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Safety Data Sheet SAFETY DATA SHEET 1. Identification Product identifier Barium Fluoride (BaF2) targets Other means of identification SDS number 2GV Materion Code 2GV CAS number 7787-32-8 Synonyms BARIUM FLUORIDE * Barium difluoride (as F) * Barium difluoride Manufacturer/Importer/Supplier/Distributor information Manufacturer Company name Materion Advanced Chemicals Inc. Address 407 N 13th Street 1316 W. St. Paul Avenue Milwaukee, WI 53233 United States Telephone 414.212.0257 E-mail [email protected] Contact person Noreen Atkinson Emergency phone number Chemtrec 800.424.9300 2. Hazard(s) identification Physical hazards Not classified. Health hazards Acute toxicity, oral Category 3 Acute toxicity, inhalation Category 4 Serious eye damage/eye irritation Category 2 Reproductive toxicity Category 2 Specific target organ toxicity, single exposure Category 3 respiratory tract irritation Specific target organ toxicity, repeated Category 1 exposure Environmental hazards Not classified. OSHA defined hazards Not classified. Label elements Hazard symbol None. Signal word None. Hazard statement The Material as sold in solid form is generally not considered hazardous. However, if the process involves grinding, melting, cutting or any other process that causes a release of dust or fumes, hazardous levels of airborne particulate could be generated. Precautionary statement Prevention Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. Response Call a physician if symptoms develop or persist. Storage Store in a well-ventilated place. Keep container tightly closed. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise None known. classified (HNOC) Supplemental information None. Material name: Barium Fluoride (BaF2) targets SDS US 2GV Version #: 01 Issue date: 01-19-2018 1 / 6 3. Composition/information on ingredients Substances Chemical name Common name and synonyms CAS number % Barium Fluoride (BaF2) targets BARIUM FLUORIDE 7787-32-8 100 Barium difluoride (as F) Barium difluoride *Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a physician if symptoms develop or persist. Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation develops and persists. Ingestion Rinse mouth. Get medical advice/attention if you feel unwell. Most important May cause respiratory irritation. symptoms/effects, acute and delayed General information If you feel unwell, seek medical advice (show the label where possible). 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2). Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from During fire, gases hazardous to health may be formed. the chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire fighting Use water spray to cool unopened containers. equipment/instructions Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. General fire hazards No unusual fire or explosion hazards noted. 6. Accidental release measures Personal precautions, protective Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear equipment and emergency appropriate protective equipment and clothing during clean-up. Avoid inhalation of dust. Ensure procedures adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for Avoid dispersal of dust in the air (i.e., clearing dust surfaces with compressed air). Stop the flow of containment and cleaning up material, if this is without risk. Large Spills: Wet down with water and dike for later disposal. Shovel the material into waste container. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains, water courses or onto the ground. Material name: Barium Fluoride (BaF2) targets SDS US 2GV Version #: 01 Issue date: 01-19-2018 2 / 6 7. Handling and storage Precautions for safe handling Minimize dust generation and accumulation. Avoid breathing dust. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Use only outdoors or in a well-ventilated area. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Conditions for safe storage, Store locked up. Store in original tightly closed container. Store in a well-ventilated place. Store including any incompatibilities away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-2 (29 CFR 1910.1000) Material Type Value Form Barium Fluoride (BaF2) TWA 2.5 mg/m3 Dust. targets (CAS 7787-32-8) Biological limit values ACGIH Biological Exposure Indices Material Value Determinant Specimen Sampling Time Barium Fluoride (BaF2) 3 mg/l Fluoride Urine * targets (CAS 7787-32-8) 2 mg/l Fluoride Urine * * - For sampling details, please see the source document. Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Control parameters Follow standard monitoring procedures. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove supplier. Other Wear suitable protective clothing. Use of an impervious apron is recommended. Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. Chemical respirator with organic vapor cartridge. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations Keep away from food and drink. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. 9. Physical and chemical properties Appearance Physical state Solid. Form Solid. Color Not available. Odor Not available. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling Not available. range Flash point Not available. Material name: Barium Fluoride (BaF2) targets SDS US 2GV Version #: 01 Issue date: 01-19-2018 3 / 6 Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower Not available. (%) Flammability limit - upper Not available. (%) Explosive limit - lower (%) Not available. Explosive limit - upper (%) Not available. Vapor pressure < 0.0000001 kPa at 25 °C Vapor density Not available. Relative density Not available. Solubility(ies) Solubility (water) Not available. Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Explosive properties Not explosive. Molecular formula BaF2 Molecular weight 19 g/mol Oxidizing properties Not oxidizing. 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous Hazardous polymerization does not occur. reactions Conditions to avoid Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition No hazardous decomposition products are known. products 11. Toxicological information Information on likely routes of exposure Inhalation Harmful if inhaled. Skin contact No adverse effects due to skin contact are expected. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Toxic if swallowed. Symptoms related to the Direct contact with eyes may cause temporary irritation. physical, chemical and toxicological characteristics Information on toxicological effects Acute toxicity Not available. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye Direct contact with eyes may cause temporary irritation. irritation Material
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