DOCSLIB.ORG

Emergent Phenomena in Spin Crossover Systems

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Emergent Phenomena in Spin Crossover Systems Emergent Phenomena in Spin Crossover Systems Jace Alex Cruddas B.Sc. (Hons) Candidate’s ORCID A thesis submitted for the degree of Doctor of Philosophy at The University of Queensland in Year School of Mathematics and Physics Abstract In general, a spin crossover (SCO) system is any complex, material or framework containing two thermodynamically accessible spin-states: one high-spin (HS) and one low-spin (LS). The transition between spin-states is addressable by temperature, pressure, light irradiation, electric and magnetic fields, and chemical environment. The transition itself can be first-order, exhibiting hysteresis, continuous or a crossover. Typically, accompanied by the ferroelastic ordering of spin-states. It can also be part of an incomplete or multi-step transition accompanied by the antiferroelastic ordering of spin-states. In general, any alterations to the structural characteristics of SCO systems can have an effect on their bulk properties and behaviours. Consequently, constructing structure-property relations has traditionally been an extremely challenging task, and one of both great theoretical and experimental interest. Understanding the mechanisms behind these bulk properties and behaviours could lead to the rational design of SCO systems with enhanced applications and the synthesis of novel properties and behaviours. In this thesis we show that a simple, elastic model of SCO systems hosts almost all experimentally reported SCO properties and behaviours. We demonstrate clear structure-property relations that explain these results, derive the mechanisms of multi-step transitions and explain why and how intermolecular interactions play a role. We also propose that a new exotic state of matter could exist in elastically frustrated SCO materials and frameworks. In this phase “spin-state ice”, so-called in analogy to water- and spin- ice, the metal ions lack any kind of long-range order. Instead, local clusters of metal ions follow a local ‘ice rule’. For example on the kagome lattice, each triangle is constrained to have two metal ions in one spin-state and one in the other. The excitations are deconfined quasi-particles, with a fractionalised spin midway between that of the HS and LS states. We show that distinctive signatures of spin-state ice can be measured by neutron scattering, electron paramagnetic resonance, and thermodynamic experiments. Unlike other examples of ices that have been theorized to exist, the unique nature of SCO systems allows for multiple spin-state ice phases to exist on the same lattice with unique properties that can be tuned with external parameters, like temperature and pressure. Declaration by author This thesis is composed of my original work, and contains no material previously published or written by another person except where due reference has been made in the text. I have clearly stated the contribution by others to jointly-authored works that I have included in my thesis. I have clearly stated the contribution of others to my thesis as a whole, including statistical assistance, survey design, data analysis, significant technical procedures, professional editorial advice, financial support and any other original research work used or reported in my thesis. The content of my thesis is the result of work I have carried out since the commencement of my higher degree by research candidature and does not include a substantial part of work that has been submitted to qualify for the award of any other degree or diploma in any university or other tertiary institution. I have clearly stated which parts of my thesis, if any, have been submitted to qualify for another award. I acknowledge that an electronic copy of my thesis must be lodged with the University Library and, subject to the policy and procedures of The University of Queensland, the thesis be made available for research and study in accordance with the Copyright Act 1968 unless a period of embargo has been approved by the Dean of the Graduate School. I acknowledge that copyright of all material contained in my thesis resides with the copyright holder(s) of that material. Where appropriate I have obtained copyright permission from the copyright holder to reproduce material in this thesis and have sought permission from co-authors for any jointly authored works included in the thesis. Publications included in this thesis • [1] Jace Cruddas, and Ben J. Powell, Structure–property relationships and the mechanisms of multistep transitions in spin crossover materials and frameworks, Inorg. Chem. Frount., Advance Article, 10.1039/D0QI00799D (2020). • [2] Jace Cruddas, and Ben J. Powell, Spin-State Ice in Elastically Frustrated Spin-Crossover Materials, J. Am. Chem. Soc. 141, 19790 (2019). Submitted manuscripts included in this thesis • [3] Jace Cruddas, and Ben J. Powell, Multiple Coulomb phases with temperature tunable ice rules in pyrochlore spin crossover materials, arXiv:2007.13983 (2020). Other publications during candidature • [176] Gian Ruzzi, Jace Cruddas, Rozz H. McKenzie and Ben J. Powell, Equivalence of elastic and Ising models for spin crossover materials, arXiv:2008.08738 (2020). Contributions by others to the thesis Elise P. Kenny and Ben J. Powell helped with the proof-reading of this thesis. Ross H. McKenzie provided the argument summarized in Fig. 3.3. All the others contributions made to this thesis are clearly documented on the page preceding the relevant chapter. Statement of parts of the thesis submitted to qualify for the award of another degree No works submitted towards another degree have been included in this thesis. Research involving human or animal subjects No animal or human subjects were involved in this research. Acknowledgments I would like to thank Elise Kenny for proof reading my thesis, and Ben Powell, Ross McKenzie, Xiuwen Zhou, Alejandro Mezio, Cameron Kepert, Suzanne Neville, Stephan Rachel, Nic Shannon, Yaroslav Kharkov, Grace Morgan, Timo Nieminen, Gian Ruzzi, Nadeem Muhammad, Nena Batenberg and Blake Peterson for their helpful conversations. In addition, I would like to extend my thanks to my family, my friends, the bartenders who served me, the bartenders who refused to serve me, and the current and former personnel of the School of Mathematics and Physics for their immeasurable support. Financial support This work was funded by the Australian Research Council through grant number DP200100305 and an Australian Government Research Training Program Scholarship. Keywords spin crossover, spin transitions, ice, spin ice, exotic states of matter, fractionalization, quasi-particles, structure-property relations, phase transitions, frustration Australian and New Zealand Standard Research Classifications (ANZSRC) 020499 Condensed Matter Physics not elsewhere classified, 60% 030206 Solid State Chemistry, 20% 030207 Transition Metal Chemistry, 20% Fields of Research (FoR) Classification 0204 Condensed Matter Physics, 60% 0302 Inorganic Chemistry, 40% Contents Abstract . ii Contents vii List of Figures ix List of Tables xii 1 Introduction 1 1.1 Frustration . 3 1.1.1 Importance of Frustration . 3 1.1.2 Landau theory and phase transitions . 4 1.1.3 Unfrustrated systems . 7 1.1.4 Frustrated Systems . 11 1.2 Microscopic Origin of Spin Crossover Systems . 19 1.2.1 A Brief Introduction to Coordination Chemistry . 19 1.2.2 Crystal field theory . 21 1.2.3 Molecular orbital theory . 23 1.2.4 Ligand Field Theory . 26 1.3 Spin crossover . 30 1.3.1 Importance of Spin Crossover . 30 1.3.2 Spin Crossover in the Solid state . 30 1.3.3 Models of Spin Crossover . 32 1.4 Thesis Outline . 37 2 Structure–property relationships 41 2.1 Introduction . 41 2.2 Model . 45 2.2.1 Elastic interactions in materials . 48 2.3 Methods . 49 2.4 Results and Discussion . 50 2.4.1 Nearest- and Next Nearest-Neighbour Interactions . 50 vii viii CONTENTS 2.4.2 Third Nearest-Neighbour Interactions . 53 2.4.3 Longer Range Interactions . 56 2.5 Conclusions . 59 2.6 Supplementary Information . 60 2.6.1 Expansion of the potential . 60 2.6.2 Additional results . 61 3 Spin-State Ice 73 3.1 Introduction . 73 3.2 Model . 78 3.3 Monte Carlo calculations . 81 3.4 Results and discussion . 81 3.5 Conclusions . 86 3.6 Supplementary Information . 88 3.6.1 Mapping between spin ice rules and spin-state ice rules . 88 3.6.2 Snapshots of Monte Carlo simulations . 88 4 Multiple Coulomb phases 95 4.1 Introduction . 95 4.2 Model . 96 4.3 Results and Discussion . 98 4.4 Conclusion . 102 4.5 Supplementary Information . 104 4.5.1 Monte Carlo simulations . 104 5 Conclusion 109 Bibliography 111 List of Figures 1.1 Illustration of spontaneous symmetry breaking transition. 3 1.2 Cartoon of frustration. 4 1.3 Cartoon phase diagram of H2O................................ 5 1.4 First-order transition. 6 1.5 Magnetic phases of the Ising model. 8 1.6 Ising Mean-field phase diagrams. 10 1.7 Illustration the 1h phase and the ice rules. 12 1.8 Examples of frustrated Lattices. 13 1.9 Ice rules for equivalent systems. 14 1.10 Illustration of pinch point singularities in the structure factor. 17 1.11 Propagation of defects in vertex ice. 18 1.12 Example of a coordination complex. 20 1.13 Molecular geometries of coordination complexes. 20 1.14 Illustration of crystal field splitting. 22 1.15 Illustration of bonding and antibonding orbitals. 24 1.16 Molecular orbitals for a ML6 complex. 25 1.17 Possible spin-states for a ML6 complex. 27 6 1.18 Tanabe-Sugano diagram for a ML6 complex with d . ................... 29 1.19 Vibronic levels for a spin crossover complex. 29 1.20 Examples of spin crossovers and transitions. 31 1.21 Thermodynamic properties of a non-interacting Ising-like model. 35 1.22 Thermodynamic properties of an Ising-like model. 35 1.23 Diagram of the elastic model. 36 2.1 Antiferroelastic spin-state orderings for the elastic model with non-zero k1, k2, k3 and k5.
Load more

Recommended publications
  • Investigation of the Magnetic and Magnetocaloric Properties of Complex Lanthanide Oxides
    Investigation of the magnetic and magnetocaloric properties of complex lanthanide oxides Paromita Mukherjee Department of Physics University of Cambridge This dissertation is submitted for the degree of Doctor of Philosophy King’s College April 2018 This thesis is dedicated to my parents. Declaration I hereby declare that except where specific reference is made to the work of others, the contents of this dissertation are original and have not been submitted in whole or in part for consideration for any other degree or qualification in the University of Cambridge, or any other university. This dissertation is my own work and contains nothing which is the outcome of work done in collaboration, except as specified in the text and Acknowledgements. This dissertation contains fewer than 60,000 words including abstract, tables, footnotes and appendices. Some of the work described herein has been published as follows: Chapter 3 is an expanded version of: P. Mukherjee, A. C. Sackville Hamilton, H. F. J. Glass, S. E. Dutton, Sensitivity of magnetic properties to chemical pressure in lanthanide garnets Ln3A2X3O12, Ln = Gd, Tb, Dy, Ho, A = Ga, Sc, In, Te, X = Ga, Al, Li, Journal of Physics: Condensed Matter 29, 405808 (2017). Chapter 4 contains material from: P. Mukherjee, S. E. Dutton, Enhanced magnetocaloric effect from Cr substitution in Ising lanthanide gallium garnets Ln3CrGa4O12 (Ln = Tb, Dy, Ho), Advanced Functional Materials 27, 1701950 (2017). P. Mukherjee, H. F. J. Glass, E. Suard, and S. E. Dutton, Relieving the frustration through Mn3+ substitution in holmium gallium garnet, Physical Review B 96, 140412(R) (2017). Chapter 5 contains material from: P.
    [Show full text]
  • A Highly Scalable Dynamical Matrix Approach Applied to a Fibonacci- Distorted Artificial Spin Ice
    University of Kentucky UKnowledge Physics and Astronomy Faculty Publications Physics and Astronomy 3-8-2021 Magnetic Normal Mode Calculations in Big Systems: A Highly Scalable Dynamical Matrix Approach Applied to a Fibonacci- Distorted Artificial Spin Ice Loris Giovannini Università di Ferrara, Italy Barry W. Farmer University of Kentucky, [email protected] Justin S. Woods University of Kentucky, [email protected] Ali Frotanpour University of Kentucky, [email protected] Lance E. De Long University of Kentucky, [email protected] Follow this and additional works at: https://uknowledge.uky.edu/physastron_facpub See next page for additional authors Part of the Physics Commons Right click to open a feedback form in a new tab to let us know how this document benefits ou.y Repository Citation Giovannini, Loris; Farmer, Barry W.; Woods, Justin S.; Frotanpour, Ali; De Long, Lance E.; and Montoncello, Federico, "Magnetic Normal Mode Calculations in Big Systems: A Highly Scalable Dynamical Matrix Approach Applied to a Fibonacci-Distorted Artificial Spin Ice" (2021). Physics and Astronomy Faculty Publications. 673. https://uknowledge.uky.edu/physastron_facpub/673 This Article is brought to you for free and open access by the Physics and Astronomy at UKnowledge. It has been accepted for inclusion in Physics and Astronomy Faculty Publications by an authorized administrator of UKnowledge. For more information, please contact [email protected]. Magnetic Normal Mode Calculations in Big Systems: A Highly Scalable Dynamical Matrix Approach Applied to a Fibonacci-Distorted Artificial Spin Ice Digital Object Identifier (DOI) https://doi.org/10.3390/magnetochemistry7030034 Notes/Citation Information Published in Magnetochemistry, v.
    [Show full text]
  • Emergence of Nontrivial Spin Textures in Frustrated Van Der Waals Ferromagnets
    nanomaterials Article Emergence of Nontrivial Spin Textures in Frustrated Van Der Waals Ferromagnets Aniekan Magnus Ukpong Theoretical and Computational Condensed Matter and Materials Physics Group, School of Chemistry and Physics, University of KwaZulu-Natal, Pietermaritzburg 3201, South Africa; [email protected]; Tel.: +27-33-260-5875 Abstract: In this work, first principles ground state calculations are combined with the dynamic evolution of a classical spin Hamiltonian to study the metamagnetic transitions associated with the field dependence of magnetic properties in frustrated van der Waals ferromagnets. Dynamically stabilized spin textures are obtained relative to the direction of spin quantization as stochastic solutions of the Landau–Lifshitz–Gilbert–Slonczewski equation under the flow of the spin current. By explicitly considering the spin signatures that arise from geometrical frustrations at interfaces, we may observe the emergence of a magnetic skyrmion spin texture and characterize the formation under competing internal fields. The analysis of coercivity and magnetic hysteresis reveals a dynamic switch from a soft to hard magnetic configuration when considering the spin Hall effect on the skyrmion. It is found that heavy metals in capped multilayer heterostructure stacks host field-tunable spiral skyrmions that could serve as unique channels for carrier transport. The results are discussed to show the possibility of using dynamically switchable magnetic bits to read and write data without the need for a spin transfer torque. These results offer insight to the spin transport signatures that Citation: Ukpong, A.M. Emergence dynamically arise from metamagnetic transitions in spintronic devices. of Nontrivial Spin Textures in Frustrated Van Der Waals Keywords: spin current; van der Waals ferromagnets; magnetic skyrmion; spin Hall effect Ferromagnets.
    [Show full text]
  • Quantum Spin-Ice and Dimer Models with Rydberg Atoms
    PHYSICAL REVIEW X 4, 041037 (2014) Quantum Spin-Ice and Dimer Models with Rydberg Atoms A. W. Glaetzle,1,2,* M. Dalmonte,1,2 R. Nath,1,2,3 I. Rousochatzakis,4 R. Moessner,4 and P. Zoller1,2 1Institute for Quantum Optics and Quantum Information of the Austrian Academy of Sciences, A-6020 Innsbruck, Austria 2Institute for Theoretical Physics, University of Innsbruck, A-6020 Innsbruck, Austria 3Indian Institute of Science Education and Research, Pune 411 008, India 4Max Planck Institute for the Physics of Complex Systems, D-01187 Dresden, Germany (Received 21 April 2014; revised manuscript received 27 August 2014; published 25 November 2014) Quantum spin-ice represents a paradigmatic example of how the physics of frustrated magnets is related to gauge theories. In the present work, we address the problem of approximately realizing quantum spin ice in two dimensions with cold atoms in optical lattices. The relevant interactions are obtained by weakly laser-admixing Rydberg states to the atomic ground-states, exploiting the strong angular dependence of van der Waals interactions between Rydberg p states together with the possibility of designing steplike potentials. This allows us to implement Abelian gauge theories in a series of geometries, which could be demonstrated within state-of-the-art atomic Rydberg experiments. We numerically analyze the family of resulting microscopic Hamiltonians and find that they exhibit both classical and quantum order by disorder, the latter yielding a quantum plaquette valence bond solid. We also present strategies to implement Abelian gauge theories using both s- and p-Rydberg states in exotic geometries, e.g., on a 4–8 lattice.
    [Show full text]
  • Spectroscopy of Spinons in Coulomb Quantum Spin Liquids
    MIT-CTP-5122 Spectroscopy of spinons in Coulomb quantum spin liquids Siddhardh C. Morampudi,1 Frank Wilczek,2, 3, 4, 5, 6 and Chris R. Laumann1 1Department of Physics, Boston University, Boston, MA 02215, USA 2Center for Theoretical Physics, MIT, Cambridge MA 02139, USA 3T. D. Lee Institute, Shanghai, China 4Wilczek Quantum Center, Department of Physics and Astronomy, Shanghai Jiao Tong University, Shanghai 200240, China 5Department of Physics, Stockholm University, Stockholm Sweden 6Department of Physics and Origins Project, Arizona State University, Tempe AZ 25287 USA We calculate the effect of the emergent photon on threshold production of spinons in U(1) Coulomb spin liquids such as quantum spin ice. The emergent Coulomb interaction modifies the threshold production cross- section dramatically, changing the weak turn-on expected from the density of states to an abrupt onset reflecting the basic coupling parameters. The slow photon typical in existing lattice models and materials suppresses the intensity at finite momentum and allows profuse Cerenkov radiation beyond a critical momentum. These features are broadly consistent with recent numerical and experimental results. Quantum spin liquids are low temperature phases of mag- The most dramatic consequence of the Coulomb interaction netic materials in which quantum fluctuations prevent the between the spinons is a universal non-perturbative enhance- establishment of long-range magnetic order. Theoretically, ment of the threshold cross section for spinon pair production these phases support exotic fractionalized spin excitations at small momentum q. In this regime, the dynamic structure (spinons) and emergent gauge fields [1–4]. One of the most factor in the spin-flip sector observed in neutron scattering ex- promising candidate class of these phases are U(1) Coulomb hibits a step discontinuity, quantum spin liquids such as quantum spin ice - these are ex- 1 q 2 q2 pected to realize an emergent quantum electrodynamics [5– S(q;!) ∼ S0 1 − θ(! − 2∆ − ) (1) 11].
    [Show full text]
  • Magnetic Monopoles in Spin Ice
    Master of Science Thesis Magnetic Monopoles in Spin Ice Axel Nordstr¨om Supervisor: Patrik Henelius Department of Theoretical Physics, School of Engineering Sciences Royal Institute of Technology, SE-106 91 Stockholm, Sweden Stockholm, Sweden 2014 Typeset in LATEX Examensarbete inom ¨amnet teoretisk fysik f¨or avl¨aggande av civilingenj¨orsexamen inom utbildningstprogrammet Teknisk fysik. Graduation thesis on the subject Theoretical Physics for the degree of Master of Science in Engineering from the School of Engineering Sciences. TRITA-FYS 2014:26 ISSN 0280-316X ISRN KTH/FYS/{14:26{SE © Axel Nordstr¨om,May 2014 Printed in Sweden by Universitetsservice US AB, Stockholm May 2014 Abstract In this thesis, we investigate the behaviour of magnetic monopoles in spin ice when an external magnetic field is applied. We find that steady state direct currents of magnetic monopoles cannot be maintained for long and consider the possibility of alternating magnetic currents by investigating the alternating current susceptibility using both analytical and Monte Carlo techniques. Moreover, we look at the transition that occurs when a magnetic field is ap- plied in a 111 direction. We show that the transition is a continuous crossover rather thanh a phasei transition in the nearest neighbour model and we study the behaviour of the system during the crossover, especially at the critical field where a temperature independent state appears. Using Monte Carlo methods and analyti- cal methods based on the Bethe approximation, we find that the mean monopole density is 0.4 monopoles per tetrahedron in the temperature independent state at the critical field. Keywords: spin ice, magnetic monopoles, phase transitions.
    [Show full text]
  • Neutron Scattering Studies of Spin Ices and Spin Liquids
    Collection SFN 13, 04001 (2014) DOI: 10.1051/sfn/20141304001 C Owned by the authors, published by EDP Sciences, 2014 Neutron scattering studies of spin ices and spin liquids T. Fennell Laboratory for Neutron Scattering, Paul Scherrer Institut, 5232 Villigen PSI, Switzerland Abstract. In frustrated magnets, competition between interactions, usually due to incompatible lattice and exchange geometries, produces an extensively degenerate manifold of groundstates. Exploration of these states results in a highly correlated and strongly fluctuating cooperative paramagnet, a broad classification which includes phases such as spin liquids and spin ices. Generally, there is no long range order and associated broken symmetry, so quantities typically measured by neutron scattering such as magnetic Bragg peaks and magnon dispersions are absent. Instead, spin correlations characterized by emergent gauge structure and exotic fractional quasiparticles may emerge. Neutron scattering is still an excellent tool for the investigation these phenomena, and this review outlines examples of frustrated magnets on the pyrochlore and kagome lattices with reference to experiments and quantities of interest for neutron scattering. 1. PREAMBLE In physics, a frustrated system is one in which all interactions cannot be simultaneously minimized, which is also to say that there is competition amongst the interactions. Frustration is most commonly associated with spin systems [1], where its consequences can be particularly well identified, but is by no means limited to magnetism. Frustrated interactions are also relevant in certain structural problems [2–6], colloids and liquid crystals [7], spin glasses [8], stripe phases [9, 10], Josephson junction arrays [11], stellar nuclear matter [12, 13], social dynamics [14], origami [15], and protein folding [16], to name a few.
    [Show full text]
  • Spin Ice in a Field: Quasi-Phases and Pseudo-Transitions
    Spin ice in a field: quasi-phases and pseudo-transitions. P.N. Timonin Southern Federal University, Rostov-on-Don, 344090, Russia. Thermodynamics of the short-range model of spin ice magnets in a field is considered in the Bethe – Peierls approximation. The results obtained for [111], [100] and [011] fields agrees reasonably well with the existing Monte-Carlo simulations and some experiments. Quite remarkably all extremely sharp field-induced anomalies are described in this approximation by the analytical functions of temperature and applied field. In spite of the absence of true phase transitions the analysis of the entropy and specific heat reliefs over H-T plane allows in most cases to discern the “pseudo-phases” with specific character of spin fluctuations and outline the curves of more or less sharp “pseudo-transitions” between them. The discovery of spin ice compounds [1, 2] has opened a wide perspective in the studies of real geometrically frustrated magnets with their reach physics stemming from the macroscopically degenerate ground states. The more so as they can be described by the relatively simple Ising model with the nearest-neighbour exchange on the pyrochlore lattice. This is due to the lucky chance that strong dipole interactions in these compounds have a negligible effect on the low-energy excitations of the Ising moments directed along the lines connecting the centres of corner-sharing tetrahedra [3]. So low-temperature physics of spin-ices can be adequately captured by the short-range Ising model except for the ultra low temperatures where the equilibrium properties may be unobservable [4]. Such model predicts the absence of phase transitions in zero field in accordance with experiments in the (established) acknowledged spin ice compounds [1, 2].
    [Show full text]
  • Topological Constraints and Defects in Spin Ice Ludovic D.C
    Topological Constraints and Defects in Spin Ice Ludovic D.C. Jaubert To cite this version: Ludovic D.C. Jaubert. Topological Constraints and Defects in Spin Ice. Condensed Matter [cond-mat]. Ecole normale supérieure de lyon - ENS LYON, 2009. English. tel-00462970 HAL Id: tel-00462970 https://tel.archives-ouvertes.fr/tel-00462970 Submitted on 10 Mar 2010 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Distributed under a Creative Commons Attribution| 4.0 International License N◦ d’ordre : 528 N◦ attribu´epar la biblioth`eque : ENSL528 Th`ese en vue d’obtenir le grade de Docteur de l’Universit´ede Lyon - Ecole Normale Sup´erieure de Lyon Laboratoire de Physique, ENS Lyon Ecole Doctorale de Physique et d’Astrophysique de Lyon pr´esent´ee et soutenue publiquement le 23 / IX / 2009 par Ludovic D. C . Jaubert Topological Constraints and Defects in Spin Ice r´ealis´ee sous la direction de Peter C . W . Holdsworth Devant la commission d’examen form´ee de : M. Fabien Alet Membre/Rapporteur M. Leon Balents Membre M. Benjamin Canals Membre/Rapporteur M. Peter Holdsworth Directeur de th`ese M. Philippe Mendels Pr´esident M.
    [Show full text]
  • Publication List (May 2020) Armin Kleibert Publications in Refereed
    Publication List (May 2020) Armin Kleibert Publications in Refereed Scientific Journals 87. K. Hofhuis, A. Hrabec, H. Arava, N. Leo, Y.-L. Huang, R. V. Chopdekar, S. Parchenko, A. Kleibert, S. Koraltan, C. Abert, C. Vogler, D. Suess, P. M. Derlet, and L. J. Heyderman Thermally Superactive Artificial Kagome Spin Ice Structures Obtained with the Interfacial Dzyaloshinskii-Moriya Interaction Submitted (2020) 86. A. Ciuciulkaite, K. Mishra, M. V. Moro, I.-A. Chioar, R. Rowan Robinson, S. Parchenko, A. Kleibert, B. Lindgren, G. Andersson, C. Davies, A. Kimel, A. Kirilyuk, and V. Kapaklis Design of Amorphous TbxCo100-x Alloys for All-Optical Magnetization Switching Submitted (2020), arxiv.org/abs/2002.07544 85. H. Arava, E. Y. Vedmedenko, J. Cui, J. Vijayakumar, A. Kleibert, and L. J. Heyderman Control of Emergent Magnetic Monopole Currents in Artificial Spin Ice Submitted (2020) 84. B. Rösner, S. Finizio, F. Koch, F. Döring, V. A. Guzenko, M. Langer, E. Kirk, B. Watts, M. Meyer, J. Loroña Ornelas, A. Späth, S. Stanescu, S. Swaraj, R. Belkhou, T. Ishikawa, T. F. Keller, B. Gross, M. Poggio, R. H. Fink, J. Raabe, A. Kleibert, and C. David Soft X-Ray Microscopy with Single-Digit Nanometer Resolution Submitted (2020) 83. M. Saccone, K. Hofhuis, D. Bracher, A. Kleibert, S. van Dijken, and A. Farhan Elevated Effective Dimension in Tree-Like Nanomagnetic Cayley Structures Nanoscale 12, 189 (2020), DOI:10.1039/c9nr07510k 82. M. Wyss, S. Gliga, D. Vasyukov, L. Ceccarelli, G. Romagnoli, J. Cui, A. Kleibert, R. L. Stamps, and M. Poggio Stray-Field Imaging of a Chiral Artificial Spin Ice During Magnetization Reversal ACS Nano 13, 13910 (2019), DOI:10.1021/acsnano.9b05428 81.
    [Show full text]
  • Magnetic Monopoles in Spin Ice Physics of Bulk Spin Ice Materials
    Magnetricity and Monopoles Displacement vectors in water Magnetic Monopoles in Spin Ice Potential magnetic monopole capacitor? ice Spin vectors in Spin Ice (Bramwell & Harris 1997) • Spin ice materials like Ho2Ti2O7 are simple Artificial System: Nanomagnets atomic spins transparent crystals that include atoms of •Magnetic charge Q at each vertex in honeycomb “rare earth” elements arranged in corner- •Q=3 monopole defects linked tetrahedra. The atomic magnetic moments or “spins” point into or out of Q= +1 or Q= -1 Ice the tetrahedral (arrows). H2O - + • Magnetic monopoles - the magnetic - + + version of a charged particle like electrons - Spin flips make magnetic or protons – have recently been shown to monopoles analogous to water exist in spin ice. We have shown that ice’s ionic defects monopoles form a magnetic version of Q= +3 or Q= -3 electricity, or “magnetricity” at very low T. + - + - - + 2H2O = [H3O +OH ] = H3O +OH • We have fabricated arrays of nanomagnets in a spin ice geometry, to + - create magnetic monopole defects at room temperature Physics of Bulk Spin Ice Materials Monopoles in Artificial Spin Ice Nanostructures H •The spin ice state has been confirmed by neutron •Scanning electron scattering to be a vacuum for magnetic charge. SEM (a) (d) micrograph of the cobalt •Magnetic monopoles live in this vacuum. They honeycomb nanostructure.Q=+3 on are analogous to water’s ionic defects. Q=+1 site •Magnetic force micrograph H =-52.4 mT •Different spin ice materials have different Hx=-48.8mT x showing a negativelyQ=+1 on (b) (e) monopole concentrations. High pressure has been charged magnetic monopoleQ=-1 site used to create a new spin ice, Dy2Ge2O7 with the defect (bright yellow).
    [Show full text]
  • Magnetic Monopole Dynamics in Spin Ice L D C Jaubert, P C W Holdsworth
    Magnetic monopole dynamics in spin ice L D C Jaubert, P C W Holdsworth To cite this version: L D C Jaubert, P C W Holdsworth. Magnetic monopole dynamics in spin ice. Journal of Physics: Condensed Matter, IOP Publishing, 2011, 23, pp.164222. 10.1088/0953-8984/23/16/164222. hal- 01541666 HAL Id: hal-01541666 https://hal.archives-ouvertes.fr/hal-01541666 Submitted on 19 Jun 2017 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Distributed under a Creative Commons Attribution| 4.0 International License Magnetic Monopole Dynamics in Spin Ice L. D. C. Jaubert∗ and P. C. W. Holdsworth† October 6, 2010 ∗Max-Plack-Institut f¨ur Physik komplexer Systeme, 01187 Dresden, Germany. †Universit´ede Lyon, Laboratoire de Physique, Ecole´ Normale Sup´erieure de Lyon, 46 All´ee d’Italie, 69364 Lyon cedex 07, France. October 6, 2010 Abstract One of the most remarkable examples of emergent quasi-particles, is that of the ”fractionalization” of magnetic dipoles in the low energy configurations of materials known as ”spin ice”, into free and unconfined magnetic monopoles interacting via Coulomb’s 1/r law [Castelnovo et.
    [Show full text]