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CHINESE JOURNAL of CATALYSIS February 2011 Vol http://www.chxb.cn ISSN 0253-9837 CN 21-1195/O6 CODEN THHPD3 催 化 学 报 CHINESE JOURNAL CHINESE JOURNAL OF CATALYSIS 主编 林励吾 2011 Editor-in-Chief LIN Liwu Vol. 32 No. 2 OF C AT AL YSIS February 2011 V ol. 32 No. 2 pages 207 - 386 中 国 化 学 会 催 化 学 会 会 刊 Transaction of the Catalysis Society of China 2011 年 2011 第 32 卷 第 2 期 CHINESE JOURNAL OF CATALYSIS Vol. 32 No. 2 In This Issue 封面: Menéndez 教授等综述了碳催化剂上 CH4 裂解及其与 CO2 的重 整反应, 见本期第 207~216 页. 碳催化剂上的 CH4 与 CO2 重整可看作是 CH4 裂解和沉积碳与 CO2 气化反应的组合. CH4 裂解生成 H2 和沉积碳, 而 后者堵塞了碳催化剂上的活性位. 随后, 至少这些具有高活性的沉积碳可 被 CO2 气化, 使得碳催化剂上的活性位得以原位和连续地再生. Cover: Prof. Menéndez and coworkers in their article on pages 207–216 reviewed the recent development of carbon catalysts for decomposition and CO2 reforming of methane. The dry reforming reaction over carbonaceous catalysts can be considered a combination of CH4 decomposition and CO2 gasification of carbon deposits. The decomposition of CH4 gives rise to hy- drogen and carbonaceous deposits, which block the active centers on the car- bon catalyst. Then, the deposits, at least those which are highly reactive, are gasified by the CO2, leading to an in situ and continuous regeneration of the active centers on the carbon catalyst. About the Journal Chinese Journal of Catalysis is published monthly by Chinese Chemical Society and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. The objective of the journal is to publish original, rigorous, and scholarly contributions in the fields of heteroge- neous and homogeneous catalysis. The journal accepts papers in Chinese and English. Scope of the Journal Impact Factor z New trends in heterogeneous and homogeneous catalysis in relation to 0.786 (ISI) 0.755 (ISI, 5-Year Impact Factor) energy, environment, new materials, petroleum chemicals, and fine 0.940 (ISTIC) chemicals Abstracting and Indexing z Scientific bases for the preparation and activation of catalysts of com- Abstract Journals (VINITI) mercial interest or that are representative models Cambridge Scientific Abstracts (CIG) z Scientific methods for the characterization of heterogeneous catalysts, Catalysts & Catalysed Reactions (RSC) especially methods for in situ characterization Current Contents/Engineering, z New heterogeneous and homogeneous catalytic reactions of potential Computing and Technology (Thomson ISI) practical interest in environment, energy, and fine chemicals applica- Chemical Abstract Service/SciFinder (CAS) Chemistry Citation Index (Thomson ISI) tions Japan Information Center of Science and Technology z Relationship between homogeneous and heterogeneous catalysis Journal Citation Reports/Science Edition (Thomson ISI) z Theoretical studies on the structure and reactivity of catalysts Science Citation Index Expanded (Thomson ISI) z The journal also accepts contributions dealing with other issues related SCOPUS (Elsevier) to catalysis, such as photo-catalysis, bio-catalysis, surface science, and Web of Science (Thomson ISI) chemical kinetics. 国内数据库收录 Types of Contributions 《中文核心期刊要目总览》 《中国学术期刊文摘》(CSA) Reviews are surveys of recent progress on important topics of catalysis, 《中国科学引文数据库》(CSCD) with entire, systematic, and important information. Authors should have 《中国科技期刊精品数据库》 published articles in the field. More than 60 references are suggested. 《中国学术期刊综合评价数据库》(CAJCED) Communications rapidly report studies with significant innovation and 《中国期刊全文数据库》(CNKI) major academic value. They are limited to four Journal pages. After pub- 《万方数据资源系统》(ChinaInfor) lication, their full-text papers can also be submitted to this or other jour- 《中文科技期刊数据库》(VIP) nals. 《中文电子期刊服务数据库》(CEPS) Articles are original full-text reports on innovative, systematic, and 《中国化学文献数据库》(CCBD) complete results in catalysis. 《中国化学化工文摘》 2011年 2011 第32卷 第2期 CHINESE JOURNAL OF CATALYSIS Vol. 32 No. 2 《催化学报》第四届编辑委员会 月刊 SCI 收录 1980 年 3 月创刊 中国化学会催化学会会刊 The Fourth Editorial Board of Chinese Journal of Catalysis 2011年2月20日出版 顾问 (Advisors) 主管 中国科学院 蔡启瑞 (CAI Qirui) 胥诲熊 (XU Huixiong) Bernard DELMON (比利时) 主办 中国化学会 闵恩泽 (MIN Enze) Jürgen CARO (德国) Gerhard ERTL (德国) 中国科学院大连化学物理研究所 彭少逸 (PENG Shaoyi) Michel CHE (法国) Masaru ICHIKAWA (日本) 主编 林励吾 宋春山 (SONG Chunshan, 美国) 编辑 《催化学报》编辑委员会 出版 主编 (Editor-in-Chief) 林励吾 (LIN Liwu) 国内统一连续出版物号 CN 21-1195/O6 副主编 (Associate Editors-in-Chief) 国际标准连续出版物号 ISSN 0253-9837 CODEN THHPD3 包信和 (BAO Xinhe) 寇 元 (KOU Yuan) 张 涛 (ZHANG Tao) 广告经营许可证号 2102002008000002 高 滋 (GAO Zi) 刘宇新 (LIU Yuxin) 编委 (Members) 总发行 安立敦 (AN Lidun) 李 灿 (LI Can) 吴 凯 (WU Kai) 北京东黄城根北街 16 号 包信和 (BAO Xinhe) 李大东 (LI Dadong) 吴通好 (WU Tonghao) 邮编: 100717 陈 德 (CHEN De, 挪威) 李微雪 (LI Weixue) 夏春谷 (XIA Chungu) 电话: (010) 64017032 E-mail: [email protected] 陈经广 (CHEN Jingguang,美国) 林励吾 (LIN Liwu) 肖丰收 (XIAO Fengshou) 国内订购 全国各地邮政局 陈庆龄 (CHEN Qingling) 刘昌俊 (LIU Changjun) 谢在库 (XIE Zaiku) 邮发代号 8-93 陈诵英 (CHEN Songying) 刘宇新 (LIU Yuxin) 熊国兴 (XIONG Guoxing) 国外订购 中国国际图书贸易总公司 陈耀强 (CHEN Yaoqiang) 刘中民 (LIU Zhongmin) 徐柏庆 (XU Boqing) 北京 399 信箱 邮编 100044 陈 懿 (CHEN Yi) 卢冠忠 (LU Guanzhong) 许建和 (XU Jianhe) 国外发行代号 M417 椿范立 日本 罗锡辉 徐 杰 印刷 大连海大印刷有限公司 (Noritatsu TSUBAKI, ) (LUO Xihui) (XU Jie) 定价 28 元 邓友全 (DENG Youquan) 沈俭一 (SHEN Jianyi) 徐龙伢 (XU Longya) 方佑龄 (FANG Youling) 沈师孔 (SHEN Shikong) 严玉山 (YAN Yushan, 美 国 ) Publication Monthly (12 issues) 伏义路 (FU Yilu) 沈之荃 (SHEN Zhiquan) 杨启华 (YANG Qihua) Started in March 1980 高 滋 (GAO Zi) 申文杰 (SHEN Wenjie) 杨维慎 (YANG Weishen) Transaction of the Catalysis Society of China 关乃佳 (GUAN Naijia) 苏宝连 (SU Baolian, 比利时) 杨向光 (YANG Xiangguang) Superintended by 郭新闻 (GUO Xinwen) 孙予罕 (SUN Yuhan) 余 林 (YU Lin) Chinese Academy of Sciences Sponsored by 何鸣元 (HE Mingyuan) 万惠霖 (WAN Huilin) 袁友珠 (YUAN Youzhu) Chinese Chemical Society and Dalian 贺鹤勇 (HE Heyong) 王德峥 (WANG Dezheng) 张 涛 (ZHANG Tao) Institute of Chemical Physics of CAS 胡友良 (HU Youliang) 王国祯 (WANG Guozhen) 赵进才 (ZHAO Jincai) Editor-in-Chief LIN Liwu Edited by Editorial Board of 贾继飞 (JIA Jifei, 美 国 ) 王建国 (WANG Jianguo) 郑小明 (ZHENG Xiaoming) Chinese Journal of Catalysis 寇 元 (KOU Yuan) 王祥生 (WANG Xiangsheng) 钟顺和 (ZHONG Shunhe) Published by Science Press 编辑部成员 (Editorial Office Staff) 主任 尹红梅 Distributed by Science Press (Managing Editor) (YIN Hongmei) 16 Donghuangchenggen North Street, 资深编辑 (Senior Editor) 刘宇新 (LIU Yuxin) Beijing 100717, China 编辑 (Editor) 初人合 (CHU Renhe) Tel: +86-10-64017032 编辑 (Editor) 张 艳 (ZHANG Yan) E-mail: [email protected] Subscription Agents 编辑部联系方式 (Editorial Office Address) Domestic All Local Post Offices in China Foreign China International Book Trading 地址: 大连市中山路 457 号 Add.: Dalian Institute of Chemical Physics, Chinese Corporation, P.O.Box 399, Beijing 100044, 中国科学院大连化学物理研究所 Academy of Sciences, 457 Zhongshan Road, China 邮编: 116023 Dalian 116023, Liaoning, China Printed by Dalian Haida Printing Company, Limited 电话: (0411)84379240 Tel: +86-411-84379240 Price $28 传真: (0411)84379600 Fax: +86-411-84379600 电子信箱: [email protected] E-mail: [email protected] 公 开 发 行 中文版 http://www.chxb.cn 国际版 http://www.sciencedirect.com/science/journal/18722067 (CUIHUA XUEBAO) CHINESE JOURNAL OF CATALYSIS 中国科学院科学出版基金资助出版 月刊 SCI 收录 2011 年 2 月 第 32 卷 第 2 期 目 次 综 述 Viswanathan BALASUBRAMANIAN 286 207 (国际版/封面文章) Si 掺杂对 TiO2 空心微球微结构和光催化性能的影响 用于甲烷分解和甲烷二氧化碳重整的碳材料催化剂研究 李纲, 刘昉, 阳启华, 张昭 进展 Beatriz FIDALGO, J. Ángel MENÉNDEZ 293 SSZ-13 和 RUB-50 分子筛上甲醇制烯烃的对比研究 李鹏, 张维萍, 韩秀文, 包信和 研究快讯 299 217 (国际版) 新型双膦配体的合成及其在 2-丁烯氢甲酰化反应中的应 动态水热合成 b 轴取向 MFI 型分子筛膜 用 李显明, 王正宝, 郑洁, 邵世群, 王胤超, 严玉山 张林, 李春, 付海燕, 袁茂林, 李瑞祥, 陈华 224 (国际版) 303 单层分散型 Ru-Zn 催化剂及其催化苯选择加氢制环己烯 载体焙烧温度对稀燃天然气汽车尾气净化 的性能 Pd/Zr0.5Al0.5O1.75 催化剂性能的影响 孙海杰, 张旭东, 陈志浩, 周小莉, 郭伟, 刘仲毅, 刘寿长 王云, 唐石云, 龙恩艳, 林之恩, 龚茂初, 陈耀强 231 (国际版) 309 胶束催化体系中的对映选择性环醚化反应 La 和 Mn 助剂对完全液相法制备的 CuZr 浆状催化剂结构 Bhupesh S. SAMANT, Sunil S. BHAGWAT 和性能的影响 235 (国际版) 高志华, 黄伟, 阴丽华, 谢克昌 用 Dawson 型聚氧钨酸乳液催化氧化燃油超深度脱硫 315 张永娜, 王璐, 张玉良, 蒋宗轩, 李灿 柠檬酸改性对掺 Ba 纳米 MgO 及其担载的 Ru 氨合成催化 剂性能的影响 研究论文 霍超, 夏庆华, 潘美华, 杨霞珍, 骆燕, 刘化章 240 (国际版) 321 炭气凝胶孔结构对其负载的 TiO2 光催化降解甲基橙性能 Al2O3 性质对加氢脱硫催化剂 Co-Mo/Al2O3 活性相形成的 影响 的影响 齐和日玛, 李会峰, 袁蕙, 张韫宏, 徐广通 崔华楠, 赵振华, 梁业如, 石建英, 吴丁财, 刘鸿, 符若文 250 (国际版) 325 载体对负载型 Ni-B 催化剂催化 2-乙基蒽醌加氢制 H2O2 反 高负载量 LaMnOx/SBA-15 的制备及其催化甲苯燃烧性能 张泽凯, 梁一微, 任倩茹, 刘华彦, 陈银飞 应性能的影响 陈雪莹, 乔明华, 贺鹤勇 258 (国际版) 333 纳米孔碳负载 Fe3O4 催化剂上苯直接羟基化制苯酚 Pezhman ARAB, Alireza BADIEI, Amir KOOLIVAND, Ti-MWW 催化氯丙烯环氧化反应动力学行为 Ghodsi MOHAMMADI ZIARANI 方向青, 王钰宁, 邓秀娟, 吴海虹, 吴鹏, 刘月明, 何鸣元 264 (国际版) 340 碱促进的钴酸镁催化剂上的氧化亚氮分解 冷等离子体喷射流对甲烷二氧化碳重整用 Ni/Al2O3 催化 Bahaa M. ABU-ZIED 剂的还原机制 胡诗婧, 龙华丽, 徐艳, 尚书勇, 印永祥 273 (国际版) 用于甲烷水蒸气重整的镍基催化剂的失活和再生 345 Seyed Meysam HASHEMNEJAD, Matin PARVARI 铜基催化剂上甘油脱水制备羟基丙酮 牛莎莎, 朱玉雷, 郑洪岩, 张维, 李永旺 280 (国际版) 聚合物负载的钯-咪唑催化烯烃加氢 352 Udayakumar VELU, Alexander STANISLAUS, Bi 添加对 MoVO/AlPO4 催化剂异丁烯选择氧化反应性能 Gayathri VIRUPAIAH, Shivakumaraiah, 的影响 王希涛, 王芬, 蒋实, 钟顺和 374 357 吸附柱色谱法制备负载型纳米金催化剂 翟新磊, 徐金光, 徐秀峰, 邹旭华, 齐世学, 祁彩霞, 核苷中 2'-位取代基对 Burkholderia cepacia 脂肪酶选择性 安立敦 酰化核苷的影响 王朝宇, 宗敏华 379 362 介孔氧化铝的制备及其在甲醇脱水制二甲醚反应中的应 用 无第二模板剂法合成多级结构 ZSM-5 分子筛微球及其在 聂仁峰, 王军华, 费金华, 侯昭胤, 郑小明 甲烷无氧芳构化反应中的应用 杨建华, 于素霞, 胡慧晔, 初乃波, 鲁金明, 殷德宏, 王金渠 相关信息 368 320 第七届全国环境催化与环境材料学术会议 制备方法对双介孔钴基催化剂结构及其费-托反应性能的 385 作者索引 影响 王俊刚, 李德宝, 侯博, 贾丽涛, 贾利宏, 孙志强, 刘斌, 郭金刚, 任润厚, 孙予罕 www.chxb.cn (CUIHUA XUEBAO) Supported by the Science Publication CHINESE JOURNAL OF CATALYSIS Foundation of the CAS Monthly Vol. 32 No. 2 February 2011 Contents Review Chin. J. Catal., 2011, 32: 207–216 doi: 10.1016/S1872-2067(10)60166-0 Carbon Materials as Catalysts for Decomposition and CO2 Reforming of Methane: A Review Beatriz FIDALGO, J. Ángel MENÉNDEZ* Instituto Nacional del Carbón (CSIC), Spain 2H2 CH4 CO2 2CO Methane CO 2 C decomposition C gasification DRY REFORMING CH4 + CO2 = 2H2 + 2CO Decomposition and CO2 reforming of methane over carbon catalysts are reviewed. The focus was on the relationship between the physicochemical properties of the carbon catalysts and their catalytic activity and why they get deactivated. Communications Chin. J. Catal., 2011, 32: 217–223 doi: 10.1016/S1872-2067(10)60167-2 Dynamic Hydrothermal Synthesis of a b-Oriented MFI Zeolite Film LI Xianming, WANG Zhengbao*, ZHENG Jie, SHAO Shiqun, WANG Yinchao, YAN Yushan Zhejiang University, China; University of California, Riverside, USA Continuous b-oriented MFI zeolite films were prepared using a rotating convection oven.
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