Vi-2842-1 28.42 (I) Salts of Non-Metal
Total Page：16
File Type：pdf, Size：1020Kb
Load more
Recommended publications
-
Transport of Dangerous Goods
ST/SG/AC.10/1/Rev.16 (Vol.I) Recommendations on the TRANSPORT OF DANGEROUS GOODS Model Regulations Volume I Sixteenth revised edition UNITED NATIONS New York and Geneva, 2009 NOTE The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the Secretariat of the United Nations concerning the legal status of any country, territory, city or area, or of its authorities, or concerning the delimitation of its frontiers or boundaries. ST/SG/AC.10/1/Rev.16 (Vol.I) Copyright © United Nations, 2009 All rights reserved. No part of this publication may, for sales purposes, be reproduced, stored in a retrieval system or transmitted in any form or by any means, electronic, electrostatic, magnetic tape, mechanical, photocopying or otherwise, without prior permission in writing from the United Nations. UNITED NATIONS Sales No. E.09.VIII.2 ISBN 978-92-1-139136-7 (complete set of two volumes) ISSN 1014-5753 Volumes I and II not to be sold separately FOREWORD The Recommendations on the Transport of Dangerous Goods are addressed to governments and to the international organizations concerned with safety in the transport of dangerous goods. The first version, prepared by the United Nations Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, was published in 1956 (ST/ECA/43-E/CN.2/170). In response to developments in technology and the changing needs of users, they have been regularly amended and updated at succeeding sessions of the Committee of Experts pursuant to Resolution 645 G (XXIII) of 26 April 1957 of the Economic and Social Council and subsequent resolutions. -
Phosphorus and Sulfur Cosmochemistry: Implications for the Origins of Life
Phosphorus and Sulfur Cosmochemistry: Implications for the Origins of Life Item Type text; Electronic Dissertation Authors Pasek, Matthew Adam Publisher The University of Arizona. Rights Copyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author. Download date 07/10/2021 06:16:37 Link to Item http://hdl.handle.net/10150/194288 PHOSPHORUS AND SULFUR COSMOCHEMISTRY: IMPLICATIONS FOR THE ORIGINS OF LIFE by Matthew Adam Pasek ________________________ A Dissertation Submitted to the Faculty of the DEPARTMENT OF PLANETARY SCIENCE In Partial Fulfillment of the Requirements For the Degree of DOCTOR OF PHILOSOPHY In the Graduate College UNIVERSITY OF ARIZONA 2 0 0 6 2 THE UNIVERSITY OF ARIZONA GRADUATE COLLEGE As members of the Dissertation Committee, we certify that we have read the dissertation prepared by Matthew Adam Pasek entitled Phosphorus and Sulfur Cosmochemistry: Implications for the Origins of Life and recommend that it be accepted as fulfilling the dissertation requirement for the Degree of Doctor of Philosophy _______________________________________________________________________ Date: 04/11/2006 Dante Lauretta _______________________________________________________________________ Date: 04/11/2006 Timothy Swindle _______________________________________________________________________ Date: 04/11/2006 -
Vanadate-Molybdate Reagent Safety Data Sheet According to Federal Register / Vol
Vanadate-Molybdate Reagent Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 12/20/2013 Revision date: 05/02/2014 Supersedes: 12/20/2013 Version: 1.1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : Vanadate-Molybdate Reagent Product code : LC26600 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : For laboratory and manufacturing use only. 1.3. Details of the supplier of the safety data sheet LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 [email protected] - www.labchem.com 1.4. Emergency telephone number Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Skin Corr. 1B H314 Eye Dam. 1 H318 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS05 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H314 - Causes severe skin burns and eye damage Precautionary statements (GHS-US) : P260 - Do not breathe mist, vapours, spray P264 - Wash exposed skin thoroughly after handling P280 - Wear protective gloves, eye protection, protective clothing, face protection P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. -
Primary-Explosives
Improvised Primary Explosives © 1998 Dirk Goldmann No part of the added copyrighted parts (except brief passages that a reviewer may quote in a review) may be reproduced in any form unless the reproduced material includes the following two sentences: The copyrighted material may be reproduced without obtaining permission from anyone, provided: (1) all copyrighted material is reproduced full-scale. WARNING! Explosives are danegerous. In most countries it's forbidden to make them. Use your mind. You as an explosives expert should know that. 2 CONTENTS Primary Explosives ACETONE PEROXIDE 4 DDNP/DINOL 6 DOUBLE SALTS 7 HMTD 9 LEAD AZIDE 11 LEAD PICRATE 13 MEKAP 14 MERCURY FULMINATE 15 "MILK BOOSTER" 16 NITROMANNITE 17 SODIUM AZIDE 19 TACC 20 Exotic and Friction Primers LEAD NITROANILATE 22 NITROGEN SULFIDE 24 NITROSOGUANIDINE 25 TETRACENE 27 CHLORATE-FRICTION PRIMERS 28 CHLORATE-TRIMERCURY-ACETYLIDE 29 TRIHYDRAZINE-ZINC (II) NITRATE 29 Fun and Touch Explosives CHLORATE IMPACT EXPLOSIVES 31 COPPER ACETYLIDE 32 DIAMMINESILVER II CHLORATE 33 FULMINATING COPPER 33 FULMINATING GOLD 34 FULMINATING MERCURY 35 FULMINATING SILVER 35 NITROGEN TRICHLORIDE 36 NITROGEN TRIIODIDE 37 SILVER ACETYLIDE 38 SILVER FULMINATE 38 "YELLOW POWDER" 40 Latest Additions 41 End 3 PRIMARY EXPLOSIVES ACETONE PEROXIDE Synonyms: tricycloacetone peroxide, acetontriperoxide, peroxyacetone, acetone hydrogen explosive FORMULA: C9H18O6 VoD: 3570 m/s @ 0.92 g/cc. 5300 m/s @ 1.18 g/cc. EQUIVALENCE: 1 gram = No. 8 cap .75 g. = No. 6 cap SENSITIVITY: Very sensitive to friction, flame and shock; burns violently and can detonate even in small amounts when dry. DRAWBACKS: in 10 days at room temp. 50 % sublimates; it is best made immediately before use. -
Ethanol Denatured
GHS SAFETY DATA SHEET DENATURED ETHANOL SDS DATE: 03/10/2021 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME (GHS Product Identifier): Denatured Ethanol (Other means of Identification): Denatured Ethyl Alcohol PRODUCT INTENDED USE AND RESTRICTION: Automobile fuel, fuel additive NAME, ADDRESS & TELEPHONE NUMBER OF THE RESPONSIBLE PARTY: Company Green Plains Trade Group LLC 1811 Aksarben Drive, Omaha, NE 68106 Phone: 402-884-8700 Email: [email protected] CHEMTREC PHONE (24HR Emergency Telephone): 1-800-424-9300 (Within U.S.A) INTERNATIONAL CHEMTREC CALL: 1-703-527-3887 OTHER CALLS: 1-402-884-8700 (M-F, 8 AM-5 PM, Central time (U.S.A & Canada); within U.S.A) FAX PHONE: 1-402-884-8776 (M-F, 8 AM-5 PM, Central time (U.S.A & Canada); within U.S.A) SECTION 1 NOTES: None Available SECTION 2: HAZARDS IDENTIFICATION GHS LABELING AND CLASSIFICATION: This product meets the definition of the following hazard classes as defined by the Globally Harmonized System of Classification and Labeling of Chemicals (GHS). GHS CLASSIFICATION ACCORDING TO ANNEX II: HEALTH ENVIRONMENTAL PHYSICAL Serious eye damage/eye irritation-2A Not classified Flammable Liquids-Category 2 Skin corrosion/irration-3 STOT SE-2 Acute toxicity (Oral)-Category 4 SIGNAL WORD: DANGER SYMBOL: HAZARD STATEMENT: H225: Highly flammable liquid and vapor. H319: Causes serious eye irritation. H315: Causes skin irritation. H335: May cause respiratory irritation H336: May cause drowsiness or dizziness H302: Harmful if swallowed. PREVENTIVE: P201: Obtain special instructions before use. P202: Do not handle until all safety precautions have been read and understood P210-Keep away from heat/sparks/open flames/hot surfaces.—No smoking. -
Chapter 2 EXPLOSIVES
Chapter 2 EXPLOSIVES This chapter classifies commercial blasting compounds according to their explosive class and type. Initiating devices are listed and described as well. Military explosives are treated separately. The ingredi- ents and more significant properties of each explosive are tabulated and briefly discussed. Data are sum- marized from various handbooks, textbooks, and manufacturers’ technical data sheets. THEORY OF EXPLOSIVES In general, an explosive has four basic characteristics: (1) It is a chemical compound or mixture ignited by heat, shock, impact, friction, or a combination of these conditions; (2) Upon ignition, it decom- poses rapidly in a detonation; (3) There is a rapid release of heat and large quantities of high-pressure gases that expand rapidly with sufficient force to overcome confining forces; and (4) The energy released by the detonation of explosives produces four basic effects; (a) rock fragmentation; (b) rock displacement; (c) ground vibration; and (d) air blast. A general theory of explosives is that the detonation of the explosives charge causes a high-velocity shock wave and a tremendous release of gas. The shock wave cracks and crushes the rock near the explosives and creates thousands of cracks in the rock. These cracks are then filled with the expanding gases. The gases continue to fill and expand the cracks until the gas pressure is too weak to expand the cracks any further, or are vented from the rock. The ingredients in explosives manufactured are classified as: Explosive bases. An explosive base is a solid or a liquid which, upon application or heat or shock, breaks down very rapidly into gaseous products, with an accompanying release of heat energy. -
The Use Op Cobalt-60 As a Radiotracer in a Study Op
THE USE OP COBALT-60 AS A RADIOTRACER IN A STUDY OP THE ANALYTICAL CHEMISTRY OF COBALT DISSERTATION Presented in Partial Fulfillment of the Requirements for the Degree Doctor of Philosophy in the Graduate School of the Ohio State University By DARNELL SALYER, B. S. The Ohio State University 1956 Approvec by: Adv^rer Department of Chemistry ACKNOWLEDGMENT The author would like to express his sincere appre ciation to Dr. T. R. Sweet for his guidance and advice during the period of this research. The author’s wife, Octavia Elizabeth Salyer, has been a source of help and encouragement during the con clusion of this work and the oreparation of the manuscript. Most of this work was completed while the author held graduate fellowships from the Cincinnati Chemical vVorks (1954-55) and the Central Division of the Allied Chemical and Dye Corporation (1955-56). The aid provided by these fellowsnips is gratefully acknowledged. ii Table of Contents Page INTRODUCTION ................................................ 1 THE ANODIC DEPOSITION PROBLEM........................... 9 Theory of Anodic Deposition ...................... 9 Conditions for the Deposition of C o b a l t ......... 13 Promising Methods, A Qualitative Study........... 16 Reproducibility, A Quantitative Study ........... 17 Nature of the Deposits................. ........... 27 Ignition of Deposits............................... 33 Summary of Optimum Conditions for Plating and Weighing...................................... 34 Preparation of the Standard Curve ................ 37 Interference Study.................................. 41 DETERMINATION OF SMALL AMOUNTS OF COBALT BY THE ISOTOPE DILUTION-ANODIC DEPOSITION' METHOD . 4 6 Separation of Cobalt from Iron............... 49 Conclusion................................... 49 A STUDY OF THE CATHODIC ElECTRODEPOSITION METHOD FOR oOBALT »»»»»••••»»»..»»•».»• 31 Previous W o r k ...................................... 53 Experimental. -
Vanadate and Peroxovanadate Complexes of Biomedical Relevance – a Speciation Approach with Focus on Diabetes
Vanadate and Peroxovanadate Complexes of Biomedical Relevance – A speciation approach with focus on diabetes András Gorzsás Department of Chemistry Inorganic Chemistry Umeå University Umeå, Sweden Akademisk avhandling som med tillstånd av rektorsämbetet vid Umeå Universitet för erhållande av Filosofie Doktorsexamen framlägges till offentlig granskning vid Kemiska institutionen, sal KB3A9, KBC–huset, fredagen den 22 april 2005, kl 13.00. Fakultetsopponent: Professor Carlos F. G. C. Geraldes, Department of Biochemistry, Faculty of Science and Technology, University of Coimbra, P. O. Box 3126, P – 3001 – 401 Coimbra, Portugal i TITLE Vanadate and Peroxovanadate Complexes of Biomedical Relevance – A speciation approach with focus on diabetes AUTHOR András Gorzsás ADDRESS Department of Chemistry, Inorganic Chemistry, Umeå University, SE – 901 87 Umeå, Sweden ABSTRACT Diabetes mellitus is one of the most threatening epidemics of modern times with rapidly increasing incidence. Vanadium and peroxovanadium compounds have been shown to exert insulin–like actions and, in contrast to insulin, are orally applicable. However, problems with side–effects and toxicity remain. The exact mechanism(s) by which these compounds act are not yet fully known. Thus, a better understanding of the aqueous chemistry of vanadates and peroxovanadates in the presence of various (bio)ligands is needed. The present thesis summarises six papers dealing mainly with aqueous speciation in different vanadate – and peroxovanadate – ligand systems of biological and medical relevance. Altogether, five ligands have been studied, including important blood constituents (lactate, citrate and phosphate), a potential drug candidate (picolinic acid), and a dipeptide (alanyl serine) to model the interaction of (peroxo)vanadate in the active site of enzymes. Since all five ligands have been studied both with vanadates and peroxovanadates, the number of systems described in the present work is eleven, including the vanadate – citrate – lactate mixed ligand system. -
UNITED STATES PATENT OFFICE. RAFAEL CAL VET, O F BAR, CEL on A, SPAIN
UNITED STATES PATENT OFFICE. RAFAEL CAL VET, o F BAR, CEL ON A, SPAIN. VANUFACTURE OF PRIMARY EXPLOSIVES, 1,189,238. Specification of Letters Patent. Patented July 4, 1916. No Drawing. Application filed June 6, 1913. Serial No. 772,097. To all whom it may concern: Be it known that I, Dr. RAFAEL CALVET, a pounds have an acid reaction and can con subject of the King of Spain, residing at Sequently be combined with metals, and so 45 No. 34 calle de Gerona, Barcelona, Spain, form definite and permanent bodies which have invented certain new and useful Im might, like the thiocyanate compounds from provements in and Relating to the Manu which they are derived, be used for the facture of Primary Explosives, of which the preparation of the improved primary explo following is a specification. sive which forms the subject matter of the 50 This invention relates to a primary ex present patent application. 0 plosive and its manufacture, the object be The compounds in question are the fol ing to produce a substance capable of re lowing: perthiocyanic acid or hydrogen per placing fulminate of mercury and the other . thiocyanate (S.C.N.H.) and its salts, par usual detonating compounds. ticularly copper perthiocyanate (SCN,Cu) 55 The improved product consists of a mix and lead perthiocyanate (SCNPb) fur. 5 ture of a thiocyanate compound or of a sub ther dithiocyanic acid or hydrogen dithio stance derived therefrom with potassium. cyanate (S.C.N.H.) and its salts, copper chlorate or potassium perchlorate. diothiocyanate (SCN,Cu) and diothiocy It has previously been proposed to utilize anate of lead (S.C.N.Pb) and finally Woh 60 certain sulfocyanids or salts of the sulfocy ler's thiocyanic compound (“pseudo sul 20 anic acid SCNH, for the above said purpose. -
APA STANDARD 87-1 Contents 1
APA STANDARD 87-1 Contents 1. INTRODUCTION..............................................................................................1 2. DEFINITIONS.....................................................................................................1 3. REQUIREMENTS FOR CONSUMER FIREWORKS, NOVELTIES AND THEATRICAL PYROTECHNICS .....................................................................4 3.1 Types of Consumer Fireworks.......................................................................5 3.2 Types of Novelties .........................................................................................8 3.4 Other Devices ................................................................................................9 3.6 Specific Requirements for Consumer Fireworks...........................................10 3.7 Prohibited Chemicals and Components.........................................................12 3.8 Requirements for Theatrical Pyrotechnics ....................................................13 3.9 Approval ........................................................................................................13 3.10 Marking and Labeling..................................................................................14 4. REQUIREMENTS FOR DISPLAY FIREWORKS DEVICES ..........................14 4.1 Types of Display Fireworks Devices.............................................................14 4.2 Construction of Aerial Shells.........................................................................15 4.3 Approval -
The First Chemical Achievements and Publications by Justus Von Liebig
MICROREVIEW The First Chemical Achievements and Publications by Justus von Liebig 1803؊1873) on Metal Fulminates and Some Further Developments in Metal) Fulminates and Related Areas of Chemistry[‡] Wolfgang Beck[a] Dedicated to Professor Wolfgang Steglich on the occasion of his 70th birthday for his great friendship, collaboration and support[‡‡] Keywords: Liebig / Fulminates / Silver / Structure elucidation The first chemical investigations and publications by Justus by Liebig. Later, explosive (fulminato)metal complexes were von Liebig dealt with the fulminates of silver and mercury. prepared by Nef, Wieland, and especially by Lothar Wöhler Even as a boy Liebig had learnt how to prepare silver fulmi- and co-workers. In Munich the HCNO structure of fulminic nate, and as student of chemistry in Erlangen (1821) he stud- acid was established by its IR spectrum and the spectroscopic ied the properties and reactions of silver fulminate. In Paris in properties of (fulminato)metal complexes were studied. A se- 1823 (together with Gay-Lussac) he succeeded in analyzing ries of new nonexplosive complexes could be obtained by quantitatively the highly explosive silver compound. This dilution of the energy-rich species with large cations or li- great experimental success with the dangerous silver fulmi- gands. Recent X-ray structure determinations have revealed nate was most important in three respects: i. The develop- the almost perfect linear, tetrahedral, square-planar, or octa- ment of the experimental method later culminated in Liebig’s hedral structures of these complexes with linear − 2− perfected and well-known C,H,N analysis of organic com- metal−CϵNO bonds, e.g. [Au(CNO)2] , [Zn(CNO)4] , 2− 3− pounds (1830). -
H. Kü PPERS, H.-H. Eulert, K.-F. Hesse, W. Kalz, and H. Hom BORG
Band 41 b Zeitschrift für Naturforschung 1986 Contents Contents of Number 1 Synthesis and Crystal Structure of Di[bis(triphenyl- phosphine)iminium]-biscyanophthalocyaninato- Original Communications ferrate(II)-dichloromethane H. K ü p p e r s , H.-H. E u l e r t , K.-F. H e s s e , The Chloro Rhodates(III) [RhCl6]3- and W. K a l z , and H . H om bo rg 44 [RhCl 5(H20)]2_. Crystal Structure of AsPh 4[W (0)Cl3(HN3S2)]; Synthesis, IR Spectrum (NH4)3RhCl 6 • H20 (In German) and Crystal Structure (In German) U. T r e ib e r , M. Z w i l l in g , E. S c h w e d a , and E. C o n r a d i , H . W a d l e , U. M ü l l e r , and K. D e h - J. S tr ä h le 1 n ic k e 48 Synthesis and Crystal Structure of Bis[l,5-ditolyl- Synthesis and Structure of N-Thiobis-N'-(phenylsul- pentaazadienido-silver(I)] and Bis[l,3-diphenyl- fonyl)sulfurdiimide (In German) triazenido-silver (I)] (In German) H . W . R o e s k y , J. S u n d e r m e y e r , M . N o l t e m e y e r , J. B eck and J. S t r ä h l e 4 G. M . S h e l d r ic k , K. M e y e r -B ä s e , and P. G.