XIX IMEKO World Congress Fundamental and Applied Metrology September 6 11, 2009, Lisbon, Portugal THERMAL DESORPTION MASS SPECTROMETRY (TDS) APPLICATION ON MASS METROLOGY Zaccaria Silvestri1 and Patrick Pinot2 1Laboratoire commun de métrologie LNE-Cnam, La Plaine Saint-Denis, France,
[email protected] 2Laboratoire commun de métrologie LNE-Cnam, La Plaine Saint-Denis, France,
[email protected] Abstract A new device has been developed for the There are different elements that affect long term stability of study of physisorbed elements on polished and large surface a mass standard of high accuracy level such as: used in mass metrology. - physical and chemical characteristics of the This technique, based on the analysis by mass materials: spectrometry of desorbed molecules caused by heating o good hardness (>180 Hv) to facilitate under vacuum from the analyzed surface, is presented. machining, polishing and to reduce wear The first application of this device is the study of the when manipulating the artefact; current and future mass standards to understand the o high density in order to limit surface effect reactivity of their surface depending of the storage in air and so to have a more stable mass; conditions, of the cleaning process and polishing method. o good homogeneity without porosity, So, an example of surface contamination analysis by thermal cavity and occluded gases in order to desorption mass spectrometry (about cleaning effect on a guarantee long-term stability; super alloy based on cobalt) is given. o sufficient electrical conductivity to avoid accumulating electrostatic charges and Keywords: Mass spectrometry, thermal desorption, good thermal conductivity to minimize cleaning effect, contamination.