions and wrap up (accompanied by coffee and tea)

Synthesis of Ni/Pd-M (M= Co, Ag, Fe) alloy catalysts for hydro-deoxygenation of bio-oil components

Rodiansonoa* , Maria Dewi Astutia, and Shogo Shimazub aDepartment of Chemistry, Lambung Mangkurat University, Banjarbaru, South 70713. bGraduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522. *corresponding author: [email protected] or [email protected]

ABSTRACT Biomass feedstock valorisations are currently being explored for the production of bio-based platform chemicals, fuels, and various commodity products by using bimetallic-based heterogeneous catalysts. The use of bimetallic catalysts is a promising option for biomass feedstock upgrading, as the interaction between metals can modify the surface properties of the catalyst meet with the complex surface. A simple hydrothermal treatment was applied to produce Ni-Sn alloys both bulk and supported under mild conditions. This synthetic method offers easy process, cost-effective, and eco-friendly procedure.[1,2] Tabel 1. Results of hydrogenolysis of furfural (FFald) using the synthesised bimetallic Ni-M alloy catalysts

Reaction conditions: cat., 44 mg; substrate, 1.2 mmol; solvent, EtOH/H2O, a H2 3.0 MPa 433 K, 12 h. Determined by GC using an internal standard technique. bDetermined by GC and GC-MS. cIt may be dimerization product of FFald or FFalc according to GC and GC-MS data. It can be observed that the catalysts demonstrated high activity in the hydrogenolysis of biomass-derived furfural, whereas the product distributions are strongly depended on the catalyst structure and the composition. In case of bimetallic Ni-Sn both bulk and supported, the main products were tetrahydrofurfuryl alcohol (THFalc), methyl furan (MeTF), and methyl tetrahydrofuran (MeTHF) (entries 1-3). On the other hand, bimetallic Ni-M (M= Co, Fe, Ag) catalyst provided high yield of MeTHF as hydrogenolysed product when the amount of M=Co, Fe, Ag metals was increased (entries 4-8). Tabel 2. Results of hydrogenolysis of phenol (PhOH) using the synthesised bimetallic Ni-M alloy catalysts

Reaction conditions: cat., 44 mg; substrate, 1.2 mmol; solvent, EtOH/H2O, a H2 3.0 MPa 433 K, 12 h. Determined by GC using an internal standard technique. bDetermined by GC and GC-MS.

In the hydrogenolysis of phenol, the Ni-Ag(3.0), R-Ni/AlOH, and Pd/C catalysts are active for the hydrogenation of benzene ring to give cyclohexanol as the main products (entries 7, 9, and 10). While the conversion of phenol was >99%, bimetallic Ni-M (Sn, Co, Ag) catalysts provided the hydrogenolysis of benzene then subsequently hydrogenated to cyclohexane (entries 1-6). As a conclusion inexpensive Ni/Pd-M (M= Co, Ag, Fe) based alloy catalysts exhibited high activity and selectivity in the hydro-deoxygenation of bio-oil components of furfural and phenol. The presence of second metal to form alloy may enhance the activity and selectivity of Ni metal catalyst toward methyl furan, methyl tetrahydrofuran, methyl benzene, and methyl cyclohexane products.

References [1] (a) Rodiansono, T. Hara, N. Ichikuni, S. Shimazu, Catal. Sci. T echnol., 2012, 2, 2139-2145. (b) Rodiansono, T. Hara, N. Ichikuni, S. Shimazu, BCREC, 2014,9(1), 53-59.