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Safety Data Sheet SAFETY DATA SHEET 1. Product and Company Identification Product identifier BOILERMATE 3300C Other means of identification Not available Recommended use Boiler Water Treatment Recommended restrictions None known. Manufacturer information Miura America Co., Ltd 2200 Steven B Smith Blvd Rockmart, GA 30153 USA Phone: 678-685-0929 Toll Free: 1-888-309-5574 Fax: 678-685-0930 Emergency Phone: 1-800-424-9300 (CHEMTREC) 2. Hazards Identification Physical hazards Flammable liquids Category 3 Health hazards Acute toxicity, oral Category 4 Acute toxicity, dermal Category 3 Skin corrosion/irritation Category 1 Serious eye damage/eye irritation Category 1 Reproductive toxicity Category 2 Environmental hazards Not classified. WHMIS 2015 defined hazards Not classified Label elements Signal word Danger Hazard statement Flammable liquid and vapor. Harmful if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Suspected of damaging fertility. Precautionary statement Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Ground and bond container and receiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe mist or vapor. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Wear protective gloves, protective clothing, eye protection and face protection. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Response In case of fire: Use appropriate media to extinguish. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a POISON CENTER or doctor. Wash contaminated clothing before reuse. Specific treatment (see information on this label). IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF exposed or concerned: Get medical attention. Storage Store in a well-ventilated place. Keep cool. Store locked up. Disposal Dispose of container in accordance with local, regional, national and international regulations. #17344 Page: 1 of 10 Issue date 01-August-2019 WHMIS 2015: Health Hazard(s) None known not otherwise classified (HHNOC) WHMIS 2015: Physical None known Hazard(s) not otherwise classified (PHNOC) Hazard(s) not otherwise None known. classified (HNOC) Supplemental information None. 3. Composition/Information on Ingredients Mixture Chemical name Common name and synonyms CAS number % Cyclohexylamine 108-91-8 10 - 30 * Morpholine 110-91-8 10 - 30 * All concentrations are in percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume. Composition comments *CANADA GHS: The exact percentage (concentration) of composition has been withheld as a trade secret. US GHS: The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of §1910.1200. 4. First Aid Measures Inhalation IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor. Skin contact IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. Immediately call a POISON CENTER or doctor. Wash contaminated clothing before reuse. Specific treatment (see information on this label). Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor. Ingestion IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor. Most important Burning pain and severe corrosive skin damage. symptoms/effects, acute and Causes serious eye damage. Symptoms may include stinging, tearing, redness, swelling, and delayed blurred vision. Permanent eye damage including blindness could result. Indication of immediate Symptoms may be delayed. medical attention and special treatment needed General information Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. Keep away from sources of ignition. No smoking. Avoid contact with eyes and skin. Wear rubber gloves and chemical splash goggles. Keep out of reach of children. 5. Fire Fighting Measures Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide. Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from Vapors may travel considerable distance to a source of ignition and flash back. Vapors may form the chemical explosive mixtures with air. Special protective equipment Firefighters should wear full protective clothing including self-contained breathing apparatus. and precautions for firefighters Fire-fighting Move containers from fire area if you can do so without risk. equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards Flammable liquid and vapor. Hazardous combustion May include and are not limited to: Oxides of nitrogen. Oxides of carbon. Ammonia. products 6. Accidental Release Measures Personal precautions, Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Do not protective equipment and touch damaged containers or spilled material unless wearing appropriate protective clothing. emergency procedures Ventilate closed spaces before entering them. Do not breathe mist or vapor. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. #17344 Page: 2 of 10 Issue date 01-August-2019 Methods and materials for Stop leak if you can do so without risk. Dike the spilled material, where this is possible. Cover with containment and cleaning up plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. Prevent entry into waterways, sewer, basements or confined areas. For waste disposal, see section 13 of the SDS. Environmental precautions Do not discharge into lakes, streams, ponds or public waters. 7. Handling and Storage Precautions for safe handling Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Avoid contact with eyes, skin and clothing. Wear appropriate personal protective equipment. Do not breathe mist or vapor. Use only with adequate ventilation. Avoid prolonged exposure. Use good industrial hygiene practices in handling this material. Wash thoroughly after handling. When using, do not eat, drink or smoke. Conditions for safe storage, Store in a cool, dry place out of direct sunlight. including any incompatibilities Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Keep out of reach of children. Store locked up. 8. Exposure Controls/Personal Protection Occupational exposure limits Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2) Components Type Value Cyclohexylamine (CAS TWA 41 mg/m3 108-91-8) 10 ppm Morpholine (CAS 110-91-8) TWA 71 mg/m3 20 ppm Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and Safety Regulation 296/97, as amended) Components Type Value Cyclohexylamine (CAS TWA 10 ppm 108-91-8) Morpholine (CAS 110-91-8) TWA 20 ppm Canada. Manitoba OELs (Reg. 217/2006, The Workplace Safety And Health Act) Components Type Value Cyclohexylamine (CAS TWA 10 ppm 108-91-8) Morpholine (CAS 110-91-8) TWA 20 ppm Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents) Components Type Value Cyclohexylamine (CAS TWA 10 ppm 108-91-8) Morpholine (CAS 110-91-8) TWA 20 ppm Canada. Quebec OELs. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment) Components Type Value Cyclohexylamine (CAS TWA 41 mg/m3 108-91-8) 10 ppm Morpholine (CAS 110-91-8) TWA 71 mg/m3 20 ppm US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Components Type Value Morpholine (CAS 110-91-8) PEL 70 mg/m3 20 ppm #17344 Page: 3 of 10 Issue date 01-August-2019 US. ACGIH Threshold Limit Values Components Type Value Cyclohexylamine (CAS TWA 10 ppm 108-91-8) Morpholine (CAS 110-91-8) TWA 20 ppm US. NIOSH: Pocket Guide to Chemical Hazards Components Type Value Cyclohexylamine (CAS TWA 40 mg/m3 108-91-8) 10 ppm Morpholine (CAS 110-91-8) STEL 105 mg/m3 30 ppm TWA 70 mg/m3 20 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Exposure guidelines See above Canada - Alberta OELs: Skin designation Morpholine (CAS 110-91-8) Can be absorbed through the skin. Canada - British Columbia OELs: Skin designation Morpholine (CAS 110-91-8) Can be absorbed through the skin. Canada - Manitoba OELs: Skin designation Morpholine (CAS 110-91-8) Can be absorbed through the skin. Canada - Ontario OELs:
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