Quality Assurance Project Plan (QAPP) for the Biological and Water Quality Survey of Ohio’s Large Rivers 2020-2021
Ohio EPA Technical Report AMS/2020-LRGRV-1 Division of Surface Water July 2020
TMDL DEVELOPMENT |
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Quality Assurance Project Plan (QAPP) for the Biological and Water Quality Survey of Ohio’s Large Rivers 2020 - 2021
July 2020
Prepared by: Ohio Environmental Protection Agency Division of Surface Water Lazarus Government Center 50 W. Town Street, Suite 700 Columbus, Ohio 43215
Ohio Environmental Protection Agency Ohio Environmental Protection Agency Ecological Assessment Section Central District Office 4675 Homer Ohio Lane 50 W. Town Street, Suite 700 Groveport, Ohio 43125 Columbus, Ohio 43215
Ohio Environmental Protection Agency Ohio Environmental Protection Agency Southeast District Office Southwest District Office 2195 Front Street 401 E. Fifth Street Logan, Ohio 43138 Dayton, Ohio 45402
Ohio Environmental Protection Agency Ohio Environmental Protection Agency Northwest District Office Northeast District Office 347 N. Dunbridge Road 2110 East Aurora Road Bowling Green, Ohio 43402 Twinsburg, Ohio 44087
Mike DeWine Governor, State of Ohio
Laurie A. Stevenson Director, Ohio Environmental Protection Agency
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
A1 – Title and Approval Quality Assurance Project Plan for the Biological and Water Quality Study of Ohio’s Large Rivers, 2020 - 2021.
______Date: ______8/24/2020 Brian Hall, Assistant Chief
______Date: ______07/29/2020 Mari Piekutowski, AMS Manager
______Date: ______8/17/2020 Ellie Hagen, DSW Quality Assurance Coordinator
______Date: ______8-3-20 Bill Zawiski, NEDO District Water Quality Supervisor
______Date: ______8/24/20 Dan Glomski, NWDO District Water Quality Supervisor
______Date: 07/27/2020______Jeff Lewis, CDO District Water Quality Supervisor
______Date: ______07/27/2020 Joby Jackson, SWDO District DSW Manager
______Date: ______Rachel Taulbee, Study Team Leader /SEDO Water Quality Supervisor 7/27/2020
Page 3 of 55 AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
A2 – Table of Contents Contents A1 – Title and Approval ...... 3 A2 – Table of Contents ...... 4 A3 – Distribution List...... 6 A4 – Project Organization and Communication...... 7 A5 – Background ...... 10 A6 – Project Description ...... 10 A7 – Data Quality Objectives ...... 11 Establish a Temporally Unbiased Dataset for Ohio’s LRAUs ...... 12 Monitor and Assess Ohio’s Waters ...... 13 Assess Causes and Sources of Impairment ...... 13 Support Water Quality Standards Development ...... 14 Support NPDES Permitting ...... 15 TMDL Implementation ...... 15 A8 – Special Training/Certification ...... 15 A9 – Documents and Records...... 15 Section B – Data Generation and Acquisition...... 16 B1 – Sampling Process and Design ...... 16 B2 – Sampling Methods ...... 16 Stream Habitat Evaluation ...... 16 Biological Community Assessment ...... 17 Water Quality Sonde Deployments ...... 17 Temperature Data...... 17 Surface Water Chemistry ...... 17 Bacteria ...... 17 Chlorophyll a ...... 18 Sediment ...... 18 Fish Tissue ...... 18 B3 – Sample Handling and Custody ...... 18 B4 – Analytical Methods...... 18 B5 – Quality Control ...... 19 Stream Habitat Evaluation ...... 19
Page 4 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Water Quality Sonde Deployments ...... 19 Temperature Data...... 19 Surface Water Chemistry ...... 19 Sediment ...... 20 B6 – Instrument/Equipment Testing, Inspection and Maintenance ...... 20 B7 – Instrument Calibration and Frequency ...... 20 B8 – Inspection/Acceptance of Supplies ...... 20 B9 – Data Acquisition ...... 20 B10 – Data Management ...... 20 Section C – Assessment and Oversight of Data Collection ...... 21 C1 – Assessment and Response Actions ...... 21 C1.1 – Assessments ...... 21 C1.2 - Response Actions ...... 21 C1.3 - Reporting and Resolution of Issues ...... 22 C1.4 - Data Completeness ...... 22 C2 – Reports to Management ...... 22 Section D – Data Validation and Usability...... 22 D1 – Data Review, Validation and Verification Requirements...... 22 D2 – Validation and Verification Methods ...... 23 D3 – Reconciliation with Data Quality Objectives ...... 24 Appendix 1 – Summary of Sampling Effort ...... 25 Appendix 2 – Streams, sampling locations and sampling types...... 26 Appendix 3 – NPDES permitted facilities (major dischargers) ...... 36 Appendix 4 – List of physical/chemical parameters ...... 42 Appendix 5 – Safety contacts and hospital locations ...... 48 Appendix 6 – US EPA, Chicago Regional Laboratory (CRL) pesticide sample collection procedures ...... 53 Appendix 7 – US EPA, Chicago Regional Laboratory pesticide sample analytes ...... 54 References ...... 55
Page 5 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
A3 – Distribution List This QAPP will be distributed to the following division management and staff, saved on the Division of Surface Water (DSW) collaboration site and posted on the DSW Biological and Water Quality Monitoring and Assessment webpage.
Table 1 — Distribution List. Name/Title Contact Email/Phone DSW Central Office Tiffani Kavalec, Environmental Administrator [email protected] (614) 644-3538 Brian Hall, Asst. Environmental Administrator [email protected] (614) 644-2033 Mari Piekutowski, Environmental Manager [email protected] (614) 644-2876 Audrey Rush, Environmental Manager [email protected] (614) 644-2035 Melinda Harris, Environmental Supervisor [email protected] (614) 728-1357 Keith Orr, Environmental Supervisor [email protected] (614) 644-2885 Chris Skalski, Environmental Specialist 3 [email protected] (614) 644-2144 Ellie Hagen, Environmental Specialist 2 [email protected] (614) 705-1011 James Kiourtsis, Environmental Specialist 2 [email protected] (614) 644-2148 Sarah Becker, Environmental Specialist 3 [email protected] (614) 728-2385 Chuck Boucher, Environmental Specialist 2 [email protected] (614) 836-8776 Ben Rich, Environmental Specialist 2 [email protected] (614) 836-8772 Angela Dripps, Environmental Specialist 2 [email protected] (614) 836-8798 Bob Miltner, Environmental Specialist 3 [email protected] (614) 836-8796 Mariah Hood, Environmental Specialist 2 [email protected] (614) 644-2865 Ed Moore, Environmental Specialist 2 [email protected] (614) 836-8785 DSW Northwest District Office Dan Glomski, Environmental Supervisor [email protected] (419) 373-3023 Chris Riddle, Environmental Specialist 2 [email protected] (419) 373-3101 Ben Smith, Environmental Specialist 2 [email protected] (419) 373-3027 DSW Southwest District Office Joby Jackson, DSW Manager [email protected] (937) 285-6029 Laura Marshall, Environmental Specialist 2 [email protected] (937) 285-6031 Michelle Waller, Environmental Specialist 2 [email protected] (937) 285-6028 DSW Southeast Office Rachel Taulbee, Environmental Supervisor [email protected] (740) 380-5433 Kelly Capuzzi, Environmental Specialist 2 [email protected] (740) 380-5283 Randy Spencer, Environmental Specialist 2 [email protected] (740) 380-5240 DSW Northeast Office Bill Zawiski, Environmental Supervisor [email protected] (330) 963-1134 Jennifer Carlson, Environmental Specialist 2 [email protected] (330) 963-1228 Greg Orr, Environmental Specialist 2 [email protected] (330) 963-1189 Mandy Razzano, Environmental Specialist 2 [email protected] (330) 963-1269 DSW Central District Office Jeff Lewis, Environmental Supervisor [email protected] (614) 466-2657 Rahel Babb, Environmental Specialist 2 [email protected] (614) 728-3855 Chloe Welch, Environmental Specialist 2 [email protected] (614) 728-3852 DES Jennifer Kraft, Environmental Manager [email protected] (614) 644-3020 Steve Roberts, Environmental Supervisor [email protected] (614) 644-4225 DDAGW Central Office Ruth Briland, Environmental Specialist 2 [email protected] (614) 369-4045
Page 6 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
A4 – Project Organization and Communication Table 2 — Roles and Responsibilities. Individual(s) Assigned: Responsible for: Authorized to: Division of Surface Water Tiffani Kavalec/Brian Hall Overall administration of Confirm project existence; approve staff and DSW Chief/Assistant Chief division. capital resources; approve plans; edit reports. Mari Piekutowski Overall management of Assign staff; approve plans; edit reports. Assessment & Modeling monitoring section. Section Manager Melinda Harris Coordination of biennial Assign and support staff; edit reports. TMDL and IR Supervisor Integrated Report update; TMDL program development. Kate Hamilton Leading TMDL projects. Write assigned TMDL sections. TMDL Staff Keith Orr Supporting modeling field Obtain approvals and signatures; develop Modeling & Assessment crews with supplies, budgets; conduct field audits; edit reports. Unit Supervisor equipment and training. Will Kiourtsis Dissolved oxygen surveys, Help plan study. Schedule and complete assigned Modeling & Assessment stream flow measurements field activities. Tabulate data and write Unit Staff and chemistry sampling. discussion for technical report. Audrey Rush Quality management (QAPPs, Approve plans and edit reports. Standards and Tech SOPs); staff training; water Support Section Manager quality standard rules. Ellie Hagen DSWs quality management Develop and implement field QA/QC guidelines. Standards and Tech program. Track field QA/QC and staff training. Support QA Officer Review and approve QAPP. Chris Skalski Water quality standard Help plan study. Make recommended beneficial Standards and Tech criteria development and rule use changes. Support Lead Worker updates. Mariah Hood Representing agency in fish Help plan study. Make waterbody specific Standards and Tech and wildlife consumption and consumption and contact advisory Support Staff contact advisory matters. recommendations. Sarah Becker Assist with property access, Help plan study. Provide landowner information Ecological Assessment Unit track project progress, for access consent. Upload fish, bug and Lead Worker managing data and compiling chemistry data into EA3. Review and comment information for Integrated on reports. Write assigned Integrated Report Report. sections. Ecological Assessment Unit Fish population and stream Help plan study. Schedule and complete assigned Fish Crew Leaders habitat assessments. field activities. Tabulate data and write discussion for technical report. Ecological Assessment Unit Macroinvertebrate Help plan study. Schedule and complete assigned Bug Crew Leaders population assessments. field activities. Tabulate data and write discussion for technical report. District Section Managers Implementing division goals Review documents and reports; suggest changes District Surface Water at the district level. and edits; obtain approvals and signatures. District Compliance NPDES permit related issues. Obtain wastewater and storm water permit Supervisors information needed for planning and reporting.
Page 7 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Individual(s) Assigned: Responsible for: Authorized to: District Water Quality Unit Supporting water quality field Obtain approvals and signatures; develop Supervisors crews with supplies, budgets; conduct field audits; edit reports. equipment and training.
District Water Quality Water and sediment data Help plan study. Schedule and complete assigned Units collection, validation and field activities. Tabulate data and write management. discussion for technical report. Division of Environmental Services Jennifer Kraft Overall administration of lab Help solve lab information management system Program Administrator activities. problems. Develop analytical methods and SOPs. Steve Roberts DES quality management Oversee data completeness, validation and QA Officer program. delivery. Division of Drinking and Ground Waters Ruth Briland (CO) Harmful Algae Bloom Coordinate with DSW on drinking water intake program implementation. and inland lake monitoring. District Source Water Source Water Assessment and Coordinate with DSW on water source protection Protection Staff Protection plans. issues.
Page 8 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Figure 1 — Organization Chart
Page 9 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
A5 – Background Ohio EPA is conducting a biological and water quality survey of Ohio’s large river assessment units (LRAUs). Large rivers are those with drainage areas 500 mi2 and larger. The survey will consist of an intensive ambient assessment of sites placed at approximately 8-mile intervals and will be conducted during the 2020 and 2021 field sampling seasons. Because biological assemblages change very little over distance in large rivers, one site can effectively represent an eight-mile reach. In other words, an 8-mile reach can be considered a population element. In this light, the survey is essentially a census, and is being proposed because samples collected from targeted surveys in the past were temporally and spatially biased (by design) such that the results from those surveys cannot be generalized to represent the entire state without interjecting those biases. The census will provide a statewide estimate of condition and attainment status, as well as an estimate of pollution gradients affecting large rivers. Thus, information from the survey will serve as a baseline for future comparisons and can also be used to guide site selection for targeted surveys in project areas in future sampling years. Ambient biology, macro-habitat and water quality data will be collected and evaluated. The statewide LRAU assessment sampling will be conducted over a two- year timeframe; however, all sampling sites on a river will be sampled during the sampling season of one calendar year. Ohio EPA has developed and implemented COVID-19 Standard Operating Procedures (SOPs) for water quality sampling. These SOPS are available upon request. A6 – Project Description The study area encompasses all LRAUs in the state of Ohio. River segments that drain >500 mi2 are categorized as LRAUs. This includes 45 river segments in 30 rivers.
Table 3: Large River Assessment Units LRAU River Segment Length (mi) 04100003 90 01 St. Joseph River Mainstem (Fish Creek to IN border) 11.25 04100005 90 01 Maumee River Mainstem (IN border to Tiffin River) 42.11 04100006 90 01 Tiffin River Mainstem (Brush Creek to mouth) 19.67 04100007 90 01 Auglaize River Mainstem (Ottawa River to mouth) 12.86 04100008 90 01 Blanchard River Mainstem (Dukes Run to mouth) 35.65 04100009 90 01 Maumee River Mainstem (Tiffin River to Beaver Creek) 34.44 04100009 90 02 Maumee River Mainstem (Beaver Creek to Maumee Bay) 31.32 04100011 90 01 Sandusky River Mainstem (Tymochtee Creek to Wolf Creek) 43.00 04100011 90 02 Sandusky River Mainstem (Wolf Creek to Sandusky Bay) 22.73 04110002 90 01 Cuyahoga River Mainstem (Brandywine Cr. to mouth); including old 25.34 channel 04110004 90 01 Grand River Mainstem (Mill Creek to mouth) 41.28 05030103 90 01 Mahoning River Mainstem (Eagle Creek to Pennsylvania Border) 35.39 05030204 90 01 Hocking River Mainstem (Scott Creek to Margaret Creek) 32.58 05030204 90 02 Hocking River (Margaret Creek to Ohio River) 36.38 05040001 90 01 Tuscarawas River Mainstem (Chippewa Creek to Sandy Creek) 30.12 05040001 90 02 Tuscarawas River Mainstem (Sandy Creek to Stillwater Creek) 26.05 05040001 90 03 Tuscarawas River Mainstem (Stillwater Creek to Muskingum River) 47.05 05040001 90 04 Sandy Creek Mainstem (Bear Run to mouth) 3.19
Page 10 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
05040002 90 01 Mohican River Mainstem (entire length) 27.58 05040003 90 01 Walhonding River Mainstem (entire length) 23.19 05040003 90 02 Killbuck Creek Mainstem (Laurel Creek to mouth) 21.18 05040004 90 01 Muskingum River Mainstem (Tuscarawas/Walhonding confluence to 34.94 Licking River) 05040004 90 02 Muskingum River Mainstem (Licking River to Meigs Creek) 46.78 05040004 90 03 Muskingum River Mainstem (Meigs Creek to Ohio River) 29.42 05040005 90 01 Wills Creek Mainstem (Salt Fork to mouth); excluding Wills Creek Lake 44.06 05040006 90 01 Licking River Mainstem (entire length); excluding Dillon Lake 30.21 05060001 90 01 Scioto River Mainstem (L. Scioto R. to Olentangy R.); excluding 32.70 O'Shaughnessy and Griggs reservoirs 05060001 90 02 Scioto River Mainstem (Olentangy River to Big Darby Creek) 31.42 05060001 90 03 Olentangy River Mainstem (Unnamed Trib. RM 9.99 to mouth) 9.99 05060001 90 04 Big Walnut Creek Mainstem (Alum Creek to mouth) 15.32 05060001 90 05 Big Darby Creek Mainstem (Springwater Run to mouth) 24.00 05060002 90 01 Scioto River Mainstem (Big Darby Creek to Paint Creek) 37.30 05060002 90 02 Scioto River Mainstem (Paint Creek to Sunfish Creek) 36.68 05060002 90 03 Scioto River Mainstem (Sunfish Creek to Ohio River) 26.82 05060002 90 04 Salt Creek Mainstem (entire length) 4.50 05060003 90 01 Paint Creek Mainstem (Paint Creek Lake dam to mouth) 39.17 05080001 90 01 Great Miami River Mainstem (Tawawa Creek to Mad River) 48.93 05080001 90 02 Stillwater River Mainstem (Greenville Creek to mouth) 32.38 05080001 90 03 Mad River Mainstem (Donnels Creek to mouth) 18.38 05080002 90 01 Great Miami River Mainstem (Mad River to Four Mile Creek) 43.10 05080002 90 02 Great Miami River Mainstem (Four Mile Creek to Ohio River) 38.38 05080003 90 01 Whitewater River Mainstem (entire length) 8.26 05090101 90 01 Raccoon Creek Mainstem (Little Raccoon Creek to mouth) 37.55 05090202 90 01 Little Miami River Mainstem (Caesar Creek to O'Bannon Creek) 26.92 05090202 90 02 Little Miami River Mainstem (O'Bannon Creek to Ohio River) 24.00
A7 – Data Quality Objectives The data collected during this large river census survey fulfills multiple objectives:
• Establish a state-wide estimate of the condition of Ohio’s LRAUs • Assess and report on the status of LRAUs as required by Clean Water Act (CWA) 305(b) and 303(d) • Assess causes and sources of impairment • Support water quality standards development • Support National Pollutant Discharge Elimination System (NPDES) permitting • Total Maximum Daily Limitation (TMDL) implementation
Page 11 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Establish a Temporally Unbiased Dataset for Ohio’s LRAUs The monitoring strategy that was employed by Ohio EPA in previous years yielded detailed information about specific basins at specific points in time. The objective of conducting bioassessments on all of Ohio’s LRAUs during a two-year sampling season is to establish a state-wide dataset that minimizes temporal bias. In addition to bioassessments, continuous temperature measurements will be collected at select sites in order to establish a baseline temperature profile for a two-month period during the sampling index period. Whole body fish tissue samples will also be collected for an ecological risk assessment for large rivers and to capture a state-wide snapshot to compare with historical and future whole body sample collections.
Page 12 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Monitor and Assess Ohio’s Waters Under Section 305(b) of the CWA, Ohio EPA is required to assess and report on the quality of Ohio’s waters. Ohio EPA determines attainment/non-attainment status of water quality standards in three main ways:
• Biological assessments determine attainment/non-attainment of aquatic life uses (ALU) as codified in OAC 3745-1-07, Table 7-1. Numerical biological criteria are based on multi-metric biological indices including the Index of Biotic Integrity (IBI) and modified Index of Well-Being (MIwb), indices measuring the response of the fish community, and the Invertebrate Community Index (ICI), which indicates the response of the macroinvertebrate community. Performance expectations for the basic aquatic life uses (Warmwater Habitat [WWH], Exceptional Warmwater Habitat [EWH], and Modified Warmwater Habitat [MWH]) were developed using the regional reference site approach (Hughes et al. 1986, Omernik 1987). • Escherichia coli (E. coli) is used as an indicator to determine attainment/non-attainment of recreational uses as codified in OAC 3745-1-07. Water quality must meet a 90-day geometric mean and a statistical threshold not to be exceeded more than ten percent of the time. • Chemical concentrations in fish tissue are used to determine attainment/non-attainment of non- drinking water human health water quality standards. Under Section 303(d) of the CWA, Ohio EPA is federally obligated to list impaired and threatened waters by determining attainment/non-attainment status of water quality standards. To support this objective, the following data are planned to be collected at every site: fish and macroinvertebrate community assemblages, physical stream habitat evaluation (Qualitative Habitat Evaluation Index, or QHEI), inorganic water column chemistry (parameters in Appendix 4), continuous sonde measurements, continuous temperature measurements, benthic chlorophyll a, and E. coli bacteria. Additional data will be collected at a select number of sites; this data includes: water column organic concentrations (parameters in Appendix 4), sediment chemistry (parameters in Appendix 4), neonicotinoids and fish tissue chemical concentrations. Assess Causes and Sources of Impairment Chemical and physical monitoring is a direct measure of the CWA goal, and can be used to determine the factors that limit biologic attainment. Specific objectives for each planned measurement are included below:
• Physical Habitat Assessments: Ambient environmental information including physical habitat (QHEI) will be collected to assess aquatic life use attainment using procedures described in the Biocriteria for Aquatic Life User’s Manual (Ohio EPA 1987) and OAC 3745-1-07. • Inorganic Surface Water Chemistry: A standard suite of inorganic surface water chemical parameters will be collected at every site denoted “” in Appendix 2. The list of parameters, analytic methods, and reporting limits are as listed in Appendix 4 and labeled with symbol “”. Physical water quality measurements will be taken with a multimeter probe each time a grab sample is collected. In order to evaluate seasonal variability, a minimum of five sets of samples will be collected across a variety of flow conditions at most sites. If this is not feasible, sites where n<3 will be noted in data summaries to question the validity of any arithmetic or geometric mean calculated. Impairment due to chemical contaminants in the water column can be determined by comparing select water column chemical concentrations to numeric criteria in Ohio EPA’s rules: aquatic life (Table 35-1), wildlife (Table 35-12), recreation/aesthetics (Table 37-1), water supply (Table 33-1) and human health (Table 34-1).
Page 13 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
• Sonde Measurement and Benthic Chlorophyll a: Sonde deployment should be done during stable, baseflow conditions. Each site will be surveyed at least one time, with follow-up sampling done as needed. The sonde deployment goal is to capture a minimum of 48 continuous hours of dissolved oxygen, pH, temperature, and specific conductivity measurements. Benthic chlorophyll a samples are to be collected during every sonde deployment if site conditions are appropriate. Continuous measurements will be evaluated against water quality criteria and, along with chlorophyll a results, be used to provide lines of evidence for causes of biological impairment such as nutrient or organic enrichment. • Nutrient Enrichment: To characterize the range, degree of enrichment, the seasonal average condition and the magnitude of disturbance associated with episodic manifestations in Ohio’s large rivers, enrichment indicators will be collected 5 to 6 times over the sampling index period at all large river sites. Enrichment indicators collected during spot sampling include the following nutrients: ammonia (NH3), total kjeldahl nitrogen (TKN), nitrate, total phosphorus (TP), dissolved phosphorus, alkalinity, pH, dissolved oxygen (DO), temperature, sestonic chlorophyll a, benthic chlorophyll a (if site conditions warrant), total suspended solids (TSS), total organic carbon (TOC), biological oxygen demand(BOD) 5, and the metals aluminum (Al) and iron (Fe). Collection of these data in conjunction with biologic assemblages and continuous measurements of dissolved oxygen will allow enrichment status to be determined following the methods contained in the draft standard that references endpoints determined from the large river nutrient study (Miltner, 2018).Organic Surface Water Chemistry: Water column samples will be analyzed for organic constituents (see Appendix 4 for parameters) at a subset of sites. Sites were selected based on local knowledge of dischargers or legacy issues. Semi-volatile organic carbons (s-VOCs) and/or volatile organic carbons (VOCs) (USEPA Method 625 and Method 624, respectively) testing will generally be focused around industrial facilities, municipal areas with categorical users of these constituents, and/or historic reference locations. The PCB/P (USEPA Method 608/8081) method tests for organochlorine insecticides and PCBs. Most of these compounds are discontinued and are typically not water soluble. For that reason, these constituents will generally only be sampled if there is evidence of legacy pollution or knowledge of current site conditions warrant an investigation. Each site where organics will be collected will be sampled a minimum of two times. The objective of two passes is to screen whether select organic constituents are present in the water column; a statistic evaluation or geometric mean does not need to be calculated for each site. • Sediment: Sediment will be collected at select locations in order to locate nonpoint, historical, or intermittent discharges that may not be readily apparent using samples collected from the water column. Chemical and physical analysis of sediments can be used as a tool for the monitoring of pollutant discharges to a river and assigning causes and sources of impairment. Each sediment site will be sampled once, unless follow up sampling is deemed necessary. Support Water Quality Standards Development • Neonicotinoid Exposure Assessment: Ohio EPA is working in conjunction with US EPA Region 5 to collect surface water samples that will be analyzed for a variety of neonicotinoids (parameter list in Appendix 7). US EPA plans to use the data to populate the SEAWAVE-QEX model which will estimate high end pesticide concentrations in surface water. This will aid in US EPA’s neonicotinoid exposure assessments. The SEAWAVE-QEX model requi continuous flow data. Use Designations: The collection of biologic assessment data assists in verifying the appropriateness of current designated usesres and ≥12 allows samples/year for updated in conjunctionrecommendations with for revisions as appropriate.
Page 14 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
• Antidegradation: The collection of biological and habitat data will support updates to the State’s list of special high quality waters. • Evaluation of the proposed eutrophication standard for large rivers. • Sampling for neonicotinoids (in conjunction with US EPA Region 5 laboratory) is tentatively planned to occur in 2021.
Support NPDES Permitting Three additional sites were selected (denoted as “*” NPDES sites in Appendix 2) to be sampled in order to provide the NDPES program with necessary biological and/or chemical sampling data. Two sites selected will include the full suite of sampling - biological, surface water chemistry and nutrient sampling, as described above. One site will have quantitative macroinvertebrate sampling. TMDL Implementation The TMDL program, established under Section 303(d) of the CWA, focuses on identifying and restoring polluted rivers, streams, lakes and other surface water bodies. TMDLs are prepared for waters identified as impaired on the 303(d) list in the Integrated Report. A TMDL is a written, quantitative assessment of water quality problems in a water body and contributing sources of pollution. It specifies the amount a pollutant needs to be reduced to meet water quality standards (WQS), allocates pollutant load reductions, and provides the basis for taking actions needed to restore a water body. The objectives of the TMDL process are to estimate pollutant loads from the various sources within the basin, define or characterize allowable loads to support the various beneficial uses, and to allocate pollutant loads among different pollutant sources through appropriate controls (e.g., NPDES permitting, storm water management, CWA Section 319 proposals, non-point source controls or other abatement strategies). The components of the TMDL process supported by this survey are primarily the identification of impaired waters, verification (and re- designation if necessary) of beneficial use designations, gathering ambient information that will factor into the wasteload allocation, and ascribing causes and sources of use impairment. These data are necessary precursors to the development of effective control or abatement strategies. A8 – Special Training/Certification Staff involved in environmental monitoring must complete training specific to their area of expertise. Annual refresher training is mandatory, and all trainings are documented using a Microsoft® Access® database. Supervisors should also conduct routine field audits. A9 – Documents and Records Microsoft® SharePoint® is used as a document library. Access is through Ohio EPA's Intranet collaboration site. Examples of documents posted to this location include:
Pre-sampling documents:
• Property access forms • Draft and final QAPP versions Project documents:
• All data files • Draft report sections
Page 15 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
• Changes to sites, staff, parameters, etc. should be filed in the project folder by the study team leader • Project photos will be moved to and stored in the Lynx® Photo Manager®. All files will be retained by Ohio EPA in accordance with established retention schedules. Changes in project leadership or major actions which might affect the data quality objectives require an updated QAPP and signoff sheet. The study team leader shall retain copies of all management reports, memoranda, and all correspondence between team members. For analytical samples the original chain of custody form is delivered to Division of Environmental Services (DES) along with the samples and retained by the lab. A copy of the form may be kept in a binder by the sample collector as well. After water samples are analyzed and the results are approved by the DES Quality Assurance (QA) Officer the data will be released to Sample Master® and subsequently uploaded to DSW's Ecological Assessment and Analysis Application (EA3). The sample collector reviews lab sheets for completeness and accuracy, validates field quality control (QC), adds comments and completes edits if necessary and approves the sheet. All data approved in EA3 is sent to U.S. EPA's Water Quality Exchange.
Datalogger temperature data files will be created for each stream location. The district study team will download the data files from the dataloggers and transmit them to the Modeling and Assessment Section staff for data reduction and analysis.
Original fish and QHEI data sheets will be retained at the Groveport Field Office. Data from the field sheet is manually entered into the EA3 database using the appropriate data entry screen. The sheets are double entered to minimize mistakes. Section B – Data Generation and Acquisition B1 – Sampling Process and Design Decades of monitoring work by Ohio EPA has resulted in an extensive data set that includes data for all 38 large river assessment units in Ohio. Therefore, this study included a minimum of one site approximately every eight miles of a LRAU, based on review of past sampling sites, access availability, reference sites and sites with historical data where practical. Ohio EPA has previously sampled nearly all LRAUs during the rotating biological and water quality surveys. Available United States Geological Survey gage sites were selected to obtain accurate stream flow data for load calculation purposes. The site selection process for recreation beneficial use is designed to obtain a representative picture of conditions in a LRAU. A summary of the planned sampling effort is shown in Appendix 1. A detailed list of sampling sites and the type of sampling at each is shown in Appendix 2. A list of facilities regulated by individual NPDES permit is shown in Appendix 3. B2 – Sampling Methods Stream Habitat Evaluation Physical habitat is evaluated based on methods described in Qualitative Habitat Evaluation Index (QHEI); Rationale, Methods, and Application (Ohio EPA 1989b, 2006). Various attributes of the available habitat are scored based on their overall importance to the establishment of viable, diverse aquatic faunas. Habitat attributes scored include the type and quality of substrate, amount of instream cover, channel morphology, extent of riparian canopy, pool and riffle development and quality and gradient are among the metrics used to evaluate the characteristics of a stream segment, not just the characteristics of a single sampling site.
Page 16 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Biological Community Assessment Fish and macroinvertebrate sampling protocols are detailed in Ohio EPA Biological Criteria for the Protection of Aquatic Life: Volume III. Standardized Biological Field Sampling and Laboratory Methods for Assessing Fish and Macroinvertebrate Communities (Ohio EPA 2015b). A combination of quantitative and qualitative methods will be employed to monitor benthic macroinvertebrate communities. Quantitative collections are made using modified Hester-Dendy multiple plate artificial substrate samplers, deployed at all biomonitoring sites draining more than 20 mi2, or at reference sites regardless of size. Once deployed, artificial substrates are left to colonize, in-stream, for a six-week period. Qualitative sampling will be conducted at all biomonitoring stations. This sampling method consists of a basic inventory of macroinvertebrate taxa from natural substrates, noting dominant taxa among major habitat types (for example, riffle, run, pool, and margin). Fish will be sampled at each sampling location using pulsed direct current (DC) boat electrofishing methods. Ten percent of the sites will be sampled twice during the sampling index period. The number of passes may be adjusted as necessary based on best professional judgment of the fish crew leader. Fish are processed in the field, which includes identifying each specimen to species level, counting individuals at all sites, weighing individuals at wading and boat sites, and recording external abnormalities.
Water Quality Sonde Deployments Water quality sondes will be placed at all locations (indicated in Appendix 2) to evaluate diel measurements of dissolved oxygen, pH, temperature and conductivity. All sampling, analysis and procedures adhere to those specified in the Appendix II of the Surface Water Field Sampling Manual for Water Quality Parameters and Flows (Ohio EPA 2019). That document is hereafter referred to as the Surface Water Field Sampling Manual. Section F of Appendix II outlines equipment preparation, deployment, equipment retrieval, data management, quality control testing, and maintenance.
Temperature Data All data processing and data analysis methods and procedures adhere to those specified in the Surface Water Field Sampling Manual. The sampling will be conducted in accordance with procedures outlined in Section G, Standard Operating Procedure for Continuous Temperature Data Logger Deployments.
Surface Water Chemistry Field measurements of dissolved oxygen, pH, temperature and conductivity will be collected using YSI® water quality meters at the same time and location that all grab samples for surface water chemistry are collected. Surface water grab samples, including bacteria samples, will be collected and preserved using appropriate methods as outlined in the Surface Water Field Sampling Manual. Samples are delivered to Ohio EPA - DES for analyses within the applicable holding time. Bacteria samples may be submitted to a contract lab due to the six-hour holding time. Pesticide analysis will be conducted by US EPA Region 5 laboratory. The standard operating procedure (SOP) for pesticide sample collection is included as Appendix 6 of this document. Bacteria Water samples will be collected into appropriate containers, cooled to 4°C, and transported to a contract lab and/or Ohio EPA - DES within six hours of sample collection. All samples will be analyzed for E. coli bacteria using U.S. EPA-approved methods.
Page 17 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Chlorophyll a Benthic and sestonic chlorophyll a will be collected and preserved using appropriate methods, as outlined in Appendix II of The Surface Water Field Sampling Manual and delivered to Ohio EPA- DES for analysis. Sediment Fine grained multi-incremental sediment samples will be collected in the upper four inches of bottom material using either decontaminated stainless steel scoops or dredges. Planned sediment sampling locations are listed in Appendix 2 and the parameters to be analyzed are listed in Table 4. Follow up sediment sampling may be conducted if evaluation of biological, chemical and/or physical data indicate the need for additional sediment investigation. Collected sediment will be placed into appropriate containers, placed on ice (to maintain 4oC) and shipped to Ohio EPA-DES for analysis. Sampling and decontamination protocols will follow those listed in Appendix III of the Surface Water Field Sampling Manual. Fish Tissue Tissue fillet samples will be collected from fish of edible size and species preferred for analysis may include spotted bass, largemouth bass, smallmouth bass, flathead catfish, walleye, saugeye, white bass, common carp, freshwater drum, buffalo and channel catfish. When possible, composite samples (by species) should include a minimum of three fish, yielding at least 150 grams of tissue. At each fish tissue sampling location, an attempt will be made to collect five fish species for analysis. Fish will be collected using standard electrofishing methods (Ohio EPA 1987). Sampling locations are listed in Table 2. Fish used for tissue analysis will be filleted in the field or at the Groveport Field Office using decontaminated stainless-steel fillet knives. Samples will be wrapped in aluminum foil, placed in a sealed plastic bag, along with necessary site documentation. Temporary storage in the field may take one of two forms. Samples may be stored on wet ice for a period not exceeding 48 hours. For longer periods of field storage, samples must be placed on dry ice. Collection, decontamination and field processing of tissue samples will follow protocols listed in the Ohio EPA Fish Tissue Collection Guidance Manual (2012). From the field, fish tissue samples will be stored and inventoried in chest freezers at the Ohio EPA Groveport Field Office prior to delivery to DES. Whole body fish tissue samples collected to assess ecological risk will follow the same processing and storage protocols as tissue samples aside from filleting. Whole body samples should consist of three individuals per sample of the following: common carp (Cyprinus crapio), a sunfish (Lepomis) species, a catfish species [(preferably channel catfish) (Ictalurus punctatus)], and a redhorse (Moxostoma) sucker species. B3 – Sample Handling and Custody Sample Master® software is used by DES to manage lab information. A guidance manual for use of the software is in Appendix IV of the Surface Water Field Manual (2019d). The sample collector logs into the system and places an order by selecting the appropriate project, stations to be sampled and test group(s) to be analyzed. The program creates a chain of custody form and container labels for each site. B4 – Analytical Methods The analytical methods to be used in this study are provided in Appendix 4 along with the preservatives, holding times, and reporting limits. SOPs for the analytical methods are available upon request.
Page 18 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
B5 – Quality Control Stream Habitat Evaluation To ensure technical proficiency and promote standardized observations between and among all Ohio EPA field staff tasked with macrohabitat assessment, participation in annual QHEI refresher training is typically required. The training pre-dates the onset of sampling activities by several weeks, is field-based, and typically organized and lead by a senior Fish Evaluation Group (FEG) biologist. Participants are asked to independently generate a QHEI from one or several target stream segments; this followed by a group discussion, on-site, where each component of each of the five metrics that comprise the QHEI are reviewed in detail. In this way all investigators are obliged to revisit guidance material and reaffirm the various definitions, categories, and related classifications that underpin this key assessment tool. The annual refresher has proved an efficient method to discipline observations made by front-line field staff and as such has served as a practical check on investigator drift. However, in 2020, due to the COVID-19 pandemic, field staff will not be permitted to congregate as an entire unit in close proximity to one another per governor’s orders. Water Quality Sonde Deployments Sondes will be calibrated according to manufacturer specification prior to deployment. A calibration record is kept for all sondes. After each deployment, sondes undergo a precision quality control check, for more details see section F and Appendix II of the Surface Water Field Sampling Manual. All field quality control requirements and data validation methods are detailed in the Surface Water Field Sampling Manual. Temperature Data Battery life and quality assurance of the loggers will be tested prior to deployment. QA of the loggers will be tested by a method called herd calibration. This is done by placing groupings of the loggers into a homogenized water bath and recording the temperature every minute for approximately 15 – 20 minutes. The deviation of each individual logger should be within 0.5°C from the group average. Loggers that fail the QA test during the pre-deployment test will not be deployed. Upon receipt of temperature data, the data will go through an initial review process to flag/remove anomalous data. Anomalous data could be a result of a malfunction of the probe or an indication that the probe was not reading accurate information which could occur if the probe was not fully submerged underwater for a period of time, became buried under fine sediment, etc. Methods employed will take advantage of the ContDataQC R package developed by Tetra Tech, Inc (https://github.com/leppott/ContDataQC). Surface Water Chemistry Ten percent of the total water samples will be submitted to the lab as field quality control samples. About five percent will be duplicates, including replicates if natural variability is a concern, and about five percent will be blanks, including equipment blanks. Matrix spike duplicates will be collected for organic water samples at a minimum of five percent. Data will be validated based on the results of the field quality control samples as outlined in Appendix IV in the Surface Water Field Sampling Manual (2019d). The laboratory will validate data according to the requirements defined in the applicable analytical method (see Appendix 4). Field instruments will be calibrated according to manufacturer guidelines. Field instruments utilizing electrochemical sensors must be calibrated daily, and dissolved oxygen caps must be replaced every two weeks to ensure the quality measurements.
Page 19 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Sediment Ten percent of the sediment samples should be collected as quality control samples, approximately five percent should be duplicates and five percent equipment blanks. Field duplicate samples are collected to determine laboratory analytical variability and/or field compositing techniques and of sediment heterogeneity within a single collected sample. Quality control sampling protocols will follow those listed in Appendix III of the Surface Water Field Sampling Manual (Ohio EPA 2019c). Sediment data will be validated based on the results of the equipment blanks and duplicates as procedures outlined in Appendix IV in the Surface Water Field Sampling Manual (2019d). B6 – Instrument/Equipment Testing, Inspection and Maintenance All instruments/equipment will be inspected prior to each use. All field meters are serviced annually to verify that they are operating within specifications. Parts are repaired or replaced at this time if necessary. B7 – Instrument Calibration and Frequency The appropriate calibration procedure, as specified in the instrument’s user manual, must be followed. All calibration solutions used will be checked for expiration dates before utilized. All equipment is assigned a logbook that will detail the equipment’s calibration and maintenance history. For more details, see Appendix II of the Surface Water Field Sampling Manual. Other equipment used will follow specifications provided in the biological and habitat methods cited. B8 – Inspection/Acceptance of Supplies Supplies and consumables will be inspected upon receipt by the field sampling teams. Nearly all supplies utilized for this project are maintained and used during Ohio EPA's normal business operations. The field team leaders will be responsible for ensuring that all sample containers and all needed supplies and consumables are available in advance of all field work. It will be their responsibility to maintain and replenish stock when needed. Consumable supplies include, but are not limited to: sample containers, acid preservatives, Lugol’s iodine solution, ethyl alcohol, buffers, filters and miscellaneous supplies such as distilled water, disposable gloves, and towels. Field personnel will confirm that all reagents are within applicable shelf life. B9 – Data Acquisition This project consists mainly of field sampling. Only Ohio EPA results will be used in data summaries. B10 – Data Management The data management process is shared by the Division of Surface Water (DSW) and Division of Environmental Services (DES). DES uses Sample Master® software to manage lab information and DSW uses the Ecological Assessment and Analysis Application (EA3) to manage data. These programs are linked together to allow the transfer of information between the two systems. EA3 software is used to assign a permanent six character station ID to each sampling location and to create a project name to associate locations so data can subsequently be exported and assessed in groups. See Appendix IV, Section B of the Surface Water Field Manual for guidelines.
Field measurements are collected instantaneously using a multi-parameter meter and saved in an internal file storage system. These files are downloaded to the manufacturer’s software, exported to Microsoft
Page 20 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Excel® and then uploaded to Sample Master® so field data can be associated with chemistry data in the database.
Field and chemistry data tabulated in Sample Master® are eventually uploaded into EA3. Then, in EA3, the sample collector will review each data sheet for accuracy, validate field QC, add comments and complete edits if necessary, before approving the sheet. This data is then available for use in IR reports. All agency files are ultimately backed up and housed in the State of Ohio Computer Center (SOCC).
The project leader will maintain the project file in a dedicated folder on SharePoint. The goal or objective is to have a complete record of all decisions about modifications of data collection, validation or interpretation between the QAPP signoff and project report completion. To achieve this, the project leader will need to be included on emails or otherwise receive summaries of all actions that meet the above description. Project photos should all be filed in the Lynx photo management system.
Section C – Assessment and Oversight of Data Collection C1 – Assessment and Response Actions C1.1 – Assessments Periodic assessment of field sites, field equipment, and laboratory equipment is necessary to ensure that data obtained meets project needs. This is an ongoing process that continues every day during project implementation, as well as on larger scale assessments that take place less frequently (e.g., annually). The assessments generally focus on readiness and consistency of implementation but also are looking for continual improvement opportunities. Daily assessments (for each day of project activities, as applicable) include assessment of field equipment and supplies, laboratory equipment and supplies, completeness of the day’s samples and associated field notes, future needs, etc. C1.2 - Response Actions Despite best preparations, assessments may find situations requiring corrective actions. Small day-to-day level assessment findings are often addressed by the individual doing the assessment in the field or in the lab and are common enough to the process, to not necessitate a formal response.
• Laboratory personnel are aware that response may be necessary. Many of these will result in changes to the analytical reporting via data qualifiers and comments, for more information see Appendix IV of the field manual if:
• QC data are outside the warning or acceptable windows for precision and accuracy • Blanks contain target analytes above acceptable levels • Undesirable trends are detected in spike recoveries or relative percent difference (RPD) between duplicates
• There are unusual changes in detection limits • Deficiencies are detected by the laboratory and or project QA officers during any internal or
Page 21 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
external audits or from the results of performance evaluation samples
• Inquiries concerning data quality are received Corrective action implementation will be determined by the likelihood that the situation may affect the quality of the data. Field corrective actions will be brought to the attention of the study team for consideration as to their impact on the data, their potential interest to other sampling teams/subcontractors, any future considerations for process improvement, and for their potential inclusion to the quarterly reports. Lab corrective actions will follow regular laboratory procedures and SOPs. Any lab corrective action with the potential to affect data quality will be conveyed to the study team leader by the laboratory. The datalogger installations will be visited periodically over the summer to make sure the logger remains in place within the stream. The dataloggers will be checked as soon as possible after large storm events which may dislodge or bury a logger. It is critical to reset the logger as soon as possible to prevent the loss of no more than several days of the entire data record. Weather and stream conditions will also be monitored if streams are at risk of going dry. Loggers may need to be relocated to deeper pools in the same area. C1.3 - Reporting and Resolution of Issues Any audits or other assessments that reveal findings of practice or procedure that do not conform to the written QAPP will be corrected as soon as possible. The study team and QA coordinator will be notified regarding deviations. C1.4 - Data Completeness Success of the project will be judged by the resulting data fulfilling the needs outlined in the data objectives. Potential data gaps will be monitored as the project progresses and the project schedule will be revised to fill these gaps where they are determined to be significant or to potentially impact the fulfillment of project objectives. C2 – Reports to Management The project leader or district supervisor will receive regular updates from field staff throughout the sampling season and will report to division management during Senior Management Team meetings. Any problems that jeopardize completion of the project will lead to memorandum and consultation with program management and quality assurance staff. The results and findings of the survey will be reported in the biennial Integrated Report. Aquatic life use attainment will be determined by biological criteria. Causes and sources of aquatic life use impairment will be identified and supported by water chemistry, sediment chemistry, and stream habitat evaluations. Public Water supply use will be determined on surface water chemistry and recreational use will be determined on bacteriological results. Section D – Data Validation and Usability D1 – Data Review, Validation and Verification Requirements Data verification will be conducted by the study team with assistance from other DSW staff. This process will confirm that sample results received are congruent with samples submitted and parameters requested
Page 22 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
from the lab. The process will also result in summaries of any differences between initial sampling and methods planned in the QAPP and results reported and available. Differences may result from samples not being collected (due to weather, scheduling, etc.), samples not being submitted (due to accidents like broken containers, or delays resulting in being past holding times, etc.), problems at the lab (methods changing, containers or equipment breaking), or other reasons. It is also possible that additional sampling would take place because of field observations/conditions. Documenting deviations from the QAPP is the responsibility of the project leader.
The DES laboratory does the initial validation on all data and may qualify data based on laboratory QA/QC alone or with feedback from the sampler (regarding specific sampling procedures, variable sampling matrix, conditions, blank contamination, duplicate agreement, matrix spike recovery, etc.). The data user can evaluate the data given their knowledge of sampling conditions, expected variability given location and matrix, data uses, etc.
All fish, macroinvertebrate, and habitat data are hand-entered into the EA3 database using a double data entry method. This helps to minimize data entry errors. Final approval of data involves a reconciliation between the paper forms and the electronic data which is completed by the data collector or a database administrator in the Ecological Assessment Unit.
Upon approval in EA3, field and laboratory data cannot be revised without intervention from database administrators in the Agency’s Office of Information Technology Services.
D2 – Validation and Verification Methods Biological and habitat field sampling results will be verified and validated based on field staff experience and qualifications and adherence to training and QA/QC procedures for current and new field staff available in Subsection 1, Part A (macroinvertebrates) and Subsection 2, Part A (Fish and Habitat) in Biological Criteria for the Protection of Aquatic Life: Volume III. Standardized Biological Field Sampling and Laboratory Methods for Assessing Fish and Macroinvertebrate Communities.
In addition to verifying data completeness, the study team will oversee data validation for the project that will include confirmation of sample holding times, proper preservatives, sample containers, analysis methods, QA/QC results (including assessment of results for blanks, spikes, and duplicates), etc. This will be an ongoing effort, concluding in a data validation summary to be included in the final report.
The study team will make final decisions regarding validity and usability and will evaluate the sample collection, analysis, and data reporting processes to determine if the data is of sufficient quality to meet the project objectives. Data validation involves all procedures used to accept or reject data after collection and prior to use. These include screening, editing, verifying, and reviewing. Data validation procedures ensure that objectives for data precision and bias will be met, that data will be generated in accordance with the QAPP and SOPs, and that data are traceable and defensible. The process is both qualitative and quantitative and is used to evaluate the project.
The laboratory QA staff will conduct a systematic review of the analytical data for compliance with the
Page 23 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
established QC criteria using batch and sample QA/QC information including spike, duplicate, and blank results. All technical holding times will be reviewed, the laboratory analytical instrument performance will be evaluated, and results of initial and continuing calibration will be reviewed and evaluated.
Field QC sample results will be evaluated using recently clarified DSW procedures available in Section I of the Surface Water Field Sampling Manual. Much of this work is facilitated by a centralized automated QC data evaluation Excel file. Use of this file is explained in the document “QC Tracking and Data Qualification” available in SharePoint in DSW Quality Management/Documents/DSW Procedures.
For most DSW chemical water quality data, data validation is generally confined to evaluation of blank results, duplicate/replicate results, paired parameter results (defined below) and confirming that samples were properly preserved/prepared (including filtration, etc. - if indicated by the method). Standards for evaluation of analytical results of those QC sample types and general field samples are described in Appendix IV, Section D of the Surface Water Field Sampling Manual.
D3 – Reconciliation with Data Quality Objectives Issues related to biological and habitat data uncertainty, including any patterns of analytical or field QC uncertainties, will be assessed by field staff and their management. For most situations, issues can be addressed with acknowledgement of factors captured in the sample metadata which can confirm, explain, and document the data quality concern. Significant, persistent, or unresolved issues will be brought to the attention of the project study team, division QC personnel, and Ecological Assessment Unit and/or DSW management for further evaluation. This combination of personnel will assess how to best label affected data for storage in the EA3 database and how to eliminate or limit any similar problems going forward. Consideration will also be given on how best to memorialize data limitations or anomalies as the data is transferred to other databases, including the WQ Portal, so that future users of the sampling data are aware of any data quality issues or limitations.
Page 24 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Appendix 1 – Summary of Sampling Effort
Type of Sample # of sites # of Total # passes Biology Fish (1 pass) 149 1 149 Fish (2 pass) 17 2 34 Macroinvertebrate (HD) 167 1 16 Water Quality Inorganic Samples 165 5 825 Organics sVOCs 50 2 100 sVOCs, VOCs and PCBs 19 2 38 Sonde deployment 165 1 165 Neonicotinoid Samples To Be Determined Continuous Temperature Data 167 1 167 Loggers Sediment Quality Metals (selected) 82 1 82 PCB’s and Semi-volatiles (BNA) 82 1 82 Bacteria E. coli cultures 165 5 825 Fish Tissue Consumption Advisory Fish Tissue 9 1 9 Whole Body Fish Tissue 40 1 40
Page 25 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Appendix 2 – Streams, sampling locations and sampling types. Ecoregion/ALU River Drain (refer to key on page 35) Station Location Mile (mi2) Latitude Longitude District Sampling 04100003 90 01– St. Joseph River (Fish Creek to IN border) (04-400-000) 510220 Near Ohio/Indiana State line @ St. Rt. 249 ECBP/WWH 42.34 609 41.38560 -84.80170 NWDO , S, Ne 04100005 90 01 - Maumee River Mainstem (IN border to Tiffin River) (04-001-000) P06K10 0.9 mi. dst. Ohio/Indiana State Line HELP/WWH 107.1 2119 41.1686 -84.7944 NWDO 201868 At Antwerp @ Antwerp City Park HELP/WWH 99 2129 41.1839 -84.7325 NWDO P06S08 4 mi. NE of Antwerp @ Eater Rd/CR 73 HELP/WWH 91.48 2168 41.2219 -84.6697 NWDO P06K06R N. of Cecil @ CR 105 HELP/WWH 85.26 2203 41.2378 -84.6022 NWDO P06S07 S. of the Bend @ The Bend Rd. HELP/WWH 76.15 2292 41.2753 -84.51500 NWDO , S, FT-WB P06K03 W. of Defiance, dst. Intersection Switzer Rd./Dowe HELP/WWH 69.2 2311 41.28670 -84.43810 NWDO , S, Ne Rd. 04100006 90 01 - Tiffin River Mainstem (Brush Creek to mouth) (04-600-000) P07K01R S. of Evansport @ Stever Rd. HELP/WWH 14 562 41.3888 -84.39840 NWDO , FT-WB 500160M Near Defiance @ Dey Rd. HELP/MWH 0.89 775 41.29030 -84.38560 NWDO , S, Ne 04100007 90 01 - Auglaize River Mainstem (Ottawa River to mouth) (04-100-000) 500110R At Cloverdale @ St. Rt. 114 HELP/WWH 28.5 719 41.02080 -84.28890 NWDO P06S10M At Charloe @ CR 138 HELP/MWH 14.94 2041 41.12860 -84.43190 NWDO , S, FT-WB 500290M Upst. Defiance @ Harding Rd. HELP/WWH 4.14 2330 41.25380 -84.38960 NWDO , Ne 04100008 90 01 - Blanchard River Mainstem (Dukes Run to mouth) (04-160-000) P05S03 At Gilboa @ CR 5-F HELP/WWH 35.24 508 41.01620 -83.92210 NWDO , S 500100 Upst. Ottawa @ CR 8 HELP/WWH 28.88 624 41.01240 -84.01530 NWDO P05P05 NW. of Ottawa @ CR 11 HELP/WWH 19.19 644 41.04470 -84.08190 NWDO , FT-WB P05S01 @ Putnam CR 15 HELP/WWH 13.37 704 41.05750 -84.15020 NWDO P05K03M S. of Dupont, near mouth HELP/WWH 0.2 771 41.04170 -84.29570 NWDO , Ne, S
Page 26 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Ecoregion/ALU River Drain (refer to key on page 35) Station Location Mile (mi2) Latitude Longitude District Sampling 04100009 90 01 - Maumee River Mainstem (Tiffin River to Beaver Creek) (04-001-000) 201858R Dst. Defiance dam pool, ust. Snyder/Weichman Rd. HELP/WWH 58.1 5548 41.29060 -84.24440 NWDO , O1 P09P02M 1.7 mi. Dst. Napoleon WWTP, adj. St. Rt. 424 HELP/MWH 44.35 5681 41.4086 -84.0906 NWDO , S, FT-WB P11K33R At Grand Rapids @ St. Rt. 578 (Bridge St.) HELP/WWH 31.64 6058 41.41420 -83.86060 NWDO , Ne 04100009 90 02 - Maumee River Mainstem (Beaver Creek to Maumee Bay) (04-001-000) P11W25 Dst. Grand Rapids HELP/WWH 29.7 6248 41.42884 -83.83077 NWDO P11K30 At east side of Granger Island, at park HELP/WWH 21.4 6327 41.4828 -83.7136 NWDO P11S41 Ust. Perrysburg, ust. 1 475 HELP/WWH 17.2 6334 41.5436 -83.6864 NWDO , Ne 301740 @ Buttonwood Recreation Area HELP/WWH 16.52 6340 41.54804 -83.67494 NWDO , Ne 04100011 90 01 - Sandusky River Mainstem (Tymochtee Creek to Wolf Creek) (05-001-000) U03G01 S. of McCutchenville @ CR 16 ECBP/WWH 65.01 655 40.964756 -83.268721 NWDO U04S29 Near Mexico @ CR 9 ECBP/WWH 57.34 760 40.988656 -83.203819 NWDO 500830R Dst. Mexico @ CR 90 ECBP/WWH 47.75 774 41.044255 -83.194919 NWDO U04S28 At Tiffin @ Ella St. ECBP/WWH 41.84 964 41.103955 -83.186619 NWDO , S, FT-WB 500880 * Dst. Tiffin @ CR 38 ECBP/WWH 36.5 1031 41.167554 -83.163019 NWDO F, MQ 500910 Dst. Tiffin @ Abbott’s Bridge ECBP/WWH 30.85 1047 41.20969 -83.14517 NWDO U04Q06R Upst. Fremont, upst. Wolf Creek HELP/WWH 23.00 1073 41.277958 -83.1647306 NWDO , Ne 04100011 90 02 - Sandusky River Mainstem (Wolf Creek to Sandusky Bay) (05-001-000) 304130 Just Upst. Historic Ballville Dam (Free Flowing) HELP/WWH 18.00 1255 41.325792 -83.135789 NWDO , Ne, FT-WB, S 04110002 90 01 - Cuyahoga River Mainstem (Brandywine Cr. to mouth); including old channel (19-001-000) F01S13 At Jaite @ Highland Rd. EOLP/WWH 24.1 555 41.288764 -81.56504 NEDO , S, O3 F01S11 @ Hillside Rd. EOLP/WWH 15.61 698 41.3789 -81.6147 NEDO , S, O3 F01S10 Upst. Cleveland Southerly WWTP @ RR & S.R. 21 EOLP/WWH 11.33 730 41.4178 -81.6417 NEDO , S, Ne, O3 F01S09 Dst. Southerly WWTP at Conrail RR EOLP/WWH 9.7 744 41.4269 -81.6658 NEDO , S, FT-WB, O3
Page 27 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Ecoregion/ALU River Drain (refer to key on page 35) Station Location Mile (mi2) Latitude Longitude District Sampling 04110004 90 01 - Grand River Mainstem (Mill Creek to mouth) (03-001-000) G02G15 @ Cork Cold Spring Rd. EOLP/EWH 40.1 522 41.73100 -80.86920 NEDO , S, O1 G02W19R @ Brandt Rd. @ RM 28.45 EOLP/EWH 28.45 554 41.7575 -80.9714 NEDO , S, Ne, O1 502510R Upst. Madison @ St. Rt. 528 EOLP/EWH 22.46 581 41.74060 -80.04670 NEDO , S, O1 G02W14R @ Madison Ave/Vrooman Rd. Bridge EOLP/EWH 13.7 630 41.72580 -80.18440 NEDO , S, FT-WB, O3 G02S13R @ Painesville @ N. end of park, adj. golf course EOLP/EWH 6.1 687 41.7361 -81.2361 NEDO , S, O1 05030103 90 01 - Mahoning River Mainstem (Eagle Creek to Pennsylvania Border) (18-001-000) N03S63 Near Leavittsburg @ US Route 422 EOLP/WWH 43.34 578 41.2575 -80.866 NEDO , S, O3 N03S60 Upst. Warren WWTP, dst. W.C. Industries EOLP/WWH 35.63 606 41.20690 -80.80830 NEDO , S, O3 N03S57 Dst. Niles WWTP, Upst. McDonald Steel EOLP/WWH 28.63 857 41.1747 -80.7328 NEDO , S, Ne, O3 N03W20 At Youngstown @ West Ave. EOLP/WWH 21.14 977 41.105 -80.6638 NEDO , S, FT-WB, O3 N03W21 At Campbell, near RR EOLP/WWH 17.63 1022 41.0761 -80.6161 NEDO , S, O3 N03S51 @ Ohio/PA State Line EOLP/WWH 11.43 1075 41.03 -80.5192 NEDO , S, O3 05030204 90 01 - Hocking River Mainstem (Scott Creek to Margaret Creek) (01-001-000) J02K07 At Logan, upst. Logan WWTP WAP/WWH 67.6 611 39.53060 -82.39500 SEDO , FT-WB, S J02K06 Near Haydenville @ Wandling Rd. WAP/WWH 60.76 562 39.4739 -82.3294 SEDO J02P20 At Glen-Ebon Rd. WAP/WWH 48.00 707 39.4042 -82.1894 SEDO J02K03 SE of Chauncey, 0.7 mi. dst. Confl Sunday Creek WAP/WWH 42.2 862 39.3839 -82.1156 SEDO , S 05030204 90 02 - Hocking River (Margaret Creek to Ohio River) (01-001-000) J02S15 At Athens @ Stimson Ave. WAP/WWH 33.03 942 39.3308 -82.0875 SEDO , S, FT-WB J03P15 At Guysville, US 50 WAP/WWH 20.6 982 39.2861 -81.9267 SEDO J03S10 At Bebee Rd./TR 189 WAP/WWH 13.56 1141 39.3117 -81.8575 SEDO 05040001 90 01 - Tuscarawas River Mainstem (Chippewa Creek to Sandy Creek) (17-500-000) R06W79 0.13 mi upst. Massillon WWTP EOLP/WWH 89.0 518 40.7706 -81.5242 NEDO , S, O1
Page 28 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Ecoregion/ALU River Drain (refer to key on page 35) Station Location Mile (mi2) Latitude Longitude District Sampling R06P81 Se of Navarre @ Riverland Ave. EOLP/WWH 81.46 556 40.6942 -81.5036 NEDO , S, Ne, FT-WB, O3 05040001 90 02 - Tuscarawas River Mainstem (Sandy Creek to Stillwater Creek) (17-500-000) R06K03 Dst. Sandy Creek WAP/WWH 72.6 1090 40.655 -81.4453 NEDO , S, O1 R10K18 NE of Dover @ Power Lines dst. Dover Dam WAP/WWH 63.2 1404 40.5519 -81.4208 NEDO , S, Ne, O3 R10K12 Dst. SR 250 WAP/EWH 52.3 1816 40.4642 -81.4308 NEDO , S, O1 05040001 90 03 - Tuscarawas River Mainstem (Stillwater Creek to Muskingum River) (17-500-000) R10K10 At CR 60 WAP/EWH 44.5 2364 40.3944 -81.3903 NEDO , S, O1 R10G02 Ust. Gnadenhutten WWTP WAP/EWH 38.68 2381 40.359 -81.442 NEDO , S, O1 R10S13 At Port Washington @ Co. Rd. 14 WAP/EWH 30.9 2399 40.3261 -81.5117 NEDO , S, O1 611790R At Newcomerstown @ River St. WAP/EWH 21.17 2443 40.2611 -81.6097 NEDO , S, Ne, O1 R10G04R Dst. Newcomerstown, 0.5 mi. dst. Blue Ridge Run WAP/EWH 17.6 2474 40.2767 -81.6506 NEDO , S, FT-WB, O3 R10K04R w. of West Lafayette, adj. U.S. Rt. 36 WAP/EWH 6.9 2574 40.2908 -81.8014 NEDO , S, O1 611730 At Coshocton @ Kia Bridge WAP/EWH 0.3 2596 40.27890 -81.87060 NEDO , S, O1 05040001 90 04– Sandy Creek (Bear Run to mouth) (17-450-000) R07S71 E of Bolivar, jut dst. Bolivar Dam WAP/WWH 0.57 504 40.6511 -81.4342 NEDO , S, FT-WB, O3 05040002 90 01 - Mohican River Mainstem (entire length) (17-700-000) 300286S Adj. Wally Rd. (Ashland CR 3175) EOLP/EWH 27.0 573 40.6029 -82.2481 CDO , FT-FCA, S 601870 S At Greer @ St. Rt. 514 WAP/EWH 16.92 948 40.5222 -82.1958 CDO , FT-FCA, S, Ne, O1, FT- WB 300284 At Tiverton @ Twp. Rd. 365 WAP/EWH 6.53 987.7 40.41270 -82.17860 CDO , FT-FCA, S 200634 Near mouth @ St. Rt. 715 WAP/EWH 0.5 998 40.3658 -82.1575 CDO , FT-FCA, S 05040003 90 01 - Walhonding River Mainstem (entire length) (17-600-000) 601910R At Nellie @ U.S. Rt. 36 WAP/EWH 15.73 1505 40.3414 -82.0647 CDO R04S35 Upst. Killbuck Creek @ U.S. Rt. 36 WAP/EWH 7.54 1575 40.3272 -81.9431 CDO , FT-WB R04W27R At Coshocton @ U.S. Rt. 36 WAP/EWH 0.76 2255 40.2839 -81.8706 CDO , S, Ne, O1
Page 29 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Ecoregion/ALU River Drain (refer to key on page 35) Station Location Mile (mi2) Latitude Longitude District Sampling 05040003 90 02 – Killbuck Creek (Laurel Creek to mouth) (17-150-000) 203606 0.1 mi. dst. Holmes/Coshocton Co. line WAP/WWH 20.7 501 40.4494 -81.9678 NEDO , S, O3 203603 At Helmick @ covered bridge (Twp. Rd. 25) WAP/WWH 13.28 581 40.3928 -81.9433 NEDO , S, O3 203602 1.5 mi. upst. Co. Rd. 28, adj. Co. Rd. 24 WAP/WWH 2.1 599 40.345 -81.9489 NEDO , S, FT-WB, O3 05040004 90 01 - Muskingum River Mainstem (Tuscarawas/Walhonding confluence to Licking River) (17-001-000) 304131* McWane Ductile-Ohio Mixing Zone WAP/WWH 111.0 4855 40.246 -81.872 SEDO F, MQ 611740S Dst. Coshocton @ St. Rt. 83 WAP/WWH 108.28 4861 40.2361 -81.8717 CDO , S, O1, FT-WB R11W03 S 1.5 miles upst. Wills Creek WAP/WWH 101.8 4883 40.1664 -81.8875 CDO 611750 S At Dresden @ St. Rt. 208 WAP/WWH 92 5993 40.1206 -82.00 CDO , S, O1 R11S12 Just dst. Ellis Dam WAP/WWH 84.7 6042 40.0411 -81.9861 CDO 05040004 90 02 - Muskingum River Mainstem (Licking River to Meigs Creek) (17-001-000) R16P06 S At Zanesville @ U.S. Rt. 22/6th St. WAP/WWH 75.67 6850 39.935 -82.0061 CDO , O1 R16P08 @ Duncan Falls Bridge WAP/WWH 67.48 7196 39.8692 -81.9094 CDO , S, O1 R16S28 S Just dst Rokeby Lock Dam WAP/WWH 56.4 7386 39.731 -81.9061 CDO R16S39 S At McConnelsville @ Lock Channel WAP/WWH 48.81 7422 39.6439 -81.8472 SEDO , S, O1, FT-WB R16S06 S Dst. Stockport Dam WAP/WWH 39.3 7457 39.5431 -81.7906 SEDO R16S20 Dst. Luke Chute Dam WAP/WWH 33.5 7470 39.5431 -81.7236 SEDO 05040004 90 03 - Muskingum River Mainstem (Meigs Creek to Ohio River) (17-001-000) R19K07 S Dst. Beverly Dam, Upst. Wolf Creek WAP/WWH 24.8 7713 36.5533 -81.6478 SEDO , S, O1 R19K05 S At Lowell, dst. Lowell Dam WAP/WWH 14.0 7995 39.5286 -81.5147 SEDO , FT-WB R19K02 S Dst. Devola Dam WAP/WWH 5.7 8035 39.4689 -81.4897 SEDO , O1, S 05040005 90 01 - Wills Creek Mainstem (Salt Fork to mouth); excluding Wills Creek Lake (17-800-000) R18S01M Dst. Salt Fork @ Twp. Rd. 365 WAP/WWH 46.57 659 40.12170 -81.59280 SEDO , So, O1 R18S22M SE of Birds Run @ St. Rt. 541 WAP/WWH 37.74 672 40.1614 -81.6256 SEDO ,
Page 30 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Ecoregion/ALU River Drain (refer to key on page 35) Station Location Mile (mi2) Latitude Longitude District Sampling R18S21M Near Linton Mills @ St. Rt. 541 WAP/WWH 27.04 738 40.1797 -81.6906 SEDO , Ne 302624 S of Plainfield, dst. Bacon Run @ St. Rt. 93 WAP/WWH 18.54 770.5 40.204599 -81.714224 SEDO , FT-WB 611770 Dst. Wills Creek dam @ Twp. Rd. 274 (USGS Gage) WAP/WWH 7.04 842 40.1594 -81.8475 SEDO , O1 203770 S of Conesville, near mouth WAP/WWH 0.3 853 40.156907 -81.90237 SEDO , O1 05040006 90 01 - Licking River Mainstem (entire length); excluding Dillon Lake (17-200-000) 601770 Near Newark @ St. Rt. 16 (Stadden Bridge) EOLP/WWH 26.75 537 40.0592 -82.3397 CDO , S, O1 603300 At Toboso @ Toboso Rd. WAP/WWH 18.87 672 40.0567 -82.2203 CDO , S, FT-WB R13S27R At Dillon Falls @ Dillon Falls Rd. WAP/WWH 3.68 753 39.9707 -82.0565 CDO , S 05060001 90 01 - Scioto River Mainstem (L. Scioto R. to Olentangy R.); excluding O'Shaughnessy and Griggs reservoirs (02-001-000) V02W23 Dst. L. Scioto R, adj. Prospect-Upper Sandusky Rd. ECBP/WWH 175.75 526 40.5006 -83.1979 CDO V02P15 Dst Fulton Creek @ Mink St. (Co. Rd. 177) ECBP/WWH 163.8 660 40.35 -83.1825 CDO 201823 Just S. of Klondike, adj. Klondike Rd. ECBP/WWH 157.1 764 40.2672 -83.1469 CDO , S, O1, FT-WB V03P30 N. of Dublin @ I-270 ECBP/WWH 145.57 990 40.1092 -83.1122 CDO V03W25 S At Columbus @ West 5th Ave. ECBP/WWH 136.5 1049 39.9889 -83.0681 CDO , S, Ne
V03P33M S At Columbus, 0.2 mi upstream of Olentangy ECBP/WWH 132.5 1068 39.963357 -83.01972 CDO , S, Ne 05060001 90 02 - Scioto River Mainstem (Olentangy River to Big Darby Creek) (02-001-000) 600860 At Columbus @ Greenlawn Ave. ECBP/WWH 129.48 1617 39.93890 -83.0000 CDO , O1 600810 S At Shadeville @ St. Rt. 665 ECBP/WWH 119.9 1697 39.83250 -83.00830 CDO , S, Ne, O1 V07W45R S 0.8 mi. dst. Walnut Creek ECBP/WWH 105.3 2615 39.67150 -82.99080 CDO , O1 05060001 90 03 – Olentangy River (Unnamed Trib. RM 9.99 to mouth) (02-400-000) V04S20M At Columbus @ W. North Broadway St. ECBP/MWH 5.28 528 40.031764 -83.024606 CDO , S, Ne, O1 V04S19 At Columbus @ Dodridge St. ECBP/WWH 3.93 535 40.016107 -83.016222 CDO , FT-WB V04S16 At Columbus @ foot bridge @ OSU ECBP/WWH 2.7 537 40.000064 -83.023806 CDO , S
Page 31 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Ecoregion/ALU River Drain (refer to key on page 35) Station Location Mile (mi2) Latitude Longitude District Sampling 05060001 90 04 – Big Walnut Creek (Alum Creek to mouth) (02-100-000) V05S40 S At Lockbourne @ Rowe Rd. ECBP/EWH 3.6 555 39.8106 -82.9756 CDO , S, Ne, O1, FT-WB 05060001 90 05 - Big Darby Creek (Springwater Run to mouth) (02-200-000) V07S03R W. of Orient @ St. Rt. 762 ECBP/EWH 23.72 501 39.8022 -83.1692 CDO , S, O1 601300R At Darbyville @ St. Rt. 316 ECBP/EWH 13.36 534 39.70080 -83.10970 CDO , S, Ne, O1 600970R Near Fox @ St. Rt. 104 ECBP/EWH 3.2 552 39.6286 -83.0097 CDO , FT-WB 05060002 90 01 - Scioto River Mainstem (Big Darby Creek to Paint Creek) (02-001-000) 600960R S At Circleville @ U.S. Rt. 22 ECBP/WWH 99.82 3217 39.6014 -82.9553 CDO , S, Ne, O1, FT-WB 201818 S At Canal Park, dst. Canal dam reminents ECBP/WWH 94.2 3242 39.5547 -83.0008 CDO , O1 600940 Ust. Deer Creek, Kellenburger Rd. ECBP/WWH 86.4 3348 39.4728 -82.9961 SEDO , O1 V13W08* Near Andersonville@ mouth of Dry Run (upper) ECBP/WWH 79.81 3823 39.4161 -83.0031 SEDO MQ 201813 W. of U.S. Rt. 23/St. Rt. 159, dst. Island ECBP/WWH 77.4 3828 39.3936 -82.9814 SEDO V13S09 0.3 mi. dst. Chillicothe WWTP WAP/WWH 67.82 3853 39.3256 -82.9397 SEDO 05060002 90 02 - Scioto River Mainstem (Paint Creek to Sunfish Creek) (02-001-000) V13W06 S Near Three Locks, 0.2 mi. dst. Dry Run WAP/WWH 60.0 5055 39.2519 -82.905 SEDO 600770 S At Higby Rd. WAP/WWH 56.17 5131 39.2122 -82.8647 SEDO , O1 201807 At Waverly, 0.9 mi. upst. St. Rt. 220 WAP/WWH 40.0 5750 39.1111 -82.9686 SEDO , Ne, FT-WB, S 201805 At Piketon, 1.5 mi. dst. U.S. RT. 23 WAP/WWH 33.0 5837 39.07970 -83.02830 SEDO 05060002 90 03 - Scioto River Mainstem (Sunfish Creek to Ohio River) (02-001-000) V15P15 Dst. Piketon D.O.E., 2.3 mi. dst. Sunfish Creek WAP/WWH 24.50 6086 38.989466 -83.0386 SEDO , O1 V15K02 At Lucasville @ St. Rt. 348 WAP/WWH 14.67 6174 38.8811 -83.0178 SEDO , Ne V15W01 S At Rosemount, adj. U.S. Rt. 23 WAP/WWH 5.0 6479 38.785 -82.9858 SEDO 05060002 90 04 – Salt Creek (entire length) (02-600-000) V11G02 @ Main Case Rd. WAP/EWH 1.38 551 39.20000 -82.81140 SEDO , S, O1, FT-WB
Page 32 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Ecoregion/ALU River Drain (refer to key on page 35) Station Location Mile (mi2) Latitude Longitude District Sampling 05060003 90 01 - Paint Creek Mainstem (Paint Creek Lake dam to mouth) (02-500-000) 300053 Dst. Paint Creek dam ECBP/EWH 39.14 570 39.25150 -83.35240 SEDO , S V10Q02 Adj. Falls Rd., at Cove Run WAP/EWH 32.5 732 39.23610 -83.28690 SEDO 601320 Near Bourneville @ @ Jones Levee Rd. WAP/EWH 21.6 807 39.2636 -83.1669 SEDO , S, O1, Ne, FT-WB V10K17 0.8 mi. upst. N adj Polk Hollow Rd @ Bend Rd WAP/EWH 8.9 895 39.30530 -83.03560 SEDO V10Q01R Near Chillicothe, upstream SR 772 WAP/EWH 5.0 1137 39.3097 -82.9906 SEDO , O1, S V10W12 Near mouth, upst. U.S. Rt. 23 WAP/WWH 1.2 1143 39.3028 -82.9494 SEDO , O1, S 05080001 90 01 - Great Miami River Mainstem (Tawawa Creek to Mad River) (14-001-000) H02P12R S At Sidney @ St. Rt. 47 ECBP/EWH 129.9 541 40.2869 -84.15 SWDO , S, O1, FT-WB 201922R Just dst. Swift Run Lake Outlet Stream ECBP/EWH 118.5 839 40.1736 -84.2572 SWDO , S, O1 H05S05R At Troy @ St. Rt. 41 ECBP/EWH 106.1 927 40.0306 -84.1875 CDO , S H05S19R S E. of Tipp City @ St. Rt. 571 ECBP/EWH 98.97 1124 39.9583 -84.1403 CDO , S H05W01R S Near Miami Villa @ Little York Rd. ECBP/EWH 91.14 1154 39.8544 -84.1718 CDO H05K01 At Dayton @ I-75 between Stillwater R./Mad R. ECBP/WWH 81.8 1853 39.7731 -84.1914 SWDO 05080001 90 02 - Stillwater River Mainstem (Greenville Creek to mouth) (14-200-000) H06P03 Near Pleasant Hill @ Lauver Rd. ECBP/EWH 27.86 503 40.0578 -84.3558 SWDO , O1 H06G04R At Horseshoe Bend Rd. ECBP/EWH 21.5 528 40.0086 -84.3201 SWDO H06P09 At West Milton @ St. Rt. 571 ECBP/EWH 17.45 602 39.9644 -84.3242 SWDO H06S11 At Martindale Rd. ECBP/EWH 11.4 645 39.8986 -84.2933 SWDO H06W30 At Dogleg Rd. ECBP/EWH 5.8 660 39.8383 -84.2458 SWDO , FT-WB H06K01 At Siebenthaler Rd ECBP/EWH 1.5 674 39.8 -84.2058 SWDO 05080001 90 03 - Mad River Mainstem (Donnels Creek to mouth) (14-100-000) H04P09 Near Enon @ Snider Rd. ECBP/WWH 17.48 527 39.8853 -83.965 CDO H04S03 Dst. Fairborn WWTP ECBP/WWH 8.7 616 39.8264 -84.0633 CDO , S, O1, FT-WB
Page 33 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Ecoregion/ALU River Drain (refer to key on page 35) Station Location Mile (mi2) Latitude Longitude District Sampling H04P23 At Webster St. ECBP/WWH 0.3 657 39.7683 -84.1836 SWDO , S, O1 05080002 90 01 - Great Miami River Mainstem (Mad River to Four Mile Creek) (14-001-000) H09W02 At Dayton at Stewart Street ECBP/WWH 78.85 2587 39.74 -84.1933 SWDO , S H09S13 At Miamisburg at Linden Ave. ECBP/WWH 66.9 2711 39.6406 -84.2922 SWDO S, O1 H09W28 N. of Middleton @ St. Rt. 4 ECBP/WWH 55.14 3117 39.5399 -84.3841 SWDO , FT-WB, S 600330 Near Middleton @ St. Rt. 73 ECBP/WWH 49.27 3189 39.4814 -84.4428 SWDO , S, O3 610090 @ Liberty-Fairfield Rd. ECBP/WWH 43.23 3280 39.4293 -84.4764 SWDO , S 05080002 90 02 - Great Miami River Mainstem (Four Mile Creek to Ohio River) (14-001-000) H11W35 0.1 mi. upst. Hamilton WWTP ECBP/WWH 34.1 3636 39.3718 -84.5702 SWDO , S H11C01 Dst. Fernald, 1.0 mi. dst. Dry Run IP/WWH 24.55 3799 39.2925 -84.6647 SWDO , S H11W20 At Miamitown at Harrison Road IP/WWH 15.49 3838 39.2161 -84.7035 SWDO , S, FT-WB H11K14 At Hooven, upst. U.S. Rt. 50 IP/WWH 9.5 3872 39.1797 -84.7481 SWDO , S, O1 05080003 90 01 - Whitewater River Mainstem (entire length) (14-300-000) H11W65 S At Lane off Lawrenceburg, ust. 1-275 IP/EWH 3.8 1384 39.2094 -84.7931 SWDO , S, O1, FT-WB 05090101 90 01 - Raccoon Creek Mainstem (Little Raccoon Creek to mouth) (09-500-000) W03S44 At Woods Mill @ Eagle Rd. WAP/WWH 35.61 542 38.9378 -82.3392 SEDO 601400 At Adamsville @ U.S. Rt. 35 WAP/WWH 29.2 586 38.8736 -82.3561 SEDO , S, O1, Ne 303503 Adj. Dan Jones Rd. WAP/WWH 22 615 38.803801 -82.3708 SEDO , FT-WB W03S24 At Northup, dst. Dam WAP/WWH 10.2 648 38.7839 -82.2819 SEDO 05090202 90 01 - Little Miami River Mainstem (Caesar Creek to O'Bannon Creek) (11-001-000) M05K01 Dst. Caesar Creek @ Shaw Property ECBP/EWH 50.25 658 39.4866 -84.1104 SWDO , S, FT-FCA M05S12R Near Fort Ancient @ St. Rt. 350 IP/EWH 43.76 680 39.40691 -84.10101 SWDO , S, FT-FCA 610520R Near Morrow @ Stubbs Mill Rd. IP/EWH 35.98 964 39.363425 -84.1736694 SWDO , S, FT-FCA, O1, FT-WB M05W34R At Loveland, 0.1 mi upst. O’Bannon Creek IP/EWH 24.1 1085 39.2713 -84.2596 SWDO , FT-FCA, S
Page 34 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Ecoregion/ALU River Drain (refer to key on page 35) Station Location Mile (mi2) Latitude Longitude District Sampling 05090202 90 02 - Little Miami River Mainstem (O'Bannon Creek to Ohio River) (11-001-000) M05P11 At Milford @ Wooster Pike IP/EWH 13.07 1203 39.1717 -84.2986 SWDO , S, FT-FCA, O1 600580 @ Beechmont Ave. (St. Rt. 125/32) IP/EWH 3.5 1744 39.109 -84.4015 SWDO , FT-FCA, S
S – Superior High Quality Water. M – modified reference site. R – reference site. *Site selected for NPDES program support Paired sites highlighted in pink will have one of the two selected after property access.
Acronym Key - Sampling Types Fish, Habitat, Macroinvertebrate, Inorganic water chemistry (Large River Summer Template), E. coli bacteria, Sonde, Continuous temperature dataloggers F Fish MQ Macroinvertebrate O1 Organics (sVOCs) O2 Organics (VOCs) O3 Organics (PCBs/Pesticides) S Sediment FT-FCA Fish Tissue (Fish Consumption Advisory samples) FT-WB Fish Tissue (whole body fish tissue) Ne Neonicotinoid
Page 35 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Appendix 3 – NPDES permitted facilities (major dischargers)
Large River Assessment Unit Ohio Permit Design Flow1 Type of Waste3 Stream (River Mile at Discharge) County Number Facility Name (MGD) 12-digit HUC LRAU 04100008 90 01 - Blanchard River Mainstem (Dukes Run to mouth) 04100008 90 01 2PD00028 Ottawa WWTP 3.0 Public Blanchard River (RM 22.16) Putnam LRAU 04100009 90 01 - Maumee River Mainstem (Tiffin River to Beaver Creek) 04100005 02 08 2PD00013 Defiance WWTP 6.0 Public Maumee River (RM 62.04) Defiance 04100009 02 01 2IN00004 GM Defiance NPA Systems - Industrial Maumee River (RM 61.95) Defiance 04100009 02 01 2IN00202 General Motors Powertrain 0.1008 Industrial Maumee River (RM 61.95) Defiance 04100009 02 01 2IS00026 Metal Management of Ohio 1.0 Industrial Maumee River (RM 60.91) Defiance 04100009 02 03 2PR00166 Camp Libbey (controlled - Public Maumee River (RM 59.8) Defiance discharge) 04100009 02 06 2IW00190 Napoleon WTP - Public Maumee River (RM 47.2) Henry 04100009 02 06 2PD00000 Napoleon WWTP 2.5 Public Maumee River (RM 46.05) Henry 04100009 02 06 2IH00021 Campbells Soup Supply Co. 10.0 Industrial Maumee River (RM 45.8) Henry 04100009 90 02 2ID00015 North Star Steel 0.29 Industrial Maumee River (RM 42.48) Fulton 04100009 02 07 2ID00014 Worthington Steel 0.13 Industrial Maumee River (RM 42.48) Fulton LRAU 04100009 90 02 - Maumee River Mainstem (Beaver Creek to Maumee Bay) 04100009 06 03 2IW00010 McDowell WTP - Industrial Maumee River (RM 23.04) Wood 04100009 06 03 2IJ00047 Hanson Aggregates MW- 0.85 Industrial Maumee River (RM 22.3) Lucas Waterville Quarry 04100009 90 03 2PK00000 Lucas County WRRFP 22.5 Public Maumee River (RM 18.2) Lucas LRAU 04100011 90 01 - Sandusky River Mainstem (Tymochtee Creek to Wolf Creek) 04100011 09 05 2PR00215 Camp Glen (controlled - Public Sandusky River (RM 50.4) Seneca discharge) 04100011 11 03 2IW00235 Aqua Ohio Water Co – Tiffin - Industrial Sandusky River (RM 41.8) Seneca WTP 04100011 11 03 2PD00025 Tiffin WWTP 4.0 Public Sandusky River (RM 38.77) Seneca 04100011 11 05 2IE00011 Church & Dwight Co. 0.0781 Industrial Sandusky River (RM 26.28) Seneca 04100011 11 05 2PD00007 Fremont WPCF 7.6 Public Sandusky River (RM 13.85) Sandusky LRAU 04110002 90 01 - Cuyahoga River Mainstem (Brandywine Cr. to mouth); including old channel 04110002 06 05 3GB00006*BG Arc Terminals Holdings LLC - - Petroleum Bulk Cuyahoga River Ship Channel Cuyahoga Cleveland Storage Facilities (RM 3.5)
Page 36 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Large River Assessment Unit Ohio Permit Design Flow1 Type of Waste3 Stream (River Mile at Discharge) County Number Facility Name (MGD) 12-digit HUC 04110002 06 05 3GH00025*BG Marathon Petroleum Company - Hydrostatic Test Cuyahoga River Ship Channel Cuyahoga LP Water (RM 3.8) 04110002 06 05 3ID00003*PD Arcelor Mittal Cleveland 4.5 Industrial Cuyahoga River Ship Channel (RM Cuyahoga 4.70) 04110002 06 05 3PF00002*MD NEORSD Southerly WWTP 400 Public Cuyahoga River (RM 10.57) Cuyahoga LRAU 04110004 90 01 - Grand River Mainstem (Mill Creek to mouth) 04110004 06 07 3PD00029 Painesville WWTP 6.0 Public Grand River (RM 2.85) Lake LRAU 05030103 90 01 - Mahoning River Mainstem (Eagle Creek to Pennsylvania Border) 05030103 04 06 3PD0001*HD Newton Falls WPCF 1.5 Public Mahoning River (RM 55.13) Trumbull 05030103 06 03 3IC00056*JD Thomas Steel Strip - Industrial Dicky Run (RM) to Mahoning Trumbull River (RM 39.06) 05030103 06 03 3ID0007*HD BDM Warren Steel Holdings - Industrial Mahoning River (RM 37.0-35.9) Trumbull 05030103 06 03 3PE00008*PD City of Warren WPCF 16.0 Public Mahoning River (RM 35.25) Trumbull 05030103 06 03 3ID00004*KD Arcelor Mittal Warren - Industrial Mahoning River (RM 34.32- Trumbull 35.68) 05030103 05 03 3PK00009*PD Trumbull Co. Mosquito Creek 4.2 Public Mosquito Creek (RM 7.23) to Trumbull WWTP Mahoning River (30.64) 05030103 07 03 3PK00011*JD Meander Creek WWTP 4.0 Public Meander Reservoir (RM 1.98) to Mahoning Mahoning River (RM 30.27) 05030103 07 05 3PD00036*RD Niles WWTP 6.2 Public Mahoning River (28.86) Trumbull 05030103 07 05 3PD00010*OD City of Girard WPCF 5.0 Public Mahoning River (25.28) Trumbull 05030103 08 01 3PK0000*2MD Mahoning County Boardman 5.0 Public Mill Creek (RM 9.59) to Mahoning WWTP Mahoning River (RM 21.65) 05030103 08 07 3PE00006*ND Youngstown WWTP 35.0 Public Mahoning River (RM 19.43) Mahoning 05030103 08 07 3PD00008*ND Campbell WWTP 1.9 Public Mahoning River (15.89) Mahoning 05030103 08 09 3PD00026*MD Struthers WPCF 6.0 Public Mahoning River (RM 14.32) Mahoning LRAU 05030204 90 01 - Hocking River Mainstem (Scott Creek to Margaret Creek) 05030204 06 05 0PD00009*ND Logan WWTP 1.6 Public Hocking River (RM 67.8) Hocking LRAU 05030204 90 02 - Hocking River Mainstem (Margaret Creek to Ohio River) 05030204 08 04 0PD00000*JD Athens WWTP 4.8 (20 wet) Public Hocking River RM (32.53) Athens LRAU 05040001 90 02 - Tuscarawas River Mainstem (Sandy Creek to Stillwater Creek) 05040004 03 01 3PD00004*LD Barberton WWTP 6.0.0 Public Tuscarawas River (RM 109.14) Stark
Page 37 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Large River Assessment Unit Ohio Permit Design Flow1 Type of Waste3 Stream (River Mile at Discharge) County Number Facility Name (MGD) 12-digit HUC 05040001 01 01 3PK00013*JD Upper Tuscarawas WWTP No. 4.0 Public Tuscarawas River (RM 119.8) Summit 36 05040001 90 01 3IG00000*ND Marathon Petroleum Company - Industrial Tuscarawas River (RM 80.51 Stark Canton Refinery 05040001 12 02 3PE00007*ND Massillon WWTP 15.8 Public Tuscarawas River (RM 88.87) Stark 05040001 12 04 0ID00003*GD Greer Steel Co 0.067 (avg.) Industrial Tuscarawas River (RM 59.36) Tuscarawas (006) 05040001 12 04 0IB00016*DD Dover Municipal Light & Power 14.12 (avg.) Industrial-Power Tuscarawas River (RM 59.27) Tuscarawas Plant (002) Plant 05040001 12 04 0PD00005*MD Dover WWTP 3.0 (6.0 wet) Public Tuscarawas River (RM 58.28) Tuscarawas 05040001 17 04 0IF00041*JD Kraton Chemical LLC 1.48 (013) Industrial Tuscarawas River RM 57.82 Tuscarawas 05040001 17 04 0PD00012*QD New Philadelphia WWTP 4.5 (10.5 wet) Public Tuscarawas River RM 53.63 Tuscarawas LRAU 05040001 90 03 - Tuscarawas River Mainstem (Stillwater Creek to Muskingum River) 05040001 18 04 0PD00024*LD Newcomerstown WWTP 1.25 Public Tuscarawas River (RM 19.8) Tuscarawas LRAU 05040004 90 01 - Muskingum River Mainstem (Tuscarawas/Walhonding confluence to Licking River) 05040004 03 01 0IN00122*GD Organic Technologies -- Industrial Muskingum River RM (RM Coshocton 109.87) 05040004 03 01 0IS00017*GD McWane Ductile Ohio 0.0373 Industrial Muskingum River RM (RM Coshocton 109.05) 05040004 03 01 0PD00004*LD Coshocton WWTP 4.4 (10.6 wet) Public Muskingum River RM (RM Coshocton 108.56) 05040004 03 01 0ID00014*OD AK Steel - Coshocton Works 1.63 (avg.) Industrial Muskingum River RM (RM Coshocton 105.88) 05040004 03 01 0IB00013*MD AEP Conesville Plant 237.6 (50th Industrial Muskingum River RM (RM Coshocton per) 102.89) 05040004 03 05 0IB00031*DD AEP- Appalachian Power - 7.657 (avg.) Industrial-Power Muskingum River (RM 89.9) Muskingum Dresden Generating Plant Plant 05040004 03 05 0ID00002*KD AK Steel Corp Zanesville 0.45 (avg.) Industrial Muskingum River (RM 78.0) Muskingum Operations LRAU 05040004 90 02 - Muskingum River Mainstem (Licking River to Meigs Creek) 05040004 08 02 0PE00000*SD Zanesville WWTP 11 Public Muskingum River (RM 74.15) Muskingum 05040004 08 06 0IC00000*ND Miba Bearings US LLC 0.32 (001) Industrial Muskingum River (RM 51.74) Morgan 05040004 08 06 0IS00025*CD Miba Sinter US LLC 1.5 Industrial-NCCW Muskingum River (RM 51.74) Morgan
Page 38 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Large River Assessment Unit Ohio Permit Design Flow1 Type of Waste3 Stream (River Mile at Discharge) County Number Facility Name (MGD) 12-digit HUC 05040004 08 06 0IC00027*DD MAHLE Engine Components -- Industrial Muskingum River (RM 51.7) Morgan USA Inc 05040004 08 09 0IB00027*ED Waterford Energy Facility 1.45 Industrial-Power Muskingum River (RM 33.8) Washington Plant LRAU 05040004 90 03 - Muskingum River Mainstem (Meigs Creek to Ohio River) 05040004 11 05 0IB00003*RD Muskingum River Development 4.1 Industrial Muskingum River (RM 28.91) Washington LLC (Avg.)(002) 05040004 11 05 0ID00005*JD Globe Metallurgical Inc 0.034 Industrial Muskingum River (RM 27.81) Washington 05040004 11 05 0IB00028*ED Dynegy Energy Wash. LLC 0.38 Industrial-Power Muskingum River (RM 27.1) Washington Plant 05040004 12 04 0IQ00020*JD ProFusion Industries LLC 0.912 Industrial Muskingum River (RM 3.39) Washington LRAU 05040005 90 01 - Wills Creek Mainstem (Salt Fork to mouth); excluding Wills Creek Lake 05040005 05 04 0PD00020*MD Cambridge WPCC 3.0 (9.0 wet) Public Wills Creek (RM 61.6) Guernsey LRAU 05040006 90 01 - Licking River Mainstem (entire length); excluding Dillon Lake 05060006 05 04 4PE00001*MD City of Newark WWTP 8.0 Municipal Licking River (RM 28.48) Licking 05060006 06 04 0IS00000*MD Casting Solutions LLC 0.030 (005) Industrial Licking River (RM 2.0) Muskingum 05060006 06 04 0IN00129*FD SAI Stone 2 LLC 0.035 Industrial Licking River (RM 1.4) Muskingum LRAU 05060001 90 02 - Scioto River Mainstem (Olentangy River to Big Darby Creek) 05060001 23 02 4PF00000*PD Jackson Pike Water Resource 68.0 (ADDF) Municipal Scioto River (RM 127.1) Franklin Recovery Facility 150.0 (WW) 05060001 23 03 4PF00001*QD Columbus Southerly WWTP 114.0 (ADDF) Municipal Scioto River (RM 118.4) Franklin 330.0 (WW) LRAU 05060002 90 01 - Scioto River Mainstem (Big Darby Creek to Paint Creek) 05060002 04 03 4PD00003*RD Circleville WWTP 4.0 Municipal Scioto River (RM 99.2) Pickaway 05060002 04 03 4IF00001*MD DuPont Circleville Plant 2.25 Industrial Scioto River (RM 95.9) Pickaway 05060002 04 05 4IF00002*OD PPG Industries Ohio, Inc. 2.66 Industrial Scippo Creek (RM 4.25) to Scioto Pickaway River (RM 89.6) LRAU 05060003 90 01 - Paint Creek Mainstem (Paint Creek Lake dam to mouth) 05060003 10 03 0IA00002*KD Pixelle Specialty Solutions LLC 30.8 Industrial Paint Creek (RM 2.45) Ross LRAU 05080001 90 01 - Great Miami River Mainstem (Tawawa Creek to Mad River) 05080001 07 03 1PD00009*QD Sidney WWTP 7.0 Municipal Great Miami River (RM 128.63) Miami
Page 39 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Large River Assessment Unit Ohio Permit Design Flow1 Type of Waste3 Stream (River Mile at Discharge) County Number Facility Name (MGD) 12-digit HUC 05080001 07 05 1PD00008*UD Piqua WWTP 4.5 Municipal Great Miami River (RM 114.06) Miami 05080001 08 05 1PD00019*MD Troy WWTP 7.0 Municipal Great Miami River (RM 105.67) Miami LRAU 05080001 90 02 - Stillwater River Mainstem (Greenville Creek to mouth) 05080001 14 04 1PC00011*JD West Milton WWTP 1.2 Municipal Stillwater River (RM 16.75) Miami 05080001 14 06 1PD00001*PD Englewood WWTP 2.5 Municipal Stillwater River (RM 8.86) Montgomery LRAU 05080001 90 03 - Mad River Mainstem (Donnels Creek to mouth) 05080001 18 06 1PV00105*DD Pleasant Valley MHP 0.052 Semipublic Mad River (RM 20.4) Clark 05080001 18 06 1PK00013*MD Southwest Regional WWTP 4.0 Municipal Mad River (RM 13.2) Clark 05080001 19 03 1PD00002*ND Fairborn WRC 6.0 Municipal Mad River (RM 9.62) Greene LRAU 05080002 90 01 - Great Miami River Mainstem (Mad River to Four Mile Creek) 05080002 01 05 1PF00000*PD City of Dayton WWTP 72 Municipal Great Miami River (RM 76.11) Montgomery 05080002 01 06 1PL00002*OD Western Regional WWTP 20 Municipal Great Miami River (RM 71.48) Montgomery 05080002 01 06 1PD00014*KD West Carrollton WWTP 1.4 Municipal Great Miami River (RM 68.8) Montgomery 05080002 04 04 1PD00017*MD Miamisburg WRF 4.0 Municipal Great Miami River (RM 65.05) Montgomery 05080002 04 04 1PD00004*QD Franklin Regional WWTP 4.5 Municipal Great Miami River (RM 59.65) Warren 05080002 07 02 1IA00119*HD Wausau Paper Towel and 4.0 Industrial Great Miami River (RM 53.0) Butler Tissue, LLC 05080002 07 06 1PE00003*QD Middletown WWTP 26 Municipal Great Miami River (RM 48.29) Butler 05080002 07 06 1IH00011*JD Miller Coors USA LLC 2.82 Industrial (WWTP) Great Miami River (RM 46.02) Butler 05080002 07 06 1PK00011*ND LeSourdsville Regional WRF 15.0 Municipal Great Miami River (RM 45.65) Butler LRAU 05080002 90 02 - Great Miami River Mainstem (Four Mile Creek to Ohio River) 05080002 09 02 1IB00008*MD Hamilton Municipal Power 109.9 Industrial Great Miami River (RM 37.12) Butler Plant 05080002 09 02 1PE00002*ND Hamilton WRF 32.0 Municipal Great Miami River 34.0 Butler 05080002 09 02 1PD00003*QD Fairfield WWTP 10.0 Municipal Great Miami River (RM 31.53) Butler 05080002 09 04 1IO00004*JD USDOE Fernald Preserve 8.2 Industrial Great Miami River (RM 24.75) Hamilton (groundwater pump and treat) 05080002 09 06 1PK00015*ED Taylor Creek WWTP 5.5 Municipal Great Miami River (RM 15.3) Hamilton
Page 40 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Large River Assessment Unit Ohio Permit Design Flow1 Type of Waste3 Stream (River Mile at Discharge) County Number Facility Name (MGD) 12-digit HUC LRAU 05080003 90 01 - Whitewater River Mainstem (entire length) 05080003 08 10 1PC00002*KD Harrison WWTP 2.3 Municipal Whitewater River (RM 7.62) Hamilton LRAU 05090202 90 01 - Little Miami River Mainstem (Caesar Creek to O'Bannon Creek) 05090202 09 03 1PC00003*HD Lebanon WWTP 6.0 Municipal Little Miami River (RM 32.12) Warren River segments that contain >500 mi2 but are not traditional LRAUs (organized by 12-digit HUC) 05060001 22 03 & 22 04 - Big Darby Creek 05060001 22 03 4PP00003*GD Ohio Dept. of Rehabilitation 2.3 Municipal Big Darby Creek (RM 22.92) Pickaway and Corrections, Pickaway Correctional Institution
Page 41 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Appendix 4 – List of physical/chemical parameters Parameter Method Surface Water Sediment Fish Tissue Type of Sample Reporting Limit Reporting Limit Reporting Limit Collected? Oxygen Demand BOD, 5 day SM 5210B /US EPA 310.1 2 mg/L COD SM 5220D/ US EPA 320.4 20 mg/L Physical Properties Alkalinity USEPA 310.1 5 mg/L Hardness, Total USEPA 200.7/6010 10 mg/L Specific Conductance SM 2510B 2 µS/cm Total Dissolved Solids SM 2540C 10 mg/L Total Suspended Solids USGS I-3753-85 5 mg/L % Solids SM 2540G 0% S % Lipids OEPA 581.5 0% FT Nutrients Ammonia USEPA 350.1 0.05 mg/L 14 mg/kg , S Nitrate-Nitrite NECi N07-0003 0.1 mg/L Nitrite USEPA 353.2 0.02 mg/L Total Kjeldahl Nitrogen USEPA 351.2 0.2 mg/L Total Phosphorus USEPA 365.4 0.01 mg/L 50 mg/kg , S Dissolved Phosphorus USEPA 365.1 0.01 mg/L Total Organic Carbon SM 5310C 2 mg/L 0.1% , S Anions Chloride USEPA 325.1 5 mg/L Sulfate USEPA 375.2 5 mg/L Cations Aluminum USEPA 200.7 200 µg/L 160 mg/kg , S Barium USEPA 200.7 15 µg/L 12 mg/kg , S Calcium USEPA 200.7 2 mg/L 1600 mg/kg , S Magnesium USEPA 200.7 1 mg/L 800 mg/kg , S Manganese USEPA 200.7 10 µg/L 8 mg/kg , S Potassium USEPA 200.7 2 mg/L 1600 mg/kg , S Sodium USEPA 200.7 5 mg/L 4000 mg/kg , S Strontium USEPA 200.7 30 µg/L 24 mg/kg , S Metals Zinc USEPA 200.7 10 µg/L 8 mg/kg , S Arsenic USEPA 200.8 2 µg/L 0.8 mg/kg 0.05mg/kg , FT, S Beryllium USEPA 200.8 0.2 µg/L 0.16 mg/kg , S Cadmium USEPA 200.8 0.2 µg/L 0.08 mg/kg .004 mg/kg , FT, S Chromium USEPA 200.8 2 µg/L 0.8 mg/kg , S Copper USEPA 200.8 2 µg/L 0.8 mg/kg , S Copper USEPA 200.8 2 µg/L 0.8 mg/kg , S
Page 42 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Parameter Method Surface Water Sediment Fish Tissue Type of Sample Reporting Limit Reporting Limit Reporting Limit Collected? Iron USEPA 200.7/6010 50 µg/L 40 mg/kg , S Lead USEPA 200.8 2 µg/L 0.8 mg/kg 0.04 mg/kg , FT, S Nickel USEPA 200.8 2 µg/L 0.8 mg/kg , S Selenium USEPA 200.8 2 µg/L 0.8 mg/kg 0.05 mg/kg , FT, S Algal Biomass/Toxins Chlorophyll a (benthic and sestonic) USEPA 445.0 0.3 µg/L 0.3 µg/L Bacteria Escherichia coliform SM 9223B 1 MPN/10 Semi-volatile Organic Compounds 1,2,4,5-Tetrachlorobenzene USEPA 624.1 2-10 µg/L O1 1,2,4-Trichlorobenzene USEPA 624.1 2-10 µg/L O1 1,3-Dinitrobenzene USEPA 624.1 2-10 µg/L O1 1,4-Naphthoquinone USEPA 624.1 2-10 µg/L O1 2,3,4,6-Tetrachlorophenol USEPA 624.1 2-10 µg/L O1 2,4,5-Trichlorophenol USEPA 624.1 2-10 µg/L O1 2,4,6-Trichlorophenol USEPA 624.1 2-10 µg/L O1 2,4-Dichlorophenol USEPA 624.1 2-10 µg/L O1 2,4-Dimethylphenol USEPA 624.1 2-10 µg/L O1 2,4-Dinitrophenol USEPA 624.1 2-10 µg/L O1 2,4-Dinitrotoluene USEPA 624.1 2-10 µg/L O1 2,6-Dichlorophenol USEPA 624.1 2-10 µg/L O1 2,6-Dinitrotoluene USEPA 624.1 2-10 µg/L O1 2-Acetylaminofluorene USEPA 624.1 2-10 µg/L O1 2-Chloronaphthalene USEPA 624.1 2-10 µg/L O1 2-Chlorophenol USEPA 624.1 2-10 µg/L O1 2-Methylnaphthalene USEPA 624.1 2-10 µg/L O1 2-Methylphenol USEPA 624.1 2-10 µg/L O1 2-Nitroaniline USEPA 624.1 2-10 µg/L O1 2-Nitrophenol USEPA 624.1 2-10 µg/L O1 2-Picoline USEPA 624.1 2-10 µg/L O1 3&4-Methylphenol USEPA 624.1 2-10 µg/L O1 3,3-Dichlorobenzidine USEPA 624.1 2-10 µg/L O1 3-Methylcholanthrene USEPA 624.1 2-10 µg/L O1 4,6-Dinitro-2-methylphenol USEPA 624.1 2-10 µg/L O1 4-Bromophenyl-phenylether USEPA 624.1 2-10 µg/L O1 4-Chloro-3-methylphenol USEPA 624.1 25 µg/L O1 4-Chlorophenyl-phenylether USEPA 624.1 2-10 µg/L O1 4-Nitroaniline USEPA 624.1 2-10 µg/L O1 4-Nitrophenol USEPA 624.1 2-10 µg/L O1 7,12-Dimethylbenz[a]anthracene USEPA 624.1 2-10 µg/L O1
Page 43 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Parameter Method Surface Water Sediment Fish Tissue Type of Sample Reporting Limit Reporting Limit Reporting Limit Collected? Acenaphthene USEPA 624.1 2-10 µg/L O1 Acenaphthylene USEPA 624.1 2-10 µg/L O1 Acetophenone USEPA 624.1 2-10 µg/L O1 Aniline USEPA 624.1 2-10 µg/L O1 Anthracene USEPA 624.1 2-10 µg/L O1 Benzo[a]anthracene USEPA 624.1 2-10 µg/L O1 Benzo[a]pyrene USEPA 624.1 2-10 µg/L O1 Benzo[b]fluoranthene USEPA 624.1 2-10 µg/L O1 Benzo[g,h,i]perylene USEPA 624.1 2-10 µg/L O1 Benzo[k]fluoranthene USEPA 624.1 2-10 µg/L O1 Benzyl alcohol USEPA 624.1 2-10 µg/L O1 bis(2-Chloroethoxy)methane USEPA 624.1 2-10 µg/L O1 bis(2-Chloroethyl)ether USEPA 624.1 2-10 µg/L O1 bis(2-Chloroisopropyl)ether USEPA 624.1 2-10 µg/L O1 bis(2-Ethylhexyl)phthalate USEPA 624.1 2-10 µg/L O1 Butylbenzylphthalate USEPA 624.1 2-10 µg/L O1 Chrysene USEPA 624.1 2-10 µg/L O1 Dibenz[a,h]anthracene USEPA 624.1 2-10 µg/L O1 Dibenzofuran USEPA 624.1 2-10 µg/L O1 Diethylphthalate USEPA 624.1 2-10 µg/L O1 Dimethylphthalate USEPA 624.1 2-10 µg/L O1 Di-n-butylphthalate USEPA 624.1 2-10 µg/L O1 Di-n-octylphthalate USEPA 624.1 2-10 µg/L O1 Diphenylamine USEPA 624.1 2-10 µg/L O1 Ethyl methanesulfonate USEPA 624.1 2-10 µg/L O1 Fluoranthene USEPA 624.1 2-10 µg/L O1 Fluorene USEPA 624.1 2-10 µg/L O1 Hexachlorobenzene USEPA 608.3 .006 µg/L O1 Hexachlorobutadiene USEPA 624.1 2-10 µg/L O1 Hexachlorocyclopentadiene USEPA 624.1 2-10 µg/L O1 Hexachloroethane USEPA 624.1 2-10 µg/L O1 Hexachloropropene USEPA 624.1 2-10 µg/L O1 Indeno[1,2,3-cd]pyrene USEPA 624.1 2-10 µg/L O1 Isophorone USEPA 624.1 2-10 µg/L O1 Methyl methanesulfonate USEPA 624.1 2-10 µg/L O1 Naphthalene USEPA 624.1 2-10 µg/L O1 Nitrobenzene USEPA 624.1 2-10 µg/L O1 N-Nitroso-di-n-butylamine USEPA 624.1 2-10 µg/L O1 N-Nitroso-di-n-propylamine USEPA 624.1 2-10 µg/L O1 N-Nitrosomorpholine USEPA 624.1 2-10 µg/L O1
Page 44 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Parameter Method Surface Water Sediment Fish Tissue Type of Sample Reporting Limit Reporting Limit Reporting Limit Collected? N-Nitrosopiperidine USEPA 624.1 2-10 µg/L O1 N-Nitrosopyrrolidine USEPA 624.1 2-10 µg/L O1 p-Dimethylaminoazobenzene USEPA 624.1 2-10 µg/L O1 Pentachlorobenzene USEPA 624.1 2-10 µg/L O1 Pentachlorophenol USEPA 624.1 2-10 µg/L O1 Phenacetin USEPA 624.1 2-10 µg/L O1 Phenanthrene USEPA 624.1 2-10 µg/L O1 Phenol USEPA 624.1 2-10 µg/L O1 Pronamide USEPA 624.1 2-10 µg/L O1 Pyrene USEPA 624.1 2-10 µg/L O1 Safrole USEPA 624.1 2-10 µg/L O1 Volatile Organic Compounds 1,1,1,2-Tetrachloroethane USEPA 624.1 2-20 µg/L O2 1,1,1-Trichloroethane USEPA 625/8270 2-20 µg/L O2 1,1,2,2-Tetrachloroethane USEPA 625/8270 2-20 µg/L O2 1,1,2-Trichloroethane USEPA 625/8270 2-20 µg/L O2 1,1-Dichloroethane USEPA 625/8270 2-20 µg/L O2 1,1-Dichloroethene USEPA 625/8270 2-20 µg/L O2 1,1-Dichloropropene USEPA 625/8270 2-20 µg/L O2 1,2,3-Trichlorobenzene USEPA 625/8270 2-20 µg/L O2 1,2,3-Trichloropropane USEPA 625/8270 2-20 µg/L O2 1,2,4-Trimethylbenzene USEPA 625/8270 2-20 µg/L O2 1,2-Dibromo-3-chloropropane USEPA 625/8270 2-20 µg/L O2 1,2-Dibromoethane USEPA 625/8270 2-20 µg/L O2 1,2-Dichlorobenzene USEPA 625/8270 2-20 µg/L O2 1,2-Dichloroethane USEPA 625/8270 2-20 µg/L O2 1,2-Dichloropropane USEPA 625/8270 2-20 µg/L O2 1,3,5-Trimethylbenzene USEPA 625/8270 2-20 µg/L O2 1,3-Dichlorobenzene USEPA 625/8270 2-20 µg/L O2 1,3-Dichloropropane USEPA 625/8270 2-20 µg/L O2 1,4-Dichlorobenzene USEPA 625/8270 2-20 µg/L O2 2,2-Dichloropropane USEPA 625/8270 2-20 µg/L O2 2-Butanone USEPA 625/8270 2-20 µg/L O2 2-Chlorotoluene USEPA 625/8270 2-20 µg/L O2 2-Hexanone USEPA 625/8270 2-20 µg/L O2 4-Chlorotoluene USEPA 625/8270 2-20 µg/L O2 4-Isopropyltoluene USEPA 625/8270 2-20 µg/L O2 4-Methyl-2-pentanone USEPA 625/8270 2-20 µg/L O2 Acetone USEPA 625/8270 2-20 µg/L O2 Acrylonitrile USEPA 625/8270 2-20 µg/L O2
Page 45 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Parameter Method Surface Water Sediment Fish Tissue Type of Sample Reporting Limit Reporting Limit Reporting Limit Collected? Benzene USEPA 625/8270 2-20 µg/L O2 Bromobenzene USEPA 625/8270 2-20 µg/L O2 Bromochloromethane USEPA 625/8270 2-20 µg/L O2 Bromodichloromethane USEPA 625/8270 2-20 µg/L O2 Bromoform USEPA 625/8270 2-20 µg/L O2 Bromomethane USEPA 625/8270 2-20 µg/L O2 Carbon disulfide USEPA 625/8270 2-20 µg/L O2 Carbon tetrachloride USEPA 625/8270 2-20 µg/L O2 Chlorobenzene USEPA 625/8270 2-20 µg/L O2 Chloroethane USEPA 625/8270 2-20 µg/L O2 Chloroform USEPA 625/8270 2-20 µg/L O2 Chloromethane USEPA 625/8270 2-20 µg/L O2 cis-1,2-Dichloroethene USEPA 625/8270 2-20 µg/L O2 cis-1,3-Dichloropropene USEPA 625/8270 2-20 µg/L O2 Dibromochloromethane USEPA 625/8270 2-20 µg/L O2 Dibromomethane USEPA 625/8270 2-20 µg/L O2 Dichlorodifluoromethane USEPA 625/8270 2-20 µg/L O2 Ethylbenzene USEPA 625/8270 2-20 µg/L O2 Iodomethane USEPA 625/8270 2-20 µg/L O2 Isopropylbenzene USEPA 625/8270 2-20 µg/L O2 Methylene chloride USEPA 625/8270 2-20 µg/L O2 Methyl-tert-butyl ether USEPA 625/8270 2-20 µg/L O2 n-Butylbenzene USEPA 625/8270 2-20 µg/L O2 n-Propylbenzene USEPA 625/8270 2-20 µg/L O2 o-Xylene USEPA 625/8270 2-20 µg/L O2 sec-Butylbenzene USEPA 625/8270 2-20 µg/L O2 Styrene USEPA 625/8270 2-20 µg/L O2 tert-Butylbenzene USEPA 625/8270 2-20 µg/L O2 Tetrachloroethene USEPA 625/8270 2-20 µg/L O2 Toluene USEPA 625/8270 2-20 µg/L O2 Total m&p-xylenes USEPA 625/8270 2-20 µg/L O2 trans-1,2-Dichloroethene USEPA 625/8270 2-20 µg/L O2 trans-1,3-Dichloropropene USEPA 625/8270 2-20 µg/L O2 trans-1,4-Dichloro-2-butene USEPA 625/8270 2-20 µg/L O2 Trichloroethene USEPA 625/8270 2-20 µg/L O2 Trichlorofluoromethane USEPA 625/8270 2-20 µg/L O2 Trihalomethanes (THMs) USEPA 625/8270 2-20 µg/L O2 Vinyl acetate USEPA 625/8270 2-20 µg/L O2 Vinyl chloride USEPA 625/8270 2-20 µg/L O2 Organic Compounds PCBs and Pesticides
Page 46 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Parameter Method Surface Water Sediment Fish Tissue Type of Sample Reporting Limit Reporting Limit Reporting Limit Collected? Aldrin USEPA 608.3 .006 µg/L 4 µg/kg 10 µg/kg FT, O3 a-BHC USEPA 608.3 .002 µg/L 4 µg/kg 10 µg/kg FT, O3 b-BHC USEPA 608.3 .002 µg/L 4 µg/kg 10 µg/kg FT, O3 d-BHC USEPA 608.3 .02 µg/L 4 µg/kg 10 µg/kg FT, O3 y-BHC USEPA 608.3 .002 µg/L 4 µg/kg 10 µg/kg FT, O3 4,4’-DDD USEPA 608.3 .006 µg/L 4 µg/kg 10 µg/kg FT, O3 4,4’-DDE USEPA 608.3 .002 µg/L 4 µg/kg 10 µg/kg FT, O3 4,4’-DDT USEPA 608.3 .006 µg/L 4 µg/kg 10 µg/kg FT, O3 Dieldrin USEPA 608.3 .006 µg/L 4 µg/kg 10 µg/kg FT, O3 Endosulfan I USEPA 608.3 .002 µg/L 4 µg/kg 10 µg/kg FT, O3 Endosulfan II USEPA 608.3 .002 µg/L 4 µg/kg 10 µg/kg FT, O3 Endosulfan Sulfate USEPA 608.3 .02 µg/L 4 µg/kg 10 µg/kg FT, O3 Endrin USEPA 608.3 .002 µg/L 4 µg/kg 10 µg/kg FT, O3 Endrin Aldehyde USEPA 608.3 .006 µg/L 4 µg/kg 10 µg/kg FT, O3 Heptachlor USEPA 608.3 .006 µg/L 4 µg/kg 10 µg/kg FT, O3 Heptachlor Epoxide USEPA 608.3 .002 µg/L 4 µg/kg 10 µg/kg FT, O3 Methoxychlor USEPA 608.3 .01 µg/L 4 µg/kg 10 µg/kg FT, O3 Mirex USEPA 608.3 .01 µg/L 4 µg/kg 10 µg/kg FT, O3 Hexachlorobenzene USEPA 608.3 .006 µg/L 4 µg/kg 10 µg/kg FT, O3 PCB-1016 USEPA 608.3 0.1 µg/L 20 µg/kg 50 µg/kg FT, O3 PCB-1221 USEPA 608.3 0.1 µg/L 20 µg/kg 50 µg/kg FT, O3 PCB-1234 USEPA 608.3 0.1 µg/L 20 µg/kg 50 µg/kg FT, O3 PCB-1242 USEPA 608.3 0.1 µg/L 20 µg/kg 50 µg/kg FT, O3 PCB-1248 USEPA 608.3 0.1 µg/L 20 µg/kg 50 µg/kg FT, O3 PCB-1254 USEPA 608.3 0.1 µg/L 20 µg/kg 50 µg/kg FT, O3 PCB-1260 USEPA 608.3 0.1 µg/L 20 µg/kg 50 µg/kg FT, O3
Page 47 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Appendix 5 – Safety contacts and hospital locations
COUNTY WILDLIFE OFFICERS COUNTY OFFICER PHONE NUMBER Ashland Vacant (330) 245-3036
Ashtabula Jason Warren (330) 245-3036
Athens Mark Basinger (740) 589-9980
Butler Aaron Ireland (513) 403-6591
Clark VACANT (937) 206-9321
Clermont Gus Kiebel (513) 673-1566
Coshocton Jerrod Allison (740) 589-9982
Cuyahoga Matt Madgar (330) 245-3033
Defiance Austin Dickinson (419) 429-8381
Delaware Maurice Irish (614) 902-4221
Franklin Brad Kiger (614) 902-4212
Gallia Roy Rucker (740) 589-9983
Greene Matthew Hunt (937) 545-6327
Guernsey Anthony Lemle (740) 589-9984
Hamilton Ryan Schock (513) 446-7028
Henry Matthew Smith (419) 429-8386
Hocking Chris Dodge (740) 589-9985
Holmes Jeremy Carter (330) 245-3045
Knox Austin Levering (614) 902-4213
Lake Ryan Pawlus (330) 245-3034
Licking Patrick Muldovan (614) 902-4214
Lucas Mike Ohlrich (419) 429-8388
Mahoning Tom Frank (330) 245-3038
Marion Chad Grote (614) 902-4217
Miami Jasmine Grossnickle (937) 470-1917
Montgomery Trent Weaver (937) 545-6768 Morgan Todd Stewart (740) 589-9990
Muskingum Jeff Berry (740) 589-9991
Paulding Levi Farley (419) 429-8390
Pickaway Josh Elster (614) 902-4219
Pike Matt Van Cleve (740) 589-9994
Putnam Jason Porinchok (419) 429-8391
Ross Bob Nelson (740) 589-9995
Sandusky VACANT (419) 429-8393
Scioto VACANT (740) 589-9996
Seneca Ethan Bingham (419) 429-8394
Shelby Tim Rourke (937) 545-5849
Page 48 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
COUNTY WILDLIFE OFFICERS COUNTY OFFICER PHONE NUMBER
Stark Evan Huegel (330) 245-3041
Summit Daniel Shroyer (330) 245-3042
Trumbull Marty Cisine (330) 245-3037
Tuscarawas Michael Budd (330) 245-3047
Warren Jason Keller (513) 520-9896 Washington Ryan Donnelly (740) 589-9998
Wood Eric VonAlmen (419) 429-8397
Wyandot Nathan West (419) 429-8398
COUNTY SHERIFF OFFICES COUNTY PHONE NUMBER Ashland (419) 289-3911
Ashtabula (440) 576-0055 Athens (740) 593-6633 Butler (513) 785-1300 Clark (937) 521-2050 Clermont (513) 732-7500 Coshocton (740) 622-2411 Cuyahoga (216) 443-6000 Defiance (419) 784-1155 Delaware (740) 833-2810 Franklin (614) 525-3360 Gallia (740) 446-1221 Greene (937) 562-4800 Guernsey (740) 439-4455 Hamilton (513) 946-6400 Henry (419) 592-8010 Hocking (740) 385-2131 Holmes (330) 674-1936 Knox (740) 397-3333 Lake (440) 350-5517 Licking (740) 670-5555 Lucas (419) 213-4900 Mahoning (330) 480-5020 Marion (740) 382-8244 Miami (937) 440-6085 Montgomery (937) 225-4192 Morgan (740) 962-4044
Page 49 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
COUNTY SHERIFF OFFICES COUNTY PHONE NUMBER Muskingum (740) 455-7928 Paulding (419) 399-3791 Pickaway (740) 474-2176 Pike (740) 947-2111 Putnam (419) 523-3208 Ross (740) 773-1186 Sandusky (419) 332-8261 Scioto (740) 355-8261 Seneca (419) 447-3456 Shelby (937) 498-1111 Stark (330) 430-3801 Summit (330) 643-2122 Trumbull (330) 675-2540 Tuscarawas (330) 339-2000 Warren (513) 695-1280 Washington (740) 373-6623 Wood (419) 354-3008 Wyandot (419) 294-2362
COUNTY HOSPITAL LOCATIONS COUNTY HOSPITAL NAME ADDRESS PHONE NUMBER 1025 Center Street, Ashland, OH Ashland UH Samaritan Medical Center (419) 289-0491 44805
2420 Lake Avenue, Ashtabula, OH Ashtabula Ashtabula County Medical Center (440) 997-2262 44004 55 Hospital Drive, Athens, OH Athens Ohio Health O’Bleness Hospital (740) 593-5551 45701 3125 Hamilton Mason Road, Butler TriHealth Bethesda Butler Hospital (513) 894-8888 Hamilton, OH 45011 Springfield Regional Medical 100 Medical Center Drive, Clark (937) 523-1000 Center Springfield, OH 45504 3000 Hospital Drive, Batavia, OH Clermont Mercy Health Clermont Hospital (513) 732-8200 45103 Coshocton Regional Medical 1460 Orange Street, Coshocton, Coshocton (740) 622-6411 Center OH 43812 Cleveland Clinic – Lutheran 1730 W. 25th Street, Cleveland, Cuyahoga (216) 696-4300 Hospital OH 44113 1404 E. 2nd Street, Defiance, OH Defiance Mercy Health – Defiance Hospital (419) 782-8444 43512
Page 50 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
COUNTY HOSPITAL LOCATIONS COUNTY HOSPITAL NAME ADDRESS PHONE NUMBER OhioHealth Grady Memorial 561 W. Central Avenue, Delaware (740) 615-1000 Hospital Delaware, OH 43015 OhioHealth Riverside Methodist 1087 Dennison Avenue, Franklin (614) 484-9600 Hospital Columbus, OH 43201 100 Jackson Pike, Gallipolis, OH Gallia Holzer Emergency Medical Center (855) 446-5937 45631 1141 N. Monroe Drive, Xenia, OH Greene Greene Memorial Hospital (937) 352-2000 45385 Southeastern Ohio Regional 1341 Clark Street, Cambridge, OH Guernsey (740) 439-8000 Medical Center 43725 10500 Montgomery Road, Hamilton TriHealth Bethesda North Hospital (513) 865-1111 Cincinnati, OH 45242 1600 E. Riverview Avenue, Henry Henry County Hospital (419) 592-4015 Napoleon, OH 43545 Hocking Valley Community 601 State Route 664 N, Logan, OH Hocking (740) 380-8000 Hospital 43138 981 Wooster Road, Millersburg, Holmes Pomerene Hospital (330) 674-1015 OH 44654 1330 Coshocton Avenue, Mt. Knox Knox Community Hospital (740) 393-9000 Vernon, OH 43050 36000 Euclid Avenue, Willoughby, Lake Lake Health West Medical Center (440) 953-9600 OH 44094 1320 W. Main Street, Newark, OH Licking Licking Memorial Hospital (220) 564-4000 43055 3404 W. Sylvania Avenue, Toledo, Lucas Mercy Health St. Anne Hospital (419) 407-2663 OH 43623 Mercy Health St. Elizabeth 1044 Belmont Avenue, Mahoning (330) 746-7211 Youngstown Hospital Youngstown, OH 44501 Ohio Health Marion General 1000 McKinley Park Drive, Marion (740) 383-8400 Hospital Marion, OH 43302 3130 N. County Road 25A, Troy, Miami Upper Valley Medical Center (937) 440-4000 OH 45373 1 Wyoming Street, Dayton, OH Montgomery Miami Valley Hospital (937) 208-8000 45409 Morgan 2951 Maple Avenue, Zanesville, Genesis Hospital (740) 454-5880 Muskingum OH 43701 1035 W. Wayne Street, Paulding, Paulding Paulding County Hospital (419) 399-4080 OH 45879 600 N. Pickaway Street, Pickaway OhioHealth Berger Hospital (740) 474-2126 Circleville, OH 43113 100 Dawn Lane, Waverly, OH Pike Adena Pike Medical Center (740) 947-2186 45690 St. Rita’s Putnam County 601 State Route 224, Ottawa, OH Putnam (419) 538-6288 Ambulatory Care Center 45875
Page 51 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
COUNTY HOSPITAL LOCATIONS COUNTY HOSPITAL NAME ADDRESS PHONE NUMBER 272 Hospital Road, Chillicothe, OH Ross Adena Regional Medical Center (740) 779-7500 45601 1400 W. Main Street, Bellevue, Sandusky The Bellevue Hospital (419) 483-4040 OH 44811 1805 27th Street, Portsmouth, OH Scioto Southern Ohio Medical Center (740) 356-5000 45662 45 St Lawrence Drive, Tiffin, OH Seneca Mercer Tiffin Hospital (419) 455-7000 44883 915 Michigan Street, Sidney, OH Shelby Wilson Memorial Hospital (937) 498-2311 45365 2600 6th Street SW, Canton, OH Stark Aultman Hospital (330) 452-9911 44710 Summa Health System – Akron 141 N. Forge Street, Akron, OH Summit (330) 375-3000 Campus 44304 1350 E. Market Street, Warren, Trumbull Trumbull Regional Medical Center (330) 841-9011 OH 44483 819 N. 1st Street, Dennison, OH Tuscarawas Trinity Hospital Twin City (740) 922-2800 44621 100 Arrow Springs Boulevard, Warren TriHealth Bethesda Arrow Springs (513) 282-7000 Lebanon, OH 45036 401 Matthew Street, Marietta, Washington Marietta Memorial Hospital (740) 374-1400 OH 45750 950 W. Wooster Avenue, Bowling Wood Wood County Hospital (419) 354-8900 Green, OH 43402 885 N. Sandusky Avenue, Upper Wyandot Wyandot Memorial Hospital (419) 294-4991 Sandusky, OH 43351
Page 52 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Appendix 6 – US EPA, Chicago Regional Laboratory (CRL) pesticide sample collection procedures Standard Operating Procedure for collection of water samples for pesticide analysis 1. Collect one grab sample/site in a glass container (pesticide samples cannot be collected in plastic containers). Rinse container with water from the collection site before collecting the sample. 2. Apply labels to 40 ml amber vials before filling. Label each vial with the site number, collection date, and collection time. Use a Sharpie to fill in the labels. The labels will be included with the vial shipment. 3. Fill 2 vials/site. Collect two duplicate samples from two randomly selected sites/round of sampling. Duplicates should be collected by utilizing methodology in the DSW Field Sampling Manual (i.e. collected with a churn splitter). Each duplicate sample needs to consist of 6 vials of sample; therefore, each duplicate site will have a total of 8 vials collected. 4. Fill each vial almost to the top leaving a small air gap. Store standing up on ice or reusable ice substitute freeze packs in the coolers provided. 5. Record collection information on CRL chain of custody forms (will be shipped with vial shipment). 6. Pack 10 vials/Ziploc bag in cooler.
CRL SAMPLE SHIPMENT REQUIREMENTS
Before collecting samples, please refer to the attached table for sample sizes, containers, and preservatives. Notify the CRL Sample Custodian (312.353.9083, [email protected]) and the CRL Sample Coordinator (312.353.9078, [email protected]) before shipping any samples and to arrange for sample receipt.
When packing samples for shipment: • Seal individual samples in plastic bags, preferably Ziploc bags. • The temperature of samples requiring refrigeration during transport MUST be maintained at or below 6° C. • Ice in a sealed plastic bag or reusable ice substitute freeze packs are acceptable cooling media. • Chain of custody forms MUST be sealed in a large Ziploc bag and taped to the inside of the cooler lid. • Include the address to which the cooler should be returned.
After items are packed for shipment, secure the cooler with tape and attach a custody seal across the seam of the cooler lid. All samples MUST be shipped overnight to arrive Monday through Friday or hand delivered. No deliveries are accepted on weekends or Federal holidays. Exceptions may be made on a case by case basis depending on sampling priority/emergency status.
Send all samples to: Robert Snyder US EPA Region 5 Chicago Regional Laboratory 536 S. Clark Street, 10th Floor Chicago, IL 60605
Page 53 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
Appendix 7 – US EPA, Chicago Regional Laboratory pesticide sample analytes Parameter Method Stream RL 2,4-D 100 ng/L Acetochlor 25.0 ng/L Alachlor 25.0 ng/L Atrazine 6.25 ng/L Azoxystrobin 6.25 ng/L Bentazon 25.0 ng/L Carbaryl 6.25 ng/L Chlorpyrifos 25.0 ng/L Clopyralid 10000 ng/L Clothianidin 6.25 ng/L Diazinon 6.25 ng/L Dicamba 2500 ng/L Fipronil 6.25 ng/L Imidacloprid 6.25 ng/L Malathion 6.25 ng/L Methomyl 6.25 ng/L Metolachlor 25.0 ng/L Metribuzin 6.25 ng/L Picloram 2500 ng/L Propiconazole 6.25 ng/L Simazine 6.25 ng/L Thiamethoxam_ 25.0 ng/L Triclopyr 250 ng/L Desisopropylatrazine 6.25 ng/L Acetochlor ESA 100 ng/L Alachlor ESA 100 ng/L MCPA 50.0 ng/L MCPP 25.0 ng/L Dimethenamid 6.25 ng/L Metolachlor ESA 25.0 ng/L Hydroxyatrazine 25.0 ng/L DACT 25.0 ng/L
Page 54 of 55
AMS/2020-LRGRV-1 Ohio’s Large Rivers Survey QAPP, 2020 - 2021 July 2020
References
Hughes, R.M., D.P. Larsen, and J.M. Omernik. 1986. Regional reference sites: a method for assessing stream pollution. Env. Mgmt. 10(5): 629-635
Karr, J.R. and D.R. Dudley. 1981. Ecological perspective on water quality goals. Env. Mgmt. 5(1): 55- 68.
Ohio Environmental Protection Agency. 2019. Surface Water Field Sampling Manual for water quality parameters and flows. Division of Surface Water. Columbus, Ohio. Version 7.0, April 22, 2019.
. 2019b. Surface Water Field Sampling Manual Appendix II
. 2019c. Surface Water Field Sampling Manual Appendix III, Sediment Sampling
. 2019d. Surface Water Field Sampling Manual Appendix IV, Data Management
. 2019e. Surface Water Field Sampling Manual Appendix I, Inland Lakes Manual
. 2015b. Ohio EPA Biological Criteria for the Protection of Aquatic Life: Volume III. Standardized Biological Field Sampling and Laboratory Methods for Assessing Fish and Macroinvertebrate Communities
. 2012. Ohio EPA Fish Tissue Collection Guidance Manual
. 1989b, 2006. Qualitative Habitat Evaluation Index (QHEI); Rationale, Methods, and Application
Page 55 of 55