POTASSIUM PERIODATE
Bio-Strategy Pty Ltd Chemwatch Hazard Alert Code: 3 Chemwatch: 21874 Issue Date: 27/06/2017 Version No: 4.1.1.1 Print Date: 16/08/2017 Safety Data Sheet according to WHS and ADG requirements S.GHS.AUS.EN.RISK
SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING
Product Identifier
Product name POTASSIUM PERIODATE Chemical Name potassium periodate Synonyms K-I-O4, potassium tetroxoiodate, potassium meta-periodate, potassium periodate meta, periodic acid, potassium salt Proper shipping name OXIDISING SOLID, N.O.S. (contains potassium periodate) Chemical formula HIO4.K Other means of Not Available identification CAS number 7790-21-8
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses In analysis and as an oxidising agent.
Details of the supplier of the safety data sheet
Registered company name Bio-Strategy Pty Ltd Address Unit 1A/60 Enterprise Place QLD 4173 Australia Telephone 1300 727 696 Fax Not Available Website www.bio-strategy.com.au Email [email protected]
Emergency telephone number
Association / Organisation Not Available Emergency telephone 07 3009 4188 numbers Other emergency telephone Not Available numbers
SECTION 2 HAZARDS IDENTIFICATION
Classification of the substance or mixture
HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
Poisons Schedule Not Applicable Oxidizing Solid Category 2, Acute Toxicity (Inhalation) Category 3, Skin Corrosion/Irritation Category 2, Eye Irritation Category 2A, Specific target organ toxicity - single exposure Category 3 (respiratory tract irritation) Classification [1] *LIMITED EVIDENCE
Legend: 1. Classified by Chemwatch; 2. Classification drawn from HSIS ; 3. Classification drawn from EC Directive 1272/2008 - Annex VI
Label elements
Hazard pictogram(s)
SIGNAL WORD DANGER
Hazard statement(s)
H272 May intensify fire; oxidiser.
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H331 Toxic if inhaled. H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation.
*LIMITED EVIDENCE
Supplementary statement(s) Not Applicable
Precautionary statement(s) Prevention
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. P221 Take any precaution to avoid mixing with combustibles/organic material. P271 Use only outdoors or in a well-ventilated area. P220 Keep/Store away from clothing/organic material/combustible materials.
Precautionary statement(s) Response
P362 Take off contaminated clothing and wash before reuse. P370+P378 In case of fire: Use water jets for extinction. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Precautionary statement(s) Storage
P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up.
Precautionary statement(s) Disposal
P501 Dispose of contents/container in accordance with local regulations.
SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS
Substances
CAS No %[weight] Name 7790-21-8 >98.5 potassium periodate
Mixtures See section above for composition of Substances
SECTION 4 FIRST AID MEASURES
Description of first aid measures
Eye Contact Skin Contact Inhalation Ingestion
Indication of any immediate medical attention and special treatment needed
SECTION 5 FIREFIGHTING MEASURES
Extinguishing media
Special hazards arising from the substrate or mixture
Fire Incompatibility
Advice for firefighters
Fire Fighting Fire/Explosion Hazard HAZCHEM 1Y
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures See section 8
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Environmental precautions See section 12
Methods and material for containment and cleaning up
Minor Spills Major Spills
Personal Protective Equipment advice is contained in Section 8 of the SDS.
SECTION 7 HANDLING AND STORAGE
Precautions for safe handling
Safe handling Other information
Conditions for safe storage, including any incompatibilities
Suitable container Storage incompatibility Avoid reaction with strong reducing agents, organic compounds, ammonium perchlorate, hydrides and finely divided aluminium or magnesium metal.
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Control parameters
OCCUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Not Available EMERGENCY LIMITS Ingredient Material name TEEL-1 TEEL-2 TEEL-3 potassium periodate Potassium periodate 1.2 mg/m3 13 mg/m3 79 mg/m3
Ingredient Original IDLH Revised IDLH potassium periodate Not Available Not Available
Exposure controls
Appropriate engineering controls
Personal protection
Eye and face protection Skin protection See Hand protection below Hands/feet protection Body protection See Other protection below Other protection Thermal hazards Not Available
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Colourless crystals or white granular crystalline powder. No odour is present.|Solubility in water: 0.42g per 100g of water @ 20 C. Very slightly soluble in Appearance potassium hydroxide.
Physical state Divided Solid Relative density (Water = 1) 3.62 Partition coefficient Odour Not Available Not Available n-octanol / water Auto-ignition temperature Odour threshold Not Available Not available. (°C) Decomposition pH (as supplied) Not Applicable Not Available temperature Melting point / freezing 582 (decomposes) Viscosity (cSt) Not Applicable point (°C) Initial boiling point and Not available. Molecular weight (g/mol) 230 boiling range (°C) Flash point (°C) Not Applicable Taste Not Available
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Evaporation rate Not Applicable Explosive properties Not Available Flammability Not Applicable Oxidising properties Not Available Surface Tension (dyn/cm or Upper Explosive Limit (%) Not available. Not Applicable mN/m) Lower Explosive Limit (%) Not available. Volatile Component (%vol) Negligible Vapour pressure (kPa) Negligible Gas group Not Available Solubility in water (g/L) Immiscible pH as a solution (1%) 4.9 - 5.3 (0.5%) Vapour density (Air = 1) Not Applicable VOC g/L Not Available
SECTION 10 STABILITY AND REACTIVITY
Reactivity See section 7 Chemical stability Possibility of hazardous See section 7 reactions Conditions to avoid See section 7 Incompatible materials See section 7 Hazardous decomposition See section 5 products
SECTION 11 TOXICOLOGICAL INFORMATION
Information on toxicological effects
Inhaled Ingestion Ingestion may cause gastro-intestinal upset with abdominal pain, vomiting, diarrhoea. Test animals exhibit kidney and blood cell damage. Skin Contact Eye Chronic Chronic symptoms of exposure are kidney dysfunction or failure, blood conditions such as haemolysis and the central nervous system may also be affected.
TOXICITY IRRITATION potassium periodate Not Available Not Available
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS - Register of Toxic Effect of chemical Substances
Asthma-like symptoms may continue for months or even years after exposure to the material ends. This may be due to a non-allergic condition known as reactive airways dysfunction syndrome (RADS) which can occur after exposure to high levels of highly irritating compound. Main criteria for diagnosing RADS include the absence of previous airways disease in a non-atopic individual, with sudden onset of persistent asthma-like symptoms within minutes to hours of a POTASSIUM PERIODATE documented exposure to the irritant. Other criteria for diagnosis of RADS include a reversible airflow pattern on lung function tests, moderate to severe bronchial hyperreactivity on methacholine challenge testing, and the lack of minimal lymphocytic inflammation, without eosinophilia. Not available.
Acute Toxicity Carcinogenicity Skin Irritation/Corrosion Reproductivity Serious Eye STOT - Single Exposure Damage/Irritation Respiratory or Skin STOT - Repeated Exposure sensitisation Mutagenicity Aspiration Hazard Legend: – Data available but does not fill the criteria for classification – Data available to make classification – Data Not Available to make classification
SECTION 12 ECOLOGICAL INFORMATION
Toxicity
ENDPOINT TEST DURATION (HR) SPECIES VALUE SOURCE potassium periodate Not Not Not Not Available Not Available Available Available Available
Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data
Persistence and degradability
Ingredient Persistence: Water/Soil Persistence: Air
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No Data available for all ingredients No Data available for all ingredients
Bioaccumulative potential
Ingredient Bioaccumulation No Data available for all ingredients
Mobility in soil
Ingredient Mobility No Data available for all ingredients
SECTION 13 DISPOSAL CONSIDERATIONS
Waste treatment methods
Product / Packaging disposal
SECTION 14 TRANSPORT INFORMATION
Labels Required
Marine Pollutant NO HAZCHEM 1Y
Land transport (ADG)
UN number 1479 UN proper shipping name OXIDISING SOLID, N.O.S. (contains potassium periodate)
Class 5.1 Transport hazard class(es) Subrisk Not Applicable
Packing group II Environmental hazard Not Applicable
Special provisions 274 Special precautions for user Limited quantity 1 kg
Air transport (ICAO-IATA / DGR)
UN number 1479 UN proper shipping name Oxidizing solid, n.o.s. * (contains potassium periodate)
ICAO/IATA Class 5.1 Transport hazard class(es) ICAO / IATA Subrisk Not Applicable ERG Code 5L
Packing group II Environmental hazard Not Applicable
Special provisions A3 Cargo Only Packing Instructions 562 Cargo Only Maximum Qty / Pack 25 kg Special precautions for user Passenger and Cargo Packing Instructions 558 Passenger and Cargo Maximum Qty / Pack 5 kg Passenger and Cargo Limited Quantity Packing Instructions Y544 Passenger and Cargo Limited Maximum Qty / Pack 2.5 kg
Sea transport (IMDG-Code / GGVSee)
UN number 1479 UN proper shipping name OXIDIZING SOLID, N.O.S. (contains potassium periodate)
IMDG Class 5.1 Transport hazard class(es) IMDG Subrisk Not Applicable
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Packing group II Environmental hazard Not Applicable
EMS Number F-A , S-Q Special precautions for user Special provisions 274 900 Limited Quantities 1 kg
Transport in bulk according to Annex II of MARPOL and the IBC code Not Applicable
SECTION 15 REGULATORY INFORMATION
Safety, health and environmental regulations / legislation specific for the substance or mixture
POTASSIUM PERIODATE(7790-21-8) IS FOUND ON THE FOLLOWING REGULATORY LISTS Australia Inventory of Chemical Substances (AICS)
National Inventory Status Australia - AICS Y Canada - DSL Y Canada - NDSL N (potassium periodate) China - IECSC Y Europe - EINEC / ELINCS / Y NLP Japan - ENCS Y Korea - KECI Y New Zealand - NZIoC Y Philippines - PICCS Y USA - TSCA Y Y = All ingredients are on the inventory Legend: N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets)
SECTION 16 OTHER INFORMATION
Other information Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered.
Definitions and abbreviations PC－TWA: Permissible Concentration-Time Weighted Average PC－STEL: Permissible Concentration-Short Term Exposure Limit IARC: International Agency for Research on Cancer ACGIH: American Conference of Governmental Industrial Hygienists STEL: Short Term Exposure Limit TEEL: Temporary Emergency Exposure Limit。 IDLH: Immediately Dangerous to Life or Health Concentrations OSF: Odour Safety Factor NOAEL :No Observed Adverse Effect Level LOAEL: Lowest Observed Adverse Effect Level TLV: Threshold Limit Value LOD: Limit Of Detection OTV: Odour Threshold Value BCF: BioConcentration Factors BEI: Biological Exposure Index
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end of SDS